Study of 3-D Numerical Simulation for Gas Transfer in the Goaf of the Coal Mining

In order to simulate field distribution rules,mathematical models for 3-D air flows and gas transfer in the goaf of the coal mining are established,based on theories of permeability and dynamic dispersion through porous media. A gas dispersion equation in a 3-D field is calculated by use of numerical method on a weighted upstream multi-element balance. Based on data of an example with a U type ventilation mode,surface charts of air pressure distribution and gas concentration are drawn by Graphtool software. Finally,a comparison between actually measured results in the model test and the numerical simulation results is made to proves the numerical implementation feasible.

Gas Absorption and Mass Transfer in a Pore-Array Intensified Tube-in-Tube Microchannel

A pore-array intensified tube-in-tube microchannel(PA-TMC),which is characterized by high throughput and low pressure drop,was developed as a gas–liquid contactor.The sulfite oxidation method was used to determine the oxygen efficiency(φ)and volumetric mass transfer coefficient(k_(L)a)of PA-TMC,and the mass transfer amount per unit energy(ε)was calculated by using the pressure drop.The effects of structural and operating parameters were investigated systematically,and the twophase flow behavior was monitored by using a charge-coupled device imaging system.The results indicated that the gas absorption efficiency and mass transfer performance of the PA-TMC were improved with increasing pore number,flow rate,and number of helical coil turns and decreasing pore size,row number,annular size,annular length,and surface tension.Theφ,εand k La of PA-TMC could reach 31.3%,1.73×10^(-4) mol/J,and 7.0 s-1,respectively.The Sherwood number was correlated with the investigated parameters to guide the design of PA-TMC in gas absorption and mass transfer processes.

Global air-sea surface carbon-dioxide transfer velocity and flux estimated using ERS-2 data and a new parametric formula

Using data from the European remote sensing scatterometer （ERS-2） from July 1997 to August 1998, glob- al distributions of the air-sea CO2 transfer velocity and flux are retrieved. A new model of the air-sea CO2 transfer velocity with surface wind speed and wave steepness is proposed. The wave steepness （6） is re- trieved using a neural network （NN） model from ERS-2 scatterometer data, while the wind speed is directly derived by the ERS-2 scatterometer. The new model agrees well with the formulations based on the wind speed and the variation in the wind speed dependent relationships presented in many previous studies can be explained by this proposed relation with variation in wave steepness effect. Seasonally global maps of gas transfer velocity and flux are shown on the basis of the new model and the seasonal variations of the transfer velocity and flux during the 1 a period. The global mean gas transfer velocity is 30 cm/h after area-weighting and Schmidt number correction and its accuracy remains calculation with in situ data. The highest transfer velocity occurs around 60°N and 60°S, while the lowest on the equator. The total air to sea CO2 flux （calcu- lated by carbon） in that year is 1.77 Pg. The strongest source of CO2 is in the equatorial east Pacific Ocean, while the strongest sink is in the 68°N. Full exploration of the uncertainty of this estimate awaits further data. An effectual method is provided to calculate the effect of waves on the determination of air-sea CO2 transfer velociW and fluxes with ERS-2 scatterometer data.

Determination of the Apparent Gas Permeability in a Macrocracked Concrete

This paper reports on analysis of an expermental study that armed to determine the apparent gas permeability in cracked concrete.There is a lack of research on this topic in the international literature,due to the difficulty of performing reliable experimental testing for gas permeability.The principal interest of this work is to present new and reliable experimental results.Analytical functions between the evolution of the apparent crack permeability and the apparent crack opening are also proposed.These functions appear to be relevant in consideration of Poiseuille theory.

Developments in the understanding of gas–solid contact efficiency in the circulating fluidized bed riser reactor:A review

In the last several decades, circulating fluidized bed reactors have been studied in many aspects including hydrodynamics, heat and mass transfer and gas–solid two phase contacting. However, despite the abundance of review papers on hydrodynamics, there is no summary paper on gas–solid contact efficiency to date, especially on high density circulating fluidized beds(CFBs). This paper gives an introduction to, and a review of the measurement of contact efficiency in circulating fluidized bed riser. Firstly, the popular testing method of contact efficiency including the method of heating transfer experiment and hot model reaction are discussed, then previous published papers are reviewed based on the discussed methods. Some key results of the experimental work are described and discussed. Gas–solid contact efficiency is affected by the operating conditions as well as the particle size distribution. The result of the contact efficiency shows that the CFB riser is far away from an ideal plug flow reactor due to the characteristics of hydrodynamics in the riser. Lacunae in the available literature have been delineated and recommendations have been made for further work.

Influence of the Channel Design on the Heat Exchange Characteristics of Pulsating Flows in the Supply System of an Engine

Heat engines based on reciprocating machines remain in demand as energy converters in a variety of industries around the world.The aim of the study was to evaluate the gas-dynamic,consumable and heat exchange characteristics of non-stationary air flows in a supply system with transverse profiling of valve channels based on experimental studies.Valve channels with cross sections in the form of a circle,square and triangle were used to control the consumable and heat exchange characteristics of the flows in the supply system of the reciprocatingengine model.The article presents data on changes in local velocity,volumetric airflow and instantaneous heat transfer coefficient of non-stationary airflow in supply systems with different valve channel designs.A spectral analysis of the pulsations of the local heat transfer coefficient was also performed.The Nusselt number was calculated for the studied supply systems.The figured valve channels lead to an increase in the volumetric airflow through the supply systemupto32%comparedwiththe basic configuration.The useof a square valve channel leads to suppression of heat transfer(drop is about 15%)compared to the basic supply system,and the use of a triangular valve channel causes an intensification of heat transfer(growth is about 17.5%).The obtained data can be useful for refining mathematical models,adjusting machine learning algorithms,and improving design methods for supply systems of reciprocating machines to improve their technical,economic,and environmental characteristics.

Oxygen-coordinated low-nucleus cluster catalysts for enhanced electrocatalytic water oxidation

The oxygen evolution reaction(OER)activity of single-atom catalysts(SACs)is closely related to the coordination environment of the active site.Oxygencoordinated atomic metal species bring about unique features beyond nitrogen-coordinated atomic metal species due to the fact that the M-O bond is weaker than the M-N bond.Herein,a series of metal-oxygen-carbon structured low-nucleus clusters(LNCs)are successfully anchored on the surface of multiwalled carbon nanotubes(M-MWCNTs,M=Ni,Co,or Fe)through a foolproof low-temperature gas transfer(300℃)method without any further treatment.The morphology and coordination configuration of the LNCs at the atomic level were confirmed by comprehensive characterizations.The synthetic Ni-MWCNTs electrocatalyst features excellent OER activity and stability under alkaline conditions,transcending the performances of Co-MWCNTs,Fe-MWCNTs and RuO_(2).Density functional theory calculations reveal that the moderate oxidation of low-nucleus Ni clusters changes the unoccupied orbital of Ni atoms,thereby lowering the energy barrier of the OER rate-limiting step and making the OER process more energy-efficient.This study demonstrates a novel versatile platform for large-scale manufacturing of oxygen-coordinated LNC catalysts.

Estimate of Global Sea-Air CO_2 Flux with Sea-State-Dependent Parameterization

Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.

Convective heat transfer for incompressible laminar gas flow in micropassage with constant wall temperature

Theoretical investigations have been performed on the convective heat transfer for incompressible laminar flow of gases through microtube and parallel-plates micropassages with constant wall temperature. Considering the change in thermal conductivity and viscosity of gas in wall adjacent region from the kinetic theory, mathematical models are built for both of the micropassages. The dimensionless temperature distribution and the corresponding heat transfer characteristics are simulated numerically, and the results discussed briefly.

Piston mechanism of interaction of non-linear geomechanical and physicochemical gas exchange and mass transfer processes in coal-bearing rocks

The article focuses on a theoretical and experimental framework for the quantification of interaction between nonlinear geomechnical and physicochemical processes in high-stress coal-bearing rock mass during mining under high seismic risk due to large-scale blasting and earthquakes,as well as because of structural and temperature effects.The tests were aimed to examine and study comprehensively the piston mechanism of gas exchange and mass transfer processes,revealed recently at the Institute of Mining,SB RAS,as well as to explain the fact that the earthquake-induced low-velocity(quasi-meter range)pendulum waves(velocity to 1 m/s and frequency of 0.5–5 Hz)could stimulate an increase in the gas content in coal mines.In order to perform laboratory investigation at the Institute of Mining SB RAS,special-purpose stand for analyzing gas exchange and mass transfer processes in coal-bearing geomaterials under various thermodynamic conditions(P,V,T)and gas composition was constructed in cooperation with the Institute of Semiconductors Physics SB RAS.Matching of air flow rate with compression pressures allowed to obtain relations showing that air flow rate increases at the uncertain time interval under the increasing of the compression pressure.The same measurements was carried out with another gases such as Hydrogen H_(2),Helium He,methane CH_(4),carbon dioxide CO_(2) and carbon oxide CO.The laboratory tests aimed to detailed investigation of the previously revealed“piston mechanism”of gas exchange and mass transfer processes in the coal specimens and their quantitative description in terms of theory of the pendulum waves were carried in the first time.Consequently,there are some arguments for the testing of the opportunity of quantitative description of the“piston mechanism”related to gas exchange and mass transfer processes in the scale of coal mines.It is relevant when pendulum waves induced by powerful earthquakes and technical blasting reaches the mine.

THE ASYMPTOTIC PRESERVING UNIFIED GAS KINETIC SCHEME FOR GRAY RADIATIVE TRANSFER EQUATIONS ON DISTORTED QUADRILATERAL MESHES

In this paper,we consider the multi-dimensional asymptotic preserving unified gas kinetic scheme for gray radiative transfer equations on distorted quadrilateral meshes.Different from the former scheme [J.Comput.Phys.285（2015）,265-279] on uniform meshes,in this paper,in order to obtain the boundary fluxes based on the framework of unified gas kinetic scheme（UGKS）,we use the real multi-dimensional reconstruction for the initial data and the macro-terms in the equation of the gray transfer equations.We can prove that the scheme is asymptotic preserving,and especially for the distorted quadrilateral meshes,a nine-point scheme [SIAM J.SCI.COMPUT.30（2008）,1341-1361] for the diffusion limit equations is obtained,which is naturally reduced to standard five-point scheme for the orthogonal meshes.The numerical examples on distorted meshes are included to validate the current approach.

Local heat transfer properties in co- and counter-current G-L-S magnetically stabilized fluidized beds

Heat transfer coefficients were measured by immersed probes in co- and counter-current G-L-S magnetically stabilized fluidized beds （MSFBs） using air, water and nickel-alloy particles as the gas, liquid and solid phases. Influences of major factors, including magnetic field intensity, superficial gas and liquid velocities, liquid viscosity and surface tension, on heat-transfer properties were studied experimentally, indicating that both co- and counter-current G-L-S MSFB can provide relatively uniform radial distribution of heat transfer coefficients under appropriate operation conditions, thus controlling operation temperature for highly exothermic multi-phase reaction systems. Two correlations were provided to estimate accurately heat transfer properties in both co- and counter-current G-L-S MSFB systems, with an average error of less than 10%.

Numerical investigation and optimisation of heat transfer performance in a vertical sinter cooling packed bed using Taguchi and ANOVA methods

The Taguchi and analysis of variance (ANOVA) methods were applied to investigate the effects of the structural and operational parameters on the heat transfer performance of a vertical sinter cooling packed bed. The analysed parameters were the gas flow rate, the air inlet temperature, the sinter inlet temperature, the cooling bed diameter and the cooling bed height, all of which contain three levels. The purpose was to improve the heat transfer performance of a vertical sinter cooling bed. A numerical analysis model was established to assess the heat transfer performance with respect to the varying parameters and their different levels. This mathematical model was validated by using data from practical industrial processes. The Taguchi method for the L27 (35) orthogonal design experiment was selected to evaluate the impacts of the design parameters on the heat transfer performance and to acquire the optimum combination of parameters. The analysis of variance was applied to assess the impact weights and the order of significance of the design parameters. The results show that the sinter inlet temperature and cooling bed diameter have great influences and impact the exergy of the wasted heat recovery by 61.65% and 23.31%, respectively. However, the gas flow rate and the air inlet temperature have small effects on the response. Furthermore, the air and sinter inlet temperatures have the most significant impacts on the efficiency of heat transfer by 68.83% and 23.31%, respectively. The optimal parameter combination (A1B1C3D3E3) was obtained, and the optimal results were validated by confirmation tests.

Heat and mass transfer study in fluidized bed granulation-Prediction of entry length

Fluidized bed granulation is a process by which granules or coated particles are produced in a single piece of equipment by spraying a hinder as solution, suspension, or melt on the fluidized powder bed. Heat and mass transfer correlation useful for designing a granulator has been derived based on the equivalence of evaporation rate of the liquid to the heat transferred from hot gas to particles： （m/A）Dp^2λ/Lmf（1-εmf）（Tg-Tl）Kg=hDp/Kg.This equation is applied to data on granulation experiments by different workers to calculate Reynolds number and Nusselt number to obtain a relation between heat and mass transfer from gas to particles during granulation on a logarithmic scale from which the following empirical relation is obtained： Nu=0.0205Re^1.3876 which is comparable to Kothari＇s correlation Nu=0.03Re^1.3.By using the heat and mass transfer correlation obtained, the entry length, that is the length of granulator up to which effective heat transfer from gas to bed particles takes place, is estimated, which is also validated with experimental study. The correct estimation of entry length is useful in optimal design of a granulator.

Conjugate Heat Transfer Investigation on the Cooling Performance of Air Cooled Turbine Blade with Thermal Barrier Coating

A hot wind tunnel of annular cascade test rig is established for measuring temperature distribution on a real gas turbine blade surface with infrared camera.Besides,conjugate heat transfer numerical simulation is performed to obtain cooling efficiency distribution on both blade substrate surface and coating surface for comparison.The effect of thermal barrier coating on the overall cooling performance for blades is compared under varied mass flow rate of coolant,and spatial difference is also discussed.Results indicate that the cooling efficiency in the leading edge and trailing edge areas of the blade is the lowest.The cooling performance is not only influenced by the internal cooling structures layout inside the blade but also by the flow condition of the mainstream in the external cascade path.Thermal barrier effects of the coating vary at different regions of the blade surface,where higher internal cooling performance exists,more effective the thermal barrier will be,which means the thermal protection effect of coatings is remarkable in these regions.At the designed mass flow ratio condition,the cooling efficiency on the pressure side varies by 0.13 for the coating surface and substrate surface,while this value is 0.09 on the suction side.

An Experimental Investigation of Heat Transfer Characteristics for Steam Cooling in a Rectangular Channel with Parallel Ribs

An experimental study of heat transfer characteristics in superheated steam cooled rectangular channels with parallel ribs was conducted.The distribution of the heat transfer coefficient on the rib-roughed channel was measured by IR camera.The blockage ratio(e/Dh) of the tested channel is 0.078 and the aspect ratio(W/H) is fixed at3.0.Influences of the rib pitch-to-height ratio(P/e) and the rib angle on heat transfer for steam cooling were investigated.In this paper,the Reynolds number(Re) for steam ranges from 3070 to 14800,the rib pitch-to-height ratios were 8,10 and 12,and rib angles were 90°,75°,60°,and 45°.Based on results above,we have concluded that:In case of channels with 90° tranverse ribs,for larger rib pitch models(the rib pitch-to-height ratio=10 and12),areas with low heat transfer coefficient in front of rib is larger and its minimum is lower,while the position of the region with high heat transfer coefficient nearly remains the same,but its maximun of heat transfer coefficient becomes higher.In case of channels with inclined ribs,heat transfer coefficients on the surface decrease along the direction of each rib and show an apparent nonuniformity,consequently the regions with low Nusselt number values closely following each rib expand along the aforementioned direction and that of relative high Nusselt number values vary inversely.For a square channel with 90° ribs at Re= 14800,wider spacing rib configurations(the rib pitch-to-height ratio=10 and 12) give an area-averaged heat transfer on the rib-roughened surface about8.4%and 11.4%more than P/e=8 model,respectively;for inclined parallel ribs with different rib angles at Re=14800,the area-averaged heat transfer coefficients of 75°,60° and 45° ribbed surfaces increase by 20.1%,42.0%and 44.4%in comparison with 90° rib angle model.45° angle rib-roughened channel leads to a maximal augmentation of the area-averaged heat transfer coefficient in all research objects in this paper.