This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentr...This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentrations of absorber-layer material and operating temperature. Our aims focused to identify the most optimal thin-film solar cell structure that offers high efficiency and lower toxicity which are desirable for sustainable and eco-friendly energy sources globally. SCAPS-1D, widely used software for modeling and simulating solar cells, has been used and solar cell fundamental performance parameters such as open-circuited voltage (), short-circuited current density (), fill-factor() and efficiency() have been optimized in this study. Based on our simulation results, it was found that CZTS solar cell with Cd<sub>0.4</sub>Zn<sub>0.6</sub>S as buffer-layer offers the most optimal combination of high efficiency and lower toxicity in comparison to other structure investigated in our study. Although the efficiency of Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS are comparable, Cd<sub>0.4</sub>Zn<sub>0.6</sub>S is preferable to use as buffer-layer for its non-toxic property. In addition, evaluation of performance as a function of buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS showed that optimum buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S was in the range from 50 to 150nm while ZnS offered only 50 – 75 nm. Furthermore, the temperature dependence performance parameters evaluation revealed that it is better to operate solar cell at temperature 290K for stable operation with optimum performances. This study would provide valuable insights into design and optimization of nanotechnology-based solar energy technology for minimizing global energy crisis and developing eco-friendly energy sources sustainable and simultaneously.展开更多
This study presents a state of the art of several studies dealing with the environmental impact assessment of fuel cell (FC) vehicles and the comparison with their conventional fossil-fuelled counterparts, by means of...This study presents a state of the art of several studies dealing with the environmental impact assessment of fuel cell (FC) vehicles and the comparison with their conventional fossil-fuelled counterparts, by means of the Life Cycle As-sessment (LCA) methodology. Results declare that, depending on the systems characteristics, there are numerous envi-ronmental advantages, but also some disadvantages can be expected. In addition, the significance of the manufac-turing process of the FC, more specifically the Polymer Electrolyte Membrane Fuel Cell (PEMFC) type, in terms of environmental impact is presented. Finally, CIEMAT’s role in HYCHAIN European project, consisting of supporting early adopters for hydrogen FCs in the transport sector, is展开更多
Starting from the supposition of time-space substitution, the Langbein-Schumm's Law was applied to deal with response of fluvial erosion System to the changes in mean annual Precipitation induced by global green-h...Starting from the supposition of time-space substitution, the Langbein-Schumm's Law was applied to deal with response of fluvial erosion System to the changes in mean annual Precipitation induced by global green-house warming. As a result, a simple method was put forward to predict change in sediment yield, with Ningxia Hui Autonomous Region in the northern fringe of the Loess Plateau of China as an example. Results show that, even the change in mean annual precipitation is the same, the direction and magnitude of the resultant chang in sediment yteld would be quite different in fferent physico-geographical zones. When mean annual precipitation is increased, sediment yield in arid or semi-arid areas with a mean anntal Peripitation of less than 400 mm will be increased, while sediment yield in sub-humid or humid areas with a mean annual precipitation of more than 400 mm will be decreased.Additionally, the complex response of fluvial erosion system in time series due to the lag of change in vegetation behind the changn in precipitation has also been qualitatively discussed in this paper.展开更多
Global surface temperature has increased by 0.2℃per decade in the past 30 years,similar to the warming rate predicted in the 1980s in initial global climate model simulations with transient greenhouse gas changes.War...Global surface temperature has increased by 0.2℃per decade in the past 30 years,similar to the warming rate predicted in the 1980s in initial global climate model simulations with transient greenhouse gas changes.Warming is larger in the Western Equatorial Pacific than in the Eastern Equatorial Pacific over the past century previous research on the economic impacts of a climate-induced sea level rise has been based on the gradual erosion of the shoreline。展开更多
To suppress the global environment pollutions, we tried to develop a new-type solar drying house by improving a typical agricultural green-house, so that an all weather-type solar drying house was invented ultimately....To suppress the global environment pollutions, we tried to develop a new-type solar drying house by improving a typical agricultural green-house, so that an all weather-type solar drying house was invented ultimately. This house is capable to dry raw wood materials (Ogako) into suitable moisture content (Mc) to make a wood pellet. The all weather-type solar Ogako drying house is covered with a triple transparent film, and an open/close free-type shield sheet is spread along with house’s inner surface with a small space, which is opened when solar radiation is incident on the house in daytime and closed to prevent heat loss from the house while out of sun shining in night. Inside of the all weather-type solar Ogako drying house, there are four belt-conveyors over which four top radiation panels are hanged, and on which four Ogako agitators are touched, a turn-table, two hoppers, four small fans, and besides, a floor heating is molded in concrete floor. Also on the north wall outside the house, two insulated cylinders (chimney) are stood up vertically to exhaust inside moist air passively. Then, to make clearly the operation performance of the house, the drying tests for the proof examination were conducted nineteen times at first test site in Ashoro where is located east-central part of Hokkaido, Japan. As a result of the drying test for the proof examination, it was made clear that the all weather-type solar Ogako drying house is practically useful as a supplementary apparatus to produce the dried Ogako, and consequently to suppress CO2 exhaustion.展开更多
Peat utilization for agriculture expansion area is commonly found extensively in tropical region during the last few decades. Most agronomical practices involve drainage resulting decomposition of organic materials an...Peat utilization for agriculture expansion area is commonly found extensively in tropical region during the last few decades. Most agronomical practices involve drainage resulting decomposition of organic materials and increasing drying. This study was carried out to determine the potential use of molecular-sieving materials (MPMs) as an ameliorant for peat soil targeted for reducing the potential hazard of peat degradation. A clinoptilolite-zeolite, empty fruit bunches of oil palm biochar (EFBOPB), and their combination were studied its characteristics to evaluate the ability in adsorbing water and green-house gas emission. A series of laboratory analyses were conducted to determine physicochemical and mineralogical characteristics of both materials and its combination, including elemental analyses, cation exchange capacity (CEC), pH, ore spaces, water holding capacity (WHC), and adsorption capacity for CO<sub>2</sub>, NH<sub>3</sub>, and N<sub>2</sub>. The study revealed that 100 - 150 mesh size of zeolite possesses higher values of CEC, WHC, and adsorption capacity for CO<sub>2</sub>, NH<sub>3</sub>, and N<sub>2</sub> compared to EFBOPB, whereas the latter indicated a higher organic-C content and pore spaces. Combination of 75% (w/w) zeolite and 25% (w/w) EFBOPB showed the best composition of these two MPMs to improve WHC of peat and as consequences slowing down the firing process of the peat. Based on the gas adsorption data, it could be assumed that the mixture of MPMs studied could be considered as an effective material to reduce risk of peat from fire potential hazard and retard GHG emission.展开更多
文摘This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentrations of absorber-layer material and operating temperature. Our aims focused to identify the most optimal thin-film solar cell structure that offers high efficiency and lower toxicity which are desirable for sustainable and eco-friendly energy sources globally. SCAPS-1D, widely used software for modeling and simulating solar cells, has been used and solar cell fundamental performance parameters such as open-circuited voltage (), short-circuited current density (), fill-factor() and efficiency() have been optimized in this study. Based on our simulation results, it was found that CZTS solar cell with Cd<sub>0.4</sub>Zn<sub>0.6</sub>S as buffer-layer offers the most optimal combination of high efficiency and lower toxicity in comparison to other structure investigated in our study. Although the efficiency of Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS are comparable, Cd<sub>0.4</sub>Zn<sub>0.6</sub>S is preferable to use as buffer-layer for its non-toxic property. In addition, evaluation of performance as a function of buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS showed that optimum buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S was in the range from 50 to 150nm while ZnS offered only 50 – 75 nm. Furthermore, the temperature dependence performance parameters evaluation revealed that it is better to operate solar cell at temperature 290K for stable operation with optimum performances. This study would provide valuable insights into design and optimization of nanotechnology-based solar energy technology for minimizing global energy crisis and developing eco-friendly energy sources sustainable and simultaneously.
文摘This study presents a state of the art of several studies dealing with the environmental impact assessment of fuel cell (FC) vehicles and the comparison with their conventional fossil-fuelled counterparts, by means of the Life Cycle As-sessment (LCA) methodology. Results declare that, depending on the systems characteristics, there are numerous envi-ronmental advantages, but also some disadvantages can be expected. In addition, the significance of the manufac-turing process of the FC, more specifically the Polymer Electrolyte Membrane Fuel Cell (PEMFC) type, in terms of environmental impact is presented. Finally, CIEMAT’s role in HYCHAIN European project, consisting of supporting early adopters for hydrogen FCs in the transport sector, is
文摘Starting from the supposition of time-space substitution, the Langbein-Schumm's Law was applied to deal with response of fluvial erosion System to the changes in mean annual Precipitation induced by global green-house warming. As a result, a simple method was put forward to predict change in sediment yield, with Ningxia Hui Autonomous Region in the northern fringe of the Loess Plateau of China as an example. Results show that, even the change in mean annual precipitation is the same, the direction and magnitude of the resultant chang in sediment yteld would be quite different in fferent physico-geographical zones. When mean annual precipitation is increased, sediment yield in arid or semi-arid areas with a mean anntal Peripitation of less than 400 mm will be increased, while sediment yield in sub-humid or humid areas with a mean annual precipitation of more than 400 mm will be decreased.Additionally, the complex response of fluvial erosion system in time series due to the lag of change in vegetation behind the changn in precipitation has also been qualitatively discussed in this paper.
文摘Global surface temperature has increased by 0.2℃per decade in the past 30 years,similar to the warming rate predicted in the 1980s in initial global climate model simulations with transient greenhouse gas changes.Warming is larger in the Western Equatorial Pacific than in the Eastern Equatorial Pacific over the past century previous research on the economic impacts of a climate-induced sea level rise has been based on the gradual erosion of the shoreline。
文摘To suppress the global environment pollutions, we tried to develop a new-type solar drying house by improving a typical agricultural green-house, so that an all weather-type solar drying house was invented ultimately. This house is capable to dry raw wood materials (Ogako) into suitable moisture content (Mc) to make a wood pellet. The all weather-type solar Ogako drying house is covered with a triple transparent film, and an open/close free-type shield sheet is spread along with house’s inner surface with a small space, which is opened when solar radiation is incident on the house in daytime and closed to prevent heat loss from the house while out of sun shining in night. Inside of the all weather-type solar Ogako drying house, there are four belt-conveyors over which four top radiation panels are hanged, and on which four Ogako agitators are touched, a turn-table, two hoppers, four small fans, and besides, a floor heating is molded in concrete floor. Also on the north wall outside the house, two insulated cylinders (chimney) are stood up vertically to exhaust inside moist air passively. Then, to make clearly the operation performance of the house, the drying tests for the proof examination were conducted nineteen times at first test site in Ashoro where is located east-central part of Hokkaido, Japan. As a result of the drying test for the proof examination, it was made clear that the all weather-type solar Ogako drying house is practically useful as a supplementary apparatus to produce the dried Ogako, and consequently to suppress CO2 exhaustion.
文摘Peat utilization for agriculture expansion area is commonly found extensively in tropical region during the last few decades. Most agronomical practices involve drainage resulting decomposition of organic materials and increasing drying. This study was carried out to determine the potential use of molecular-sieving materials (MPMs) as an ameliorant for peat soil targeted for reducing the potential hazard of peat degradation. A clinoptilolite-zeolite, empty fruit bunches of oil palm biochar (EFBOPB), and their combination were studied its characteristics to evaluate the ability in adsorbing water and green-house gas emission. A series of laboratory analyses were conducted to determine physicochemical and mineralogical characteristics of both materials and its combination, including elemental analyses, cation exchange capacity (CEC), pH, ore spaces, water holding capacity (WHC), and adsorption capacity for CO<sub>2</sub>, NH<sub>3</sub>, and N<sub>2</sub>. The study revealed that 100 - 150 mesh size of zeolite possesses higher values of CEC, WHC, and adsorption capacity for CO<sub>2</sub>, NH<sub>3</sub>, and N<sub>2</sub> compared to EFBOPB, whereas the latter indicated a higher organic-C content and pore spaces. Combination of 75% (w/w) zeolite and 25% (w/w) EFBOPB showed the best composition of these two MPMs to improve WHC of peat and as consequences slowing down the firing process of the peat. Based on the gas adsorption data, it could be assumed that the mixture of MPMs studied could be considered as an effective material to reduce risk of peat from fire potential hazard and retard GHG emission.
