Octa-membered Water Ring Chain Based on Sulfonic Group in Ni(II) Complex with 2-[(E)-(2-Oxidophenyl)methyleneamino] Ethanesulfonato and 2,2′-Bipyridinyl

The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.

Some Group Runs Based Multivariate Control Charts for Monitoring the Process Mean Vector

In this article, we propose two control charts namely, the “Multivariate Group Runs’ (MV-GR-M)” and the “Multivariate Modified Group Runs’ (MV-MGR-M)” control charts, based on the multivariate normal processes, for monitoring the process mean vector. Methods to obtain the design parameters and operations of these control charts are discussed. Performances of the proposed charts are compared with some existing control charts. It is verified that, the proposed charts give a significant reduction in the out-of-control “Average Time to Signal” (ATS) in the zero state, as well in the steady state compared to the Hotelling’s T2 and the synthetic T2 control charts.

VANET Security through Group Broadcast Encryption

VANET security is an evolving topic in mobile networks, as providing a secure layer of communications in such a dynamic and fast network is a challenge. The work presented in this article was conducted in order to verify and evaluate the feasibility of applying group broadcast cryptography to the VANET environment, as an attempt to gain performance by decreasing the number of messages in the wireless network. Group broadcast is a symmetric/asymmetric hybrid cryptography method, aiming to merge the best of the two approaches without their major drawbacks. Simulations were set-up and run using the ONE simulator, comparing the usage of the three different cryptography approaches for VANETs. Results consider the number of connections, the number messages and the number of revocation messages per day. The resulting data promises that group broadcast encryption can be used to simplify the encrypting phase, reduce required storage and significantly decrease the number of messages in the network.

Second Group of National Human Rights Education and Training Bases Established

The Ministry of Education and the State Council Information Office on July 22 announced the second group of national human rights education and training bases, in- cluding the Human Rights Research Center at Renmin University of China, the Human Rights Research Center at Fudan University, the Human Rights Research Academy at Wuhan University, the Human Rights Research Center at Shandong University and the Human Rights Education and Research Center at the Southwest University of Politica~ Science arid Law.

一种无线传感器网络的密钥管理机制

介绍了一种用于无线传感器网络(WSNs)的密钥预分配机制:多密钥空间哈希随机密钥预分配(HARPMS)机制。该机制针对group-based节点投放模型,将密钥空间划分成多个子空间,在密钥分配和建立时使用Hash链技术,以提高网络的抗节点俘获能力。分析表明:相比传统的用于group-based投放模型的随机密钥预分配机制,HARPMS获得了同等的连通性,但却有更好的抗节点俘获能力。

Statistical Characteristics of Complete Tobacco Necrosis Virus Genome and Clustering

[Objective] The study aimed to extract the statistical features of complete tobacco necrosis virus genome and conduct clustering analysis.[Method] On the base sequence of complete tobacco necrosis virus genome,by using three base groups which was composed of each base and its subsequent two bases,a new sequence S was arranged;the probability of all 64 kinds of three base groups occurred on S was calculated,a 64-dimensional vector L was obtained;L-vector of each genome was compared,8 three base groups were obtained,their probabilities have significant differences.[Result] The emergence probability of 8 three base groups （CGT;CAA;TAC;TAA;AGG;ATG;ATA;AAG） has significant association with genetic variation of tobacco necrosis virus genome;according to genetic variation result,4 different sources tobacco necrosis virus complete genome formed 2 major categories.[Conclusion] The study will provide theoretical basis for the control of tobacco necrosis virus.

Synthesis and catalytic activity of Ln (III) complexes with an unsymmetrical Schiff base including multi“非汉字符号” C=N—groups

A synthetic method for a new unsymmetrical Schiff base and its Ln(Ⅲ)complexes including multi > C = N — groups is reported. The complexes are characterized byelemental analysis, IR spectra, ~1H and ^(13)C NMR, especially 2D-COSY ~1H, ~1H NMR spectra. Thegeneral formula of the obtained complexes is [Ln_3(TBLY)(NO_3)_3] · nH_2O (Ln = La, n = 3; Ln = Nd,n=5; Ln = Gd, Dy, Yb, Y, n = 7), where TBLY = tetraglycol aldehyde-2,4-dihydroxy benzaldehydebis-lysine Schiff base. In addition, the evidence for existence of > C = CH — NH — group issupported by the AM1 method. The complexes obtained may be used as a catalyst. Conversion rate of80% with the viscosity-average molecular weight 220000 for the polymerization of methyl methacrylate(MMA) without addition of any cocatalyst has been obtained.

Jizhong Energy Group Mulls Salt Chemical Base

The Hebei provincial government recentlyapproved Jizhong Energy Group Co.,Ltd.to develop the salt mine reserve inNingjin county,Xingtai,Hebei provinceto build an important salt chemical basein China.It was predicted that the recentlyproved salt mine has a salt reserve of morethan 100 billion tons,with an

An Efficient Synthesis of Highly Optically Active 4-Substituted- 2(5H)-furanones from Chiral 3-Bromo-2(5H)-furanone

gHighly optically active 4-substituted-2(5H)-furanones 6a—6j were obtained in good yields with de≥98% by the tandem Michael addition/elimination reaction of chiral 3-bromo-2(5H)-furanone (4a), which was conveniently prepared starting from 2-furaldehyde under mild conditions. The products were identified on the basis of their sat-isfactory elemental analysis and spectroscopic data of IR, UV, 1H NMR, 13C NMR and mass spectra. The stereo-chemistry and absolute configuration of this type of compounds were established by the X-ray crystallographic study. The reaction provided a short and efficient synthesis of the interesting highly optically active 4-substituted-2(5H)-furanones containing an active pyrimidine and a purine base group.