FRACTAL GEOMETRY STUDY OF CORRELATION BETWEEN IMPACT TOUGHNESS OF STEEL AND PARAMETERS OF FREE-CUTTING PHASE

Studies were made of the calculation of fractal dimension of transverse impact fracture sur- face,and of the correlation between impact toughness of steel and parameters of free-cutting phase by means of the developed fractal geometry model of crack propagation.It is believed that the area fraction,f,of free-cutting phase is negligibly influential to the longitudinal im- pact toughness,as f1 .While the aspect ratio,saying ratio of length to width,of free-cut. ting phase is inversely influential to the transverse impact toughness.This may .be the reason why the transverse impact toughness of free-cutting steel containing more rare earth contrast to sulphur is even higher than the low sulphur containing steel.

Effect of normalized plasma frequency on electron phase-space orbits in a free-electron laser

Irregular phase-space orbits of the electrons are harmful to the electron-beam transport quality and hence deteriorate the performance of a free-electron laser （FEL）. In previous literature, it was demonstrated that the irregularity of the electron phase-space orbits could be caused in several ways, such as varying the wiggler amplitude and inducing sidebands. Based on a Hamiltonian model with a set of self-consistent differential equations, it is shown in this paper that the electron- beam normalized plasma frequency functions not only couple the electron motion with the FEL wave, which results in the evolution of the FEL wave field and a possible power saturation at a large beam current, but also cause the irregularity of the electron phase-space orbits when the normalized plasma frequency has a sufficiently large value, even if the initial energy of the electron is equal to the synchronous energy or the FEL wave does not reach power saturation.

A solid phase radioimmunoassay for free triiodothyronine in serum:assay development and validation

A solid phase radioimmunoassay for free triiodothyronine in serum was developed based on double-antibody coated tubes. The method was turned out to be reliable with good reproducibility, higher sensitivity and easy performance. The measurable range of FT3 in serum was 1.2 to 38 pmol/L. The mean coefficients of variation within and between assays were 1.79%-3.18% and 4.72%-9.31%, respectively. The FT3 concentrations in euthyroid serum as determined by this method were 2.8 to 7.8pmol/L. The FT3 values determined by this new method correlated well with those measured by a commercial radioimmunoassay （r=0.853）.

Modified phase transition and electrical properties of [Li_(0.05)(Na_(0.535)K_(0.48))_(0.95)]- (Nb_(0.94)Sb_(0.06))O_3 lead-free piezoelectric ceramic by sintering temperature

Li/Sb-doped (Na,K)NbO3 with a nominal composition of [Li0.05(Na0.535K0.48)0.95](Nb0.94Sb0.06)O3 ceramic was synthesized by normal sintering. The phase structure, microstructure, and electrical properties were investigated with a special emphasis on the influence of the sintering temperature. A polymorphic phase transition (PPT) from orthorhombic to tetragonal symmetry was observed when the sintering temperature was raised from 1040 to 1050 ℃, whereby the piezoelectric coefficient d33 and the electromechanical coupling coefficient kp reached the peak values of 245 pC·N-1 and 41.2%, respectively. The PPT induced by varying the sintering temperature is due to the different volatilization extents of alkali metals and appears to a lower sintering temperature with increasing Li content. The trace modifying of alkali metal content is more effective than doping B site element to enhance the d33 value.

Phase-sensitive fat suppression steady-state free procession sequence with phase correction

Robust and fast fat suppression is a challenge in balanced steady-state free precession （SSFP） magnetic resonance imaging. Although single-acquisition phase-sensitive SSFP can provide fat-suppressed images in short scan time, phase errors, especially spatially-dependent phase shift, caused by a variety of factors may result in misplacement of fat and water voxels. In this paper, a novel phase correction algorithm was used to calibrate those phase errors during image reconstruction. This algorithm corrects phase by region growing, employing both the magnitude and the phase information of image pixels. Phantom and in vivo imagings were performed to validate the technique. As a result, excellent fat-suppressed images were acquired by using single-acquisition phase-sensitive SSFP with phase correction.

Study on the phase transition of the fractal scale-free networks

Based on the Ising spin, the phase transition on fractal scale-free networks with tree-like skeletons is studied, where the loops are generated by local links. The degree distribution of the tree-like skeleton satisfies the power-law form P（k）～ k^-δ.It is found that when δ≥3, the renormalized scale-free network will have the same degree distribution as the original network. For a special case of δ = 4.5, a ferromagnetic to paramagnetic transition is found and the critical temperature is determined by the box-covering renormalization method. By keeping the structure of the fractal scale-free network constant, the numerical relationship between the critical temperature and the network size is found, which is the form of power law.

Phase transition in evolution of traffic flow with scale-free property

This paper investigates the behaviour of traffic flow in traffic systems with a new model based on the NaSch model and cluster approximation of mean-field theory. The proposed model aims at constructing a mapping relationship between the microcosmic behaviour and the macroscopic property of traffic flow. Results demonstrate that scale-free phenomenon of the evolution network becomes obvious when the density value of traffic flow reaches at the critical point of phase transition from free flow to traffic congestion, and jamming is limited in this scale-free structure.

Experimental Study and Thermodynamical Calculation on the Formation of Eutectic Phase of MnS-RE_2S_3 and(Mn,Ca)S-RE_2S_3 in Sulfur-Containing Free-Cutting Steel

The free-cutting phase in RE or Ca-RE treated sulfur-containing free-cutting steel is the eutectic phases of MnS-RE_2S_3 and (Mn,Ca)S-RE_2S_3,respectively.The atomic ratio of RE/S needed to modify all the MnS into the eutectic phase is higher than 1.48 or 1.41-1.37 Ca/S,when RE or Ca-RE is used as the modifiz- er in the sulfur-containing free-cutting steel.Moreover,the thermodynamical calculation shows that the eutectic temperature is lower than the solidifying temperature,which is the key condition for the eutectic phase to keep globual during solidifying.

Heavy metal free primers: Polymorphism of gadolinium and titanium in the context of GSR glass phase

The possibility of identifying gunshot residue (GSR) particles produced by non-toxic primers containing only titanium and zinc is a very difficult task using SEM/EDX analysis employed in the analysis of GSR originating from primers containing lead, barium and antimony. However, Bauer et al. demonstrated that non-toxic (TieZn) primers form a TiZn2O4 spinel crystalline structure using SEM/EDX with EBSD (Electron Back Scatter Diffraction) and TKD (Transmission Kikuchi Diffraction), whereas GSR originating from gadolinium-doped TieZn primers form a non-crystalline glass phase. Here, a possible explanation of these different phenomena is hypothesized.

Characterization of a 3-Phase a.c. Free Burning Arc Plasma

A 3-phase a.c. arc plasma reactor with large volume plasma has been developed for the synthesis of new carbon nano-structures. One of the main characteristics of the plasma system is related to the absence of a fixed neutral point. This gives rise to a rich and complex phenomenology related to instabilities and arc motion since the arcs are ＂burning＂ freely in the gas flow between the three electrodes. This paper is dedicated to the analysis of the behavior of such a system under typical conditions using argon and nitrogen as plasma gases. A classification of are configuration, arc commutating, arc interaction, arc motion and arc instabilities are discussed based on ultra high-speed cine camera analysis. A simple model describing the time evolution of the system is also presented and compared with the experimental measurements. The results show that an adequate control could allow the improvement of the overall system.

Effects of Na/K ratio on the phase structure and electrical properties of Na_xK_(1-x)NbO_3 lead-free piezoelectric ceramics

Lead-free piezoelectric NaxK1-xNbO3（x = 0.3-0.8）（NKN） ceramics were fabricated by normal sintering at 1060°C for 2 h.Microstructures and electrical properties of the ceramics were investigated with a special emphasis on the influence of Na content.The grain size of the produced dense ceramic was decreased by increasing Na content.A discontinuous change in the space distance was found at the composition close to Na0.7K0.3NbO3 ceramic, which indicates the presence of a transitional composition between two different orthorhombic phases, which is similar to the behavior of morphotropic phase boundary（MPB） in NaxK1-xNbO3 ceramics.Such MPB-like behavior contributes to the enhanced piezoelectric coefficient d33 of 122 pC/N, planar-mode electromechanical coupling coefficient kP of 28.6%, and dielectric constant εr of 703, respectively for the Na0.7K0.3NbO3 ceramic.Cubic temperature TC and the transitional temperature TO-T from orthorhombic to tetragonal phase are observed at around 420°C and 200°C, respectively.

增效型无土相仿生油基钻井液技术的研究与应用

针对深井超深井钻井过程中钻遇高温高压、井壁失稳及井下复杂情况的难题,基于仿生学、超分子化学以及岩石表面润湿性理论,通过优选仿生增效剂、仿生提切剂及仿生降滤失剂,配套相关处理剂,最终形成了一套适用于深井、超深井地层钻探的增效型无土相仿生油基钻井液体系。研究发现,建立的增效型无土相仿生油基钻井液体系可抗220℃高温,配制密度为2.4 g/cm^(3),破乳电压大于400 V,高温高压滤失量为3.2 mL,人造岩心在该体系中220℃下老化后的抗压强度达到7.1 MPa,平均渗透率恢复值为93.9%。现场应用情况表明,体系流变性能稳定,平均机械钻速比邻井提高16%,平均井径扩大率仅为1.25%,可有效解决深井超深井钻井过程中出现的井壁失稳难题,为我国深井超深井的钻探提供了技术保障。

Modified surface tension model for free surface flow with single-phase lattice Boltzmann method

A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced.The restriction to the relaxation factor （which needs to be smaller than 1） is circumvented by the new surface tension algebra,due to its rational physical nature compared with the treatment of Xing,Buther and Yang in their paper （Comp.Mater.Sci.,2007,39（2）：282-290）.The proposed stable surface tension scheme is applied to simulate the free deformation of a square droplet with surface tension effect and the process of a droplet impinging on a liquid film.The numerical solution for free deformation of a droplet agrees well with thermodynamic principles,and also achieves high accuracy in comparison with Xing,et al.＇s model.Three typical impinging modes are successfully obtained with the new scheme,and another particular mode found by Wang and Chen is also successfully simulated.The evolutions of liquid crown agree well with the power law related to time.

FREE BOUNDARY VALUE PROBLEM OF ONE DIMENSIONAL TWO-PHASE LIQUID-GAS MODEL

In this paper, we study a free boundary value problem for two-phase liquid- gas model with mass-dependent viscosity coefficient when both the initial liquid and gas masses connect to vacuum continuously. The gas is assumed to be polytropic whereas the liquid is treated as an incompressible fluid. We give the proof of the global existence and uniqueness of weak solutions whenβ∈ （0, 1）, which have improved the result of Evje and Karlsen, and we obtain the regularity of the solutions by energy method.

铝合金细化剂细化行为研究现状与展望

晶粒细化处理能够显著改善铝合金的综合性能,对拓展其应用领域意义重大。本文基于异质形核,探讨了点阵错配模型、边边匹配模型以及自由生长模型,肯定了边边匹配模型在筛选潜在晶粒细化剂方面的高效性;根据自由生长模型关于异质相尺寸、形态、分布等对晶粒细化效果影响的理论研究,归纳了物理、化学方法调控第二相进而优化细化效果的研究进展,并且对第二相尺寸影响细化效果的原因进行了理论阐述,最后对优化晶粒细化剂的方向做了展望。

Efficient Solvent- and Catalyst-Free Syntheses of Imine Derivatives Applying the Pressure Reduction Technique: Remarkable Change of the Reaction Rate with the Phase Transition

Because imines could be used as convenient starting materials in various fields, the development of an easy synthetic method of imine was strongly desired. In response to this demand, we thought that it would be an effective synthesis method if an aldehyde and an amine could be reacted to give an imine in good yield under solvent- and catalyst-free conditions. In fact, we tried the reaction of benzaldehyde with various amines under solvent- and catalyst-free conditions followed by removal of water that was produced in the reaction system by a vacuum pump, and desired imines could be obtained in good yields. Observation of this reaction using a nuclear magnetic resonance spectrometer revealed that the reaction rate was extremely fast at the initial stage but slowed over time. However, the reaction of benzaldehyde with aniline differed greatly, and the reaction rate dramatically improved in 47 - 48 minutes after the start of the reaction. At this time, we found that the reaction system underwent a phase transition from the liquid phase to the solid phase.

某油井G105钻杆断裂失效分析

在某油井深400~500 m处,钻杆1在解卡时断裂,随后钻杆2在打捞落鱼时断裂。采用断口形貌分析、化学成分分析、显微组织分析、力学性能测试等手段分析了两根钻杆断裂的原因。结果表明,钻杆1与井壁摩擦过程中发生相变,强度下降塑性增加,发生韧性断裂;钻杆2与井壁摩擦时,形成大量马氏体,韧性恶化,当再次承受拉力时发生脆性断裂。建议监测井内结构变化,保证钻井液的循环畅通,优化钻具结构设计,防止钻杆因相变而断裂,同时禁止工人违规操作,避免钻杆因超载发生断裂。

海洋天然气水合物系统动态调整的异常特征及主控因素

似海底反射(bottom simulating reflectors,BSRs)是指示天然气水合物赋存深度的重要标识,已在全球多个海域研究中发现了千年时间尺度上天然气水合物系统的动态调整,地震剖面上的典型表征是存在多种类型BSR及埋深变化。本文对比分析全球典型海域BSR的地震反射特征及测井响应差异,提出BSR调整及发育的主控因素为:①冰期—间冰期旋回、快速沉积、逆冲-褶皱与基底隆升,导致稳定带底界或BSR发生调整;②构造活动释放的热流体导致BSR上移;③海底侵蚀作用、地层超压,导致BSR下移等;④重烃气体形成Ⅱ型水合物,甲烷水合物稳定带底界下部出现水合物与游离气共存层;⑤合适温度条件下细粒沉积物发生矿物相变,形成与水合物无关的双BSR;⑥局部热异常会导致同一水平地层从含天然气水合物向游离气变化,横向上出现极性反转,无BSR调整。不同因素导致的稳定带底界调整,会伴随着水合物的形成—分解—再形成的动态变化,导致地层内水合物-游离气-水的三相共存,同时伴随着多层游离气的复杂分布,在地震剖面上呈现出多种类型BSR,指示天然气水合物系统复杂性及其与游离气间的相互影响。

自贸试验区如何促进绿色发展——基于环境污染视角的实证研究

有效减少环境污染是绿色发展的前提,也是实现绿色发展的关键。基于2009—2020年中国257个地级及以上城市的面板数据,采用多期双重差分法研究自贸试验区试点政策对城市环境污染的影响,构建中介效应模型分析产业结构高级化和绿色技术创新的具体作用,同时运用空间杜宾模型检验自贸试验区试点的设立对环境污染的影响是否具有空间辐射效应。研究结果表明:自贸试验区试点政策有利于减少城市环境污染;自贸试验区试点政策从产业结构高级化和绿色技术创新这两个途径改善了城市环境状况;自贸区试点政策对环境污染的改善具有显著的空间辐射作用。

实时周跳探测与修复的MGF周跳解算方法的改进

周跳的探测和修复是基于载波相位高精度定位的关键技术之一。基于改进的几何无关相位组合MGF方法具有直接分离不同频率上的周跳,对高频数据中较小的周跳实现有效探测,探测速度远快于TurboEdit法等优点。但MGF法无法探测4周以上的周跳,并对低采样率和低卫星高度角下的数据进行周跳探测时,会选取错误的周跳备选值作为周跳检验量从而造成周跳的误判。针对MGF法所存在的问题,通过联合相位减伪距法PRP法,构建新的周跳备选值判断方程,并对MGF法的周跳检验量进行二次历元间差分STMGF,组成PRP-STMGF周跳探测组合。PRP-STMGF周跳探测组合能够探测任意周的周跳,与TurboEdit法相比,修复时无需分离周跳,直接对PRP-STMGF法的周跳检验量进行四舍五入即可确定出正确的周跳值,且适用于低采样率和低卫星高度角下的实时周跳探测与修复。最后通过北斗双频实测数据进行实验验证,结果表明,PRP-STMGF周跳探测组合,避免了MGF法选取错误周跳备选值的问题,相较于TurboEdit法不仅低延时,准确率高,且适用于不同采样率和低卫星高度角下周跳探测与修复。