Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporizatio...Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporization temperatures are very high for a liquid that is neither ionic nor metallic, and whose molar mass is low. Thus, water remains liquid at atmospheric pressure up to 100C while similar molecules such as H2S, H2Se, H2Te for example would give a vaporization temperature close to 80C. This cohesion is in fact ensured by hydrogen bonds between water molecules. This type of bonds between neighboring molecules, hydrogen bonds, is quite often found in chemistry [1] [2]. Any change in the state of aggregation of a substance occurs with the absorption or release of a certain amount of latent heat of transformation. Latent heat of fusion, vaporization or sublimation is the ratio of the energy supplied as heat to the mass of the substance that is melted, vaporized or sublimated. As a result of the reversibility of the processes, the fusion heat is equal to the heat released in the reverse process: crystallization and solidification heat. And likewise the heat of vaporization is equal to the heat of condensation. This equality of heat is often used to determine experimentally either of these quantities. There are two main measurement methods: 1) Direct measurement using the calorimeter, 2) Indirect measure based on the use of the VantHoff relationship. The objective of this work is to measure the latent heat of water vaporization and verify the compatibility of the experimental values with the values given by the tables using the indirect method.展开更多
Fractions of β-HMX(β-1,3,5,7-tetranitro-1,3,5,7-tetrazocane) have been used to demonstrate the mutual relationship between friction and impact sensitivities.Inclusion of an additional twelve nitramines into this sce...Fractions of β-HMX(β-1,3,5,7-tetranitro-1,3,5,7-tetrazocane) have been used to demonstrate the mutual relationship between friction and impact sensitivities.Inclusion of an additional twelve nitramines into this scenario resulted in a series of partial relationships,which were determined from the molecular structure of these substances.It was also found that there is a relation between increasing heats of fusion of the nitramines studied and their decreasing friction sensitivities.Comparison of friction sensitivity with heats of fusion,ΔHm,tr of the studied nitramines shows that the increase in ΔHm,tr values is more or less connected with a decrease in friction sensitivity.展开更多
The paper specifies an unambiguous basic relationship between the published results of ab initio calculations of lattice energies, E L,and heats of sublimation, ΔH s,of individual energetic materials. In this relatio...The paper specifies an unambiguous basic relationship between the published results of ab initio calculations of lattice energies, E L,and heats of sublimation, ΔH s,of individual energetic materials. In this relationship,the ΔH s value has been replaced by heats of fusion, ΔH m,tr . Thereby its unambiguity has been lost,and the similarity of details of molecular structure begins to be of decisive importance. The resulting partial relationships,together with the basic relationship,have been used for prediction of ΔH s,and ΔH m,tr values of technically attractive polynitro compounds.展开更多
Based on the thermodynamical principle the new formula for calculation of heat of fusion and its error have been derived from binary phase diagrams which could be classified to eutectic,solid solution,degenerate eutec...Based on the thermodynamical principle the new formula for calculation of heat of fusion and its error have been derived from binary phase diagrams which could be classified to eutectic,solid solution,degenerate eutectic and involving a compound phase diagram and so on.Using these formulae heats of fusion of some rare earth ox- ides have been predicted.展开更多
The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density meas...The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density measurement techniques. According to Starkweatber' s method crystalline density ρ_c and amorphous density ρ_a were estimated to be 1.098 and 1.003 g/cm^3 respectively by extrapolating the straight lines of the IR absorbanee against density to zero intensity. Owing to the less intense in absorbance and less sensitive to the change in crystallinity of the amorphors band the thus obtained ρ_c was too low in value. Thereby the value of the ratio ρ_c /ρ_a is far less than generally accepted mean value for most crystalline polymers. Accordingly, traditional X-ray diffraction method was used through determining thc crystalline dimension(a=4.9, b=5.4, c=27.8, α=49° β=77.0°, γ=63.5°), and a rather correct value of ρ_c or the crystal density 1.13 g/cm^3 was obtained. The equilibrium heat of fusion △H_m^0 was estimated to be 244.0 J/g piotting △H_m 's of specimens with different crystallinity against their corre sponding specific volumes_(sp), and extrapolating to completely crystalline condition (_(sp)~c= 1/ρ_c) As to the equilibrium melting temperature T_m^0, because of the easiness of recrystallization of melt crystallized Nylon 1010 specimen, the well-known Hoffman's T_m-T_c method failed in determining this value and an usually rarely used Kamide double extrapolation method was adopted. The so obtained value of T_m^0 487 seems to be fairly reasonable.展开更多
On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle class...On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.展开更多
随着航空航天工业的快速发展,人们对高性能耐热铝合金的需求逐渐增加。为了实现复杂构件的一体化成型,激光粉末床熔融(Laser powder bed fusion,L-PBF)增材制造技术成为目前的研究热点。相比传统铸造成型,采用激光粉末床熔融增材制造的...随着航空航天工业的快速发展,人们对高性能耐热铝合金的需求逐渐增加。为了实现复杂构件的一体化成型,激光粉末床熔融(Laser powder bed fusion,L-PBF)增材制造技术成为目前的研究热点。相比传统铸造成型,采用激光粉末床熔融增材制造的构件具有更优异的综合性能。目前,对L-PBF增材制造传统高强韧铝合金已开展较为深入的研究,而针对耐热铝合金的研究还处于起步阶段。本综述首先介绍了激光粉末床熔融增材制造技术的特点,随后总结了近年来针对耐热铝合金体系及相应高温性能的研究,对目前存在的问题与难点进行了概括,最后对未来的主要研究方向进行了展望。展开更多
为解决核聚变发电热功率输出不稳定性和汽轮发电机组平稳运行之间的矛盾,中国聚变工程实验堆(China Fusion Engineering Test Reactor,CFETR)核聚变发电厂可运用储热技术对核聚变堆的功率输出进行削峰平谷。储热技术有多种类型,各类储...为解决核聚变发电热功率输出不稳定性和汽轮发电机组平稳运行之间的矛盾,中国聚变工程实验堆(China Fusion Engineering Test Reactor,CFETR)核聚变发电厂可运用储热技术对核聚变堆的功率输出进行削峰平谷。储热技术有多种类型,各类储热技术对于核聚变发电厂的适用性亟须进行对比。本文选取核聚变反应堆氦冷陶瓷增殖包层的参数作为储热技术边界条件,通过对储热技术适用温度范围进行评估,初步分析出有潜力运用于CFETR核聚变发电厂的三种储热技术,并对其进行成本初步预测。三大类储热技术均可选出适用CFETR核聚变发电厂氦冷增殖包层温度参数的储热介质。但化学储热由于其吸热和放热存在温差,不利于系统的稳定性及造成能量的损耗,显热储热技术和相变储热技术吸热温度和放热温度温差较小,具有应用于CFETR核聚变发电厂的潜力。初步经济性分析结果显示:相变储热成本最低,其次为熔融盐储热,再次为固相显热储热技术中利用硅砖作为储热介质,固相显热储热技术中利用铸钢作为储热介质成本最高。储热技术中,熔融盐储热技术、相变储热技术、固相显热储热具有应用于核聚变发电厂氦冷增殖包层的先决条件。熔融盐储热技术成熟度较高,有大量工程应用,造价在相变储热和固相显热储热之间,运用潜力较大。相变储热的成本最低,参数适用于核聚变发电,但其技术成熟度较低,有望成为未来研究的重点。展开更多
The resistance spot welding quality is always one of the key subjects for studying, to which many welding scholars at home and abroad devote themselves. It has not been solved satisfactorily at present. The complexity...The resistance spot welding quality is always one of the key subjects for studying, to which many welding scholars at home and abroad devote themselves. It has not been solved satisfactorily at present. The complexity of spot welding process, invisibility of nugget formation and singleness of control method decide that stabilizing quality is a rather difficult task. The limitations of describing how the nugget grows up based on single-sensor information source are analyzed. A control method based on multi-information fusion for the purpose of equivalent heating of each weld nugget during spot welding is put forward. The experiment results show that nugget size flactuations are within 8.3% -20% uacter constant current control, and are within 6. 3% - 11.1% under information fusion control.展开更多
文摘Water is the most abundant liquid on the surface of the earth. It is a liquid whose properties are quite surprising, both as a pure liquid and as a solvent. Water is a very cohesive liquid: its melting and vaporization temperatures are very high for a liquid that is neither ionic nor metallic, and whose molar mass is low. Thus, water remains liquid at atmospheric pressure up to 100C while similar molecules such as H2S, H2Se, H2Te for example would give a vaporization temperature close to 80C. This cohesion is in fact ensured by hydrogen bonds between water molecules. This type of bonds between neighboring molecules, hydrogen bonds, is quite often found in chemistry [1] [2]. Any change in the state of aggregation of a substance occurs with the absorption or release of a certain amount of latent heat of transformation. Latent heat of fusion, vaporization or sublimation is the ratio of the energy supplied as heat to the mass of the substance that is melted, vaporized or sublimated. As a result of the reversibility of the processes, the fusion heat is equal to the heat released in the reverse process: crystallization and solidification heat. And likewise the heat of vaporization is equal to the heat of condensation. This equality of heat is often used to determine experimentally either of these quantities. There are two main measurement methods: 1) Direct measurement using the calorimeter, 2) Indirect measure based on the use of the VantHoff relationship. The objective of this work is to measure the latent heat of water vaporization and verify the compatibility of the experimental values with the values given by the tables using the indirect method.
基金the project of the Ministry of Education,Youth and Sports of the Czech Republic,No.MSM 0021627501
文摘Fractions of β-HMX(β-1,3,5,7-tetranitro-1,3,5,7-tetrazocane) have been used to demonstrate the mutual relationship between friction and impact sensitivities.Inclusion of an additional twelve nitramines into this scenario resulted in a series of partial relationships,which were determined from the molecular structure of these substances.It was also found that there is a relation between increasing heats of fusion of the nitramines studied and their decreasing friction sensitivities.Comparison of friction sensitivity with heats of fusion,ΔHm,tr of the studied nitramines shows that the increase in ΔHm,tr values is more or less connected with a decrease in friction sensitivity.
文摘The paper specifies an unambiguous basic relationship between the published results of ab initio calculations of lattice energies, E L,and heats of sublimation, ΔH s,of individual energetic materials. In this relationship,the ΔH s value has been replaced by heats of fusion, ΔH m,tr . Thereby its unambiguity has been lost,and the similarity of details of molecular structure begins to be of decisive importance. The resulting partial relationships,together with the basic relationship,have been used for prediction of ΔH s,and ΔH m,tr values of technically attractive polynitro compounds.
文摘Based on the thermodynamical principle the new formula for calculation of heat of fusion and its error have been derived from binary phase diagrams which could be classified to eutectic,solid solution,degenerate eutectic and involving a compound phase diagram and so on.Using these formulae heats of fusion of some rare earth ox- ides have been predicted.
文摘The density, equilibrium heat of fusion and equilibrium melting temperature of Nylon 1010 were determined by means of infrared spectrum, differential scanning calorimetry, wide angle X-ray diffraction and density measurement techniques. According to Starkweatber' s method crystalline density ρ_c and amorphous density ρ_a were estimated to be 1.098 and 1.003 g/cm^3 respectively by extrapolating the straight lines of the IR absorbanee against density to zero intensity. Owing to the less intense in absorbance and less sensitive to the change in crystallinity of the amorphors band the thus obtained ρ_c was too low in value. Thereby the value of the ratio ρ_c /ρ_a is far less than generally accepted mean value for most crystalline polymers. Accordingly, traditional X-ray diffraction method was used through determining thc crystalline dimension(a=4.9, b=5.4, c=27.8, α=49° β=77.0°, γ=63.5°), and a rather correct value of ρ_c or the crystal density 1.13 g/cm^3 was obtained. The equilibrium heat of fusion △H_m^0 was estimated to be 244.0 J/g piotting △H_m 's of specimens with different crystallinity against their corre sponding specific volumes_(sp), and extrapolating to completely crystalline condition (_(sp)~c= 1/ρ_c) As to the equilibrium melting temperature T_m^0, because of the easiness of recrystallization of melt crystallized Nylon 1010 specimen, the well-known Hoffman's T_m-T_c method failed in determining this value and an usually rarely used Kamide double extrapolation method was adopted. The so obtained value of T_m^0 487 seems to be fairly reasonable.
文摘On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.
文摘随着航空航天工业的快速发展,人们对高性能耐热铝合金的需求逐渐增加。为了实现复杂构件的一体化成型,激光粉末床熔融(Laser powder bed fusion,L-PBF)增材制造技术成为目前的研究热点。相比传统铸造成型,采用激光粉末床熔融增材制造的构件具有更优异的综合性能。目前,对L-PBF增材制造传统高强韧铝合金已开展较为深入的研究,而针对耐热铝合金的研究还处于起步阶段。本综述首先介绍了激光粉末床熔融增材制造技术的特点,随后总结了近年来针对耐热铝合金体系及相应高温性能的研究,对目前存在的问题与难点进行了概括,最后对未来的主要研究方向进行了展望。
文摘为解决核聚变发电热功率输出不稳定性和汽轮发电机组平稳运行之间的矛盾,中国聚变工程实验堆(China Fusion Engineering Test Reactor,CFETR)核聚变发电厂可运用储热技术对核聚变堆的功率输出进行削峰平谷。储热技术有多种类型,各类储热技术对于核聚变发电厂的适用性亟须进行对比。本文选取核聚变反应堆氦冷陶瓷增殖包层的参数作为储热技术边界条件,通过对储热技术适用温度范围进行评估,初步分析出有潜力运用于CFETR核聚变发电厂的三种储热技术,并对其进行成本初步预测。三大类储热技术均可选出适用CFETR核聚变发电厂氦冷增殖包层温度参数的储热介质。但化学储热由于其吸热和放热存在温差,不利于系统的稳定性及造成能量的损耗,显热储热技术和相变储热技术吸热温度和放热温度温差较小,具有应用于CFETR核聚变发电厂的潜力。初步经济性分析结果显示:相变储热成本最低,其次为熔融盐储热,再次为固相显热储热技术中利用硅砖作为储热介质,固相显热储热技术中利用铸钢作为储热介质成本最高。储热技术中,熔融盐储热技术、相变储热技术、固相显热储热具有应用于核聚变发电厂氦冷增殖包层的先决条件。熔融盐储热技术成熟度较高,有大量工程应用,造价在相变储热和固相显热储热之间,运用潜力较大。相变储热的成本最低,参数适用于核聚变发电,但其技术成熟度较低,有望成为未来研究的重点。
基金This project is supported by Shenyang Key Science Foundation （No1041020-1-04）.
文摘The resistance spot welding quality is always one of the key subjects for studying, to which many welding scholars at home and abroad devote themselves. It has not been solved satisfactorily at present. The complexity of spot welding process, invisibility of nugget formation and singleness of control method decide that stabilizing quality is a rather difficult task. The limitations of describing how the nugget grows up based on single-sensor information source are analyzed. A control method based on multi-information fusion for the purpose of equivalent heating of each weld nugget during spot welding is put forward. The experiment results show that nugget size flactuations are within 8.3% -20% uacter constant current control, and are within 6. 3% - 11.1% under information fusion control.
