Metapelitic Garnet-Muscovite-Al_2SiO_5-Quartz(GMAQ) Geothermobarometry

The garnet-muscovite geothermometer and garnet-muscovite-Al2SiO5 -quartz （GMAQ） geobarometer have been empirically calibrated under P-T conditions of 1-12 kbar and 460-760 ℃ using natural metapelitic rocks. The chemical compositions of the calibrant muscovite are in the ranges of Fe=0.03-0.21 atoms, Mg=0.02-0.32 atoms and AI VI=1.62-1.96 atoms, respectively, on the ll-oxygen basis per formula unit. The garnet-muscovite thermometer yields similar temperature estimates to the well calibrated garnet-biotite thermometer within error of 4-55 ℃, and successfully discriminates the systematic temperature change of the different zones of either the prograde or inverted metamorphic terranes or thermal contact aureoles. The six formulations of GMAQ barometry yield similar pressure estimates to the well calibrated GASP barometer within error of ±1.2 kbar, and plot the Al2SiOs-bearing metapelite into the correct stability field of the AI2SiOs polymorphs. Moreover, the GMAQ thermobarometers show that the pressure is almost constant for every thermal contact aureole within limited geographic region, which reflects geological condition. The random errors are estimated to be of ca. 4-60 ℃ and 4-1.4 kbar for the geothermometer and geobarometer, respectively. A spreadsheet for applying GMAQ geothermo- barometry is supplied in the Electronic Supplementary Materials.

Mineral Chemistry Indicates the Petrogenesis of Rhyolite From The Southwestern Okinawa Trough

To reveal the petrogenesis of rhyolite from the southwestern Okinawa Trough, the mineral chemistry of plagioclase, orthopyroxene, amphibole, quartz and Fe-Ti oxide phenocrysts were analyzed using an electron microprobe, and in suit Sr and Ba contents of plagioclase analysed by LA-ICPMS were chosen for fingerprinting plagioclases of different provenances. Results indicate an overall homogeneous composition for each of the mineral phases except for plagioclase phenocrysts which have a wide range of composition(An=39~88). Plagioclase crystals characterized by An contents of >70 are not in equilibrium with their whole-rock compositions, and coarse-sieved plagioclase phenocryst interiors record high An contents(>70) and Sr/Ba ratios(>7), which are similar to the those of plagioclase crystals in basalt. Therefore, these crystals must have been introduced to the rhyolitic magma from a more mafic source. Equilibrium temperatures estimated using orthopyroxene-liquid, iron–titanium oxide, titanium-in-quartz and amphibole geothermometers show consistent values ranging from 792 to 869℃. The equilibrium pressure calculated using amphibole compositions is close to 121 MPa which corresponds to an approximate depth of 4 km. The fO_2 conditions estimated from Fe-Ti oxides and amphiboles plot slightly above the NNO buffer, which indicates that the rock formed under more oxidized conditions. Our results suggests that petrogenesis of the rhyolite due to basaltic magma ascend with the high An and Sr/Ba plaigoclases from deep magma chamber into the shallow chamber where the fractional crystallization and crustal assimilation happened. It also indicates that a two-layer magma chamber structure may occur under the southwestern Okinawa Trough.

Petrology,geochemistry,and zircon U-Pb geochronology of the Zambezi Belt in Zimbabwe:Implications for terrane assembly in southern Africa

The Zambezi Belt in southern Africa has been regarded as a part of the 570-530 Ma Kuunga Orogen formed by a series of collision of Archean cratons and Proterozoic orogenic belts.Here,we report new petrological,geochemical,and zircon U-Pb geochronological data of various metamorphic rocks(felsic to mafic orthogneiss,pelitic schist,and felsic paragneiss)from the Zambezi Belt in northeastern Zimbabwe,and evaluate the timing and P-T conditions of the collisional event as well as protolith formation.Geochemical data of felsic orthogneiss indicate within-plate granite signature,whereas those of mafic orthogneiss suggest MORB,ocean-island,or within-plate affinities.Metamorphic P-Testimates for orthogneisses indicate significant P-T variation within the study area(700-780 C/6.7-7.2 kbar to 800-875 C/10-11 kbar)suggesting that the Zambezi Belt might correspond to a suture zone with several discrete crustal blocks.Zircon cores from felsic orthogneisses yielded two magmatic ages:2655±21 Ma and 813士5 Ma,which suggests Neoarchean and Early Neoproterozoic crustal growth related to within-plate magmatism.Detrital zircons from metasediments display various ages from Neoarchean to Neoproterozoic(ca.2700-750 Ma).The Neoarchean(ca.2700-2630 Ma)and Paleoproterozoic(ca.2200-1700 Ma)zircons could have been derived from the adjacent Kalahari Craton and the Magondi Belt in Zimbabwe,respectively.The Choma-Kalomo Block and the Lufilian Belt in Zambia might be proximal sources of the Meso-to Neoproterozoic(ca.1500-950 Ma)and early Neoproterozoic(ca.900-750 Ma)detrital zircons,respectively.Such detrital zircons from adjacent terranes possibly deposited during late Neoproterozoic(744-670 Ma),and subsequently underwent highgrade metamorphism at 557-555 Ma possibly related to the collision of the Congo and Kalahari Cratons during the latest Neoproterozoic to Cambrian.In contrast,670-627 Ma metamorphic ages obtained from metasediments are slightly older than previous reports,but consistent with^680-650 Ma metamorphic ages reported from different parts of the Kuunga Orogen,suggesting Cryogenian thermal events before the final collision.

Spinel-Bearing Lherzolite Xenoliths from Hossere Garba(Likok,Adamawa-Cameroon):Mineral Compositions and Geothermobarometric Implications

Spinel-bearing lherzolite xenoliths from the Hossere Garba (1272 m.a.s.l) volcano on the Adamawa Plateau, is located in Likok village, at about 35 km to WSW of Ngaoundere. These xenoliths (~11 cm size) have been sampled into the host basaltic lava flows from the NE flank of the Hossere Garba volcano. These xenoliths characterized by porphyroclastic texture consisted of olivine (~55 vol.%), orthopyroxene (~19 vol.%) and clinopyroxene (~21 vol.%) crystals. Spinel crystals (~5 vol.%) are red brown and interstitial between the crystals of olivine and pyroxenes. CaO contents are low (<0.08 wt%) in olivine and similar to those estimated (CaO: 0.05 - 0.1 wt%) for the mantle origin. The values of AlVI/AlIV ratio range between 1.1 and 1.3 for the Cr-diopside crystals from Hossere Garba xenoliths. The constant value of the volumes V(Cell) and V(M1) for clinopyroxene compositions, indicates the similar pressures. Hossere Garba represents a residual sequence issued from partial melting of a mantle source. Similar compositions have been recorded in minerals of ultramafic xenoliths from other ultramafic xenoliths domains of the Cameroon Line and the Adamawa Plateau.

Mica Types as Indication of Magma Nature,Central Anatolia,Turkey

This study focuses on the nature of giant micas occurring at the contact between theÖzvatan(foid-bearing)syenites and the metamorphic basement in Central Anatolia.The studied micas are dark greenish-black in color and crystallized within vein shape like bodies as a narrow lens.The origin and processes responsible for the formation of these independent crystals of the giant micas were investigated by mineralogical,petrographical and geochemical analyses with the use of Confocal Raman Spectroscopy(CRS),Fourier Transform Infrared(FTIR)Spectroscopy,X-Ray Diffraction(XRD),Polarized Energy Dispersive X-Ray Fluorescence Spectrometer(PED-XRF)and Electron Probe Micro Analysis(EPMA).According to XRD,CRS,FTIR and EPMA data,the giant micas are phlogopite.EPMA results reveal that studied mica minerals represent the products of re-equilibrated primary mica characterized by high MgO and FeO and low Al2O3 and TiO2 contents.The trace element concentrations of the giant micas display similar patterns with the upper crust.The giant micas are crystallized within small cubicles from an alkaline magma and their composition is possibly modified by a mixing event between the crust-and mantle-derived magmas and contaminated at varying extent by the basement metamorphic rocks.

GEOBAROMETRIC CONSTRAINTS ON THE DEPTH OF EMPLACEMENT OF GRANITE FROM THE LADAKH BATHOLITH, NORTHWEST HIMALAYA, INDIA

The Ladakh batholith is exposed along the 600km long and 20 to 80km wide NW—SE trending Ladakh range north of the Indus\|Tsangpo Suture Zone. It was emplaced into an unmetamorphosed thick pile of mafic and felsic volcanics, ultramafics and sediments of Upper Cretaceous\|Eocene age (Dras Volcanics, Khardung Volcanics). The granites from the Ladakh batholith within the Leh\|Khardung La and Sakti—Chang La sections (samples collected between altitude of 3600m and 5440m above mean sea level, Fig.1) have been estimated for pressure and temperature of crystallization employing the hornblende geobarometer of Schmidt (1992) and hornblende\|plagioclase geothermometer of Blundy and Holland (1990), with the results of pressure of (250±60)MPa and temperature of (695±22)℃. Therefore, these granites were solidified at a depth of (8 6±2)km suggesting an unroofing of this thickness in this region. The importance of this geobarometric data in conjunction with age data on the cooling and unroofing history of the Trans\|Himalayan Ladakh batholith and geodynamic implications of the India—Asia collision are discussed.