With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic ...With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic movements,the strike-slip faults have controlled the distribution of hydrocarbon resources owing to the special fault characteristics and fault-related structures.In contrast,the kinematics and formation mechanism of strike-slip faults in buried sedimentary basins are difficult to investigate,limiting the discussion of these faults and hydrocarbon accumulation.In this study,we identified the characteristics of massive sigmoidal tension gashes(STGs)that formed in the Shunnan area of the Tarim Basin.High-resolution three-dimensional seismic data and attribute analyses were used to investigate their geometric and kinematic characteristics.Then,the stress state of each point of the STGs was calculated using seismic curvature attributes.Finally,the formation mechanism of the STGs and their roles in controlling hydrocarbon migration and accumulation were discussed.The results suggest that:(1)the STGs developed in the Shunnan area have a wide distribution,with a tensile fault arranged in an enéchelon pattern,showing an S-shaped bending.These STGs formed in multiple stages,and differential rotation occurred along the direction of strike-slip stress during formation.(2)Near the principal displacement zone of the strike-slip faults,the stress value of the STGs was higher,gradually decreasing at both ends.The shallow layer deformation was greater than the deep layer deformation.(3)STGs are critical for connecting source rocks,migrating oil and gas,sealing horizontally,and developing efficient reservoirs.This study not only provides seismic evidence for the formation and evolution of super large STGs,but also provides certain guidance for oil and gas exploration in this area.展开更多
Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nan...Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model.展开更多
Agronomic measures are the key to promote the sustainable development of ratoon rice by reducing the damage from mechanical crushing to the residual stubble of the main crop, thereby mitigating the impact on axillary ...Agronomic measures are the key to promote the sustainable development of ratoon rice by reducing the damage from mechanical crushing to the residual stubble of the main crop, thereby mitigating the impact on axillary bud sprouting and yield formation in ratoon rice. This study used widely recommended conventional rice Jiafuzhan and hybrid rice Yongyou 2640 as the test materials to conduct a four-factor block design field experiment in a greenhouse of the experimental farm of Fujian Agricultural and Forestry University, China from 2018 to 2019.The treatments included fertilization and no fertilization, alternate wetting and drying irrigation and continuous water flooding irrigation, and plots with and without artificial crushing damage on the rice stubble. At the same time, a 13C stable isotope in-situ detection technology was used to fertilize the pot experiment. The results showed significant interactions among varieties, water management, nitrogen application and stubble status.Relative to the long-term water flooding treatment, the treatment with sequential application of nitrogen fertilizer coupled with moderate field drought for root-vigor and tiller promotion before and after harvesting of the main crop, significantly improved the effective tillers from low position nodes. This in turn increased the effective panicles per plant and grains per panicle by reducing the influence of artificial crushing damage on rice stubble and achieving a high yield of the regenerated rice. Furthermore, the partitioning of 13C assimilates to the residual stubble and its axillary buds were significantly improved at the mature stage of the main crop, while the translocation rate to roots and rhizosphere soil was reduced at the later growth stage of ratooning season rice. This was triggered by the metabolism of hormones and polyamines at the stem base regulated by the interaction of water and fertilizer at this time. We therefore suggest that to achieve a high yield of ratoon rice with low stubble height under mechanized harvesting, the timely application of nitrogen fertilizer is fundamental,coupled with moderate field drying for root-vigor preservation and tiller promotion before and after the mechanical harvesting of the main crop.展开更多
Based on core and thin section data,the source rock samples from the Fengcheng Formation in the Mahu Sag of the Junggar Basin were analyzed in terms of zircon SIMS U-Pb geochronology,organic carbon isotopic compositio...Based on core and thin section data,the source rock samples from the Fengcheng Formation in the Mahu Sag of the Junggar Basin were analyzed in terms of zircon SIMS U-Pb geochronology,organic carbon isotopic composition,major and trace element contents,as well as petrology.Two zircon U-Pb ages of(306.0±5.2)Ma and(303.5±3.7)Ma were obtained from the first member of the Fengcheng Formation.Combined with carbon isotopic stratigraphy,it is inferred that the depositional age of the Fengcheng Formation is about 297-306 Ma,spanning the Carboniferous-Permian boundary and corresponding to the interglacial period between C4 and P1 glacial events.Multiple increases in Hg/TOC ratios and altered volcanic ash were found in the shale rocks of the Fengcheng Formation,indicating that multiple phases of volcanic activity occurred during its deposition.An interval with a high B/Ga ratio was found in the middle of the second member of the Fengcheng Formation,associated with the occurrence of evaporite minerals and reedmergnerite,indicating that the high salinity of the water mass was related to hydrothermal activity.Comprehensive analysis suggests that the warm and humid climate during the deposition of Fengcheng Formation is conducive to the growth of organic matter such as algae and bacteria in the lake,and accelerates the continental weathering,driving the input of nutrients.Volcanic activities supply a large amount of nutrients and stimulate primary productivity.The warm climate and high salinity are conducive to water stratification,leading to water anoxia that benefits organic matter preservation.The above factors interact and jointly control the enrichment of organic matter in the Fengcheng Formation of Mahu Sag.展开更多
Wnts are secreted,lipid-modified proteins that bind to different receptors on the cell surface to activate canonical or non-canonical Wnt signaling pathways,which control various biological processes throughout embryo...Wnts are secreted,lipid-modified proteins that bind to different receptors on the cell surface to activate canonical or non-canonical Wnt signaling pathways,which control various biological processes throughout embryonic development and adult life.Aberrant Wnt signaling pathway underlies a wide range of human disease pathogeneses.展开更多
The coupling relationship between shelf-edge deltas and deep-water fan sand bodies is a hot and cutting-edge field of international sedimentology and deep-water oil and gas exploration.Based on the newly acquired high...The coupling relationship between shelf-edge deltas and deep-water fan sand bodies is a hot and cutting-edge field of international sedimentology and deep-water oil and gas exploration.Based on the newly acquired high-resolution 3D seismic,logging and core data of Pearl River Mouth Basin(PRMB),this paper dissected the shelf-edge delta to deep-water fan(SEDDF)depositional system in the Oligocene Zhuhai Formation of Paleogene in south subsag of Baiyun Sag,and revealed the complex coupling relationship from the continental shelf edge to deep-water fan sedimentation and its genetic mechanisms.The results show that during the deposition of the fourth to first members of the Zhuhai Formation,the scale of the SEDDF depositional system in the study area showed a pattern of first increasing and then decreasing,with deep-water fan developed in the third to first members and the largest plane distribution scale developed in the late stage of the second member.Based on the development of SEDDF depositional system along the source direction,three types of coupling relationships are divided,namely,deltas that are linked downdip to fans,deltas that lack downdip fans and fans that lack updip coeval deltas,with different depositional characteristics and genetic mechanisms.(1)Deltas that are linked downdip to fans:with the development of shelf-edge deltas in the shelf area and deep-water fans in the downdip slope area,and the strong source supply and relative sea level decline are the two key factors which control the development of this type of source-to-sink(S2S).The development of channels on the continental shelf edge is conducive to the formation of this type of S2S system even with weak source supply and high sea level.(2)Deltas that lack downdip fans:with the development of shelf edge deltas in shelf area,while deep water fans are not developed in the downdip slope area.The lack of“sources”and“channels”,and fluid transformation are the three main reasons for the formation of this type of S2S system.(3)Fans that lack updip coeval deltas:with the development of deep-water fans in continental slope area and the absence of updip coeval shelf edge deltas,which is jointly controlled by the coupling of fluid transformation at the shelf edge and the“channels”in the continental slope area.展开更多
For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture ...For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.展开更多
Based on new data from cores,drilling and logging,combined with extensive rock and mineral testing analysis,a systematic analysis is conducted on the characteristics,diagenesis types,genesis and controlling factors of...Based on new data from cores,drilling and logging,combined with extensive rock and mineral testing analysis,a systematic analysis is conducted on the characteristics,diagenesis types,genesis and controlling factors of deep to ultra-deep abnormally high porosity clastic rock reservoirs in the Oligocene Linhe Formation in the Hetao Basin.The reservoir space of the deep to ultra-deep clastic rock reservoirs in the Linhe Formation is mainly primary pores,and the coupling of three favorable diagenetic elements,namely the rock fabric with strong compaction resistance,weak thermal compaction diagenetic dynamic field,and diagenetic environment with weak fluid compaction-weak cementation,is conducive to the preservation of primary pores.The Linhe Formation clastic rocks have a superior preexisting material composition,with an average total content of 90%for quartz,feldspar,and rigid rock fragments,and strong resistance to compaction.The geothermal gradient in Linhe Depression in the range of(2.0–2.6)°C/100 m is low,and together with the burial history of long-term shallow burial and late rapid deep burial,it forms a weak thermal compaction diagenetic dynamic field environment.The diagenetic environment of the saline lake basin is characterized by weak fluid compaction.At the same time,the paleosalinity has zoning characteristics,and weak cementation in low salinity areas is conducive to the preservation of primary pores.The hydrodynamic conditions of sedimentation,salinity differentiation of ancient water in saline lake basins,and sand body thickness jointly control the distribution of high-quality reservoirs in the Linhe Formation.展开更多
This paper explores the deformation mechanism and control technology of roof pre-splitting for gob-side entries in hard roof full-mechanized longwall caving panel(LTCC).The investigation utilizes a comprehensive appro...This paper explores the deformation mechanism and control technology of roof pre-splitting for gob-side entries in hard roof full-mechanized longwall caving panel(LTCC).The investigation utilizes a comprehensive approach that integrates field monitoring,theoretical analysis,and numerical simulation.Theoretical analysis has illuminated the influence of the length of the lateral cantilever beam of the main roof(LCBM)above the roadway on the stability of the gob-side entry behind the panel.Numerical simulations have further revealed that the longer LCBM results in heightened vertical stress within the coal pillar,developed cracks around the roadway,and more pronounced damage to the roadway.Moreover,numerical simulations also demonstrate the potential of roof pre-splitting technology in optimizing the fracture position of the hard roof.This technology significantly reduces the length of the LCBM,thereby alleviating stress concentration in the coal pillars and integrated coal rib while minimizing the destruction of the gob-side entry.Therefore,this manuscript first proposes the use of roof pre-splitting technology to control roadway deformation,and automatically retain the entry within a hard roof LTCC panel.Field implementation has demonstrated that the proposed automatically retained entry by roof pre-splitting technology effectively reduces gob-side entry deformation and achieves automatically retained entry.展开更多
The failure modes of rock after roadway excavation are diverse and complex.A comprehensive investigation of the internal stress field and the rotation behavior of the stress axis in roadways is essential for elucidati...The failure modes of rock after roadway excavation are diverse and complex.A comprehensive investigation of the internal stress field and the rotation behavior of the stress axis in roadways is essential for elucidating the mechanism of roadway failure.This study aimed to examine the spatial relationship between roadways and stress fields.The law of stress axis rotation under three-dimensional(3D)stress has been extensively studied.A stress model of roadways in the spatial stress field was established,and the far-field stress state at different spatial positions of the roadways was analyzed.A mechanical model of roadways under a 3D stress state was established using far-field stress solutions as boundary conditions.The distribution of principal stressesσ1,σ2 andσ3 around the roadways and the variation of the stress principal axis were solved.It was found that the stability boundary of the stress principal axis exhibits hysteresis when compared with that of the principal stress magnitudes.A numerical analysis model for spatial roadways was established to validate the distribution of principal stress and the mechanism of principal axis rotation.Research has demonstrated that the stress axis undergoes varying degrees of spatial rotation in different orientations and radial depths.Based on the distribution of principal stress and the rotation law of the stress principal axis,the entire evolution mechanism of the two stress adjustments to form the final failure form after roadway excavation has been revealed.The on-site detection results also corroborate the findings presented in this paper.The results provide a basis for the analysis of the failure mechanism under a 3D stress state.展开更多
The orthorhombic CuNb_(2)O_(6)(O-CNO)is established as a competitive anode for lithium-ion capacitors(LICs)owing to its attractive compositional/structural merits.However,the high-temperature synthesis(>900℃)and c...The orthorhombic CuNb_(2)O_(6)(O-CNO)is established as a competitive anode for lithium-ion capacitors(LICs)owing to its attractive compositional/structural merits.However,the high-temperature synthesis(>900℃)and controversial charge-storage mechanism always limit its applications.Herein,we develop a low-temperature strategy to fabricate a nano-blocks-constructed hierarchical accordional O-CNO framework by employing multilayered Nb_(2)CT_(x)as the niobium source.The intrinsic stress-induced formation/transformation mechanism of the monoclinic CuNb_(2)O_(6)to O-CNO is tentatively put forward.Furthermore,the integrated phase conversion and solid solution lithium-storage mechanism is reasonably unveiled with comprehensive in(ex)situ characterizations.Thanks to its unique structural merits and lithium-storage process,the resulted O-CNO anode is endowed with a large capacity of 150.3 mAh g^(-1)at 2.0 A g^(-1),along with long-duration cycling behaviors.Furthermore,the constructed O-CNO-based LICs exhibit a high energy(138.9 Wh kg^(-1))and power(4.0 kW kg^(-1))densities with a modest cycling stability(15.8%capacity degradation after 3000 consecutive cycles).More meaningfully,the in-depth insights into the formation and charge-storage process here can promote the extensive development of binary metal Nb-based oxides for advanced LICs.展开更多
Based on a large number of newly added deep well data in recent years,the subsidence of the Ordos Basin in the Mid-Late Triassic is systematically studied,and it is proposed that the Ordos Basin experienced two import...Based on a large number of newly added deep well data in recent years,the subsidence of the Ordos Basin in the Mid-Late Triassic is systematically studied,and it is proposed that the Ordos Basin experienced two important subsidence events during this depositional period.Through contrastive analysis of the two stages of tectonic subsidence,including stratigraphic characteristics,lithology combination,location of catchment area and sedimentary evolution,it is proposed that both of them are responses to the Indosinian Qinling tectonic activity on the edge of the craton basin.The early subsidence occurred in the Chang 10 Member was featured by high amplitude,large debris supply and fast deposition rate,with coarse debris filling and rapid subsidence accompanied by rapid accumulation,resulting in strata thickness increasing from northeast to southwest in wedge-shape.The subsidence center was located in Huanxian–Zhenyuan–Qingyang–Zhengning areas of southwestern basin with the strata thickness of 800–1300 m.The subsidence center deviating from the depocenter developed multiple catchment areas,until then,unified lake basin has not been formed yet.Under the combined action of subsidence and Carnian heavy rainfall event during the deposition period of Chang 7 Member,a large deep-water depression was formed with slow deposition rate,and the subsidence center coincided with the depocenter basically in the Mahuangshan–Huachi–Huangling areas.The deep-water sediments were 120–320 m thick in the subsidence center,characterized by fine grain.There are differences in the mechanism between the two stages of subsidence.The early one was the response to the northward subduction of the MianLüe Ocean and intense depression under compression in Qinling during Mid-Triassic.The later subsidence is controlled by the weak extensional tectonic environment of the post-collision stage during Late Triassic.展开更多
Based on the new data of drilling, seismic, logging, test and experiments, the key scientific problems in reservoir formation, hydrocarbon accumulation and efficient oil and gas development methods of deep and ultra-d...Based on the new data of drilling, seismic, logging, test and experiments, the key scientific problems in reservoir formation, hydrocarbon accumulation and efficient oil and gas development methods of deep and ultra-deep marine carbonate strata in the central and western superimposed basin in China have been continuously studied.(1) The fault-controlled carbonate reservoir and the ancient dolomite reservoir are two important types of reservoirs in the deep and ultra-deep marine carbonates. According to the formation origin, the large-scale fault-controlled reservoir can be further divided into three types:fracture-cavity reservoir formed by tectonic rupture, fault and fluid-controlled reservoir, and shoal and mound reservoir modified by fault and fluid. The Sinian microbial dolomites are developed in the aragonite-dolomite sea. The predominant mound-shoal facies, early dolomitization and dissolution, acidic fluid environment, anhydrite capping and overpressure are the key factors for the formation and preservation of high-quality dolomite reservoirs.(2) The organic-rich shale of the marine carbonate strata in the superimposed basins of central and western China are mainly developed in the sedimentary environments of deep-water shelf of passive continental margin and carbonate ramp. The tectonic-thermal system is the important factor controlling the hydrocarbon phase in deep and ultra-deep reservoirs, and the reformed dynamic field controls oil and gas accumulation and distribution in deep and ultra-deep marine carbonates.(3) During the development of high-sulfur gas fields such as Puguang, sulfur precipitation blocks the wellbore. The application of sulfur solvent combined with coiled tubing has a significant effect on removing sulfur blockage. The integrated technology of dual-medium modeling and numerical simulation based on sedimentary simulation can accurately characterize the spatial distribution and changes of the water invasion front.Afterward, water control strategies for the entire life cycle of gas wells are proposed, including flow rate management, water drainage and plugging.(4) In the development of ultra-deep fault-controlled fractured-cavity reservoirs, well production declines rapidly due to the permeability reduction, which is a consequence of reservoir stress-sensitivity. The rapid phase change in condensate gas reservoir and pressure decline significantly affect the recovery of condensate oil. Innovative development methods such as gravity drive through water and natural gas injection, and natural gas drive through top injection and bottom production for ultra-deep fault-controlled condensate gas reservoirs are proposed. By adopting the hierarchical geological modeling and the fluid-solid-thermal coupled numerical simulation, the accuracy of producing performance prediction in oil and gas reservoirs has been effectively improved.展开更多
The additive manufacturing(AM)of Ni-based superalloys has attracted extensive interest from both academia and industry due to its unique capabilities to fabricate complex and high-performance components for use in hig...The additive manufacturing(AM)of Ni-based superalloys has attracted extensive interest from both academia and industry due to its unique capabilities to fabricate complex and high-performance components for use in high-end industrial systems.However,the intense temperature gradient induced by the rapid heating and cooling processes of AM can generate high levels of residual stress and metastable chemical and structural states,inevitably leading to severe metallurgical defects in Ni-based superalloys.Cracks are the greatest threat to these materials’integrity as they can rapidly propagate and thereby cause sudden and non-predictable failure.Consequently,there is a need for a deeper understanding of residual stress and cracking mechanisms in additively manufactured Ni-based superalloys and ways to potentially prevent cracking,as this knowledge will enable the wider application of these unique materials.To this end,this paper comprehensively reviews the residual stress and the various mechanisms of crack formation in Ni-based superalloys during AM.In addition,several common methods for inhibiting crack formation are presented to assist the research community to develop methods for the fabrication of crack-free additively manufactured components.展开更多
A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geogr...A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geographical distribution,dynamic development process,and failure mechanism of these ground fissures by employing field monitoring,numerical simulation,and theoretical analysis.The findings demonstrate that ground fissure development has an obvious feature of subregion,and its geographical distribution is significantly affected by topography.Tensile type,open type,and stepped type are three different categories of ground fissure.Ground fissures emerge dynamically as the panel advances,and they typically develop with a distance of less than periodic weighting step distance in advance of panel advancing position.Ground fissures present the dynamic development feature,temporary fissure has the ability of self-healing.The dynamic development process of ground fissure with closed-distance coal seam repeated mining is expounded,and the development scale is a dynamic development stage of“closure→expansion→stabilized”on the basis of the original development scale.From the perspective of topsoil deformation,the computation model considering two points movement vectors towards two directions of the gob and the ground surface is established,the development criterion considering the critical deformation value of topsoil is obtained.The mechanical model of hinged structure of inclined body is proposed to clarify the ground fissure development,and the interaction between slope activity and ground fissure development is expounded.These research results fulfill the gap of ground fissures about development regularity and formation mechanism,and can contribute to ground fissure prevention and treatment with Karst landform.展开更多
This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome a...This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome and proteome.The quantity of K.marxianus L1-1 varied significantly in the fermentation process of rice-acid soup and the first and third days were the two key turning points in the growth phase of K.marxianus L1-1.Importantly,the concentrations of ethyl acetate,ethanol,acetic acid,and L-lactic acid increased from day 1 to day 3.At least 4231 genes and 2937 proteins were identified and 610 differentially expressed proteins were annotated to 30 Kyoto Encyclopedia of Genes and Genomes(KEGG)pathways based on the analysis results of transcriptome and proteome.The key genes and proteins including up-regulated alcohol dehydrogenase family,alcohol O-acetyltransferase,acetyl-CoA C-acetyltransferase,acyl-coenzyme A thioester hydrolase,and down-regulated aldehyde dehydrogenase family were involved in glycolysis/gluconeogenesis pathways,starch and sucrose metabolism pathways,amino sugar and nucleotide sugar metabolism pathways,tricarboxylic acid(TCA)cycle,and pyruvate metabolism pathways,thus promoting the formation of ethyl acetate,organic acids,alcohols,and other esters.Our results revealed the formation mechanisms of ethyl acetate and organic acids in rice-acid soup inoculated with K.marxianus L1-1.展开更多
Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir.In this paper,Pinghu Formation of Xihu Sag was taken as a target.Characteristics,distribution...Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir.In this paper,Pinghu Formation of Xihu Sag was taken as a target.Characteristics,distribution and formation of carbonate cements were investigated via optical microscopy,cathodoluminescence(CL),electron probe and in-situ carbon-oxygen isotope.The results showed that carbonate cements varied in types and shapes.Calcite/dolomite mainly present as poikilotopic cements,while ferrocalcite/ferrodolomite/ankerite generally present as pore-filling cements.Carbon isotope(δ^(13)C)values of carbonate cements were ranging from–7.77‰to–2.67‰,with an average of–4.52‰,while oxygen isotope(δ^(18)O)values were ranging from–18.94‰to–12.04‰,with an average of–14.86‰.Theδ^(13)C/δ^(18)O indicated that the paleo-fluid of carbonate cement was mainly freshwater.Organic carbon mainly came from organic matter within mature source rocks,and inorganic carbon came from dissolution of carbonate debris and early carbonate cements.Distinctiveδ^(13)C/δ^(18)O values manifest that carbonate cements with different types formed in different periods,which make different contributions to the reservoir properties.Calcite/dolomite formed during eodiagenesis(70–90℃)and early mesodiagenesis stage(90–120℃),and were favorable to reservoir owing to their compacted resistance and selective dissolution.Ferrocalcite/ferrodolomite/ankerite formed during middle-late mesodiagenetic stage(above 120℃),and were unfavorable to reservoir due to cementing the residual intergranular pores.Hence,in order to evaluate the reservoir characteristics,it is of significantly important to distinguish different types of carbonate cements and explore their origins.展开更多
Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with ...Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with misorientations of 102°,109°,142°and 149°,respectively,which had not only a shared[1120]zone axis of neighboring grains,but also overlapped diffraction spots similar to twins.However,highresolution transmission electron microscope(HRTEM)analysis revealed that the interfaces in real space deviated from the supposed twinning planes in reciprocal space,i.e.their overlapped diffraction spots.We clarified that the incoherent interfaces were co-axial grain boundaries(CGBs).Additionally,a special angle ofθ,close to 90°,between the interface and one side of basal plane,was frequently formed in CGBs.We proposed that interaction of multiple twinning contributes to the formation of CGBs,and theθis formed due to alternative tensile and compression twinning under a uniaxial loading.展开更多
With the construction of the Xiluodu hydropower station on the Jinsha River,the reservoir impoundment began in 2013 and the water level fluctuates annually between 540 m and 600 m above sea level.The Yanjiao rock slop...With the construction of the Xiluodu hydropower station on the Jinsha River,the reservoir impoundment began in 2013 and the water level fluctuates annually between 540 m and 600 m above sea level.The Yanjiao rock slope which is located on the left bank of the Jinsha River 75 km upstream of the Xiluodu dam site,began to deform in 2014.The potential failure of the slope not only threatens Yanjiao town but also affects the safe operation of the Xiluodu reservoir.This paper is to find the factors influencing the Yanjiao slope deformation through field investigation,geotechnical reconnaissance,and monitoring.Results show that the Yanjiao slope can be divided into a bank collapse area(BCA)and a strong deformation area(SDA)based on the crack distribution characteristics of the slope.The rear area of the slope has been experiencing persistent deformation with a maximum cumulative displacement(GPS monitoring point G4)of 505 mm and 399 mm in the horizontal and vertical directions,respectively.The potential failure surface of the slope is formed 36 m below the surface based on the borehole inclinometer.The bank collapses of the Yanjiao slope are directly caused by the reservoir impoundment while the deformation area of the slope is affected by the combination of the rainfall and reservoir water level fluctuation.Based on mechanism of the Yanjiao slope,prestressed anchor combined with the surface drainage and slope unloading are recommended to prevent potential deformation.展开更多
We investigated the asymmetric tension-compression(T-C)behavior of ZA21 bars with bimodal and uniform structures through axial tension and compression tests.The results show that the yield strengths of bars having bim...We investigated the asymmetric tension-compression(T-C)behavior of ZA21 bars with bimodal and uniform structures through axial tension and compression tests.The results show that the yield strengths of bars having bimodal structure are 206.42 and 140.28 MPa under tension and compression,respectively,which are higher than those of bars having uniform structure with tensile and compressive yield strength of 183.71 and 102.86 MPa,respectively.Prismatic slip and extension twinning under tension and basal slip and extension twinning under compression dominate the yield behavior and induce the T-C asymmetry.However,due to the basal slip activated in fine grains under tension and the inhibition of extension twinning by fine grains under compression,the bimodal structure possesses a lower T-C asymmetry(0.68)compared to the uniform structure(0.56).Multiple extension twins occur during deformation,and the selection of twin variants depends on the Schmid factor of the six variants activated by parent grains.Furthermore,the strengthening effect of the bimodal structure depends on the grain size and the ratio of coarse and fine grains.展开更多
基金Thanks to the Northwest Oilfield Branch,SINOPEC,for providing the seismic data.We thank Dr.Yi-Duo Liu of University of Houston,Ying-Chang Cao and Fang Hao of China University of Petroleum(East China)for their constructive suggestions of this manuscript.We also thank two anonymous reviewers for their comments that helped us to improve the manuscript.This research is jointly supported by the National Natural Science Foundation of China(No.42272155)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA14010301)+1 种基金the Science Fund for Creative Research Groups of the National Natural Science Foundation of China(Grant No.41821002)National Natural Science Foundation of China(No.41702138).
文摘With the theoretical and technological developments related to cratonic strike-slip faults,the Shuntuoguole Low Uplift in the Tarim Basin has attracted considerable attention recently.Affected by multi-stage tectonic movements,the strike-slip faults have controlled the distribution of hydrocarbon resources owing to the special fault characteristics and fault-related structures.In contrast,the kinematics and formation mechanism of strike-slip faults in buried sedimentary basins are difficult to investigate,limiting the discussion of these faults and hydrocarbon accumulation.In this study,we identified the characteristics of massive sigmoidal tension gashes(STGs)that formed in the Shunnan area of the Tarim Basin.High-resolution three-dimensional seismic data and attribute analyses were used to investigate their geometric and kinematic characteristics.Then,the stress state of each point of the STGs was calculated using seismic curvature attributes.Finally,the formation mechanism of the STGs and their roles in controlling hydrocarbon migration and accumulation were discussed.The results suggest that:(1)the STGs developed in the Shunnan area have a wide distribution,with a tensile fault arranged in an enéchelon pattern,showing an S-shaped bending.These STGs formed in multiple stages,and differential rotation occurred along the direction of strike-slip stress during formation.(2)Near the principal displacement zone of the strike-slip faults,the stress value of the STGs was higher,gradually decreasing at both ends.The shallow layer deformation was greater than the deep layer deformation.(3)STGs are critical for connecting source rocks,migrating oil and gas,sealing horizontally,and developing efficient reservoirs.This study not only provides seismic evidence for the formation and evolution of super large STGs,but also provides certain guidance for oil and gas exploration in this area.
基金financially supported by the National Natural Science Foundation of China(Nos.51777097,51577093)。
文摘Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model.
基金supported by the National Nature Science Foundation of China,the National Key Research and Development Program of China(302001109,2016YFD0300508,2017YFD0301602,2018YFD0301105)the Fujian and Taiwan Cultivation Resources Development and Green Cultivation Coordination Innovation Center,China(Fujian 2011 Project,2015-75)the Natural Science Foundation of Fujian Province,China(2022J01142)。
文摘Agronomic measures are the key to promote the sustainable development of ratoon rice by reducing the damage from mechanical crushing to the residual stubble of the main crop, thereby mitigating the impact on axillary bud sprouting and yield formation in ratoon rice. This study used widely recommended conventional rice Jiafuzhan and hybrid rice Yongyou 2640 as the test materials to conduct a four-factor block design field experiment in a greenhouse of the experimental farm of Fujian Agricultural and Forestry University, China from 2018 to 2019.The treatments included fertilization and no fertilization, alternate wetting and drying irrigation and continuous water flooding irrigation, and plots with and without artificial crushing damage on the rice stubble. At the same time, a 13C stable isotope in-situ detection technology was used to fertilize the pot experiment. The results showed significant interactions among varieties, water management, nitrogen application and stubble status.Relative to the long-term water flooding treatment, the treatment with sequential application of nitrogen fertilizer coupled with moderate field drought for root-vigor and tiller promotion before and after harvesting of the main crop, significantly improved the effective tillers from low position nodes. This in turn increased the effective panicles per plant and grains per panicle by reducing the influence of artificial crushing damage on rice stubble and achieving a high yield of the regenerated rice. Furthermore, the partitioning of 13C assimilates to the residual stubble and its axillary buds were significantly improved at the mature stage of the main crop, while the translocation rate to roots and rhizosphere soil was reduced at the later growth stage of ratooning season rice. This was triggered by the metabolism of hormones and polyamines at the stem base regulated by the interaction of water and fertilizer at this time. We therefore suggest that to achieve a high yield of ratoon rice with low stubble height under mechanized harvesting, the timely application of nitrogen fertilizer is fundamental,coupled with moderate field drying for root-vigor preservation and tiller promotion before and after the mechanical harvesting of the main crop.
基金Supported by the National Natural Science Foundation of China(41802177,42272188,42303056)PetroChina Prospective and Basic Technological Project(2022DJ0507)+1 种基金Research Fund of PetroChina Basic Scientific Research and Strategic Reserve Technology(2020D-5008-04)National Natural Science of Sichuan Province(23NSFSC546)。
文摘Based on core and thin section data,the source rock samples from the Fengcheng Formation in the Mahu Sag of the Junggar Basin were analyzed in terms of zircon SIMS U-Pb geochronology,organic carbon isotopic composition,major and trace element contents,as well as petrology.Two zircon U-Pb ages of(306.0±5.2)Ma and(303.5±3.7)Ma were obtained from the first member of the Fengcheng Formation.Combined with carbon isotopic stratigraphy,it is inferred that the depositional age of the Fengcheng Formation is about 297-306 Ma,spanning the Carboniferous-Permian boundary and corresponding to the interglacial period between C4 and P1 glacial events.Multiple increases in Hg/TOC ratios and altered volcanic ash were found in the shale rocks of the Fengcheng Formation,indicating that multiple phases of volcanic activity occurred during its deposition.An interval with a high B/Ga ratio was found in the middle of the second member of the Fengcheng Formation,associated with the occurrence of evaporite minerals and reedmergnerite,indicating that the high salinity of the water mass was related to hydrothermal activity.Comprehensive analysis suggests that the warm and humid climate during the deposition of Fengcheng Formation is conducive to the growth of organic matter such as algae and bacteria in the lake,and accelerates the continental weathering,driving the input of nutrients.Volcanic activities supply a large amount of nutrients and stimulate primary productivity.The warm climate and high salinity are conducive to water stratification,leading to water anoxia that benefits organic matter preservation.The above factors interact and jointly control the enrichment of organic matter in the Fengcheng Formation of Mahu Sag.
基金supported by the National Natural Science Foundation of China (81772017 to[L.F.H.],and 82072106 and 32371371 to[A.R.Q.])The Project Supported by Natural Science Basic Research Plan in Shaanxi Province of China (2023-JC-YB-163 to[L.F.H.])the National Institutes of Health[AR-070135 and AG-056438 to W.C.,and AR075735,DE023813,AR074954,and DE028264 to Y.P.L.]。
文摘Wnts are secreted,lipid-modified proteins that bind to different receptors on the cell surface to activate canonical or non-canonical Wnt signaling pathways,which control various biological processes throughout embryonic development and adult life.Aberrant Wnt signaling pathway underlies a wide range of human disease pathogeneses.
基金Supported by the National Natural Science Foundation of China(91528303)CNOOC Technology Project(2021-KT-YXKY-05).
文摘The coupling relationship between shelf-edge deltas and deep-water fan sand bodies is a hot and cutting-edge field of international sedimentology and deep-water oil and gas exploration.Based on the newly acquired high-resolution 3D seismic,logging and core data of Pearl River Mouth Basin(PRMB),this paper dissected the shelf-edge delta to deep-water fan(SEDDF)depositional system in the Oligocene Zhuhai Formation of Paleogene in south subsag of Baiyun Sag,and revealed the complex coupling relationship from the continental shelf edge to deep-water fan sedimentation and its genetic mechanisms.The results show that during the deposition of the fourth to first members of the Zhuhai Formation,the scale of the SEDDF depositional system in the study area showed a pattern of first increasing and then decreasing,with deep-water fan developed in the third to first members and the largest plane distribution scale developed in the late stage of the second member.Based on the development of SEDDF depositional system along the source direction,three types of coupling relationships are divided,namely,deltas that are linked downdip to fans,deltas that lack downdip fans and fans that lack updip coeval deltas,with different depositional characteristics and genetic mechanisms.(1)Deltas that are linked downdip to fans:with the development of shelf-edge deltas in the shelf area and deep-water fans in the downdip slope area,and the strong source supply and relative sea level decline are the two key factors which control the development of this type of source-to-sink(S2S).The development of channels on the continental shelf edge is conducive to the formation of this type of S2S system even with weak source supply and high sea level.(2)Deltas that lack downdip fans:with the development of shelf edge deltas in shelf area,while deep water fans are not developed in the downdip slope area.The lack of“sources”and“channels”,and fluid transformation are the three main reasons for the formation of this type of S2S system.(3)Fans that lack updip coeval deltas:with the development of deep-water fans in continental slope area and the absence of updip coeval shelf edge deltas,which is jointly controlled by the coupling of fluid transformation at the shelf edge and the“channels”in the continental slope area.
基金Supported by the Key Fund Project of the National Natural Science Foundation of China and Joint Fund of Petrochemical Industry(Class A)(U1762212)National Natural Science Foundation of China(52274009)"14th Five-Year"Forward-looking and Fundamental Major Science and Technology Project of CNPC(2021DJ4402)。
文摘For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.
基金Supported by the CNPC Science and Technology Project(2023ZZ022023ZZ14-01).
文摘Based on new data from cores,drilling and logging,combined with extensive rock and mineral testing analysis,a systematic analysis is conducted on the characteristics,diagenesis types,genesis and controlling factors of deep to ultra-deep abnormally high porosity clastic rock reservoirs in the Oligocene Linhe Formation in the Hetao Basin.The reservoir space of the deep to ultra-deep clastic rock reservoirs in the Linhe Formation is mainly primary pores,and the coupling of three favorable diagenetic elements,namely the rock fabric with strong compaction resistance,weak thermal compaction diagenetic dynamic field,and diagenetic environment with weak fluid compaction-weak cementation,is conducive to the preservation of primary pores.The Linhe Formation clastic rocks have a superior preexisting material composition,with an average total content of 90%for quartz,feldspar,and rigid rock fragments,and strong resistance to compaction.The geothermal gradient in Linhe Depression in the range of(2.0–2.6)°C/100 m is low,and together with the burial history of long-term shallow burial and late rapid deep burial,it forms a weak thermal compaction diagenetic dynamic field environment.The diagenetic environment of the saline lake basin is characterized by weak fluid compaction.At the same time,the paleosalinity has zoning characteristics,and weak cementation in low salinity areas is conducive to the preservation of primary pores.The hydrodynamic conditions of sedimentation,salinity differentiation of ancient water in saline lake basins,and sand body thickness jointly control the distribution of high-quality reservoirs in the Linhe Formation.
基金Project(52104139)supported by the National Natural Science Foundation of China Youth Science FoundationProject(SKLGDUEK2132)supported by the State Key Laboratory for Geomechanics and Deep Underground Engineering,China University of Mining and Technology/China University of Mining and Technology-BeijingProjects([2020]2Y030,[2020]2Y019,[2020j3007,[2020]3008,and[2022j0il]supported by the Guizhou Province Science and Technology Planning,China Project(2022B01051)supported by the Key Research and Development Special Tasks of Xinjiang,China。
文摘This paper explores the deformation mechanism and control technology of roof pre-splitting for gob-side entries in hard roof full-mechanized longwall caving panel(LTCC).The investigation utilizes a comprehensive approach that integrates field monitoring,theoretical analysis,and numerical simulation.Theoretical analysis has illuminated the influence of the length of the lateral cantilever beam of the main roof(LCBM)above the roadway on the stability of the gob-side entry behind the panel.Numerical simulations have further revealed that the longer LCBM results in heightened vertical stress within the coal pillar,developed cracks around the roadway,and more pronounced damage to the roadway.Moreover,numerical simulations also demonstrate the potential of roof pre-splitting technology in optimizing the fracture position of the hard roof.This technology significantly reduces the length of the LCBM,thereby alleviating stress concentration in the coal pillars and integrated coal rib while minimizing the destruction of the gob-side entry.Therefore,this manuscript first proposes the use of roof pre-splitting technology to control roadway deformation,and automatically retain the entry within a hard roof LTCC panel.Field implementation has demonstrated that the proposed automatically retained entry by roof pre-splitting technology effectively reduces gob-side entry deformation and achieves automatically retained entry.
基金supported by the National Natural Science Foundation of China (Grant No.52225404)Beijing Outstanding Young Scientist Program (Grant No.BJJWZYJH01201911413037)Central University Excellent Youth Team Funding Project (Grant No.2023YQTD01).
文摘The failure modes of rock after roadway excavation are diverse and complex.A comprehensive investigation of the internal stress field and the rotation behavior of the stress axis in roadways is essential for elucidating the mechanism of roadway failure.This study aimed to examine the spatial relationship between roadways and stress fields.The law of stress axis rotation under three-dimensional(3D)stress has been extensively studied.A stress model of roadways in the spatial stress field was established,and the far-field stress state at different spatial positions of the roadways was analyzed.A mechanical model of roadways under a 3D stress state was established using far-field stress solutions as boundary conditions.The distribution of principal stressesσ1,σ2 andσ3 around the roadways and the variation of the stress principal axis were solved.It was found that the stability boundary of the stress principal axis exhibits hysteresis when compared with that of the principal stress magnitudes.A numerical analysis model for spatial roadways was established to validate the distribution of principal stress and the mechanism of principal axis rotation.Research has demonstrated that the stress axis undergoes varying degrees of spatial rotation in different orientations and radial depths.Based on the distribution of principal stress and the rotation law of the stress principal axis,the entire evolution mechanism of the two stress adjustments to form the final failure form after roadway excavation has been revealed.The on-site detection results also corroborate the findings presented in this paper.The results provide a basis for the analysis of the failure mechanism under a 3D stress state.
基金financially supported by the National Natural Science Foundation of China(No.52072151,52171211,52102253,52271218,and U22A20145)Taishan Scholars(No.ts201712050)+1 种基金Jinan Independent Innovative Team(2020GXRC015)Major Program of Shandong Province Natural Science Foundation(ZR2021ZD05)
文摘The orthorhombic CuNb_(2)O_(6)(O-CNO)is established as a competitive anode for lithium-ion capacitors(LICs)owing to its attractive compositional/structural merits.However,the high-temperature synthesis(>900℃)and controversial charge-storage mechanism always limit its applications.Herein,we develop a low-temperature strategy to fabricate a nano-blocks-constructed hierarchical accordional O-CNO framework by employing multilayered Nb_(2)CT_(x)as the niobium source.The intrinsic stress-induced formation/transformation mechanism of the monoclinic CuNb_(2)O_(6)to O-CNO is tentatively put forward.Furthermore,the integrated phase conversion and solid solution lithium-storage mechanism is reasonably unveiled with comprehensive in(ex)situ characterizations.Thanks to its unique structural merits and lithium-storage process,the resulted O-CNO anode is endowed with a large capacity of 150.3 mAh g^(-1)at 2.0 A g^(-1),along with long-duration cycling behaviors.Furthermore,the constructed O-CNO-based LICs exhibit a high energy(138.9 Wh kg^(-1))and power(4.0 kW kg^(-1))densities with a modest cycling stability(15.8%capacity degradation after 3000 consecutive cycles).More meaningfully,the in-depth insights into the formation and charge-storage process here can promote the extensive development of binary metal Nb-based oxides for advanced LICs.
基金Supported by the National Science and Technology Major Project(2017ZX05001)CNPC Science and Technology Project(2021DJ22).
文摘Based on a large number of newly added deep well data in recent years,the subsidence of the Ordos Basin in the Mid-Late Triassic is systematically studied,and it is proposed that the Ordos Basin experienced two important subsidence events during this depositional period.Through contrastive analysis of the two stages of tectonic subsidence,including stratigraphic characteristics,lithology combination,location of catchment area and sedimentary evolution,it is proposed that both of them are responses to the Indosinian Qinling tectonic activity on the edge of the craton basin.The early subsidence occurred in the Chang 10 Member was featured by high amplitude,large debris supply and fast deposition rate,with coarse debris filling and rapid subsidence accompanied by rapid accumulation,resulting in strata thickness increasing from northeast to southwest in wedge-shape.The subsidence center was located in Huanxian–Zhenyuan–Qingyang–Zhengning areas of southwestern basin with the strata thickness of 800–1300 m.The subsidence center deviating from the depocenter developed multiple catchment areas,until then,unified lake basin has not been formed yet.Under the combined action of subsidence and Carnian heavy rainfall event during the deposition period of Chang 7 Member,a large deep-water depression was formed with slow deposition rate,and the subsidence center coincided with the depocenter basically in the Mahuangshan–Huachi–Huangling areas.The deep-water sediments were 120–320 m thick in the subsidence center,characterized by fine grain.There are differences in the mechanism between the two stages of subsidence.The early one was the response to the northward subduction of the MianLüe Ocean and intense depression under compression in Qinling during Mid-Triassic.The later subsidence is controlled by the weak extensional tectonic environment of the post-collision stage during Late Triassic.
基金Supported by the National Natural Science Foundation of ChinaCorporate Innovative Development Joint Fund(U19B6003)。
文摘Based on the new data of drilling, seismic, logging, test and experiments, the key scientific problems in reservoir formation, hydrocarbon accumulation and efficient oil and gas development methods of deep and ultra-deep marine carbonate strata in the central and western superimposed basin in China have been continuously studied.(1) The fault-controlled carbonate reservoir and the ancient dolomite reservoir are two important types of reservoirs in the deep and ultra-deep marine carbonates. According to the formation origin, the large-scale fault-controlled reservoir can be further divided into three types:fracture-cavity reservoir formed by tectonic rupture, fault and fluid-controlled reservoir, and shoal and mound reservoir modified by fault and fluid. The Sinian microbial dolomites are developed in the aragonite-dolomite sea. The predominant mound-shoal facies, early dolomitization and dissolution, acidic fluid environment, anhydrite capping and overpressure are the key factors for the formation and preservation of high-quality dolomite reservoirs.(2) The organic-rich shale of the marine carbonate strata in the superimposed basins of central and western China are mainly developed in the sedimentary environments of deep-water shelf of passive continental margin and carbonate ramp. The tectonic-thermal system is the important factor controlling the hydrocarbon phase in deep and ultra-deep reservoirs, and the reformed dynamic field controls oil and gas accumulation and distribution in deep and ultra-deep marine carbonates.(3) During the development of high-sulfur gas fields such as Puguang, sulfur precipitation blocks the wellbore. The application of sulfur solvent combined with coiled tubing has a significant effect on removing sulfur blockage. The integrated technology of dual-medium modeling and numerical simulation based on sedimentary simulation can accurately characterize the spatial distribution and changes of the water invasion front.Afterward, water control strategies for the entire life cycle of gas wells are proposed, including flow rate management, water drainage and plugging.(4) In the development of ultra-deep fault-controlled fractured-cavity reservoirs, well production declines rapidly due to the permeability reduction, which is a consequence of reservoir stress-sensitivity. The rapid phase change in condensate gas reservoir and pressure decline significantly affect the recovery of condensate oil. Innovative development methods such as gravity drive through water and natural gas injection, and natural gas drive through top injection and bottom production for ultra-deep fault-controlled condensate gas reservoirs are proposed. By adopting the hierarchical geological modeling and the fluid-solid-thermal coupled numerical simulation, the accuracy of producing performance prediction in oil and gas reservoirs has been effectively improved.
基金This work was supported by Shenzhen-Hong Kong Science and Technology Innovation Cooperation Zone Shenzhen Park Project:HZQB-KCZYB-2020030the National Natural Science Foundation of China(No.91860131and No.52074157)+2 种基金Guangdong Provincial Department of Science and Technology,Key-Area Research and Development Program of Guangdong Province(No.2020B090923002)the National Key Research and Development Program of China(No.2017YFB0702901)the Shenzhen Science and Technology Innovation Commission(No.JCYJ20170817111811303,No.KQTD20170328154443162and No.ZDSYS201703031748354).
文摘The additive manufacturing(AM)of Ni-based superalloys has attracted extensive interest from both academia and industry due to its unique capabilities to fabricate complex and high-performance components for use in high-end industrial systems.However,the intense temperature gradient induced by the rapid heating and cooling processes of AM can generate high levels of residual stress and metastable chemical and structural states,inevitably leading to severe metallurgical defects in Ni-based superalloys.Cracks are the greatest threat to these materials’integrity as they can rapidly propagate and thereby cause sudden and non-predictable failure.Consequently,there is a need for a deeper understanding of residual stress and cracking mechanisms in additively manufactured Ni-based superalloys and ways to potentially prevent cracking,as this knowledge will enable the wider application of these unique materials.To this end,this paper comprehensively reviews the residual stress and the various mechanisms of crack formation in Ni-based superalloys during AM.In addition,several common methods for inhibiting crack formation are presented to assist the research community to develop methods for the fabrication of crack-free additively manufactured components.
基金funded by State Key Laboratory of Strata Intelligent Control and Green Mining Cofounded by Shandong Province and the Ministry of Science and Technology,Shandong University of Science and Technology(Grant No.MDPC2023ZR01)Open Fund of State Key Laboratory of Water Resource Protection and Utilization in Coal Mining(Grant No.WPUKFJJ2019-19)Major research project of Guizhou Provincial Department of Education on innovative groups(Grant No.Qianjiaohe KY[2019]070)。
文摘A comprehensive study was undertaken at Jiaozi coal mine to investigate the development regularity of ground fissures in shallow buried coal seam mining with Karst landform,shedding light on the development type,geographical distribution,dynamic development process,and failure mechanism of these ground fissures by employing field monitoring,numerical simulation,and theoretical analysis.The findings demonstrate that ground fissure development has an obvious feature of subregion,and its geographical distribution is significantly affected by topography.Tensile type,open type,and stepped type are three different categories of ground fissure.Ground fissures emerge dynamically as the panel advances,and they typically develop with a distance of less than periodic weighting step distance in advance of panel advancing position.Ground fissures present the dynamic development feature,temporary fissure has the ability of self-healing.The dynamic development process of ground fissure with closed-distance coal seam repeated mining is expounded,and the development scale is a dynamic development stage of“closure→expansion→stabilized”on the basis of the original development scale.From the perspective of topsoil deformation,the computation model considering two points movement vectors towards two directions of the gob and the ground surface is established,the development criterion considering the critical deformation value of topsoil is obtained.The mechanical model of hinged structure of inclined body is proposed to clarify the ground fissure development,and the interaction between slope activity and ground fissure development is expounded.These research results fulfill the gap of ground fissures about development regularity and formation mechanism,and can contribute to ground fissure prevention and treatment with Karst landform.
基金financially supported by National Natural Science Foundation of China (32060530)Guizhou University, Gui Da Te Gang He Zi (2022) 39, Technology platform and talent team plan of Guizhou. China ((2018)5251)+2 种基金Graduate Research Fund Project of Guizhou (YJSCXJH(2019]028)Industry-University-Research Cooperation Project of Guizhou (701/700465172217)China Scholarship Council (201906670006)
文摘This study aims to explore the formation mechanism of ethyl acetate and organic acids in acid rice soup(rice-acid soup)inoculated with Kluyveromyces marxianus L1-1 through the complementary analysis of transcriptome and proteome.The quantity of K.marxianus L1-1 varied significantly in the fermentation process of rice-acid soup and the first and third days were the two key turning points in the growth phase of K.marxianus L1-1.Importantly,the concentrations of ethyl acetate,ethanol,acetic acid,and L-lactic acid increased from day 1 to day 3.At least 4231 genes and 2937 proteins were identified and 610 differentially expressed proteins were annotated to 30 Kyoto Encyclopedia of Genes and Genomes(KEGG)pathways based on the analysis results of transcriptome and proteome.The key genes and proteins including up-regulated alcohol dehydrogenase family,alcohol O-acetyltransferase,acetyl-CoA C-acetyltransferase,acyl-coenzyme A thioester hydrolase,and down-regulated aldehyde dehydrogenase family were involved in glycolysis/gluconeogenesis pathways,starch and sucrose metabolism pathways,amino sugar and nucleotide sugar metabolism pathways,tricarboxylic acid(TCA)cycle,and pyruvate metabolism pathways,thus promoting the formation of ethyl acetate,organic acids,alcohols,and other esters.Our results revealed the formation mechanisms of ethyl acetate and organic acids in rice-acid soup inoculated with K.marxianus L1-1.
文摘Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir.In this paper,Pinghu Formation of Xihu Sag was taken as a target.Characteristics,distribution and formation of carbonate cements were investigated via optical microscopy,cathodoluminescence(CL),electron probe and in-situ carbon-oxygen isotope.The results showed that carbonate cements varied in types and shapes.Calcite/dolomite mainly present as poikilotopic cements,while ferrocalcite/ferrodolomite/ankerite generally present as pore-filling cements.Carbon isotope(δ^(13)C)values of carbonate cements were ranging from–7.77‰to–2.67‰,with an average of–4.52‰,while oxygen isotope(δ^(18)O)values were ranging from–18.94‰to–12.04‰,with an average of–14.86‰.Theδ^(13)C/δ^(18)O indicated that the paleo-fluid of carbonate cement was mainly freshwater.Organic carbon mainly came from organic matter within mature source rocks,and inorganic carbon came from dissolution of carbonate debris and early carbonate cements.Distinctiveδ^(13)C/δ^(18)O values manifest that carbonate cements with different types formed in different periods,which make different contributions to the reservoir properties.Calcite/dolomite formed during eodiagenesis(70–90℃)and early mesodiagenesis stage(90–120℃),and were favorable to reservoir owing to their compacted resistance and selective dissolution.Ferrocalcite/ferrodolomite/ankerite formed during middle-late mesodiagenetic stage(above 120℃),and were unfavorable to reservoir due to cementing the residual intergranular pores.Hence,in order to evaluate the reservoir characteristics,it is of significantly important to distinguish different types of carbonate cements and explore their origins.
基金supported by the National Key R&D Program of China[grant number 2021YFA1200203]the Key Program of National Natural Science Foundation of China[grant number 51931003]+3 种基金the National Natural Science Foundation of China[grant numbers 52171118,52071178,51901103]the Projects in Science and Technique Plans of Ningbo City[grant number 2019B10083]the China Postdoctoral Science Foundation[grant number 2021M701715]the Opening Project of the Key Laboratory of Advanced Manufacturing and Intelligent Technology(Ministry of Education)of Harbin University of Science and Technology[grant number KFKT202103]
文摘Due to the insufficient slip systems in hexagonal close-packed structure,twinning is frequently activated to support stable plastic deformation of Mg alloy.In this work,we found four typical twin-like interfaces with misorientations of 102°,109°,142°and 149°,respectively,which had not only a shared[1120]zone axis of neighboring grains,but also overlapped diffraction spots similar to twins.However,highresolution transmission electron microscope(HRTEM)analysis revealed that the interfaces in real space deviated from the supposed twinning planes in reciprocal space,i.e.their overlapped diffraction spots.We clarified that the incoherent interfaces were co-axial grain boundaries(CGBs).Additionally,a special angle ofθ,close to 90°,between the interface and one side of basal plane,was frequently formed in CGBs.We proposed that interaction of multiple twinning contributes to the formation of CGBs,and theθis formed due to alternative tensile and compression twinning under a uniaxial loading.
基金the project of POWERCHINA Chengdu Engineering Corporation Limited,Power China under Grant No.P46220the Natural Science Foundation of Sichuan,China under Grant No.2022NSFSC0425the Science and Technology Department of Sichuan Province under Grant No.2021YJ0053。
文摘With the construction of the Xiluodu hydropower station on the Jinsha River,the reservoir impoundment began in 2013 and the water level fluctuates annually between 540 m and 600 m above sea level.The Yanjiao rock slope which is located on the left bank of the Jinsha River 75 km upstream of the Xiluodu dam site,began to deform in 2014.The potential failure of the slope not only threatens Yanjiao town but also affects the safe operation of the Xiluodu reservoir.This paper is to find the factors influencing the Yanjiao slope deformation through field investigation,geotechnical reconnaissance,and monitoring.Results show that the Yanjiao slope can be divided into a bank collapse area(BCA)and a strong deformation area(SDA)based on the crack distribution characteristics of the slope.The rear area of the slope has been experiencing persistent deformation with a maximum cumulative displacement(GPS monitoring point G4)of 505 mm and 399 mm in the horizontal and vertical directions,respectively.The potential failure surface of the slope is formed 36 m below the surface based on the borehole inclinometer.The bank collapses of the Yanjiao slope are directly caused by the reservoir impoundment while the deformation area of the slope is affected by the combination of the rainfall and reservoir water level fluctuation.Based on mechanism of the Yanjiao slope,prestressed anchor combined with the surface drainage and slope unloading are recommended to prevent potential deformation.
基金financially supported by the National Natural Science Foundation of China (No. 52275305)the Fundamental Research Funds for the Central Universities (No. FRF-IC-20-10)the China Postdoctoral Science Foundation (No. 2021M700378)
文摘We investigated the asymmetric tension-compression(T-C)behavior of ZA21 bars with bimodal and uniform structures through axial tension and compression tests.The results show that the yield strengths of bars having bimodal structure are 206.42 and 140.28 MPa under tension and compression,respectively,which are higher than those of bars having uniform structure with tensile and compressive yield strength of 183.71 and 102.86 MPa,respectively.Prismatic slip and extension twinning under tension and basal slip and extension twinning under compression dominate the yield behavior and induce the T-C asymmetry.However,due to the basal slip activated in fine grains under tension and the inhibition of extension twinning by fine grains under compression,the bimodal structure possesses a lower T-C asymmetry(0.68)compared to the uniform structure(0.56).Multiple extension twins occur during deformation,and the selection of twin variants depends on the Schmid factor of the six variants activated by parent grains.Furthermore,the strengthening effect of the bimodal structure depends on the grain size and the ratio of coarse and fine grains.