A simplified numerical model of groundwater and solute transport is developed. At large scale area there exists a big spatial scale difference between horizontal and vertical length scales. In the resultant model, the...A simplified numerical model of groundwater and solute transport is developed. At large scale area there exists a big spatial scale difference between horizontal and vertical length scales. In the resultant model, the seepage region is particularly divided into several virtual layers along the z direction and vertical 1-D columns covering x-y 2-D area according to stratum properties. The numerical algorithm is replacing the full 3-D water and mass balance analysis as the 2-D Galerkin finite element method in x- and y-directions and 1-D finite differential approach in the z direction. The reasonable method of giving minimum thickness is successfully used to handle transient change of water table, drying cells and problem of rewetting. The solution of the simplified model is preconditioned conjugate gradient and ORTHOMIN method. The validity of the developed 3-D groundwater model is tested with the typical pumping and backwater scenarios. Results of water balance of the computed example reveal the model computation reliability. Based on a representative 3-D pollution case, the solute transport module is tested against computing results using the MT3DMS. The capability and high efficiency to predict non-stationary situations of free groundwater surface and solute plume in regional scale problem is quantitatively investigated. It is shown that the proposed model is computationally effective.展开更多
In the present work, potential groundwater pollution by methabenzthiazuron （MTBU） and the effect of three different amendments （composted sheep manure, composted pine bark and spent coffee grounds） on its mobility...In the present work, potential groundwater pollution by methabenzthiazuron （MTBU） and the effect of three different amendments （composted sheep manure, composted pine bark and spent coffee grounds） on its mobility were investigated under laboratory conditions. The efficiency of ZnO and TiO2 suspensions in the photocatalytic degradation of MTBU in leaching water was also investigated. The relative and cumulative breakthrough curves were obtained from disturbed soil columns. The presence and/or addition of organic matter drastically reduced the movement of the herbicide. On other hand, photocatalytic experiments showed that the addition of ZnO and TiO2 strongly enhances the degradation rate of this herbicide compared with the results of photolytic experiments under artificial light. ZnO appeared to be more effective in MTBU oxidation than TiO2. The results obtained point to the interest of using organic wastes and heterogeneous photocatalysis for reducing the pollution of groundwater by pesticide drainage.展开更多
基金supported by the National Science Fund for Distinguished Young Scholars(Grant No.40701071)
文摘A simplified numerical model of groundwater and solute transport is developed. At large scale area there exists a big spatial scale difference between horizontal and vertical length scales. In the resultant model, the seepage region is particularly divided into several virtual layers along the z direction and vertical 1-D columns covering x-y 2-D area according to stratum properties. The numerical algorithm is replacing the full 3-D water and mass balance analysis as the 2-D Galerkin finite element method in x- and y-directions and 1-D finite differential approach in the z direction. The reasonable method of giving minimum thickness is successfully used to handle transient change of water table, drying cells and problem of rewetting. The solution of the simplified model is preconditioned conjugate gradient and ORTHOMIN method. The validity of the developed 3-D groundwater model is tested with the typical pumping and backwater scenarios. Results of water balance of the computed example reveal the model computation reliability. Based on a representative 3-D pollution case, the solute transport module is tested against computing results using the MT3DMS. The capability and high efficiency to predict non-stationary situations of free groundwater surface and solute plume in regional scale problem is quantitatively investigated. It is shown that the proposed model is computationally effective.
基金financial support from Ramón and Cajal Subprogram,the Instituto Nacional de Investigacióny Tecnologīa Agraria y Alimentaria(ProjectRTA2011-00022-00-00)the Ministerio de Espana de Ciencia e Innovación(Project AGL2010-20458-C02-01)
文摘In the present work, potential groundwater pollution by methabenzthiazuron （MTBU） and the effect of three different amendments （composted sheep manure, composted pine bark and spent coffee grounds） on its mobility were investigated under laboratory conditions. The efficiency of ZnO and TiO2 suspensions in the photocatalytic degradation of MTBU in leaching water was also investigated. The relative and cumulative breakthrough curves were obtained from disturbed soil columns. The presence and/or addition of organic matter drastically reduced the movement of the herbicide. On other hand, photocatalytic experiments showed that the addition of ZnO and TiO2 strongly enhances the degradation rate of this herbicide compared with the results of photolytic experiments under artificial light. ZnO appeared to be more effective in MTBU oxidation than TiO2. The results obtained point to the interest of using organic wastes and heterogeneous photocatalysis for reducing the pollution of groundwater by pesticide drainage.
