Surface sediments from the Changjiang River (Yangtze River) Estuary, Hangzhou Bay, and their adjacent waters were analyzed for their grain size distribution, organic carbon (OC) concentration, and stable carbon is...Surface sediments from the Changjiang River (Yangtze River) Estuary, Hangzhou Bay, and their adjacent waters were analyzed for their grain size distribution, organic carbon (OC) concentration, and stable carbon isotope composition (δ13C). Based on this analysis, about 36 surface sediment samples were selected from various environments and separated into sand (〉0.250 ram, 0.125-0.250 ram, 0.063-0.125 mm) and silt (0.025-0.063 mm) fractions by wet-sieving fractionation methods, and further into silt- (0.004-0.025 mm) and clay-sized (〈0.004 mm) fractions by centrifugal fractionation. Sediments of six grain size categories were analyzed for their OC and 613C contents to explore the grain size composition and transport paths of sedimentary OC in the study area. From fine to coarse fractions, the OC content was 1.18%, 0.51%, 0.46%, 0.42%, 0.99%, and 0.48%, respectively, while the δ13C was -21.64‰, -22.03‰, -22.52‰, -22.46‰, -22.36‰, and -22.28%0, respectively. In each size category, the OC contribution was 42.96%, 26.06%, 9.82%, 5.75%, 7.09%, and 8.33%, respectively. The OC content in clay and fine silt fractions (〈0.025 ram) was about 69.02%. High OC concentrations were mainly found in offshore modern sediments in the northeast of the Changjiang River Estuary, in modern sediments in the lower estuary of the Changjiang River and Hangzhou Bay, and in Cyclonic Eddy modern sediments to the southwest of the Cheju Island. Integrating the distribution of terrestrial OC content of each grain size category with the δ13C of the bulk sediment indicated that the terrestrial organic material in the Changjiang River Estuary was transported seaward and dispersed to the Cyclonic Eddy modern sediments to the southwest of the Cheju Island via two pathways: one was a result of the Changjiang River Diluted Water (CDW) northeastward extending branch driven by the North Jiangsu Coastal Current and the Yellow Sea Coastal Current, while the other one was the result of the CDW southward extending branch driven by the Taiwan Warm Current.展开更多
The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to...The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.展开更多
There is fine and uniform clay with aluminous and ferrous cementation in the red clay found in Guigang, Guangxi. It has the characteristics of shrinkage outwardly, rigid upper but soft lower and well grown fissure. I...There is fine and uniform clay with aluminous and ferrous cementation in the red clay found in Guigang, Guangxi. It has the characteristics of shrinkage outwardly, rigid upper but soft lower and well grown fissure. In addition there are engineering characteristics such as high water content, low compactness and low compressibility, high strength and high contractility but slight expansibility. This paper discusses the red clay's engineering characteristics and its change regulation with depth by analyzing changes in the red clay's grain size composition, mineralogical constitution, and chemical composition.展开更多
An Fe–44Ni nanocrystalline(NC) alloy thin film was prepared through electrodeposition. The relation between the microstructure and corrosion behavior of the NC film was investigated using electrochemical methods an...An Fe–44Ni nanocrystalline(NC) alloy thin film was prepared through electrodeposition. The relation between the microstructure and corrosion behavior of the NC film was investigated using electrochemical methods and chemical analysis approaches. The results show that the NC film is composed of a face-centered cubic phase(γ-(Fe,Ni)) and a body-centered cubic phase(α-(Fe,Ni)) when it is annealed at temperatures less than 400℃. The corrosion resistance increases with the increase in grain size, and the corresponding corrosion process is controlled by oxygen reduction. The NC films annealed at 500℃ and 600℃ do not exhibit the same pattern, although their grain sizes are considerably large. This result is attributed to the existence of an anodic phase, Fe0.947Ni0.054, in these films. Under this condition, the related corrosion process is synthetically controlled by anodic dissolution and depolarization.展开更多
Road dust is one of the most common pollutants and causes a series of negative effects on plant physiology. Dust's impacts on plants can be regarded as a combination of load,composition and grain size impacts on plan...Road dust is one of the most common pollutants and causes a series of negative effects on plant physiology. Dust's impacts on plants can be regarded as a combination of load,composition and grain size impacts on plants; however, there is a lack of integrated dust effect studies involving these three aspects. In our study, Sophora japonica seedlings were artificially dusted with road dust collected from the road surface of Beijing so that we could study the impacts of this dust on nitrogen/carbon allocation, biomass allocation and photosynthetic pigments from the three aspects of composition, load and grain size. The results showed that the growth characteristics of S. japonica seedlings were mostly influenced by dust composition and load. Leaf N, root–shoot ratio and chlorophyll a/b were significantly affected by dust composition and load; leaf C/N, shoot biomass, total chlorophyll and carotenoid were significantly affected by dust load; stem N and stem C/N were significantly affected by dust composition; while the dust grain size alone did not affect any of the growth characteristics. Road dust did influence the growth characteristics more extensively than loam. Therefore, a higher dust load could increase the differences between road dust and loam treatments. The elements in dust are well correlated to the shoot N, shoot C/N, and root–shoot ratio of S. japonica seedlings. This knowledge could benefit the management of urban green spaces.展开更多
基金The National Basic Research Program(973 Program)of China under contract No.2010CB428903the National Natural Science Foundation of China under contract Nos 41106050,41203085 and 41076036+1 种基金the Public Welfare Industry Research Specific Funding of China under contract Nos 201105014,201105012 and 201205008the Basic Scientific Research Fund of the Second Institute of Oceanography of State Oceanic Administration of China under contract Nos JG1108 and JG1219
文摘Surface sediments from the Changjiang River (Yangtze River) Estuary, Hangzhou Bay, and their adjacent waters were analyzed for their grain size distribution, organic carbon (OC) concentration, and stable carbon isotope composition (δ13C). Based on this analysis, about 36 surface sediment samples were selected from various environments and separated into sand (〉0.250 ram, 0.125-0.250 ram, 0.063-0.125 mm) and silt (0.025-0.063 mm) fractions by wet-sieving fractionation methods, and further into silt- (0.004-0.025 mm) and clay-sized (〈0.004 mm) fractions by centrifugal fractionation. Sediments of six grain size categories were analyzed for their OC and 613C contents to explore the grain size composition and transport paths of sedimentary OC in the study area. From fine to coarse fractions, the OC content was 1.18%, 0.51%, 0.46%, 0.42%, 0.99%, and 0.48%, respectively, while the δ13C was -21.64‰, -22.03‰, -22.52‰, -22.46‰, -22.36‰, and -22.28%0, respectively. In each size category, the OC contribution was 42.96%, 26.06%, 9.82%, 5.75%, 7.09%, and 8.33%, respectively. The OC content in clay and fine silt fractions (〈0.025 ram) was about 69.02%. High OC concentrations were mainly found in offshore modern sediments in the northeast of the Changjiang River Estuary, in modern sediments in the lower estuary of the Changjiang River and Hangzhou Bay, and in Cyclonic Eddy modern sediments to the southwest of the Cheju Island. Integrating the distribution of terrestrial OC content of each grain size category with the δ13C of the bulk sediment indicated that the terrestrial organic material in the Changjiang River Estuary was transported seaward and dispersed to the Cyclonic Eddy modern sediments to the southwest of the Cheju Island via two pathways: one was a result of the Changjiang River Diluted Water (CDW) northeastward extending branch driven by the North Jiangsu Coastal Current and the Yellow Sea Coastal Current, while the other one was the result of the CDW southward extending branch driven by the Taiwan Warm Current.
文摘The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.
文摘There is fine and uniform clay with aluminous and ferrous cementation in the red clay found in Guigang, Guangxi. It has the characteristics of shrinkage outwardly, rigid upper but soft lower and well grown fissure. In addition there are engineering characteristics such as high water content, low compactness and low compressibility, high strength and high contractility but slight expansibility. This paper discusses the red clay's engineering characteristics and its change regulation with depth by analyzing changes in the red clay's grain size composition, mineralogical constitution, and chemical composition.
基金financially supported by the Major State Basic Research Development Program of China (No. 2014CB643300)the National Natural Science Foundation of China (No. U1560104)the National Environmental Corrosion Platform (NECP)
文摘An Fe–44Ni nanocrystalline(NC) alloy thin film was prepared through electrodeposition. The relation between the microstructure and corrosion behavior of the NC film was investigated using electrochemical methods and chemical analysis approaches. The results show that the NC film is composed of a face-centered cubic phase(γ-(Fe,Ni)) and a body-centered cubic phase(α-(Fe,Ni)) when it is annealed at temperatures less than 400℃. The corrosion resistance increases with the increase in grain size, and the corresponding corrosion process is controlled by oxygen reduction. The NC films annealed at 500℃ and 600℃ do not exhibit the same pattern, although their grain sizes are considerably large. This result is attributed to the existence of an anodic phase, Fe0.947Ni0.054, in these films. Under this condition, the related corrosion process is synthetically controlled by anodic dissolution and depolarization.
基金supported by the National Natural Science Foundation of China(Project 41430638 to KMM)
文摘Road dust is one of the most common pollutants and causes a series of negative effects on plant physiology. Dust's impacts on plants can be regarded as a combination of load,composition and grain size impacts on plants; however, there is a lack of integrated dust effect studies involving these three aspects. In our study, Sophora japonica seedlings were artificially dusted with road dust collected from the road surface of Beijing so that we could study the impacts of this dust on nitrogen/carbon allocation, biomass allocation and photosynthetic pigments from the three aspects of composition, load and grain size. The results showed that the growth characteristics of S. japonica seedlings were mostly influenced by dust composition and load. Leaf N, root–shoot ratio and chlorophyll a/b were significantly affected by dust composition and load; leaf C/N, shoot biomass, total chlorophyll and carotenoid were significantly affected by dust load; stem N and stem C/N were significantly affected by dust composition; while the dust grain size alone did not affect any of the growth characteristics. Road dust did influence the growth characteristics more extensively than loam. Therefore, a higher dust load could increase the differences between road dust and loam treatments. The elements in dust are well correlated to the shoot N, shoot C/N, and root–shoot ratio of S. japonica seedlings. This knowledge could benefit the management of urban green spaces.