Apically guiding electron/mass transfer reaction induced by Ag/FeN_(x)Mott-Schottky effect within a hollow star reactor toward high performance zinc-air batteries

The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.

Guiding of 150 keV O^(6+) ions through nanocapillaries in an uncoated Al_2O_3 membrane:special time dependence of the transmission profile width

This paper reports that the transmission of O6＋ ions with energy of 150keV through capillaries in an uncoated Al2O3 membrane was measured, and agreements with previously reported results in general angular distribution of the transmitted ions and the transmission fractions as a function of the tilt angle well fitted to Gaussian-like functions were observed. Due tousing an uncoated capillary membrane, our φc is larger than that using a gold-coated one with a smaller value of Ep/q, which suggests a larger equilibrium charge Q∞ in our experiment. The observed special width variation with time and a larger width than that using a smaller Ep/q were qualitatively explained by using mean-field classical transport theory based on a classical-trajectory Monte Carlo simulation.

Spatial-temporal characterization of the San Andreas Fault by fault-zone trapped waves at seismic experiment site,Parkfield,California

In this article,we review our previous research for spatial and temporal characterizations of the San Andreas Fault(SAF)at Parkfield,using the fault-zone trapped wave(FZTW)since the middle 1980s.Parkfield,California has been taken as a scientific seismic experimental site in the USA since the 1970s,and the SAF is the target fault to investigate earthquake physics and forecasting.More than ten types of field experiments(including seismic,geophysical,geochemical,geodetic and so on)have been carried out at this experimental site since then.In the fall of 2003,a pair of scientific wells were drilled at the San Andreas Fault Observatory at Depth(SAFOD)site;the main-hole(MH)passed a~200-m-wide low-velocity zone(LVZ)with highly fractured rocks of the SAF at a depth of~3.2 km below the wellhead on the ground level(Hickman et al.,2005;Zoback,2007;Lockner et al.,2011).Borehole seismographs were installed in the SAFOD MH in 2004,which were located within the LVZ of the fault at~3-km depth to probe the internal structure and physical properties of the SAF.On September 282004,a M6 earthquake occurred~15 km southeast of the town of Parkfield.The data recorded in the field experiments before and after the 2004 M6 earthquake provided a unique opportunity to monitor the co-mainshock damage and post-seismic heal of the SAF associated with this strong earthquake.This retrospective review of the results from a sequence of our previous experiments at the Parkfield SAF,California,will be valuable for other researchers who are carrying out seismic experiments at the active faults to develop the community seismic wave velocity models,the fault models and the earthquake forecasting models in global seismogenic regions.

The single-longitudinal-mode operation of a ridge waveguide laser based on two-dimensional photonic crystals

An electrically driven, single-longitudinal-mode GaAs based photonic crystal （PC） ridge waveguide （RWG） laser emitting at around 850 nm is demonstrated. The single-longitudinal-mode lasing characteristic is achieved by introducing the PC to the RWG laser. The triangle PC is etched on both sides of the ridge by photolithography and inductive coupled plasma （ICP） etching. The lasing spectra of the RWG lasers with and without the PC are studied, and the result shows that the PC purifies the longitudinal mode. The power per facet versus current and current-voltage characteristics have also been studied and compared.

Review on second-harmonic generation of ultrasonic guided waves in solid media(Ⅰ): Theoretical analyses

Considering the high sensitivity of the nonlinear ultrasonic measurement technique and great advantages of the guided wave testing method, the use of nonlinear ultrasonic guided waves provides a promising means for evaluating and characterizing the hidden and/or inaccessible damage/degradation in solid media. Increasing attention on the development of the testing method based on nonlinear ultrasonic guided waves is largely attributed to the theoretical advances of nonlinear guided waves propagation in solid media. One of the typical acoustic nonlinear responses is the generation of second harmonics that can be used to effectively evaluate damage/degradation in materials/structures. In this paper, the theoretical progress of second-harmonic generation（SHG） of ultrasonic guided wave propagation in solid media is reviewed. The advances and developments of theoretical investigations on the effect of SHG of ultrasonic guided wave propagation in different structures are addressed. Some obscure understandings and the ideas in dispute are also discussed.

Transmission of 18 keV negative ions Cl^-through nanocapillariesin Al_2O_3 membrane

We investigate the angular distribution of the transmitted 18keV negative ions Cl- through Al2O3 nanocapillaries of 50 nm in diameter and 10 μm in length. Elastic scattering ions and inelastic scattering ions are obtained simultaneously. The experimental result is partially consistent with the guiding effect. We can qualitatively explain our experimental result through a dynamic process.

The Effect of Lateral Guiding Mechanism on Noise Characteristics in Semiconductor Lasers

A comparison between intensity noise spectra and also the line shapes of gain-guided, weakly-index-guided, and strongly-index-guided semiconductor lasers are made using numerical solution of Maxwell-Bloch equations including spontaneous emission noise.