New criterion in predicting glass forming ability of various glass-forming systems

It has been confirmed that glass-forming ability （GFA） of supercooled liquids is related to not only liquid phase stability but also the crystallization resistance. In this paper, it is found that the liquid region interval （T1 - Tg） characterized by the normalized parameter of Tg/T1 could reflect the stability of glass-forming liquids at the equilibrium state, whilst the normalization of supercooled liquid region △Tx=（Tx - Tg）, i.e. △Tx/Tx （wherein T1 is the liquidus temperature, Tg the glass transition temperature, and Tx the onset crystallization temperature） could indicate the crystallization resistance during glass formation. Thus, a new parameter, defined as ζ = Tg/T1＋△Tx/Tx is established to predict the GFA of supercooled liquids. In comparison with other commonly used criteria, this parameter demonstrates a better statistical correlation with the GFA for various glass-forming systems including metallic glasses, oxide glasses and cryoprotectants.

Film forming systems for topical and transdermal drug delivery

Skin is considered as an important route of administration of drugs for both local and systemic effects. The effectiveness of topical therapy depends on the physicochemical properties of the drug and adherence of the patient to the treatment regimen as well as the system’s ability to adhere to skin during the therapy so as to promote drug penetration through the skin barrier.Conventional formulations for topical and dermatological administration of drugs have certain limitations like poor adherence to skin, poor permeability and compromised patient compliance.For the treatment of diseases of body tissues and wounds, the drug has to be maintained at the site of treatment for an effective period of time. Topical film forming systems are such developing drug delivery systems meant for topical application to the skin, which adhere to the body, forming a thin transparent film and provide delivery of the active ingredients to the body tissue. These are intended for skin application as emollient or protective and for local action or transdermal penetration of medicament for systemic action. The transparency is an appreciable feature of this polymeric system which greatly influences the patient acceptance.In the current discussion, the film forming systems are described as a promising choice for topical and transdermal drug delivery. Further the various types of film forming systems (sprays/solutions, gels and emulsions) along with their evaluation parameters have also been reviewed.

A method for calculation of ion distribution in reaction system forming hydroxide

A formula was proposed to calculate the distribution of metal ions quantitatively in chemical reaction system forming hydroxide where precipitation and complex are formed together. The effects of some factors on formation of precipitation and complex were investigated, and the corresponding precipitation rates of zinc, iron （III）, aluminum, copper and magnesium were calculated. As a result, it shows that the proposed formula is reliable. By the proposed formula, the existence state of metal ions in hydroxides reaction system with any metal ions can be well described and the effects of some factors on the distribution of metal ions were determined.

Effect of Low pH on Forming Process of Desulfurization Gypsum Composite Boards Strengthened by Melamine-formaldehyde Resin

Through exploring the effects of low pH on the composite system of desulfurization gypsum(DG)enhanced by melamine-formaldehyde resin(MF),it is found that the inducing of sulfate-ion,in contrast to chloride and oxalate ions,favors the longitudinal growth of the crystalline form of the hydration product,which was relatively simple and had the highest length to width(L/D)ratio.At the same time,MF can also improve L/D ratio of gypsum hydration products,which favors the formation of hydrated whiskers.Finally,in a composite system composed of hemihydrate gypsum,MF,and glass fibers,when dilute sulfuric acid was used to regulate pH=3-4,the tight binding formed among the components of the composite system compared to pH=5-6.The hydration product of gypsum adheres tightly to glass fiber surface and produces a good cross-linking and binding effect with MF.The flexural strength,compressive strength,elastic modulus,and water absorption of the desulphurized gypsum composite board is 22.7 MPa,39.8 MPa,5608 MPa,and 1.8%,respectively.

The development of real time data driving multi-axis linkage and synergic movement control system of 3D variable cross-section roll forming machine

The three dimensional variable cross-section roll forming is a kind of new metal forming technol- ogy which combines large forming force, multi-axis linkage movement and space synergic movement, and the sequential synergic movement of the ganged roller group is used to complete the metal sheet forming according to the shape of the complicated and variable forming part data. The control system should meet the demands of quick response to the test requirements of the product part. A new kind of real time data driving multi-axis linkage and synergic movement control strategy of 3D roll forming is put forward in the paper. In the new control strategy, the forming data are automatically generated according to the shape of the parts, and the multi-axis linkage movement together with cooperative motion among the six stands of the 3D roll forming machine is driven by the real-time information, and the control nodes are also driven by the forming data. The new control strategy is applied to a 48 axis 3D roll forming machine developed by our research center, and the control servo period is less than 10ms. A forming experiment of variable cross section part is carried out, and the forming preci- sion is better than ＋ 0.5mm by the control strategy. The result of the experiment proves that the control strategy has significant potentiality for the development of 3D roll forming production line with large scale, multi-axis ganged and svner^ic movement

Thermodynamic model for glass forming ability of ternary metallic glass systems

The thermodynamic model of multicomponent chemical short range order (MCSRO) was established in order to evaluate the glass forming ability (GFA) of ternary alloys. Comprehensive numerical calculations using MSCRO software were conducted to obtain the composition dependence of the MCSRO undercooling in Zr Ni Cu, Zr Si Cu and Pd Si Cu ternary systems. By the MCSRO undercooling principle, the composition range of Zr Ni Cu system with optimum GFA is determined to be 62.5 ～ 75 Zr, 5～ 20 Cu, 12.5 ～ 25 Ni ( n (Ni)/ n (Cu)=1～5). The TTT curves of Zr Ni Cu system were also calculated based on the MCSRO model. The critical cooling rates for Zr based alloy with deep MSCRO undercooling are estimated to be as low as 100?K/s, which is consistent with the practical cooling rate in the preparation of Zr based bulk metallic glass (BMG). The calculation also illustrates that the easy glass forming systems such as Pd based alloys exhibit an extraordinary deep MCSRO undercooling. It is shown that the thermodynamic model of MCSRO provides an effective method for the alloy designing of BMG.

NUMERICAL SIMULATION AND EXPERIMENTS FOR PANEL FORMING BASED ON CAD/CAE SYSTEM

A comparison research about the implicit and explicit solutions of sheet forming simulation was presented. On the platform of Autoform and Ls dyna3D, a dynamic forming simulation of a sideframe, of Santana 2000 was done, and the engineering strain, the thickness distribution and the FLD between the two softwares were compared. It indicates that their results coincide with each other very much and the areas of the wrinkle and failure are the same roughly. Further, the characteristics of the two softwares in geometric model and preprocessing of the finite element were discussed and the questions which need attention provided.

An introduction to the riometer system deployed at China-Iceland joint Arctic observatory and its beam-forming correction method based on the preliminary data

The China-Iceland joint Arctic observatory(CIAO)has formally been operating since October 18,2018,and an imaging riometer system was deployed at CIAO in August 2019 for the conjunction observation purpose with the co-located ground-based all sky imager auroral observation system.The features of the riometer and antenna system are presented.The riometer’s beam-forming performance were evaluated with the analysis method introduced in detail.The analysis results showed that the mapping of beams was incorrectly ordered,and the correction has been made.The revised ordering result was reasonably verified and the analysis method was proved to be effective.

Microstructure and forming mechanism of metals subjected to ultrasonic vibration plastic forming: A mini review

Compared with traditional plastic forming,ultrasonic vibration plastic forming has the advantages of reducing the forming force and improving the surface quality of the workpiece.This technology has a very broad application prospect in industrial manufactur-ing.Researchers have conducted extensive research on the ultrasonic vibration plastic forming of metals and laid a deep foundation for the development of this field.In this review,metals were classified according to their crystal structures.The effects of ultrasonic vibration on the microstructure of face-centered cubic,body-centered cubic,and hexagonal close-packed metals during plastic forming and the mech-anism underlying ultrasonic vibration forming were reviewed.The main challenges and future research direction of the ultrasonic vibra-tion plastic forming of metals were also discussed.

MPI/OpenMP-Based Parallel Solver for Imprint Forming Simulation

In this research,we present the pure open multi-processing(OpenMP),pure message passing interface(MPI),and hybrid MPI/OpenMP parallel solvers within the dynamic explicit central difference algorithm for the coining process to address the challenge of capturing fine relief features of approximately 50 microns.Achieving such precision demands the utilization of at least 7 million tetrahedron elements,surpassing the capabilities of traditional serial programs previously developed.To mitigate data races when calculating internal forces,intermediate arrays are introduced within the OpenMP directive.This helps ensure proper synchronization and avoid conflicts during parallel execution.Additionally,in the MPI implementation,the coins are partitioned into the desired number of regions.This division allows for efficient distribution of computational tasks across multiple processes.Numerical simulation examples are conducted to compare the three solvers with serial programs,evaluating correctness,acceleration ratio,and parallel efficiency.The results reveal a relative error of approximately 0.3%in forming force among the parallel and serial solvers,while the predicted insufficient material zones align with experimental observations.Additionally,speedup ratio and parallel efficiency are assessed for the coining process simulation.The pureMPI parallel solver achieves a maximum acceleration of 9.5 on a single computer(utilizing 12 cores)and the hybrid solver exhibits a speedup ratio of 136 in a cluster(using 6 compute nodes and 12 cores per compute node),showing the strong scalability of the hybrid MPI/OpenMP programming model.This approach effectively meets the simulation requirements for commemorative coins with intricate relief patterns.

Method of fabricating artificial rock specimens based on extrusion free forming(EFF)3D printing

Three-dimensional(3D)printing technology has been widely used to create artificial rock samples in rock mechanics.While 3D printing can create complex fractures,the material still lacks sufficient similarity to natural rock.Extrusion free forming(EFF)is a 3D printing technique that uses clay as the printing material and cures the specimens through high-temperature sintering.In this study,we attempted to use the EFF technology to fabricate artificial rock specimens.The results show the physico-mechanical properties of the specimens are significantly affected by the sintering temperature,while the nozzle diameter and layer thickness also have a certain impact.The specimens are primarily composed of SiO_(2),with mineral compositions similar to that of natural rocks.The density,uniaxial compressive strength(UCS),elastic modulus,and tensile strength of the printed specimens fall in the range of 1.65–2.54 g/cm3,16.46–50.49 MPa,2.17–13.35 GPa,and 0.82–17.18 MPa,respectively.It is capable of simulating different types of rocks,especially mudstone,sandstone,limestone,and gneiss.However,the simulation of hard rocks with UCS exceeding 50 MPa still requires validation.

A Hybrid Optimization Approach of Single Point Incremental Sheet Forming of AISI 316L Stainless Steel Using Grey Relation Analysis Coupled with Principal Component Analysiss

We investigated the parametric optimization on incremental sheet forming of stainless steel using Grey Relational Analysis(GRA) coupled with Principal Component Analysis(PCA). AISI 316L stainless steel sheets were used to develop double wall angle pyramid with aid of tungsten carbide tool. GRA coupled with PCA was used to plan the experiment conditions. Control factors such as Tool Diameter(TD), Step Depth(SD), Bottom Wall Angle(BWA), Feed Rate(FR) and Spindle Speed(SS) on Top Wall Angle(TWA) and Top Wall Angle Surface Roughness(TWASR) have been studied. Wall angle increases with increasing tool diameter due to large contact area between tool and workpiece. As the step depth, feed rate and spindle speed increase,TWASR decreases with increasing tool diameter. As the step depth increasing, the hydrostatic stress is raised causing severe cracks in the deformed surface. Hence it was concluded that the proposed hybrid method was suitable for optimizing the factors and response.

Forming and Springback Prediction of Strips Under Multi-square Punch Concave Forming Process Considering Partial-unloading Effects

To further investigate the forming mechanism and springback characteristics of strips under multi-square punch forming (MSPF) considering partial-unloading effects, a series of concave form ing tests of strips are conducted on the MSPF machine. This paper aims to reveal the physical mecha nism of the elastic-plastic deformation in the MSPF process considering the effect of the forming ap proaches, and derive appropriate mathematical interpretations. The theoretical model is firstly estab lished to analyse the concave forming mechanism and springback characteristics of the strip, and its accuracy is then validated by experimental data. The forming history and load evolutions are depicted to explore the required forming capacity through the proposed analytical method. Besides, the paramet ric studies are carried out to discuss their effects on the springback of the strip. The results suggest that the deformation paths of the strip are influenced by the forming approach, and the springback of the strip in convex forming is larger than that in concave forming.

Study of microstructure evolution of magnesium alloy cylindrical part with longitudinal inner ribs during hot flow forming by coupling ANN-modified CA and FEA

Hot flow forming(HFF)is a promising forming technology to manufacture thin-walled cylindrical part with longitudinal inner ribs(CPLIRs)made of magnesium(Mg)alloys,which has wide applications in the aerospace field.However,due to the thermo-mechanical coupling effect and the existence of stiffened structure,complex microstructure evolution and uneven microstructure occur easily at the cylindrical wall(CW)and inner rib(IR)of Mg alloy thin-walled CPLIRs during the HFF.In this paper,a modified cellular automaton(CA)model of Mg alloy considering the effects of deformation conditions on material parameters was developed using the artificial neural network(ANN)method.It is found that the ANN-modified CA model exhibits better predictability for the microstructure of hot deformation than the conventional CA model.Furthermore,the microstructure evolution of ZK61 alloy CPLIRs during the HFF was analyzed by coupling the modified CA model and finite element analysis(FEA).The results show that compared with the microstructure at the same layer of the IR,more refined grains and less sufficient DRX resulted from larger strain and strain rate occur at that of the CW;various differences of strain and strain rate in the wall-thickness exist between the CW and IR,which leads to the inhomogeneity of microstructure rising firstly and declining from the inside layer to outside layer;the obtained Hall-Petch relationship between the measured microhardness and predicted grain sizes at the CW and the IR indicates the reliability of the coupled FEA-CA simulation results.

Patterns and drivers of plant sexual systems in the dry-hot valley region of southwestern China

Sexual systems play important roles in angiosperm evolution and exhibit substantial variations among different floras. Thus, studying their evolution in a whole flora is crucial for understanding the formation and maintenance of plant biodiversity and predicting its responses to environmental change. In this study, we determined the patterns of plant sexual systems and their associations with geographic elements and various life-history traits in dry-hot valley region of southwestern China, an extremely vulnerable ecosystem. Of the 3166 angiosperm species recorded in this area, 74.5% were hermaphroditic,13.5% were monoecious and 12% were dioecious, showing a high incidence of diclinous species. Diclinous species were strongly associated with tropical elements, whereas hermaphroditic species were strongly associated with temperate and cosmopolitan elements. We also found that hermaphroditism was strongly associated with showy floral displays, specialist entomophily, dry fruits and herbaceous plants.Dioecy was strongly associated with inconspicuous, pale-colored flowers, generalist entomophily, fleshy fruits, and woody plants, whereas monoecy was strongly associated with inconspicuous, pale-colored flowers, anemophily, dry fruits, and herbaceous plants. In addition, hermaphroditic species with generalist entomophily tended to flower in the dry season, whereas diclinous species with specialist entomophily tended to flower in the rainy season. However, independent of sexual systems, plants that produce dry fruits tended to flower in the rainy season and set fruits in the dry season, but the opposite pattern was found for fleshy fruit-producing plants. Our results suggest that in the dry-hot valleys, plant sexual systems are associated with geographic elements as well as various life-history traits that are sensitive to environmental change.

Analysis and Optimization of the Electrohydraulic Forming Process of Sinusoidal Corrugation Tubes

Aluminum alloy thin-walled structures are widely used in the automotive industry due to their advantages related to light weight and crashworthiness.They can be produced at room temperature by the electrohydraulic forming process.In the present study,the influence of the related parameters on the forming quality of a 6063 aluminum alloy sinusoidal corrugation tube has been assessed.In particular,the orthogonal experimental design(OED)and central composite design(CCD)methods have been used.Through the range analysis and variance analysis of the experimental data,the influence degree of wire diameter(WD)and discharge energy(DE)on the forming quality was determined.Multiple regression analysis was performed using the response surface methodology.A prediction model for the attaching-die state coefficient was established accordingly.The following optimal arrangement of parameters was obtained(WD=0.759 mm,DE=2.926 kJ).The attaching-die state coefficient reached the peak value of 0.001.Better optimized wire diameter and discharge energy for a better attaching-die state could be screened by CCD compared with OED.The response surface method in CCD was more suitable for the design and optimization of the considered process parameters.

How elevation and soil properties affect plant distribution patterns and species diversity in the Mediterranean mountain ecosystem of Al-Jabal Al- Akhdar, Libya

The objectives of this study were to assess distribution patterns of plant species richness,plant diversity and vegetation structure in relation to environmental factors along elevation gradient in Al-Jabal Al-Akhdar,Libya.For each species,its growth form,chorological affinities,degree of occurrence,endemism status and originality were provided.A total of 534 taxa were generated from 70 families of the flowering plants,and 3 of the non-flowering plants were identified.The native flora of the study area was counted for 80.2%of the total indigenous taxa(465).The hump-shaped pattern of plant species richness was obtained,with the highest species richness at the mid-elevations,and both ends of the gradient have the lowest.The annuals(300 species,56.2%)and non-succulent perennial herbs(165 species,30.9%)were the most dominant growth forms of the total species composition.Along the elevation gradient,Asteraceae,Fabaceae,Poaceae,Lamiaceae and Apiaceae were the dominant families with the highest numbers of species.This investigation recorded 31 endemic taxa,comprising 25 dicots and 6 monocots,primarily of Mediterranean origin,with most belonging to the Asteraceae and Lamiaceae families.Mediterranean chorotype was the dominant,whether pure(mono-),or combined with one(bi-and pluri-regional)or more(pluri-regional).Application of cluster analysis on the vegetation data yielded four cluster groups;each was linked to an elevation level.It emphasized the importance of establishing conservation strategies to minimize human disturbance and safeguard relic habitats of Juniperus phoenicea L.at its southern distribution limits in Africa,underlining the proactive management required for species preservation.The application of Redundancy Analysis revealed that Shannon diversity index(H'),pH and Fe were the determinant soil factor in the mid-elevation levels(L2 and L3)whereas altitude,fine sand,HCO3,OM,and soil contents of Na,SO4 and Cl for the extreme levels(L1 and L4).

Atmospheric nitrogen deposition affects forest plant and soil system carbon:nitrogen:phosphorus stoichiometric flexibility:A meta-analysis

Background:Nitrogen(N)deposition affects forest stoichiometric flexibility through changing soil nutrient availability to influence plant uptake.However,the effect of N deposition on the flexibility of carbon(C),N,and phosphorus(P)in forest plant-soil-microbe systems remains unclear.Methods:We conducted a meta-analysis based on 751 pairs of observations to evaluate the responses of plant,soil and microbial biomass C,N and P nutrients and stoichiometry to N addition in different N intensity(050,50–100,>100 kg·ha^(-1)·year^(-1)of N),duration(0–5,>5 year),method(understory,canopy),and matter(ammonium N,nitrate N,organic N,mixed N).Results:N addition significantly increased plant N:P(leaf:14.98%,root:13.29%),plant C:P(leaf:6.8%,root:25.44%),soil N:P(13.94%),soil C:P(10.86%),microbial biomass N:P(23.58%),microbial biomass C:P(12.62%),but reduced plant C:N(leaf:6.49%,root:9.02%).Furthermore,plant C:N:P stoichiometry changed significantly under short-term N inputs,while soil and microorganisms changed drastically under high N addition.Canopy N addition primarily affected plant C:N:P stoichiometry through altering plant N content,while understory N inputs altered more by influencing soil C and P content.Organic N significantly influenced plant and soil C:N and C:P,while ammonia N changed plant N:P.Plant C:P and soil C:N were strongly correlated with mean annual precipitation(MAT),and the C:N:P stoichiometric flexibility in soil and plant under N addition connected with soil depth.Besides,N addition decoupled the correlations between soil microorganisms and the plant.Conclusions:N addition significantly increased the C:P and N:P in soil,plant,and microbial biomass,reducing plant C:N,and aggravated forest P limitations.Significantly,these impacts were contingent on climate types,soil layers,and N input forms.The findings enhance our comprehension of the plant-soil system nutrient cycling mechanisms in forest ecosystems and plant strategy responses to N deposition.

Experimental study on the forming characteristics of 1.5 GPa ultrahigh-strength dual-phase steel

The DP1500 steel series successfully produced by Baosteel is a marked improvement over the cold-rolled hot-dip galvanized dual-phase steel series.Sufficient parameter data related to forming characteristics are needed for the successful application of dual-phase steel series in engineering structures.Therefore,differences in the mech-anical properties,forming limit,hole expansion ratio,and stretch bend limit of the 1.5 GPa ultrahigh-strength steel,including DP1500,QP1500,and MS1500,have been systematically studied.Results show that the DP1500 exhibits good plastic deformation performance and approximately 5% uniform elongation,and its true major strain minimum on the forming limit curve(FLC_(0)) value is approximately 0.083,which is higher and lower than the FLC_(0) values of MS1500 and QP1500 of the same strength grade,respectively.DP1500 also exhibits good flanging and pore expansion capabilities and superior performance to QP1500 and MS1500.The minimum radius-to-thickness(R/T) ratio(1.4) of DP1500 in the 90° bend tests transverse to the rolling direction is between the R/T ratios of MS1500 and the QP1500.Overall,the formability performance of DP1500 is between that of MS1500 and QP1500.Its excellent crash energy absorption and formability performance render it a suitable structural component,and it has been successfully tested and verified on a typical complex ultrahigh-strength steel skeleton structure.

Relationship of Edge States to Anomaly and Construction of Dual Systems in Quantum Hall Systems

The hierarchy of bulk actions is developed which are associated with Chern-Simons theories. The connection between the bulk and edge arising from the requirement there is a cancelation of an anomaly which arises in the theory. A duality transformation is studied for the Chern-Simons example. The idea that is used has been employed to describe duality in a scalar theory. The link between the edge theory with the Chern-Simons theory in the bulk then suggests that similar transformations can be implemented in the bulk Chern-Simons theory as well.