In Situ Analyses of Trace Elements, U–Pb and Lu–Hf Isotopes in Zircons from the Tongshankou Granodiorite Porphyry in Southeast Hubei Province, Middle-Lower Yangtze River Metallogenic Belt, China

The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma（n=20, mean square weighted deviation was 0.75）, which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements（LREE） to the heavy-group rare-earth elements（HREE） with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions（εHf（t）） ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.

A geochronological and geochemical study on the granodiorite porphyry and its implication for the mineralization in the Dayaoshan metallogenic belt,Southeastern China

A systematic study combining U-Pb zircon dating,lithogeochemical and Sr-Nd isotopic analyses was carried out upon the Xinping granodiorite porphyry in the Dayaoshan metallogenic belt to understand its petrogenesis and tectonic significance.LA-ICP-MS U-Pb zircon dating yielded a 442.7±5.8 Ma age,indicating that the granodiorite porphyry was emplaced during the Llandovery Silurian of the Early Paleozoic.The granodiorite porphyry shares the same geochemical characteristics such as Eu negative anomaly as other syn-tectonic granite plutons in the region,including the granodiorite porphyry in Dawangding and granite porphyries in the Dali Cu-Mo deposit and Longtoushang old deposit,indicating a similar magma evolution process.The Xinping granodiorite porphyry has high contents of SiO2(67.871.8%)and K2O(1.78-3.42%)and is metaluminous-peraluminous with A/CNK ratios ranging from 0.97 to 1.06,indicative of high-potassium calc-alkaline to calc-alkaline affinity.It is a I-type granite enriched in large ion lithophile elements Rb,Sr,while depleted in Ba and high field-strength element Nb.Tectonically,a collision between the Yunkai Block from the south and the Guangxi Yunnan-North Vietnam Block from the north during the Early Paleozoic was followed by uplifting of the Dayaoshan terrane.The Xinping granodiorite porphyry was likely emplaced during the collision.Sr-Nd isotopic analyses show that the granodiorite porphyry has initial 87Sr/86Sr ratios(Isr)of 0.7080-0.7104,εNd(t)range from-0.08 to-4.09,and t2DM between 1.19 and 1.51 Ga,well within the north-east low-value zone of the Cathaysia block,indicating a Paleoproterozoic Cathaysia basement source and an involvement of under plating mantle magma.Field observations,geochronological data,and 3D spatial distribution all lead to the conclusion that the Early Paleozoic Xinping granodiorite porphyry does not have any metallogenic and temporal relationships with the Xinping gold deposit(which has a Jurassic-Early Cretaceous age based on previous studies)but a close metallogenic relation to W-Mo mineralization.

Geochemistry Characteristics of Granodiorite Porphyry in the Degongniuchang Copper Deposit, Muli, Sichuan Province, China

1 Introduction 1The Sanjiang region in SE Tibet Plateau and NW Yunnan is known to have formed by amalgamation of Gongwanaderived continental blocks and arc terranes as a result of oceanic subduction followed by continental

Geology and mineralization of the Daheishan supergiant porphyry molybdenum deposit(1.65 Bt),Jilin,China:A review

The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with total molybdenum reserves of 1.65 billion tons,an average molybdenum ore grade of 0.081%,and molybdenum resources of 1.09 million tons.The main ore body is housed in the granodiorite porphyry plutons and their surrounding inequigranular granodiorite plutons,with high-grade ores largely located in the ore-bearing granodiorite porphyries in the middle-upper part of the porphyry plutons.Specifically,it appears as an ore pipe with a large upper part and a small lower part,measuring about 1700 m in length and width,extending for about 500 m vertically,and covering an area of 2.3 km^(2).Mineralogically,the main ore body consists of molybdenite,chalcopyrite,and sphalerite horizontally from its center outward and exhibits molybdenite,azurite,and pyrite vertically from top to bottom.The primary ore minerals include pyrite and molybdenite,and the secondary ore minerals include sphalerite,chalcopyrite,tetrahedrite,and scheelite,with average grades of molybdenum,copper,sulfur,gallium,and rhenium being 0.081%,0.033%,1.67%,0.001%,and 0.0012%,respectively.The ore-forming fluids of the Daheishan deposit originated as the CO_(2)-H_(2)O-NaCl multiphase magmatic fluid system,rich in CO_(2)and bearing minor amounts of CH4,N2,and H2S,and later mixed with meteoric precipitation.In various mineralization stages,the ore-forming fluids had homogenization temperatures of>420℃‒400℃,360℃‒350℃,340℃‒230℃,220℃‒210℃,and 180℃‒160℃and salinities of>41.05%‒9.8%NaCleqv,38.16%‒4.48%NaCleqv,35.78%‒4.49%NaCleqv,7.43%NaCleqv,and 7.8%‒9.5%NaCleqv,respectively.The mineralization of the Daheishan deposit occurred at 186‒167 Ma.The granites closely related to the mineralization include granodiorites(granodiorite porphyries)and monzogranites(monzogranite porphyries),which were mineralized after magmatic evolution(189‒167 Ma).Moreover,these mineralization-related granites exhibit low initial strontium content and high initial neodymium content,indicating that these granites underwent crust-mantle mixing.The Daheishan deposit formed during the Early-Middle Jurassic,during which basaltic magma underplating induced the lower-crust melting,leading to the formation of magma chambers.After the fractional crystallization of magmas,ore-bearing fluids formed.As the temperature and pressure decreased,the ore-bearing fluids boiled drops while ascending,leading to massive unloading of metal elements.Consequently,brecciated and veinlet-disseminated ore bodies formed.

Mantle contributions to granitoids associated with Sn mineralization:Geochemical and isotopic evidence from the giant Dachang deposit,South China

Major Sn deposits are commonly linked to crust-derived and highly evolved granites,with magma generation aided by mantle heating.However,whether and how the mantle components contribute to Sn polymetallic mineralization remains unclear.In this study,in combination with a compilation of equivalent data in the region,we provide new constraints on this issue based on detailed investigations on the petrogenesis and metallogenic significance of granitoids including the causative batholith and later granodiorite porphyry dike in the giant Dachang Sn deposit from South China.The former has zircon U-Pb ages of 93-91 Ma and belongs to highly evolved S-type biotite granite,which experienced fractionation of massive feldspar.The latter shows zircon U-Pb ages of 90 Ma and displays I-type granite features.The batholith was mainly derived from the dehydration melting of biotite in the metasedimentary sources,as revealed by the relatively low whole-rock Pb contents(<30 ppm)and high Ba/Pb ratios(2.71-17.1)and initial T(ti-zr)of 790℃.Compared with the adjacent crust-derived S-type granites(-24.8--5.1)and I-type granites(-11.0 to-5.2),the Dachang S-type biotite granites present higher zirconεHf(t)values(-9.1 to-2.1).Furthermore,the low magmatic zirconδ18O values(6.2‰)and higher apatite LREE(3277-4114 ppm)and Sr(1137-1357 ppm)contents than of arc-type basic rocks were discerned.These characteristics jointly hint the contributions of mantle components.The higher initial T(ti-zr)(>850℃),whole-rock Mg#(52 to 58),apatiteεNd(t)(-9.2 to-6.5)and zirconεHf(t)(-7.6 to 2.5)values but lower zirconδ18O values(6.33 to 8.30‰)of the later granodiorite porphyry dike than those of the batholith also suggest that mantle material was involved in the generation of the dikes,which is evident by the variational features of zircon and apatite trace elements.In addition,at the zircon Hf<12000 ppm and Eu/Eu*>0.05,the higher zirconΔFMQ values(mostly from-1.8 to 2.0)and H2O contents(100-1100 ppm)of the Dachang granitoids than the pure crust-derived S-type granites(ΔFMQ=mostly from-3.7 to-1.5;H2O<100 ppm)imply that mantle materials involved are relatively rich in water and oxidized.These suggest that the addition of mantle components is conducive to the extraction of Sn from metasedimentary sources,and moderately facilitates the increase of oxygen fugacity which still maintains the incompatibility of Sn in magmas withΔFMQ<2.Also,the involvement of mantle components upgrades the H2O contents in S-type magmas,favoring the migration of ore-forming elements from magmas to hydrothermal fluids.The sediment-derived causative granites displayed higherεHf(t)andεNd(t)values with greater Sn tonnages of their associated world-class Sn polymetallic deposits,supporting the opinion that the contributions of mantle components play an important role in the generation of giant Sn deposits.