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Evaluation of slope stability through rock mass classification and kinematic analysis of some major slopes along NH-1A from Ramban to Banihal, North Western Himalayas
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作者 Amit Jaiswal A.K.Verma T.N.Singh 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期167-182,共16页
The network of Himalayan roadways and highways connects some remote regions of valleys or hill slopes,which is vital for India’s socio-economic growth.Due to natural and artificial factors,frequency of slope instabil... The network of Himalayan roadways and highways connects some remote regions of valleys or hill slopes,which is vital for India’s socio-economic growth.Due to natural and artificial factors,frequency of slope instabilities along the networks has been increasing over last few decades.Assessment of stability of natural and artificial slopes due to construction of these connecting road networks is significant in safely executing these roads throughout the year.Several rock mass classification methods are generally used to assess the strength and deformability of rock mass.This study assesses slope stability along the NH-1A of Ramban district of North Western Himalayas.Various structurally and non-structurally controlled rock mass classification systems have been applied to assess the stability conditions of 14 slopes.For evaluating the stability of these slopes,kinematic analysis was performed along with geological strength index(GSI),rock mass rating(RMR),continuous slope mass rating(CoSMR),slope mass rating(SMR),and Q-slope in the present study.The SMR gives three slopes as completely unstable while CoSMR suggests four slopes as completely unstable.The stability of all slopes was also analyzed using a design chart under dynamic and static conditions by slope stability rating(SSR)for the factor of safety(FoS)of 1.2 and 1 respectively.Q-slope with probability of failure(PoF)1%gives two slopes as stable slopes.Stable slope angle has been determined based on the Q-slope safe angle equation and SSR design chart based on the FoS.The value ranges given by different empirical classifications were RMR(37-74),GSI(27.3-58.5),SMR(11-59),and CoSMR(3.39-74.56).Good relationship was found among RMR&SSR and RMR&GSI with correlation coefficient(R 2)value of 0.815 and 0.6866,respectively.Lastly,a comparative stability of all these slopes based on the above classification has been performed to identify the most critical slope along this road. 展开更多
关键词 Rock mass classification Kinematic analysis Slope stability Himalayan road Static and dynamic conditions
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A method for establishing a bearing residual life prediction model for process enhancement equipment based on rotor imbalance response analysis
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作者 Feng Wang Haoran Li +3 位作者 Zhenghui Zhang Yan Bai Hong Yin Jing Bian 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期203-215,共13页
A rotating packed bed is a typical chemical process enhancement equipment that can strengthen micromixing and mass transfer.During the operation of the rotating packed bed,the nonreactants and products irregularly adh... A rotating packed bed is a typical chemical process enhancement equipment that can strengthen micromixing and mass transfer.During the operation of the rotating packed bed,the nonreactants and products irregularly adhere to the wire mesh packing in the rotor,thus resulting in an imbalance in the vibration of the rotor,which may cause serious damage to the bearing and material leakage.This study proposes a model prediction for estimating the bearing residual life of a rotating packed bed based on rotor imbalance response analysis.This method is used to determine the influence of the mass on the imbalance in the vibration of the rotor on bearing damage.The major influence on rotor vibration was found to be exerted by the imbalanced mass and its distribution radius,as revealed by the results of orthogonal experiments.Through implementing finite element analysis,the imbalance response curve for the rotating packed bed rotor was obtained,and a correlation among rotor imbalance mass,distribution radius of imbalance mass,and bearing residue life was established via data fitting.The predicted value of the bearing life can be used as the reference basis for an early safety warning of a rotating packed bed to effectively avoid accidents. 展开更多
关键词 Rotating packed bed mass imbalance Harmonic response analysis Residual life Prediction model
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A Simplified Method for the Stress Analysis of Underground Transfer Structures Crossing Multiple Subway Tunnels
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作者 Shen Yan Dajiang Geng +2 位作者 Ning Dai Mingjian Long Zhicheng Bai 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第6期2893-2915,共23页
According to the design specifications,the construction of extended piles involves traversing the tunnel’s upper region and extending to the underlying rock layer.To address this challenge,a subterranean transfer str... According to the design specifications,the construction of extended piles involves traversing the tunnel’s upper region and extending to the underlying rock layer.To address this challenge,a subterranean transfer structure spanning multiple subway tunnels was proposed.Deliberating on the function of piles in the transfer structure as springs with axial and bending stiffness,and taking into account the force balance and deformation coordination conditions of beams and plates within the transfer structure,we established a simplified mechanical model that incorporates soil stratification by combining it with the Winkler elastic foundation beam model.The resolved established simplifiedmechanicalmodel employed finite difference technology and the Newton-Simpsonmethod,elucidating the mechanical mechanism of the transfer structure.The research findings suggest that the load carried by the upper structural columns can be transferred to the pile foundation beneath the beams through the transfer structure,subsequently reaching the deep soil layer and ensuring minimal impact on adjacent tunnels.The established simplified analysis method can be used for stress analysis of the transfer structure,concurrently considering soil stratification,pile foundation behavior,and plate action.The pile length,pile section size,and beam section size within the transfer structure should account for the characteristics of the upper load,ensuring an even distribution of the beam bending moment. 展开更多
关键词 Crossing tunnels transfer structure force mechanism simplify analysis layered soil mass
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Online pharmaceutical process analysis of Chinese medicine using a miniature mass spectrometer: Extraction of active ingredients as an example
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作者 Wangmin Hu Junling Hou +4 位作者 Wenjing Liu Xuan Gu Yulei Yang Hongcai Shang Mei Zhang 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2023年第5期535-543,共9页
The automation of traditional Chinese medicine(TCM)pharmaceuticals has driven the development of process analysis from offline to online.Most of common online process analytical technologies are based on spectroscopy,... The automation of traditional Chinese medicine(TCM)pharmaceuticals has driven the development of process analysis from offline to online.Most of common online process analytical technologies are based on spectroscopy,making the identification and quantification of specific ingredients still a challenge.Herein,we developed a quality control(QC)system for monitoring TCM pharmaceuticals based on paper spray ionization miniature mass spectrometry(mini-MS).It enabled real-time online qualitative and quantitative detection of target ingredients in herbal extracts using mini-MS without chromatographic separation for the first time.Dynamic changes of alkaloids in Aconiti Lateralis Radix Praeparata(Fuzi)during decoction were used as examples,and the scientific principle of Fuzi compatibility was also investigated.Finally,the system was verified to work stably at the hourly level for pilot-scale extraction.This mini-MS based online analytical system is expected to be further developed for QC applications in a wider range of pharmaceutical processes. 展开更多
关键词 Process analytical technology TCM Pharmaceuticals Miniature mass spectrometry Online analysis
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Fuzzy cluster analysis of water mass in the western Taiwan Strait in spring 2019
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作者 Zhiyuan Hu Jia Zhu +4 位作者 Longqi Yang Zhenyu Sun Xin Guo Zhaozhang Chen Linfeng Huang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第12期1-8,共8页
The classification of the springtime water mass has an important influence on the hydrography,regional climate change and fishery in the Taiwan Strait.Based on 58 stations of CTD profiling data collected in the wester... The classification of the springtime water mass has an important influence on the hydrography,regional climate change and fishery in the Taiwan Strait.Based on 58 stations of CTD profiling data collected in the western and southwestern Taiwan Strait during the spring cruise of 2019,we analyze the spatial distributions of temperature(T)and salinity(S)in the investigation area.Then by using the fuzzy cluster method combined with the T-S similarity number,we classify the investigation area into 5 water masses:the Minzhe Coastal Water(MZCW),the Taiwan Strait Mixed Water(TSMW),the South China Sea Surface Water(SCSSW),the South China Sea Subsurface Water(SCSUW)and the Kuroshio Branch Water(KBW).The MZCW appears in the near surface layer along the western coast of Taiwan Strait,showing low-salinity(<32.0)tongues near the Minjiang River Estuary and the Xiamen Bay mouth.The TSMW covers most upper layer of the investigation area.The SCSSW is mainly distributed in the upper layer of the southwestern Taiwan Strait,beneath which is the SCSUW.The KBW is a high temperature(core value of 26.36℃)and high salinity(core value of 34.62)water mass located southeast of the Taiwan Bank and partially in the central Taiwan Strait. 展开更多
关键词 water mass classification western Taiwan Strait fuzzy cluster analysis T-S similarity number
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基于GC-IMS和GC-MS技术结合化学计量法分析干燥方式对香椿挥发性成分的影响
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作者 张乐 魏依馨 +5 位作者 史冠莹 蒋鹏飞 赵丽丽 王继红 张少南 王赵改 《食品工业科技》 CAS 北大核心 2024年第11期222-234,共13页
为研究干燥方式对香椿挥发性风味物质的影响,利用气相色谱-离子迁移谱技术(gaschromatography-ion mobility spectrometry,GC-IMS)和气相色谱-质谱联用技术(gas chromatography-mass spectrometry,GC-MS)、相对香气活性值(relative odor... 为研究干燥方式对香椿挥发性风味物质的影响,利用气相色谱-离子迁移谱技术(gaschromatography-ion mobility spectrometry,GC-IMS)和气相色谱-质谱联用技术(gas chromatography-mass spectrometry,GC-MS)、相对香气活性值(relative odor activity value,ROAV)对真空冷冻干燥、热泵干燥、热风干燥、微波真空干燥的香椿样品进行挥发性成分分析,并进一步结合化学计量方法主成分分析(principal component analysis,PCA)和偏最小二乘判别分析(partial least squares-discriminant analysis,PLS-DA),探究样品间挥发性成分的差异性。结果表明,通过GC-IMS检测到78个峰,鉴定出59种化合物。通过GC-MS鉴定出94种挥发性化合物,主要挥发性成分是硫化物、烯烃类和醛类。经过干燥后总挥发性化合物的含量显著降低。通过ROAV法确定了(E,Z)-二-1-丙烯基二硫化物、2-巯基-3,4-二甲基-2,3-二氢噻吩、正己醛、2-己烯醛、丁香酚等为香椿样品中关键香气化合物。PCA和PLS-DA结果表明,不同干燥方式的样品与新鲜样品有明显的分离,彼此之间也有明显的区别。鲜样和真空冷冻干燥样品为一组,其他3个干燥香椿样品为一组。根据变量投影重要性(variable importance in projection,VIP)得分共筛选出10种(VIP>1)标志挥发性化合物。干燥方式对香椿风味特性影响显著,真空冷冻干燥组与鲜样最为接近,考虑实际应用热泵干燥为香椿最适宜的脱水方式。本研究为热加工过程中风味品质控制提供一定的理论参考。 展开更多
关键词 香椿 干燥方式 气相色谱-离子迁移谱(gc-IMS) 气相色谱-质谱联用技术(gc-MS) 挥发性化合物
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GC-MS结合电子鼻技术对不同茶区茉莉花茶香气的差异比较
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作者 李璐 尹礼国 +4 位作者 陆安霞 王秋卫 陈丽 赵先明 黄彤 《现代食品科技》 CAS 北大核心 2024年第2期302-311,共10页
为探究不同产区茉莉花茶香气差异,采用气相色谱-质谱(GasChromatography-Mass Spectrometry,GC-MS)结合电子鼻(Electronic Nose,E-nose)技术对西南、华南、江南三大茶区的8种茉莉花茶进行香气研究。结果表明,8个样品共鉴定出香气成分58... 为探究不同产区茉莉花茶香气差异,采用气相色谱-质谱(GasChromatography-Mass Spectrometry,GC-MS)结合电子鼻(Electronic Nose,E-nose)技术对西南、华南、江南三大茶区的8种茉莉花茶进行香气研究。结果表明,8个样品共鉴定出香气成分58种,其中西南、江南、华南茶区分别为45种、51种、47种。江南茶区香气化合物总量最高。共有香气成分主要包括邻氨基苯甲酸甲酯、顺式-3-己烯醇苯甲酸酯、乙酸苄酯、水杨酸甲酯、芳樟醇、吲哚等。其中水杨酸甲酯在江南茶区含量最高(22.32μg/g),分别较华南、西南茶区高33.96%、68.01%;邻氨基苯甲酸甲酯(67.39μg/g)和吲哚(43.84μg/g)含量在华南茶区最高。茉莉花茶香气评价指数(JasmineTea Flavor Index,JTF index)分析表明西南茶区样品等级最高。香气聚类分析将共有香气成分分为3类,分别呈花香、茉莉花香和草木香。通过电子鼻技术可知样品香气物质变化与硫化物、碳氢化合物、芳香化合物有关,并能有效区别样品香气。综上,三大茶区样品香气种类差异不明显,但各香气成分含量差异显著(P<0.05),江南和华南茶区的样品特征性香气成分含量较高,西南茶区样品综合指数高。 展开更多
关键词 香气 茉莉花茶 气相色谱-质谱法(gc-MS) 电子鼻 茉莉花茶香气评价指数(JTF index)
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Multiscale hierarchical analysis of rock mass and prediction of its mechanical and hydraulic properties 被引量:8
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作者 Xiaoli Liu Guofeng Han +2 位作者 Enzhi Wang Sijing Wang Kumar Nawnit 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2018年第4期694-702,共9页
Engineering geological and hydro-geological characteristics of foundation rock and surrounding rock mass are the main factors that affect the stability of underground engineering. This paper presents the concept of mu... Engineering geological and hydro-geological characteristics of foundation rock and surrounding rock mass are the main factors that affect the stability of underground engineering. This paper presents the concept of multiscale hierarchical digital rock mass models to describe the rock mass, including its structures in different scales and corresponding scale dependence. Four scales including regional scale,engineering scale, laboratory scale and microscale are determined, and the corresponding scaledependent geological structures and their characterization methods are provided. Image analysis and processing method, geostatistics and Monte Carlo simulation technique are used to establish the multiscale hierarchical digital rock mass models, in which the main micro-and macro-structures of rock mass in different geological units and scales are reflected and connected. A computer code is developed for numerically analyzing the strength, fracture behavior and hydraulic conductivity of rock mass using the multiscale hierarchical digital models. Using the models and methods provided in this paper, the geological information of rock mass in different geological units and scales can be considered sufficiently,and the influence of downscale characteristics(such as meso-scale) on the upscale characteristics(such as engineering scale) can be calculated by considering the discrete geological structures in the downscale model as equivalent continuous media in the upscale model. Thus the mechanical and hydraulic properties of rock mass may be evaluated rationally and precisely. The multiscale hierarchical digital rock mass models and the corresponding methods proposed in this paper provide a unified and simple solution for determining the mechanical and hydraulic properties of rock mass in different scales. 展开更多
关键词 Multiscale hierarchical digital rock mass MODELS Numerical analysis Evaluation of rock mass quality
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GC-MS analysis of volatile compounds of Perilla frutescens Britton var. Japonica accessions: morphological and seasonal variability 被引量:6
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作者 Bimal Kumar Ghimire Ji Hye Yoo +1 位作者 Chang Yeon Yu Ill-Min Chung 《Asian Pacific Journal of Tropical Medicine》 SCIE CAS 2017年第7期705-714,共10页
Objective: To investigate the composition of volatile compounds in the different accessions of Perilla frutescens(P. frutescens) collected from various habitats of China and Japan. Methods: In the present study, the e... Objective: To investigate the composition of volatile compounds in the different accessions of Perilla frutescens(P. frutescens) collected from various habitats of China and Japan. Methods: In the present study, the essential oil from the leaves of P. frutescens cultivars from China and Japan was extracted by hydro-distillation and the chemical composition and concentration of the volatile components present in the oils were determined by gas chromatography–mass spectrometry(GC–MS) analysis. Results: Among the volatile components, the major proportion was of perilla ketone, which was followed by elemicin and beta-caryophyllene in the Chinese Perilla cultivars. The main component in the oil extracted from the Japanese accessions was myristicin, which was followed by perilla ketone and beta-caryophyllene. We could distinguish seven chemotypes, namely the perilla ketone(PK) type, perilla ketone, myristicin(PM) type, perilla ketone, unknown(PU) type, perilla ketone, beta-caryophyllene, myristicine(PB) type, perilla ketone, myristicin, unknown(PMU) type, perilla ketone, elemicine, myristicin, beta-caryophyllene(PEMB) type, and the perilla ketone, limonene, betacryophyllene, myristicin(L) type. Most of the accessions possessed higher essential oil content before the flowering time than at the flowering stage. The average plant height, leaf length, leaf width of the Chinese accessions was higher than those of the Japanese accessions. Conclusion:The results revealed that the harvest time and geographical origin caused polymorphisms in the essential oil composition and morphological traits in the Perilla accessions originating from China and Japan. Therefore, these chemotypes with desirable characters might be useful for industrial exploitation and for determining the harvest time. 展开更多
关键词 Perilla frutescens Essential oil gc–MS analysis Morphological character Harvesting time
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Volumetric analysis of rock mass instability around haulage drifts in underground mines 被引量:3
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作者 Shahé Shnorhokian Bryce MacNeil Hani S.Mitri 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2018年第1期60-71,共12页
Haulage networks are vital to underground mining operations as they constitute the arteries through which blasted ore is transported to surface. In the sublevel stoping method and its variations, haulage drifts are ex... Haulage networks are vital to underground mining operations as they constitute the arteries through which blasted ore is transported to surface. In the sublevel stoping method and its variations, haulage drifts are excavated in advance near the ore block that will be mined out. Numerical modeling is a technique that is frequently employed to assess the redistribution of mining-induced stresses, and to compare the impact of different stope sequence scenarios on haulage network stability. In this study,typical geological settings in the Canadian Shield were replicated in a numerical model with a steeplydipping tabular orebody striking EW. All other formations trended in the same direction except for two dykes on either side of the orebody with a WNW-ESE strike. Rock mass properties and in situ stress measurements from a case study mine were used to calibrate the model. Drifts and crosscuts were excavated in the footwall and two stope sequence scenarios-a diminishing pillar and a center-out one-were implemented in 24 mining stages. A combined volumetric-numerical analysis was conducted for two active levels by comparing the extent of unstable rock mass at each stage using shear,compressive, and tensile instability criteria. Comparisons were made between the orebody and the host rock, between the footwall and hanging wall, and between the two stope sequence scenarios. It was determined that in general, the center-out option provided a larger volume of instability with the shear criterion when compared to the diminishing pillar one(625,477 m~3 compared to 586,774 m~3 in the orebody; 588 m~3 compared to 403 m~3 in the host rock). However, the reverse was true for tensile(134,298 m~3 compared to 128,834 m~3 in the orebody; 91,347 m~3 compared to 67,655 m~3 in the host rock)instability where the diminishing pillar option had the more voluminous share. 展开更多
关键词 Haulage drifts Rock mass instability Volumetric analysis Stope sequences Numerical modeling
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The cluster analysis of the water masses in western Taiwan Strait from hydrologic And chemical factors 被引量:2
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作者 Huang Ziqiang and Ji Weidong (Third Institute of Oceanography, State Oceanic Administration, Xiamen 361005, China) 《Acta Oceanologica Sinica》 SCIE CAS CSCD 1994年第4期501-518,共18页
On the basis of mixture theory of concentration of Helland-Hansen (Mao et al, 1964; Helland-Hansen, 1916), this paper takes salinity as a conservative factor in the process of dilution and mixture and selects by relat... On the basis of mixture theory of concentration of Helland-Hansen (Mao et al, 1964; Helland-Hansen, 1916), this paper takes salinity as a conservative factor in the process of dilution and mixture and selects by relating analysis the bydrological and chemical factors which are closely related to salinity. Then making use of the Q type multi-dimensions cluster analysis, we get the results that the water masses in the western Taiwan Strait include the follying: the coastal water along Fujian, Zhejiang and Guangdong Provinces, the diluted fresh water of Minjiang, Jiulong and Hanjiang Rivers; the mixing water in the Taiwan Strait; upwelling cold/warm water to the northwest of the Taiwan Shoal and the upwelling water to the east of Guangdong. The mixing weter in the Taiwan Strait during spring and summer is composed of a Kuroshio branch, the surface weter of the South China Sea, outal wier along Fujian, Zhejiang and Guangdong Provinces. While in autunm and winter, it is mixed up from Kuroshio branch, the shelf weter in the East China Sea, and the coastal water along Fujian, Zhejiang and Guangdong. There is an obvious seasonal change of growth and decline in these water masses. 展开更多
关键词 The western Taiwan Strait water mass correlation analysis cluster analysis
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基于HS-GC-IMS分析爆珠香精挥发性风味成分差异
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作者 金强 孙学锋 +4 位作者 唐伟 胡玉轩 罗亮 陆飞 廖惠云 《分析测试学报》 CAS CSCD 北大核心 2024年第4期574-581,共8页
采用顶空气相色谱-离子迁移谱(HS-GC-IMS)技术,对不同清新玫瑰爆珠样品中的香精挥发性成分进行鉴定,并通过感官评价,结合主成分分析(PCA)、偏最小二乘判别分析(PLS-DA)、偏最小二乘回归法(PLSR)等多元统计方法识别判定不同样品的主要风... 采用顶空气相色谱-离子迁移谱(HS-GC-IMS)技术,对不同清新玫瑰爆珠样品中的香精挥发性成分进行鉴定,并通过感官评价,结合主成分分析(PCA)、偏最小二乘判别分析(PLS-DA)、偏最小二乘回归法(PLSR)等多元统计方法识别判定不同样品的主要风味成分差异。结果表明:①感官评价显示该爆珠样品风格特征主要以花香、果香、木香为主,并辅以青香、甜香与酒香香韵,不同样品在花香、果香属性上呈显著差异(p<0.05);②GC-IMS非靶向定性出样品中22种主要的挥发性风味组分,其中醇类8种、酯类3种、酮类3种、醛类3种、烯烃类3种、酸类1种、吡嗪类1种,且指纹图谱直观显示出挥发性较强的醇类、酯类等香气化合物在样品间差异明显;③PCA、PLS-DA能对不同样品进行有效区别,并筛选出10个特征差异组分(VIP>1),PLSR得出样品感官差异主要与2-甲基丁酸乙酯、丁酸乙酯、环己酮、苯乙酮、辛醛、正丙醇和芳樟醇有关。该方法可有效区分不同清新玫瑰爆珠样品,其判定结果与感官评价结果一致,具有准确可靠、可视化强等特点,能够为烟用爆珠产品感官质量快速检验提供技术支持。 展开更多
关键词 烟草 爆珠 气相色谱-离子迁移谱 风味 分析
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GC-MS结合化学计量学方法分析桂花净油分子蒸馏馏分的挥发性成分 被引量:1
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作者 郭智鑫 郝丹丹 +5 位作者 卞建明 谢秋涛 孙亚丽 汪凯 李高阳 朱向荣 《食品工业科技》 CAS 北大核心 2024年第7期276-285,共10页
为了探究分子蒸馏技术纯化桂花净油的不同馏分挥发性成分与香气差异,采用气相色谱-质谱(Gas chromatography-mass spectrometry,GC-MS)结合化学计量学方法中的正交偏最小二乘判别分析法(Orthogonal partial least-squares discriminatio... 为了探究分子蒸馏技术纯化桂花净油的不同馏分挥发性成分与香气差异,采用气相色谱-质谱(Gas chromatography-mass spectrometry,GC-MS)结合化学计量学方法中的正交偏最小二乘判别分析法(Orthogonal partial least-squares discrimination analysis,OPLS-DA)、P-value与变量投影重要性(Variableimportant in the projection,VIP)与相对气味活度值(Relative odor activity value,ROAV)对桂花净油的轻组分、重组分和残留物组分挥发性成分进行分析。结果表明:三种馏分中共检测到8大类挥发性成分共73种,其中醇类22种、醛类5种、酸类10种、酚类3种、酮类5种、酯类17种、烷烃类5种、烯萜类6种。各馏分中醇类物质的种类与相对含量最高,是桂花净油挥发性成分的主要贡献物质,且各馏分的挥发性成分种类与相对含量具有显著性差异(P<0.05);建立的三种馏分挥发性成分判别模型,分类准确率为98.2%;并在分析确定出三种馏分27种差异性挥发物成分(VIP>1)后,对轻组分14种、重组分9种和残留物组分11种的关键香气贡献成分(ROAV>1)进行香气轮廓分析,轻组分与重组分、残留组分相比,表现出的花香味、甜味以及松木香味更为强烈。轻组分的挥发性成分种类与相对含量最多,香气特征中的桂花花香味最为浓郁强烈。本研究采用GC-MS结合化学计量学方法分析桂花净油各馏分挥发性成分差异与香气特征,为桂花净油分子蒸馏各馏分综合利用提供理论依据。 展开更多
关键词 分子蒸馏技术 桂花净油 化学计量学方法 气质分析 挥发性成分
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基于GC-IMS技术分析五种市售不同工艺油莎豆油理化品质与风味差异 被引量:1
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作者 牛志雅 王亚杰 +3 位作者 张高虔 万一来 刘文玉 魏长庆 《食品工业科技》 CAS 北大核心 2024年第1期258-267,共10页
为研究市售不同工艺油莎豆油理化品质与风味的差异性,采用气相离子迁移谱(Gas Chromatography-Ion Mobility Spectroscopy,GC-IMS)技术结合主成分分析法对比不同工艺(物理压榨、热榨、亚临界萃取、高压冷榨和冷榨工艺)油莎豆油挥发性化... 为研究市售不同工艺油莎豆油理化品质与风味的差异性,采用气相离子迁移谱(Gas Chromatography-Ion Mobility Spectroscopy,GC-IMS)技术结合主成分分析法对比不同工艺(物理压榨、热榨、亚临界萃取、高压冷榨和冷榨工艺)油莎豆油挥发性化合物之间的差异性。GC-IMS结果显示,不同工艺油莎豆油中共鉴定出76种挥发性化合物,其中包括酯类12种、醇类16种、醛类29种、酮类9种、酸类5种、呋喃类3种、吡嗪类1种、硫类1种。热榨组醛类、酯类和呋喃类物质相对含量较高(53.54%,13.06%,5.41%)。不同工艺油莎豆油风味差异性主要来源于四种关键风味物质:1-烯-3-辛醇、壬醛、(E)-2-辛烯醛和己醛。主成分分析(Principal Component Analysis,PCA)结果表明PC1和PC2分别为48.7%和30.1%,累计差异贡献率为78.8%,不同工艺油莎豆油风味物质差异显著,能够对不同工艺油莎豆油良好区分。Pearson相关性分析结果表明不同工艺油莎豆油b*值与酸价、过氧化值、p-丙二醛值和1-烯-3-辛醇之间呈显著正相关(0.57<r<0.88,P<0.05)。本研究结对市售油莎豆油生产加工、理论研究和质量检测等领域具有一定的参考价值。 展开更多
关键词 气相色谱-离子迁移谱(gc-IMS) 油莎豆油 不同工艺 挥发性化合物 主成分分析(PCA)
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Displacement-based back analysis of mitigating the effects of displacement loss in underground engineering
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作者 Hui Li Weizhong Chen Xianjun Tan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第10期2626-2638,共13页
Displacement-monitoring-based back analysis is a popular method for geomechanical parameter estimation.However,due to the delayed installation of multi-point extensometers,the monitoring curve is only a part of the ov... Displacement-monitoring-based back analysis is a popular method for geomechanical parameter estimation.However,due to the delayed installation of multi-point extensometers,the monitoring curve is only a part of the overall one,leading to displacement loss.Besides,the monitoring and construction time on the monitoring curve is difficult to determine.In the literature,the final displacement was selected for the back analysis,which could induce unreliable results.In this paper,a displacement-based back analysis method to mitigate the influence of displacement loss is developed.A robust hybrid optimization algorithm is proposed as a substitute for time-consuming numerical simulation.It integrates the strengths of the nonlinear mapping and prediction capability of the support vector machine(SVM)algorithm,the global searching and optimization characteristics of the optimized particle swarm optimization(OPSO)algorithm,and the nonlinear numerical simulation capability of ABAQUS.To avoid being trapped in the local optimum and to improve the efficiency of optimization,the standard PSO algorithm is improved and is compared with other three algorithms(genetic algorithm(GA),simulated annealing(SA),and standard PSO).The results indicate the superiority of OPSO algorithm.Finally,the hybrid optimization algorithm is applied to an engineering project.The back-analyzed parameters are submitted to numerical analysis,and comparison between the calculated and monitoring displacement curve shows that this hybrid algorithm can offer a reasonable reference for geomechanical parameters estimation. 展开更多
关键词 Rock mass Intelligent back analysis Geomechanical parameters Displacement loss Underground engineering
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Statistical analysis on the influence of mechanical parameters in the vibration of pylons
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作者 Georgios I.Dadoulis George D.Manolis 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2023年第1期263-278,共16页
We present a statistical investigation of the degree of influence that assumptions made in relation to the mechanical parameters of a pylon have on its ground-induced vibrations.The study is set up by using as a key k... We present a statistical investigation of the degree of influence that assumptions made in relation to the mechanical parameters of a pylon have on its ground-induced vibrations.The study is set up by using as a key kinematic variable the displacement at the top of a reference,a stand-alone pylon with a uniform cross-section and fixity at its base.Next,statistics are produced using a dimensionless displacement ratio defined between the‘parental’and the‘subsidiary’cases,the latter defined for the pylon(a)resting on compliant soil,(b)having an attached top mass,and(c)being non-uniform with height.Furthermore,two materials are examined,namely,steel and reinforced concrete(R/C).More specifically,this displacement ratio is independent of the excitation and plays the role of a transfer function between the base and the top of the pylon.Both horizontal and vertical motions are considered,and the equations of motion are solved in the frequency domain.The ensuing statistical analysis is conducted for the following parameter combinations:(a)pylon founded on soft,intermediate,and stiff soil;(b)low,intermediate,and high-mass ratios of the attached mass to the pylon′s mass;(c)a constant and quadratic degree of pylon tapering with height.Spearman correlation coefficients are calculated for all the above combinations to arrive at statistical results that establish validity bounds and quantify the degree of influence of each assumption on the pylon′s response. 展开更多
关键词 pylons statistical analysis spearman coefficients structural vibrations elastic waveguides attached masses soil springs TAPERING
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Sequence Analysis of Polypeptide by Mass Spectrometry 被引量:1
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作者 YANG Hou-jun , LI Xiao-ling, HU Xiao-yu and CHEN Yao-zu (State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1993年第4期288-295,共8页
The method described in this work provides a sensitive and fast technique for investigating the primary structure of peptides with molecular weight up to 3340 amu. Usually, the metastable ion kinetic energy spectra (M... The method described in this work provides a sensitive and fast technique for investigating the primary structure of peptides with molecular weight up to 3340 amu. Usually, the metastable ion kinetic energy spectra (MIKES) and collisional activated decomposition (CAD) spectra provide complementary information for the FAB mass spectra, the MIKES and CAD spectra generally contain high-mass sequence ions. 展开更多
关键词 PEPTIDE Sequence analysis mass spectrometry.
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Computer Aided Mass Balance Analysis for AC Electric Arc Furnace Steelmaking 被引量:1
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作者 anal amdali Murat Tun 《Journal of Iron and Steel Research(International)》 SCIE CAS CSCD 2005年第3期11-13,共3页
A mass balance analysis was undertaken for liquid steel production using a computer program specially developed for the AC electric arc furnace at an important alloy steel producer in Turkey. The data obtained by usin... A mass balance analysis was undertaken for liquid steel production using a computer program specially developed for the AC electric arc furnace at an important alloy steel producer in Turkey. The data obtained by using the computer program were found to be very close to the actual production ones. 展开更多
关键词 electric arc furnace liquid steel mass balance analysis
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Analysis of the Material Properties of Vehicle Suspension Coil Spring
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作者 Issifu Imoro Jacob Kwaku Nkrumah +1 位作者 Baba Ziblim Abdul-Hamid Mohammed 《World Journal of Engineering and Technology》 2023年第4期827-858,共32页
The suspension coil spring is one of the most important components in a vehicle suspension system. Its primary function is to absorb the vibrational shocks that are occasioned by irregular road surface to provide the ... The suspension coil spring is one of the most important components in a vehicle suspension system. Its primary function is to absorb the vibrational shocks that are occasioned by irregular road surface to provide the vehicle with stability and ride comfort. The main objective of this study is to design a suspension coil spring made of structural steel for light duty vehicles with the aim of weight and cost reduction. This study was motivated by the government of Ghana’s actions to industrialise the automotive sector of the country through government policies and programs. The study made use of high carbon steel and low carbon steel as the control materials and structural steel as the implementing material. This was done to determine the suitability of structural steel for vehicle suspension coil spring. The study analysed parameters such as total deformation, equivalent Von Mises stress, maximum shear stress, and safety factor in the static structural analysis. The fatigue analysis also analysed parameters such as fatigue life and fatigue alternating stress. The results of the study revealed that the suspension spring made of structural steel has superior properties against all the parameters set for this study apart from deformation. The two control materials that are known for suspension coil spring design and manufacture have better properties to withstand deformation than the implementing material. 展开更多
关键词 Suspension Spring Unsprung mass Fatigue analysis Structural analysis Ride Comfort Vehicle Stability
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Simulation analysis of regional surface mass anomalies inversion based on different types of constraints 被引量:2
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作者 Bo Zhong Jiangtao Tan +2 位作者 Qiong Li Xianpao Li Tao Liu 《Geodesy and Geodynamics》 CSCD 2021年第4期298-307,共10页
Surface mass anomalies estimated by mass concentration(mascon)approach using Gravity Recovery and Climate Experiment(GRACE)observations with regularization constraints generally present higher spatial resolution than ... Surface mass anomalies estimated by mass concentration(mascon)approach using Gravity Recovery and Climate Experiment(GRACE)observations with regularization constraints generally present higher spatial resolution than the spheric harmonic(SH)solutions.To analyze the influence of different types of constraints on the estimation of mascon solutions,we carried out a closed-loop simulation experiment to estimate surface mass anomalies over South America based on simulated GRACE intersatellite geopotential differences.Tikhonov regularization with spatial constraint(SC),uniform weighting constraint(UWC),and a prior information constraint(APC)were employed to stabilize the mascon solutions,and the corresponding optimal regularization parameters were determined based on the minimum residual root-mean-square(RMS)criterion.The results show that mascon solutions estimated under different types of constraints are consistent and equivalent when the optimal regularization parameters are selected.The spatial distributions and main characteristics of regional surface mass anomalies estimated by the three types of constraints agree well,and the values of residual RMS with different constraints are very close.But due to the smoothing effect of regularization,the signal strength of mascon solutions is a bit weaker than that of original true signal,especially in the regions with strong signals.In addition,due to the ill-conditioned problem is more serious for higher grid resolution,the relative contribution of the three types of constraints to the final mascon solutions would be stronger.The results show that the averages of relative contribution percentages of these constraints for 2°×2° mascon grids are 80%-90%,while the corresponding values for 4°×4° mascon grids are 30%-60%.However,based on the minimum residual RMS criterion,the accuracy of estimation results is not affected by the type of constraints and their relative contribution to the final mascon solutions. 展开更多
关键词 Regional surface mass anomalies Regularization constraints Intersatellite geopotential differences GRACE mascon solutions Simulation analysis
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