The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop rel...The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop reliable monitoring and control strategies. This paper described one approach based on generation function technique with the following two steps. First, a new mechanism for propylene polymerization was proposed by considering the effects of the reactive impurities in the material on the propylene polymerization. Second, a series of equations of population balance for the propylene polymerization in loop reactors were established based on the proposed mechanism. Accordingly, the equations were transformed into the mathematic matrix through the generation function technique to investigate the effects of the reactive impurities on the propylene polymerization. Significant effects of the reactive impurities were analyzed through computational simulation. The results show that the concentration of active centre on catalysts and the polymerization conversion both decrease with the increase of the initial concentration of any reactive impurity; hydrogen concentration decreases with the increase of the initial concentration of ethylene or butylenes, whereas, it increases with the increase of the initial concentration of propadiene; the simulated weight average molecular weight and the molecular weight distribution index of polymer resins both increase with the increase of the initial concentration of ethylene or butylenes. They decrease with the increase of the initial concentration of propadiene.展开更多
We demonstrate a fiber-loop ring down multi-function sensors system, which can be used to measure refractive index and curvature simultaneously. Good agreement has been found between theoretical analyses and experimen...We demonstrate a fiber-loop ring down multi-function sensors system, which can be used to measure refractive index and curvature simultaneously. Good agreement has been found between theoretical analyses and experimental results. It has great potential for sensor applications.展开更多
在硬件在回路仿真系统中,模型需与数据采集卡之间进行实时数据的采集和交换,Simulink下Real Time Workspace工具箱提供了与硬件之间的实时数据采集和交换,但是工具箱并不支持市面上所有采集板卡的类型,给用户对采集板卡选型带来一定局...在硬件在回路仿真系统中,模型需与数据采集卡之间进行实时数据的采集和交换,Simulink下Real Time Workspace工具箱提供了与硬件之间的实时数据采集和交换,但是工具箱并不支持市面上所有采集板卡的类型,给用户对采集板卡选型带来一定局限性。因此本文使用Simulink中S-Function模块编写不同采集板卡的硬件驱动,证明只要是数据采集工具箱支持的板卡型号,都可以用S-Function进行模块化硬件驱动编写,解决了Simulink中Real Time Workspace工具箱给用户在使用Simulink建模过程中对板卡选型的局限性这一问题。展开更多
基金This work was financially supported by the National Natural Science Foundation of China (No. 20406016)Fujian Petrochemical Company of SINOPEC (No. MS/FJ-08-JS-15-2005-01)
文摘The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop reliable monitoring and control strategies. This paper described one approach based on generation function technique with the following two steps. First, a new mechanism for propylene polymerization was proposed by considering the effects of the reactive impurities in the material on the propylene polymerization. Second, a series of equations of population balance for the propylene polymerization in loop reactors were established based on the proposed mechanism. Accordingly, the equations were transformed into the mathematic matrix through the generation function technique to investigate the effects of the reactive impurities on the propylene polymerization. Significant effects of the reactive impurities were analyzed through computational simulation. The results show that the concentration of active centre on catalysts and the polymerization conversion both decrease with the increase of the initial concentration of any reactive impurity; hydrogen concentration decreases with the increase of the initial concentration of ethylene or butylenes, whereas, it increases with the increase of the initial concentration of propadiene; the simulated weight average molecular weight and the molecular weight distribution index of polymer resins both increase with the increase of the initial concentration of ethylene or butylenes. They decrease with the increase of the initial concentration of propadiene.
文摘We demonstrate a fiber-loop ring down multi-function sensors system, which can be used to measure refractive index and curvature simultaneously. Good agreement has been found between theoretical analyses and experimental results. It has great potential for sensor applications.
文摘在硬件在回路仿真系统中,模型需与数据采集卡之间进行实时数据的采集和交换,Simulink下Real Time Workspace工具箱提供了与硬件之间的实时数据采集和交换,但是工具箱并不支持市面上所有采集板卡的类型,给用户对采集板卡选型带来一定局限性。因此本文使用Simulink中S-Function模块编写不同采集板卡的硬件驱动,证明只要是数据采集工具箱支持的板卡型号,都可以用S-Function进行模块化硬件驱动编写,解决了Simulink中Real Time Workspace工具箱给用户在使用Simulink建模过程中对板卡选型的局限性这一问题。
