Hot-dip galvanized sheet is wildly used in construction,household appliances,ship,vehicle and vessel building and machinery,etc.In last ten years,with the development of automobile industry,the anti-eorrosion requirem...Hot-dip galvanized sheet is wildly used in construction,household appliances,ship,vehicle and vessel building and machinery,etc.In last ten years,with the development of automobile industry,the anti-eorrosion requirements for car body are increasingly strict,by which the rapid development in technology has been promoted.The application of hot-dip galvanized sheet,technological progress in production and some Chinese large units were introduced.展开更多
China has become the maximum household appliances manufacturing base worldwide.It is a new challenge facing the steel industry to develop the low-cost and environment-friendly sheet for household appliance industry,so...China has become the maximum household appliances manufacturing base worldwide.It is a new challenge facing the steel industry to develop the low-cost and environment-friendly sheet for household appliance industry,so Cr-free anti-fingerprint hot-dip galvanized sheet for household appliances is the upgraded product which satisfies the requirement of China household appliance industry' s nuisanceless treatment.The paper discusses the technical key points of development on Cr-free anti-fingerprint galvanized sheet for household appliances,including the development of the Cr-free anti-fingerprint chemical and the production technology of Cr-free anti-fingerprint galvanized sheet for household appliances.The paper elaborates the main compositions,physical features and properties of the Cr-free anti-fingerprint chemical, surface quality control technology,anti-fingerprint coating quality control technology,influence of anti-fingerprint film weight on corrosion resistance,conductibility,high-temperature discolouration resistance,acid resistance,alkaline resistance and solvent resistance of Cr-free anti-fingerprint hot-dip galvanized sheet, influence of anti-fingerprint coating uniformity on paintability of the sheet,influence of strip surface roughness on corrosion resistance and conductivity of the sheet and influence of strip surface quality on corrosion resistance of the sheet.Adopting the suitable Cr-free anti-fingerprint chemical and the reasonable production process parameters,the properties of the Cr-free anti-fingerprint hot-dip galvanized sheet conform to the delivery technical norms and the Cr-free anti-fingerprint hot-dip galvanized sheet becomes the new material for household appliances such as computer case.展开更多
The process properties and interface behavior of CO_2 laser brazing with automatic wire feed for galvanized steel sheets were investigated, in which the brazing filler metal was CuSi3 and no flux was used. As to the a...The process properties and interface behavior of CO_2 laser brazing with automatic wire feed for galvanized steel sheets were investigated, in which the brazing filler metal was CuSi3 and no flux was used. As to the appearance quality of the brazing seams, the roles of the processing parameters, such as brazing speed, wire feeding rate, inclination and feeding direction of the wire, laser power, spot diameter and heating position, were assessed. The further investigation indicates that the behavior of the active elements Si, Mn and Zn are significantly influenced by energy input. At the interface, the microstructure of the base metal was composed of columnar crystals and the acicular α solid solution was found on the filler metal side.展开更多
Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication perform...Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication performance of the steel sheets were examined using a friction coefficient tester. Results revealed large dynamic friction coefficients for the galvanized steel sheets, which increased remarkably with surface roughness. Once the self-lubricated coating was applied, significant drops in the dynamic friction coefficients were measured. After the first stage of the friction test,the coefficients were almost unchanged, which reflected a weak dependence on the surface roughness of the self-lubricated steel sheets. However, the dynamic friction coefficients gradually increased as the test progressed, where these increase clearly correlated with the surface roughness of the self-lubricated steel sheets.展开更多
In recent years, the waterborne free intermediate coating process has been widely used in the automotive industry. Because the baking times and coating thickness are decreased, the surface covering capability of the p...In recent years, the waterborne free intermediate coating process has been widely used in the automotive industry. Because the baking times and coating thickness are decreased, the surface covering capability of the painting process is reduced, which directly affects the appearance quality（ long-and short-wave values） of the body paint. Thus, there are correspondingly higher requirements for the white body surface profile prior to painting. The surface profile of the white body is mainly affected by the plate material, the surface profile, and the deformation process. So,the change rule for the surface profile during deformation of the steel plate is a key factor in coating appearance optimization. In this paper, we first analyze the typical deformation of the outer cover of a car body. Then ,we examine the change tendency of the surface profile of steel plates with respect to different deformation rates, specifically for a steel plate comprising a hot-dip galvanized bake-hardened steel sheet. Based on our analysis of the influence of the deformation on the coating appearance,we selected 3% ,5% ,and 8% deformation rates in this research. We found the roughness （Ra） value in the typical deformation range （3% -8% ） of the car body to exhibit a decreasing trend at first and then an increasing trend. The Ra value of the 8% deformation is not more than the original plate test value. When the Pc value of the original plate is in the lower range （ about 60）, it exhibits a slight increasing trend in the deformation process （3 % -8 % ）. And when the Pc value of the original plate is in the higher range （ about 120 ）, it exhibits no increasing trend in the deformation process （ 3% -8% ）. In contrast,the waviness （WCA） value in the car body＇s typical deformation range （3%-8%） shows a significant growth trend.展开更多
An inorganic lubrication treatment for a galvanized steel sheet was developed to improve the press formability of automotive body panels. The properties and application of Baosteel＇s inorganic-lubricant-coated galvan...An inorganic lubrication treatment for a galvanized steel sheet was developed to improve the press formability of automotive body panels. The properties and application of Baosteel＇s inorganic-lubricant-coated galvanized steel sheet are demonstrated. Compared with galvanized steel sheets without the inorganic lubricant coating,the Baosteel inorganic-lubricant-coated galvanized steel sheet has a lower friction coefficient and excellent lubricating ability,more homogeneous tribological and stamping behaviors,lower sensitivity to stamping parameters,excellent spot weldability,good adhesivity,and perfect phosphate compatibility and paintability. These results verify that the Baosteel inorganic-lubricant-coated galvanized steel sheet has excellent press formability and a huge market application potential.展开更多
In this study,the factors affecting the formation of small black spot defects on the surface of a hot-dip galvanized pure zinc strip are analyzed. These defects are primarily formed w hen the iron-aluminum inhibition ...In this study,the factors affecting the formation of small black spot defects on the surface of a hot-dip galvanized pure zinc strip are analyzed. These defects are primarily formed w hen the iron-aluminum inhibition layer is incompletely formed or fails to form or when foreign matter adheres to the surface or embeds in the zinc layer.The defects can be reduced by controlling the cleanliness and activity of the strip base before coating,regulating the zinc pot process parameters,and ensuring the cleanliness of the passline and workshop.展开更多
A group of projection welding experiments and joints tension-shear tests are carried out for cold-rolled steel sheets, galvanized steel sheets (GSS) without treatment, GSS with phosphating and GSS with surface greasin...A group of projection welding experiments and joints tension-shear tests are carried out for cold-rolled steel sheets, galvanized steel sheets (GSS) without treatment, GSS with phosphating and GSS with surface greasing, respectively. The experimental results are regressively analyzed on the computers, then the projection welded joint tension-shear strength curve and the perfect welding currents range of each material are obtained. The results show that surface treatments of galvanized steels have effects on their spot weldabilities. Among the four kinds of materials, GSS with surface greasing have the worst spot weldability, for they need higher welding current and have a narrow welding current range.展开更多
Ultrasonic-assisted metal inert gas(U-MIG)welding experiments were performed to analyze the effect of Cu addition on the microstructure and mechanical properties of galvanized steel sheet welds,and first-principles ca...Ultrasonic-assisted metal inert gas(U-MIG)welding experiments were performed to analyze the effect of Cu addition on the microstructure and mechanical properties of galvanized steel sheet welds,and first-principles calculations were undertaken to predict the effect of Cu on the mechanical properties ofα-Fe based structures.As shown by scanning electron microscopy analysis,Cu is conducive to the refinement and uniformity of the microstructure in the weld zone.Energy-dispersive spectrometry data indicated the presence of Cu in the welds after welding with Cu powder.The elastic moduli of the welds without and with Cu powder,obtained from nanoindentation tests,were(217.66±5.11)GPa and(223.13±9.12)GPa,respectively,which were close to the calculated results.The mechanical properties of the crystal structures ofα-Fe andα-Fe_(1.9)Cu_(0.1)were calculated using Materials Studio software.Both the experimental and calculated results showed that Cu doping reduced the bulk modulus of the weld but increased its shear modulus.展开更多
基金Item Sponsored by National Natural Science Foundation of China(59995440)
文摘Hot-dip galvanized sheet is wildly used in construction,household appliances,ship,vehicle and vessel building and machinery,etc.In last ten years,with the development of automobile industry,the anti-eorrosion requirements for car body are increasingly strict,by which the rapid development in technology has been promoted.The application of hot-dip galvanized sheet,technological progress in production and some Chinese large units were introduced.
文摘China has become the maximum household appliances manufacturing base worldwide.It is a new challenge facing the steel industry to develop the low-cost and environment-friendly sheet for household appliance industry,so Cr-free anti-fingerprint hot-dip galvanized sheet for household appliances is the upgraded product which satisfies the requirement of China household appliance industry' s nuisanceless treatment.The paper discusses the technical key points of development on Cr-free anti-fingerprint galvanized sheet for household appliances,including the development of the Cr-free anti-fingerprint chemical and the production technology of Cr-free anti-fingerprint galvanized sheet for household appliances.The paper elaborates the main compositions,physical features and properties of the Cr-free anti-fingerprint chemical, surface quality control technology,anti-fingerprint coating quality control technology,influence of anti-fingerprint film weight on corrosion resistance,conductibility,high-temperature discolouration resistance,acid resistance,alkaline resistance and solvent resistance of Cr-free anti-fingerprint hot-dip galvanized sheet, influence of anti-fingerprint coating uniformity on paintability of the sheet,influence of strip surface roughness on corrosion resistance and conductivity of the sheet and influence of strip surface quality on corrosion resistance of the sheet.Adopting the suitable Cr-free anti-fingerprint chemical and the reasonable production process parameters,the properties of the Cr-free anti-fingerprint hot-dip galvanized sheet conform to the delivery technical norms and the Cr-free anti-fingerprint hot-dip galvanized sheet becomes the new material for household appliances such as computer case.
文摘The process properties and interface behavior of CO_2 laser brazing with automatic wire feed for galvanized steel sheets were investigated, in which the brazing filler metal was CuSi3 and no flux was used. As to the appearance quality of the brazing seams, the roles of the processing parameters, such as brazing speed, wire feeding rate, inclination and feeding direction of the wire, laser power, spot diameter and heating position, were assessed. The further investigation indicates that the behavior of the active elements Si, Mn and Zn are significantly influenced by energy input. At the interface, the microstructure of the base metal was composed of columnar crystals and the acicular α solid solution was found on the filler metal side.
文摘Four kinds of galvanized steel sheets having different surface roughness values were used to prepare the steel sheets with a self-lubricated coating. The effects of surface roughness on the surface lubrication performance of the steel sheets were examined using a friction coefficient tester. Results revealed large dynamic friction coefficients for the galvanized steel sheets, which increased remarkably with surface roughness. Once the self-lubricated coating was applied, significant drops in the dynamic friction coefficients were measured. After the first stage of the friction test,the coefficients were almost unchanged, which reflected a weak dependence on the surface roughness of the self-lubricated steel sheets. However, the dynamic friction coefficients gradually increased as the test progressed, where these increase clearly correlated with the surface roughness of the self-lubricated steel sheets.
文摘In recent years, the waterborne free intermediate coating process has been widely used in the automotive industry. Because the baking times and coating thickness are decreased, the surface covering capability of the painting process is reduced, which directly affects the appearance quality（ long-and short-wave values） of the body paint. Thus, there are correspondingly higher requirements for the white body surface profile prior to painting. The surface profile of the white body is mainly affected by the plate material, the surface profile, and the deformation process. So,the change rule for the surface profile during deformation of the steel plate is a key factor in coating appearance optimization. In this paper, we first analyze the typical deformation of the outer cover of a car body. Then ,we examine the change tendency of the surface profile of steel plates with respect to different deformation rates, specifically for a steel plate comprising a hot-dip galvanized bake-hardened steel sheet. Based on our analysis of the influence of the deformation on the coating appearance,we selected 3% ,5% ,and 8% deformation rates in this research. We found the roughness （Ra） value in the typical deformation range （3% -8% ） of the car body to exhibit a decreasing trend at first and then an increasing trend. The Ra value of the 8% deformation is not more than the original plate test value. When the Pc value of the original plate is in the lower range （ about 60）, it exhibits a slight increasing trend in the deformation process （3 % -8 % ）. And when the Pc value of the original plate is in the higher range （ about 120 ）, it exhibits no increasing trend in the deformation process （ 3% -8% ）. In contrast,the waviness （WCA） value in the car body＇s typical deformation range （3%-8%） shows a significant growth trend.
文摘An inorganic lubrication treatment for a galvanized steel sheet was developed to improve the press formability of automotive body panels. The properties and application of Baosteel＇s inorganic-lubricant-coated galvanized steel sheet are demonstrated. Compared with galvanized steel sheets without the inorganic lubricant coating,the Baosteel inorganic-lubricant-coated galvanized steel sheet has a lower friction coefficient and excellent lubricating ability,more homogeneous tribological and stamping behaviors,lower sensitivity to stamping parameters,excellent spot weldability,good adhesivity,and perfect phosphate compatibility and paintability. These results verify that the Baosteel inorganic-lubricant-coated galvanized steel sheet has excellent press formability and a huge market application potential.
文摘In this study,the factors affecting the formation of small black spot defects on the surface of a hot-dip galvanized pure zinc strip are analyzed. These defects are primarily formed w hen the iron-aluminum inhibition layer is incompletely formed or fails to form or when foreign matter adheres to the surface or embeds in the zinc layer.The defects can be reduced by controlling the cleanliness and activity of the strip base before coating,regulating the zinc pot process parameters,and ensuring the cleanliness of the passline and workshop.
文摘A group of projection welding experiments and joints tension-shear tests are carried out for cold-rolled steel sheets, galvanized steel sheets (GSS) without treatment, GSS with phosphating and GSS with surface greasing, respectively. The experimental results are regressively analyzed on the computers, then the projection welded joint tension-shear strength curve and the perfect welding currents range of each material are obtained. The results show that surface treatments of galvanized steels have effects on their spot weldabilities. Among the four kinds of materials, GSS with surface greasing have the worst spot weldability, for they need higher welding current and have a narrow welding current range.
基金the National Natural Science Foundation of China(No.51665037)the Open Fund of the Key Laboratory of Lightweight and High Strength Structural Materials of Jiangxi Province(No.20171BCD40003)the Open Fund of Key Laboratory of Nondestructive Testing Ministry of Education,Nanchang Hangkong University of China(No.EW201980090)。
文摘Ultrasonic-assisted metal inert gas(U-MIG)welding experiments were performed to analyze the effect of Cu addition on the microstructure and mechanical properties of galvanized steel sheet welds,and first-principles calculations were undertaken to predict the effect of Cu on the mechanical properties ofα-Fe based structures.As shown by scanning electron microscopy analysis,Cu is conducive to the refinement and uniformity of the microstructure in the weld zone.Energy-dispersive spectrometry data indicated the presence of Cu in the welds after welding with Cu powder.The elastic moduli of the welds without and with Cu powder,obtained from nanoindentation tests,were(217.66±5.11)GPa and(223.13±9.12)GPa,respectively,which were close to the calculated results.The mechanical properties of the crystal structures ofα-Fe andα-Fe_(1.9)Cu_(0.1)were calculated using Materials Studio software.Both the experimental and calculated results showed that Cu doping reduced the bulk modulus of the weld but increased its shear modulus.
