The action mechanisms and structures designs of F-containing functional materials for high performance oxygen electrocatalysis

Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.

Paracrine and endocrine actions of bone——the functions of secretory proteins from osteoblasts, osteocytes, and osteoclasts

The skeleton is a dynamic organ that is constantly remodeled. Proteins secreted from bone cells, namely osteoblasts, osteocytes,and osteoclasts exert regulation on osteoblastogenesis, osteclastogenesis, and angiogenesis in a paracrine manner. Osteoblasts secrete a range of different molecules including RANKL/OPG, M-CSF, SEMA3A, WNT5A, and WNT16 that regulate osteoclastogenesis. Osteoblasts also produce VEGFA that stimulates osteoblastogenesis and angiogenesis. Osteocytes produce sclerostin（SOST） that inhibits osteoblast differentiation and promotes osteoclast differentiation. Osteoclasts secrete factors including BMP6, CTHRC1, EFNB2, S1P, WNT10B, SEMA4D, and CT-1 that act on osteoblasts and osteocytes, and thereby influencea A osteogenesis. Osteoclast precursors produce the angiogenic factor PDGF-BB to promote the formation of Type H vessels, which then stimulate osteoblastogenesis. Besides, the evidences over the past decades show that at least three hormones or ＂osteokines＂from bone cells have endocrine functions. FGF23 is produced by osteoblasts and osteocytes and can regulate phosphate metabolism. Osteocalcin（OCN） secreted by osteoblasts regulates systemic glucose and energy metabolism, reproduction, and cognition. Lipocalin-2（LCN2） is secreted by osteoblasts and can influence energy metabolism by suppressing appetite in the brain.We review the recent progresses in the paracrine and endocrine functions of the secretory proteins of osteoblasts, osteocytes, and osteoclasts, revealing connections of the skeleton with other tissues and providing added insights into the pathogenesis of degenerative diseases affecting multiple organs and the drug discovery process.

Existing form and action mechanism of minor scandium and zirconium in Al-Cu-Mg alloy

In order to investigate the existing form and action mechanism of minor scandium （Sc） and zirconium （Zr） in AI-Cu-Mg alloy, microstructures of Al-4Cu-1Mg-Sc-Zr alloy under different conditions, including states of as-cast, homogenized, hot-rolled, as-solution and natural aged, were observed by scanning electron microscopy （SEM）, X-ray diffractometry （XRD） and transmission electron microscopy （TEM）. It is revealed that Sc and Zr are completely dissolved into the supersaturated solid solution in as-cast ingot, but grain refinement is not observed. Coffee-bean-like AI3（Sc, Zr） particles deposit during homogenization of ingot induce an increase in hardness. Al3（Sc, Zr） particles are slightly coarsened in as-solution samples, but they still maintain coherent to matrix, which indicates a high thermal stability of these particles. Good coherency ofAl3（Sc, Zr） particles makes some benefits for inhibiting recrystallization and reserving work-hardening.

Trifunctional strategy for the design and synthesis of a Ni-CeO_(2)@SiO_(2)catalyst with remarkable low-temperature sintering and coking resistance for methane dry reforming

In this study,a trifunctional strategy was developed to prepare a confined Ni-based catalyst(Ni-CeO_(2)@SiO_(2))for dry reforming of methane(DRM)of two main greenhouse gases-CO_(2)and CH_(4).The Ni-CeO_(2)@SiO_(2)catalyst was fabricated by utilizing the confinement effect of the SiO_(2)shell and the synergistic interaction between Ni-Ce and the decoking effect of CeO_(2).The catalysts were systematically characterized via X-ray diffraction,N_(2 )adsorption/desorption,transmission electron microscopy,energy dispersive X-ray spectroscopy,hydrogen temperature reduction and desorption set by program,oxygen temperature program desorption,Raman spectroscopy,thermogravimetric analysis,and in situ diffuse reflectance infrared Fourier transform spectroscopy measurements to reveal their physicochemical properties and reaction mechanism.The Ni-CeO_(2)@SiO_(2)catalyst exhibited higher activity and stability than the catalyst synthesized via the traditional impregnation method.In addition,no carbon deposition was detected over Ni-CeO_(2)@SiO_(2)after a 100 h durability test at 800℃,and the average particle size of Ni nanoparticles(NPs)in the catalyst increased from 5.01 to 5.77 nm.Remarkably,Ni-CeO_(2)@SiO_(2)also exhibited superior low-temperature stability;no coke deposition was observed when the catalyst was reacted at 600℃ for 20 h.The high coking and sintering resistance of this confined Ni-based DRM catalyst can be attributed to its trifunctional effect.The trifunctional strategy developed in this study could be used as a guideline to design other high-performance catalysts for CO_(2)and CH4 dry forming and accelerate their industrialization.

A two-grid algorithm based on Newton iteration for the stream function form of the Navier-Stokes equations

In this paper, we propose a two-grid algorithm for solving the stream function formulation of the stationary Navies-Stokes equations. The algorithm is constructed by reducing the original system to one small, nonlinear system on the coarse mesh space and two similar linear systems （with same stiffness matrix but different right-hand side） on the fine mesh space. The convergence analysis and error estimation of the algorithm are given for the case of conforming elements. Furthermore, the Mgorithm produces a numerical solution with the optimal asymptotic H^2-error. Finally, we give a numerical illustration to demonstrate the effectiveness of the two-grid algorithm for solving the Navier-Stokes equations.

Comprehensive form of solution for Lamb's dynamic problem expressed by Green's functions

By the analysis for the vectors of a wave field in the cylindrical coordinate and Sommerfeld＇s identity as well as Green＇s functions of Stokes＇ solution pertaining the conventional elastic dynamic equation, the results of Green＇s function in an infinite space of an axisymmetric coordinate are shown in this paper. After employing a supplementary influence field and the boundary conditions in the free surface of a senti-space, the authors obtain the solutions of Green＇s function for Lamb＇s dynamic problem. Besides, the vertical displacement uzz and the radial displacement urz can match Lamb＇s previous results, and the solutions of the linear expansion source u^r and the linear torsional source uee are also given in the paper. The authors reveal that Green＇s function of Stokes＇ solution in the semi-space is a comprehensive form of solution expressing the dynamic Lamb＇s problem for various situations. It may benefit the investigation of deepening and development of Lamb＇s problems and solution for pertinent dynamic problems conveniently.

Form and Function——An Overview

Long before,the research of form has already entered its heyday,but the study of function is a somewhat new branch of language study.This essay is an attempt to take a brief look at the most significant distinction between"form and function",and then aims at making clear the definition of"form and function"in discourse analysis.

A FORM FUNCTION METHOD FOR FORM FINDING OF TENSION STRUCTURE

A new form function involving parameters Pi is presented. On the basis of the form function, an initial form of tension structure was Sound by interpolating through the control points on boundary of the structure. The form function can be controlled by changing beta (1) according to the pre-tension and the boundary of the structure. The final form of a tension structure should be an equilibrium system under the pretension. To examine the nature of the initial form, the FEM was used. Many examples show that the initial form gives a very ideal result for equal or unequal pre-tension in two directions of the structure. In general cases, there is little difference between the initial form and the final one.

Multi-group pin power reconstruction method based on colorset form functions

A multi-group pin power reconstruction method that fully exploits nodal information obtained from global coarse mesh solution has been developed.It expands the intra-nodal flux distributions into nonseparable semi-analytic basis functions,and a colorset based form function generating method is proposed,which can accurately model the spectral interaction occurring at assembly interface.To demonstrate its accuracy and applicability to realistic problems, the new method is tested against two benchmark problems,including a mixed-oxide fuel problem.The results show that the new method is comparable in accuracy to fine-mesh methods.

TRANSFORMATION OF SYMMETRIC MULTIPLICATIVE FUNCTIONALS

In the present paper the transformation of symmetric Markov processes by symmetric martingale multiplicative functionals is studied and the corresponding Dirichlet form is formulated.

A modeling approach for fuzzy programming with echelon form membership functions

In order to solve fuzzy mathematical programming with soft constraints,the initial models must first be converted into crisp models.Membership functions are employed to describe the fuzzy right-hand side parameters needed to achieve this conversion.In some cases,echelon form membership functions(EFMFs)are required to depict the actual fuzzy situation.However,due to their discrete properties,fuzzy programming problems with such membership functions cannot be modeled by traditional methods.Motivated by these challenges,this paper introduces a novel absolute value representation modeling approach to formulate fuzzy programming using EFMFs.This approach can translate a discrete model to a continuous one which can then be easily solved.Finally,by means of a numerical example,the effectiveness of our new approach is demonstrated.

A NEW METHOD FOR ESTABLISHING PSEUDO ORTHOGONAL PROPERTIES OF EIGENFUNCTION EXPANSION FORM IN FRACTURE MECHANICS

A new and simple method is developed to establish the pseudo orthogonal properties (POP) of the eigenfunction expansion form (EEF) of crack-tip stress complex potential functions for cracked anisotropic and piezoelectric materials, respectively. Di?erent from previous research, the complex argument separation technique is not required so that cumbersome manipulations are avoided. Moreover, it is shown, di?erent from the previous research too, that the orthogonal properties of the material characteristic matrices A and B are no longer necessary in obtaining the POP of EEF in cracked piezoelectric materials. Of the greatest signi?cance is that the method presented in this paper can be widely extended to treat many kinds of problems concerning path- independent integrals with multi-variables.

RESIDUAL A POSTERIORI ERROR ESTIMATE TWO-GRID METHODS FOR THE STEADY (NAVIER-STOKES) EQUATION WITH STREAM FUNCTION FORM

Residual based on a posteriori error estimates for conforming finite element solutions of incompressible Navier-Stokes equations with stream function form which were computed with seven recently proposed two-level method were derived. The posteriori error estimates contained additional terms in comparison to the error estimates for the solution obtained by the standard finite element method. The importance of these additional terms in the error estimates was investigated by studying their asymptotic behavior. For optimal scaled meshes, these bounds are not of higher order than of convergence of discrete solution.

Some Methods of Solution of Problems of Sound Diffraction on Bodies of Non-Analytical Form

This review analyzes following numerical methods of a solution of problems of a sound diffraction on ideal and elastic scatterers of a non-analytical form: a method of integral equations, a method of Green’s functions, a method of finite elements, a boundary elements method, a method of Kupradze, a T-matrix method and a method of a geometrical theory of a diffraction.

Plasma spray forming of functionally graded materials mould

A new technology of functionally graded materials(FGM) mould fabricated by plasma spraying and arc spraying was developed. According to applied characteristic of plastic mould, the reasonable coatings of FGM were designed and their microstructures were analyzed. At the same time, some key problems were solved including spray mould fabricating, FGM forming and demoulding, etc. The results show that the service performance of the FGM mould is much more excellent than the one composed of the traditional materials, and the life span can also be greatly increased. The technology will have a significant influence on materials development in mould industry.

Grand Zero Density Estimates of L-functions Associated with Cusp Forms

In this paper a zero-density estimate of the large sieve type is given for the automorphic L-function L f (s,χ),where f is a holomorphic cusp form and χ a Dirichlet character of mod q.

Functional Enrichment of Utopian Distribution of Plant Life-Forms

Adaptive fuzzy neural inference systems are used to illustrate the primary nodal number of plant life-forms. Categorization of two candidate areas is carried out using the water-energy dynamic (for Ecuador, South America) and Macedonia, Southern Europe), within which the life-form spectra are distributed. Genetic optimization methods are used to expand the primary nodal number to the complete number of life-form categories. The distribution of the elements exhibits a stochastic, binomial distribution and the utopia line and curve are summarized which enhance accuracy of the climatic data and of the consequent numbers of plant species occurrences. Expansion of the distribution of each life-form category is approximated within the Z utopia hyperplane with use of the functional approximation algorithm. This process gives additional structure and informative value to the Z plane, enhancing our ability to make informed policy decisions concerning species and ecosystem conservation.

Neutral Pion Electromagnetic Form Factor as a Bound System of 3 + 1 Dimensional QCD

We investigate a neutral pion electromagnetic form factor in momentum space and obtain Gaussian-like function for it. The characteristic form of our neutral pion electromagnetic form factor is consistent with the results published by Jefferson Lab Hall A Collaboration. .