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Utilization of Basalt Saw Mud as a Spherical Porous Functional Aggregate for the Preparation of Ordinary Structure Concrete 被引量:1
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作者 周永祥 关青锋 +2 位作者 LENG Faguang WANG Jing LI Tianjun 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期364-375,共12页
To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs)... To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural concrete.In our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and 0.33.The effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were analyzed.The experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 MPa.Low W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs concrete.Through the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of concrete.SPFAs exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete. 展开更多
关键词 lightweight concrete civil concrete building basalt saw mud fly ash internal curing environmentally friendly
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Mechanism study of Cu(Ⅱ) adsorption from acidic wastewater by ultrasonic-modified municipal solid waste incineration fly ash
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作者 Shunda lin Yang Lu +3 位作者 Lin Zheng Ling Long Xuguang Jiang Jianhua Yan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期157-165,共9页
High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(M... High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(MSWI) fly ash for Cu(Ⅱ) adsorption to achieve the purpose of “treating waste by waste.” The effects of p H, adsorption time, initial concentration, and temperature on the modified MSWI fly ash’s adsorption efficiency were systematically studied in this article. The adsorption performance of the modified MSWI fly ash can be enhanced by the ultrasonic modification. At pH = 2, 3 and 4, the adsorption capacity of the modified MSWI fly ash for Cu(Ⅱ) increased by 2.7, 1.9 and 1.2 times, respectively. Furthermore, it was suggested that the adsorption process of the modified MSWI fly ash can be better simulated by the pseudo-second-order kinetic model, with a maximum adsorption capacity calculated by the Langmuir model of 24.196 mg.g-1. Additionally, the adsorption process is spontaneous,endothermic, and chemisorption-dominated from the thermodynamic studies(ΔH and ΔS > 0, ΔG < 0).Finally, the enhanced adsorption performance of the modified MSWI fly ash for Cu(Ⅱ) may be attributed to electrostatic interaction and chelation effects. 展开更多
关键词 ULTRASOUND MSWI fly ash Cu(Ⅱ) WASTEWATER ADSORPTION
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Effect of Na_(2)CO_(3)Roasting Activation on Acid Leaching Property of Fly Ash
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作者 LIU Chenjia ZHAO Aichun +4 位作者 YE Xin ZHAO Zi ZHANG Tingan YANG Xiaorong QIN Yanmei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1613-1620,共8页
By using high-alumina fly ash as raw material,a process was proposed for activating the fly ash with Na_(2)CO_(3)calcination and extracting aluminum from activated clinker with sulfuric acid leaching.The feasibility o... By using high-alumina fly ash as raw material,a process was proposed for activating the fly ash with Na_(2)CO_(3)calcination and extracting aluminum from activated clinker with sulfuric acid leaching.The feasibility of roasting process of activated fly ash by Na_(2)CO_(3)was discussed based on thermodynamic analysis.The experimental results showed that Na_(2)CO_(3)gradually reactes with mullite over 700 K to produce NaAlSiO_(4).The optimal process conditions for the activation stage are:a material ratio of 1:1 between sodium carbonate and fly ash,a calcination temperature of 900℃,and a calcination time of 2.5 hours.Under these conditions,the leaching rate of aluminum is 90.3%.By comparing the SEM and XRD analysis of raw and clinker materials,it could be concluded that the mullite phase of fly ash is almost completely destroyed and transformed into sodium aluminosilicate with good acid solubility. 展开更多
关键词 fly ash calcination activation acid leaching ALUMINUM
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Solvothermal synthesis and adsorption performance of layered boehmite using aluminum chloride and high-alumina fly ash
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作者 Jing Wen Ruirui Yuan +2 位作者 Tao Jiang Tangxia Yu Yufan Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第6期280-290,共11页
High alumina fly ash(FAHAl)is a kind of bulk solid waste unique to China,whose availability of high-value aluminum and the threat to the environment makes its high-value utilization urgent.In this work,the alumina con... High alumina fly ash(FAHAl)is a kind of bulk solid waste unique to China,whose availability of high-value aluminum and the threat to the environment makes its high-value utilization urgent.In this work,the alumina containing leaching solution obtained from Na_(2)CO_(3) roasting and HCl leaching of FAHAl was used as the mother liquor to prepare layered boehmite in situ.The preparation process with AlCl_(3) as the raw material was also compared.The formation process and mechanism of boehmite,the choice of solvent,along with the adsorption capability of Congo red were analyzed by X-ray diffraction,scanning electron microscopy,Fourier transform infrared spectroscopy,Brunauer-Emmett-Teller method and adsorption experiments.Results showed that during the preparation of layered boehmite,the precursor Al(OH)_(3) from the reaction of Al^(3+) and OH-is transformed into boehmiteγ-AlOOH.The existence of ethanol is beneficial to regulate and promote the growth of boehmite crystal effectively.When water and ethanol are mixed with a volume ratio of 2:1 and used as the solvent,the maximum specific surface area of the boehmite is obtained at 135.7 m^(2)·g^(-1),and 99.16%of Congo red can be absorbed after 10 min when AlCl3 is used as a raw material.As purified leaching solution is used as the mother liquid,the crystallinity of boehmite decreases slightly when the pH value decreases from 12.5 to 11.When pH is 11,the removal efficiency of Congo red reaches a maximum of 72.25%.This process not only achieves the extraction of aluminum and high-value utilization of FAHAl but also provides a thought to prepare layered boehmite with adsorption properties. 展开更多
关键词 High-alumina fly ash Layered boehmite In-situ preparation Solvothermal synthesis Adsorption High-value utilization
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Effect of Partial Replacement of Fly Ash by Decoration Waste Powder on the Fresh and Mechanical Properties of Geopolymer Masonry Mortar
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作者 刘惠 ZHANG Ruidong +2 位作者 朱平华 WANG Xinjie CHEN Chunhong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期698-704,共7页
This study aims to investigate the feasibility of using decoration waste powder(DWP)as a partial replacement for fly ash(FA)in the preparation of geopolymer masonry mortar,and to examine the effect of different DWP re... This study aims to investigate the feasibility of using decoration waste powder(DWP)as a partial replacement for fly ash(FA)in the preparation of geopolymer masonry mortar,and to examine the effect of different DWP replacement rates(0%-40%)on the fresh and mechanical properties of the mortar.The results showed that each group of geopolymer masonry mortar exhibited excellent water retention performance,with a water retention rate of 100%,which was due to the unique geopolymer mortar system and high viscosity of the alkaline activator solution.Compared to the control group,the flowability of the mortar containing lower contents of DWP(10%and 20%)was higher.However,as the DWP replacement rate further increased,the flowability gradually decreased.The DWP could absorb the free water in the reaction system of geopolymer mortar,thereby limiting the occurrence of geopolymerization reaction.The incorporation of DWP in the mortar resulted in a decrease in compressive strength compared to the mortar without DWP.However,even at a replacement rate of 40%,the compressive strength of the mortar still exceeded 15 MPa,which met the requirements of the masonry mortar.It was feasible to use DWP in the geopolymer masonry mortar.Although the addition of DWP caused some performance loss,it did not affect its usability. 展开更多
关键词 fly ash-based geopolymer decoration waste powder masonry mortar WORKABILITY compressive strength
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Long-Term Performance and Microstructural Characterization of Dam Concrete in the Three Gorges Project
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作者 Chen Lyu Cheng Yu +3 位作者 Chao Lu Li Pan Wenwei Li Jiaping Liu 《Engineering》 SCIE EI CAS CSCD 2024年第2期237-262,共26页
This study investigates the long-term performance of laboratory dam concrete in different curing environments over ten years and the microstructure of 17-year-old laboratory concrete and actual concrete cores drilled ... This study investigates the long-term performance of laboratory dam concrete in different curing environments over ten years and the microstructure of 17-year-old laboratory concrete and actual concrete cores drilled from the Three Gorges Dam.The mechanical properties of the laboratory dam concrete,whether cured in natural or standard environments,continued to improve over time.Furthermore,the laboratory dam concrete exhibited good resistance to diffusion and a refined microstructure after 17 years.However,curing and long-term exposure to the local natural environment reduced the frost resistance.Microstructural analyses of the laboratory concrete samples demonstrated that moderate-heat cement and fine fly ash(FA)particles were almost fully hydrated to form compact micro structures consisting of large quantities of homogeneous calcium(alumino)silicate hydrate(C-(A)-S-H)gels and a few crystals.No obvious interfacial transition zones were observed in the microstructure owing to the longterm pozzolanic reaction.This dense and homogenous microstructure was the crucial reason for the excellent long-term performance of the dam concrete.A high FA volume also played a significant role in the microstructural densification and performance growth of dam concrete at a later age.The concrete drilled from the dam surface exhibited a loose microstructure with higher microporosity,indicating that concrete directly exposed to the actual service environment suffered degradation caused by water and wind attacks.In this study,both macro-performance and microstructural analyses revealed that the application of moderate-heat cement and FA resulted in a dense and homogenous microstructure,which ensured the excellent long-term performance of concrete from the Three Gorges Dam after 17 years.Long-term exposure to an actual service environment may lead to microstructural degradation of the concrete surface.Therefore,the retained long-term dam concrete samples need to be further researched to better understand its microstructural evolution and development of its properties. 展开更多
关键词 Three Gorges Dam Long-term performance Microstructural analysis Moderate-heat cement Fly ash
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Tensile Strain Capacity Prediction of Engineered Cementitious Composites (ECC) Using Soft Computing Techniques
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作者 Rabar H.Faraj Hemn Unis Ahmed +2 位作者 Hardi Saadullah Fathullah Alan Saeed Abdulrahman Farid Abed 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期2925-2954,共30页
Plain concrete is strong in compression but brittle in tension,having a low tensile strain capacity that can significantly degrade the long-term performance of concrete structures,even when steel reinforcing is presen... Plain concrete is strong in compression but brittle in tension,having a low tensile strain capacity that can significantly degrade the long-term performance of concrete structures,even when steel reinforcing is present.In order to address these challenges,short polymer fibers are randomly dispersed in a cement-based matrix to forma highly ductile engineered cementitious composite(ECC).Thismaterial exhibits high ductility under tensile forces,with its tensile strain being several hundred times greater than conventional concrete.Since concrete is inherently weak in tension,the tensile strain capacity(TSC)has become one of the most extensively researched properties.As a result,developing a model to predict the TSC of the ECC and to optimize the mixture proportions becomes challenging.Meanwhile,the effort required for laboratory trial batches to determine the TSC is reduced.To achieve the research objectives,five distinct models,artificial neural network(ANN),nonlinear model(NLR),linear relationship model(LR),multi-logistic model(MLR),and M5P-tree model(M5P),are investigated and employed to predict the TSCof ECCmixtures containing fly ash.Data from115 mixtures are gathered and analyzed to develop a new model.The input variables include mixture proportions,fiber length and diameter,and the time required for curing the various mixtures.The model’s effectiveness is evaluated and verified based on statistical parameters such as R2,mean absolute error(MAE),scatter index(SI),root mean squared error(RMSE),and objective function(OBJ)value.Consequently,the ANN model outperforms the others in predicting the TSC of the ECC,with RMSE,MAE,OBJ,SI,and R2 values of 0.42%,0.3%,0.33%,0.135%,and 0.98,respectively. 展开更多
关键词 Engineered cementitious composites fly ash curing time tensile strain capacity MODELING
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Barley chitinase genes expression revamp resistance against whitefly (Bemisia Tabaci) in transgenic cotton (Gossypium hirsutum L.)
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作者 BASHIR Samina YAQOOB Amina +7 位作者 BASHIR Rohina BUKHARI Shanila SHAHID Naila AZAM Saira BAKHSH Allah HUSNAIN Tayyab SHAHID Ahmad Ali RAO Abdul Qayyum 《Journal of Cotton Research》 CAS 2024年第1期90-100,共11页
Background Chitinase is an enzyme that hydrolyzes chitin,a major component of the exoskeleton of insects,including plant pests like whiteflies.The present study aimed to investigate the expression of chemically synthe... Background Chitinase is an enzyme that hydrolyzes chitin,a major component of the exoskeleton of insects,including plant pests like whiteflies.The present study aimed to investigate the expression of chemically synthesized barley ch1 and chi2 genes in cotton(Gossypium hirsutum)through Agrobacterium-mediated transformation.Fifty-five putative transgenic cotton plants were obtained,out of which fifteen plants successfully survived and were shifted to the field.Using gene-specific primers,amplification of 447 bp and 401 bp fragments confirmed the presence of the ch1 and chi2 genes in five transgenic cotton plants of the T0 generation.These five plants were further evalu-ated for their mRNA expression levels.The T0 transgenic cotton plants with the highest mRNA expression level and better yield performance in field,were selected to raise their subsequent progenies.Results The T1 cotton plants showed the highest mRNA expression levels of 3.5-fold in P10(2)for the ch1 gene and 3.7-fold in P2(1)for the chi2 gene.Fluorescent in situ hybridization(FISH)confirmed a single copy number of ch1 and chi2(hemizygous)on chromosome no.6.Furthermore,the efficacy of transgenes on whitefly was evaluated through an insect bioassay,where after 96 h of infestation,mortality rates of whitefly were calculated to be 78%–80%in transgenic cotton plants.The number of eggs on transgenic cotton plants were calculated to be 0.1%–0.12 per plant compared with the non-transgenic plants where egg number was calculated to be 0.90–1.00 per plant.Conclusion Based on these findings,it can be concluded that the chemically synthesized barley chitinase genes(ch1 and chi2)have the potential to be effective against insects with chitin exoskeletons,including whiteflies.The transgenic cotton plants expressing these genes showed increased resistance to whiteflies,resulting in reduced egg numbers and higher mortality rates. 展开更多
关键词 CHITINASE Cotton White fly TRANSGENE BIOASSAY
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A mini review on the separation of Al,Fe and Ti elements from coal fly ash leachate
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作者 Yuan Shi Fengqi Jiang +3 位作者 Rongjiao Wang Sasha Yang Xiaofeng Zhu Yingying Shen 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期1-15,共15页
The electricity demand is increasing rapidly with the development of society and technology.Coal-fired thermal power plants have become one of the primary sources of electricity generation for urbanization.However,coa... The electricity demand is increasing rapidly with the development of society and technology.Coal-fired thermal power plants have become one of the primary sources of electricity generation for urbanization.However,coal-fired thermal power plants produce a great amount of by-product coal fly ash every year.Coal fly ash disposal in landfills requires a sizable space and has negative environmental impacts.Therefore,it is crucial to develop new technologies and methods to utilize this enormous volume of solid waste in order to protect the environment.In this review,the fundamental physical and chemical character-istics of coal fly ash are introduced,and afterward the disposal policies and utilization ways of coal fly ash are discussed to gain a comprehensive understanding of the various ways this waste.The leaching of valuable metals in coal fly ash and the extraction of metal elements in leachate under different conditions are also summarized.Furthermore,the possibility of coal fly ash to serve as a supplementary source for mineral resources is analyzed,providing a basis for its extensive use as a raw material in the metal industry in China and worldwide. 展开更多
关键词 Coal fly ash Waste utilization Metals extraction
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Synergistic CO_(2) mineralization using coal fly ash and red mud as a composite system
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作者 Zhenchao Yao Yugao Wang +3 位作者 Jun Shen Yanxia Niu Jiang Feng Yang Xianyong Wei 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期149-158,共10页
CO_(2) mineralization plays a critical role in the storage and utilization of CO_(2).Coal fly ash(CFA)and red mud(RM)are widely utilized as CO_(2) mineralizers.However,the inert calcium species in CFA limit its carbon... CO_(2) mineralization plays a critical role in the storage and utilization of CO_(2).Coal fly ash(CFA)and red mud(RM)are widely utilized as CO_(2) mineralizers.However,the inert calcium species in CFA limit its carbonation capacity,meanwhile the substantial Ca^(2+)releasing of RM is hindered by a covering layer of calcium carbonate.In this study,CO_(2) mineralization in a composite system of CFA and RM was investigated to enhance the carbonation capacity.Multiple analyzers were employed to characterize the raw materials and resulting mineralization products.The results demonstrated that a synergistic effect existed in the composite system of CFA and RM,resulting in improving CO_(2) mineralization rate and efficiency.The produced calcium carbonate was ectopically attached the surface of CFA in the composite system,thus slowing down its coverage on the surface of RM.This phenomenon facilitated further releasing Ca^(2+)from the internal RM,thereby enhancing CO_(2) mineralization efficiency.Meanwhile,the inclusion of RM significantly improved the alkalinity of the composite system,which not only promoted the dissolution of Ca^(2+)of the inert CaSO_(4)(H_(2)O)_(2) in CFA,but also accelerated CO_(2) mineralization rate.The investigation would be beneficial to CO_(2) mineralization using industrial solid wastes. 展开更多
关键词 CO_(2)mineralization Coal fly ash Red mud Synergistic effect
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Experimental study on the activation of coal gasification fly ash from industrial CFB gasifiers
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作者 Qiyao Yang Xiaobin Qi +1 位作者 Qinggang Lyu Zhiping Zhu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期8-18,共11页
Coal gasification fly ash(CGFA)is an industrial solid waste from the coal circulating fluidized bed(CFB)gasification process,and it needs to be effectively disposed to achieve sustainable development of the environmen... Coal gasification fly ash(CGFA)is an industrial solid waste from the coal circulating fluidized bed(CFB)gasification process,and it needs to be effectively disposed to achieve sustainable development of the environment.To realize the application of CGFA as a precursor of porous carbon materials,the physicochemical properties of three kinds of CGFA from industrial CFB gasifiers are analyzed.Then,the activation potential of CGFA is acquired via steam activation experiments in a tube furnace reactor.Finally,the fluidization activation technology of CGFA is practiced in a bench-scale CFB test rig,and its advantages are highlighted.The results show that CGFA is characterized by a high carbon content in the range of 54.06%–74.09%,an ultrafine particle size(d50:16.3–26.1 μm),and a relatively developed pore structure(specific surface area SSA:139.29–551.97 m^(2)·g^(-1)).The proportion of micropores in CGFA increases gradually with the coal rank.Steam activation experiments show that the pore development of CGFA mainly includes three stages:initial pore development,dynamic equilibrium between micropores and mesopores and pore collapse.The SSA of lignite fly ash(LFA),subbituminous fly ash(SBFA)and anthracite fly ash(AFA)is maximally increased by 105%,13%and 72%after steam activation;the order of the largest carbon reaction rate and decomposition ratio of steam among the three kinds of CGFA is SBFA>LFA>AFA.As the ratio of oxygen to carbon during the fluidization activation of LFA is from 0.09 to 0.19,the carbon conversion ratio increases from 14.4%to 26.8%and the cold gas efficiency increases from 6.8%to 10.2%.The SSA of LFA increases by up to 53.9%during the fluidization activation process,which is mainly due to the mesoporous development.Relative to steam activation in a tube furnace reactor,fluidization activation takes an extremely short time(seconds)to achieve the same activation effect.It is expected to further improve the activation effect of LFA by regulating the carbon conversion ratio range of 27%–35%to create pores in the initial development stage. 展开更多
关键词 Circulating fluidized bed Coal gasification fly ash Steam activation Pore structure evolution Fluidization activation
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Prediction of Geopolymer Concrete Compressive Strength Using Convolutional Neural Networks
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作者 Kolli Ramujee Pooja Sadula +4 位作者 Golla Madhu Sandeep Kautish Abdulaziz S.Almazyad Guojiang Xiong Ali Wagdy Mohamed 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第5期1455-1486,共32页
Geopolymer concrete emerges as a promising avenue for sustainable development and offers an effective solution to environmental problems.Its attributes as a non-toxic,low-carbon,and economical substitute for conventio... Geopolymer concrete emerges as a promising avenue for sustainable development and offers an effective solution to environmental problems.Its attributes as a non-toxic,low-carbon,and economical substitute for conventional cement concrete,coupled with its elevated compressive strength and reduced shrinkage properties,position it as a pivotal material for diverse applications spanning from architectural structures to transportation infrastructure.In this context,this study sets out the task of using machine learning(ML)algorithms to increase the accuracy and interpretability of predicting the compressive strength of geopolymer concrete in the civil engineering field.To achieve this goal,a new approach using convolutional neural networks(CNNs)has been adopted.This study focuses on creating a comprehensive dataset consisting of compositional and strength parameters of 162 geopolymer concrete mixes,all containing Class F fly ash.The selection of optimal input parameters is guided by two distinct criteria.The first criterion leverages insights garnered from previous research on the influence of individual features on compressive strength.The second criterion scrutinizes the impact of these features within the model’s predictive framework.Key to enhancing the CNN model’s performance is the meticulous determination of the optimal hyperparameters.Through a systematic trial-and-error process,the study ascertains the ideal number of epochs for data division and the optimal value of k for k-fold cross-validation—a technique vital to the model’s robustness.The model’s predictive prowess is rigorously assessed via a suite of performance metrics and comprehensive score analyses.Furthermore,the model’s adaptability is gauged by integrating a secondary dataset into its predictive framework,facilitating a comparative evaluation against conventional prediction methods.To unravel the intricacies of the CNN model’s learning trajectory,a loss plot is deployed to elucidate its learning rate.The study culminates in compelling findings that underscore the CNN model’s accurate prediction of geopolymer concrete compressive strength.To maximize the dataset’s potential,the application of bivariate plots unveils nuanced trends and interactions among variables,fortifying the consistency with earlier research.Evidenced by promising prediction accuracy,the study’s outcomes hold significant promise in guiding the development of innovative geopolymer concrete formulations,thereby reinforcing its role as an eco-conscious and robust construction material.The findings prove that the CNN model accurately estimated geopolymer concrete’s compressive strength.The results show that the prediction accuracy is promising and can be used for the development of new geopolymer concrete mixes.The outcomes not only underscore the significance of leveraging technology for sustainable construction practices but also pave the way for innovation and efficiency in the field of civil engineering. 展开更多
关键词 Class F fly ash compressive strength geopolymer concrete PREDICTION deep learning convolutional neural network
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Combined use of fly ash and silica to prevent the long-term strength retrogression of oil well cement set and cured at HPHT conditions
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作者 Guo-Dong Cheng Xue-Yu Pang +4 位作者 Jin-Sheng Sun Zheng-Song Qiu Chuang-Chuang Wang Jian-Kun Qin Ning Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1122-1134,共13页
The long-term strength retrogression of silica-enriched oil well cement poses a significant threat to wellbore integrity in deep and ultra-deep wells, which is a major obstacle for deep petroleum and geothermal energy... The long-term strength retrogression of silica-enriched oil well cement poses a significant threat to wellbore integrity in deep and ultra-deep wells, which is a major obstacle for deep petroleum and geothermal energy development. Previous attempts to address this problem has been unsatisfactory because they can only reduce the strength decline rate. This study presents a new solution to this problem by incorporating fly ash to the traditional silica-cement systems. The influences of fly ash and silica on the strength retrogression behavior of oil well cement systems directly set and cured under the condition of 200°C and 50 MPa are investigated. Test results indicate that the slurries containing only silica or fly ash experience severe strength retrogression from 2 to 30 d curing, while the slurries containing both fly ash and silica experience strength enhancement from 2 to 90 d. The strength test results are corroborated by further evidences from permeability tests as well as microstructure analysis of set cement. Composition of set cement evaluated by quantitative X-ray diffraction analyses with partial or no known crystal structure(PONKCS) method and thermogravimetry analyses revealed that the conversion of amorphous C-(A)-S-H to crystalline phases is the primary cause of long-term strength retrogression.The addition of fly ash can reduce the initial amount of C-(A)-S-H in the set cement, and its combined use with silica can prevent the crystallization of C-(A)-S-H, which is believed to be the working mechanism of this new admixture in improving long-term strength stability of oil well cement systems. 展开更多
关键词 Fly ash Long-term strength retrogression High temperature Quantitative X-ray diffraction(QXRD) Partial or no known crystal structure(PONKCS)
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One new species in the genus Elaphropeza(Diptera:Empididae)from Chongqing,China
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作者 Renhui WU Chunmin ZHANG +1 位作者 Naizhong CHEN Ding YANG 《Entomotaxonomia》 CSCD 2024年第3期241-244,共4页
Elaphropeza is distributed worldwide with over 220 known species,of which 61 species were known to occur in China.Two species of Elaphropeza are reported from Chongqing for the first time.One species,Elaphropeza chong... Elaphropeza is distributed worldwide with over 220 known species,of which 61 species were known to occur in China.Two species of Elaphropeza are reported from Chongqing for the first time.One species,Elaphropeza chongqingana sp.nov.,is described as new to science.A key to the species of Elaphropeza from Chongqing is presented. 展开更多
关键词 dance fly taxonomy key
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Study on Fly Ash Based Porous Ceramsite as Biological Filter Media
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作者 Ruigang WANG Shuo WANG +1 位作者 Weijie LI Hailong LIU 《Agricultural Biotechnology》 2024年第1期71-73,共3页
Using fly ash as a raw material,porous ceramic particles with an apparent density of 1.21 g/cm^(3),a visible porosity of 51.03%,and a specific surface area of 4.26 m^(2)/g were prepared and used as biofilter materials... Using fly ash as a raw material,porous ceramic particles with an apparent density of 1.21 g/cm^(3),a visible porosity of 51.03%,and a specific surface area of 4.26 m^(2)/g were prepared and used as biofilter materials for wastewater treatment.Through SEM,XRD analysis,and heavy metal leaching analysis,it was found that porous ceramsite were porous materials with rough surfaces.After calcination,the newly formed mineral was silicate calcium feldspar.The heavy metal concentration in the leaching solution of porous ceramsite met the national surface water quality requirements.The treatment of domestic sewage showed that the volumetric loads of COD Cr,NH_(4)^(+)-N,and TN removed by the aerated biofilter were 5.23,0.98,and 0.35 kg/(m^(3)·d),respectively,with removal rates of 85.46%,96.13%,and 32.31%. 展开更多
关键词 Porous ceramsite Domestic sewage Fly ash
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Development of a New Polymercement Waterproofing Screed with Secondary Materials
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作者 LubošTaranza 《Journal of Civil Engineering and Architecture》 2024年第2期80-85,共6页
Throughout the world the issue of waste raw materials is still a very important topic.This paper is focused on the possibility of the use of waste raw material originated at high temperatures by the combustion of blac... Throughout the world the issue of waste raw materials is still a very important topic.This paper is focused on the possibility of the use of waste raw material originated at high temperatures by the combustion of black coal as a partial substitution of filler component during the development of new waterproof levelling material designated for concrete constructions.The use of the fly-ash as partial substitution of the filler component has important ecological and economic contribution. 展开更多
关键词 Fly ash SCREED FILLER CONCRETE
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Behavior of Fly Ash at Different Mix Ratios with Plastic Recycled Polymers
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作者 Tushar Vasant Salunkhe 《Journal of Civil Engineering and Architecture》 2024年第9期438-444,共7页
Fly ash is a waste produced from burning of coals in thermal power stations. The staggering increase in the production of fly ash and its disposal in an environment friendly manner is increasingly becoming a matter of... Fly ash is a waste produced from burning of coals in thermal power stations. The staggering increase in the production of fly ash and its disposal in an environment friendly manner is increasingly becoming a matter of global concern. Many efforts have been made to use the fly ash in various geotechnical applications viz. embankment, roadway, railway, backfill material. In this study, PRPs (plastic recycled polymers) were mixed with fly ash at different mix ratios so as to inspect its influence on the geotechnical properties of fly ash. In this regard, the laboratory study includes Atterberg limits, compaction characteristics, unconfined compressive strength, direct shear test, Triaxial shear test and X-ray fluorescence test. Tests were carried out on only fly ash and treated fly ash with PRPs. Results indicate increase in MDD (maximum dry density) and also in shear parameters of the fly ash with inclusion of PRPs. 展开更多
关键词 Fly ash PRPs X-ray fluorescence shear parameters
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On the Range of Action of Adult Culex pipiens s.l.
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作者 Maria da Conceição Proença Maria Teresa Rebelo 《Journal of Biosciences and Medicines》 2024年第3期113-121,共9页
Mosquitoes are an interesting topic due to their medical importance, as they play an active role in the transmission of many pathogens and parasites, acting as vectors for various pathologies that are deadly to humans... Mosquitoes are an interesting topic due to their medical importance, as they play an active role in the transmission of many pathogens and parasites, acting as vectors for various pathologies that are deadly to humans, such as dengue, yellow fever, chikungunya, West Nile virus, encephalitis and malaria, among many others that are less common. In terms of morbidity and mortality caused by vector-borne diseases, mosquitoes are the most dangerous animals for humanity and, although they also play a role in the ecosystem as a food source for other organisms, their importance for public health cannot be overlooked. As highly efficient vectors, they put more than three billion people at risk, mainly in tropical and subtropical regions as well as in Europe, since heat waves and flooding are becoming more frequent and severe, and summers are getting longer and warmer, accelerating mosquito development, biting rates, and the incubation of the pathogens within their bodies. Female mosquitoes bite to acquire proteins for the development of their ovaries and eggs and, in the process, acquire pathogens and/or parasites from one vertebrate host and transmit them to another, usually after a short period of replication. Three of their four life stages are lived in still freshwater, so it is crucial to understand their range of action when they reach adulthood and leave the water, in order to plan and implement local prevention measures. A set of georeferenced abundance data collected in mainland Portugal over seven years was linked to cartographed water bodies in a geographic information system to estimate the distances at which Culex pipiens s.l. had a significant presence, with criteria based on the size of the catches. The result allows for an estimate of the fly range of those mosquitoes, which can be used to focus countermeasures. 展开更多
关键词 Mosquito Fly Distance Vector-Borne Diseases Culex pipiens s.l. Geographic Information Systems
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First Report of the Bee Fly Eurycarenus dichopticus Bezzi (Diptera: Bombyliidae) in North Kordofan State, Sudan
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作者 Maha A. Abdelatif Abdel Gadir M. Abdellah +2 位作者 Essra A. ElAggab Ahmed I. Ahmed Safi Ishtiag H. Abdalla 《Advances in Entomology》 2024年第4期275-282,共8页
Sudan’s semi-arid land constitutes a diversity of habitats, species, and genetic resources of high ecological and economic value. This diversity is gradually degrading due to climate change and human misuse. Biodiver... Sudan’s semi-arid land constitutes a diversity of habitats, species, and genetic resources of high ecological and economic value. This diversity is gradually degrading due to climate change and human misuse. Biodiversity monitoring began in Sudan before independence when a considerable number of flora and fauna species were identified. Insects were among the identified fauna where many orders, families, and species were classified especially those of economic, medicinal, and veterinary importance. Bombyliidae or bee flies are considered native to African countries and confined to the semi-arid ecosystem as pollinators of higher plants. The bee fly, Eurycarenus dichopticus recorded from these ecosystems, has gained little attention, and meager data on its biology and reproduction have been published. Adults of this insect are nectar feeders, and females also feed on pollen grains while larvae are parasitoids on certain insects. This study was conducted in three Sudanese states that lie within the semi-arid ecosystem;Khartoum, Gezira, and North Kordofan. Field surveys were conducted in these states and insect fauna was obtained and identified. Bee fly specimens were collected from North Kordofan using the butterfly net method. The specimens were then preserved and sent to the Agricultural Research Corporation ARC in (2020) where they were identified as Eurycarenus dichopticus Bezzi (Diptera: Bombyliidae) which is the first report in North Kordofan. This identification may contribute to the understanding of its ecological significance and role. 展开更多
关键词 SUDAN Semi-Arid Ecosystem Diversity Bee Fly Eurycarenus sp.
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A Study on the Effect of Low Calcium Ultra-fine Fly Ash as a Partial Sustainable Supplementary Material to Cement in Self-compacting Concrete 被引量:2
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作者 Adapala Sunny Suprakash Karthiyaini S 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第2期330-341,共12页
The aim and scope of the present study were to determine the efficacy of UFFA in evaluating the workability,static and dynamic stabilization properties,retention period,and slump loss of SCC systems in their fresh sta... The aim and scope of the present study were to determine the efficacy of UFFA in evaluating the workability,static and dynamic stabilization properties,retention period,and slump loss of SCC systems in their fresh state,as well as their compressive strength at various ages.Microstructure(SEM and XRD)of blended SCC systems were studied.Also,the thermogravimetry behavior of blended SCC specimens were researched.According to the evaluated results,incorporating up to 20%UFFA into fresh concrete improved its performance due to its engineered fine particle size and spherical geometry,both of which contribute to the enhancement of characteristics.Blends of 25%and 30%of UFFA show effect on the water-binder ratio and chemical enhancer dosage,resulting in a loss of homogeneity in fresh SCC systems.The reduced particle size,increased amorphous content,and increased surface area all contribute to the pozzolanic reactivity of the early and later ages,resulting in denser packing and thus an increase in compressive strength.The experimental results indicate that UFFA enhances the properties of SCC in both its fresh and hardened states,which can be attributed to the particles’fineness and their relative effect on SCC. 展开更多
关键词 ultra fine fly ash self-compacting concrete WORKABILITY SEGREGATION compressive strength microstructure TGA
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