The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with e...The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.展开更多
The classical Pauli particle(CPP) serves as a slow manifold, substituting the conventional guiding center dynamics. Based on the CPP, we utilize the averaged vector field(AVF) method in the computations of drift orbit...The classical Pauli particle(CPP) serves as a slow manifold, substituting the conventional guiding center dynamics. Based on the CPP, we utilize the averaged vector field(AVF) method in the computations of drift orbits. Demonstrating significantly higher efficiency, this advanced method is capable of accomplishing the simulation in less than one-third of the time of directly computing the guiding center motion. In contrast to the CPP-based Boris algorithm, this approach inherits the advantages of the AVF method, yielding stable trajectories even achieved with a tenfold time step and reducing the energy error by two orders of magnitude. By comparing these two CPP algorithms with the traditional RK4 method, the numerical results indicate a remarkable performance in terms of both the computational efficiency and error elimination. Moreover, we verify the properties of slow manifold integrators and successfully observe the bounce on both sides of the limiting slow manifold with deliberately chosen perturbed initial conditions. To evaluate the practical value of the methods, we conduct simulations in non-axisymmetric perturbation magnetic fields as part of the experiments,demonstrating that our CPP-based AVF method can handle simulations under complex magnetic field configurations with high accuracy, which the CPP-based Boris algorithm lacks. Through numerical experiments, we demonstrate that the CPP can replace guiding center dynamics in using energy-preserving algorithms for computations, providing a new, efficient, as well as stable approach for applying structure-preserving algorithms in plasma simulations.展开更多
The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of...The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of Advanced Geochemistry has effectively stimulated students’interest in learning and further improved their scientific thinking and research innovation skills through the implementation of“Guiding Interactive”teaching reform measures,which has important theoretical significance and practical value.展开更多
Through analyzing Marx's agricultural intensive management thought,this paper points out that the existence and development of agricultural management mode experience historical course and the development of agric...Through analyzing Marx's agricultural intensive management thought,this paper points out that the existence and development of agricultural management mode experience historical course and the development of agricultural intensification depends on many objective conditions.On the basis of this,it discusses the guiding significance of Marx's agricultural intensive management thought to China's agricultural development.It is required to fully realize basic current situations of China's agriculture,widely popularize agricultural mechanization and electrification,speed up artificial transformation of soil structure,promote chemical application of agriculture,make rational use of water resource,and spread improved seeds.展开更多
We develop two types of adaptive energy preserving algorithms based on the averaged vector field for the guiding center dynamics,which plays a key role in magnetized plasmas.The adaptive scheme is applied to the Gauss...We develop two types of adaptive energy preserving algorithms based on the averaged vector field for the guiding center dynamics,which plays a key role in magnetized plasmas.The adaptive scheme is applied to the Gauss Legendre’s quadrature rules and time stepsize respectively to overcome the energy drift problem in traditional energy-preserving algorithms.These new adaptive algorithms are second order,and their algebraic order is carefully studied.Numerical results show that the global energy errors are bounded to the machine precision over long time using these adaptive algorithms without massive extra computation cost.展开更多
The essay has two main purposes.The first consists of discussing some literary and philosophical thoughts on the epistemological value of science by one of the most famous and celebrated poets in Italian literature,Gi...The essay has two main purposes.The first consists of discussing some literary and philosophical thoughts on the epistemological value of science by one of the most famous and celebrated poets in Italian literature,Giacomo Leopardi.The poet firmly believes in the cognitive power of science,capable of revealing false beliefs with the light of reason.However,in his mature reflections,what will radically change will not be the value of scientific activity itself,always admirably accepted,but rather its true salvific force.Leopardi was not a scientist,but he used the scientific culture of his time to critically address the great existential themes of man concerning nature and the universe.He had amply demonstrated a scientific culture since his youthful'History of Astronomy',which would reappear in many of his other literary works.His deep and meditative reflections on the nature of finite and infinite space and time are a clear and fruitful testimony to this.However,Giacomo writes icastically,reason alone is not enough;it needs imagination.The second concerns a first reconstruction of the influence that the philosophy of Enlightenment had on Leopardi’s thought especially in relation to these topics:atheism,rejection of providentialism and anthropocentrism,the conception of nature,the question of the relationship between human and animal intelligence,the rejection of metaphysics,the importance of scientific knowledge.展开更多
This paper discusses Master Tanxu’s Thought of Middle Way from three aspects:interpreting the Middle Way with the Tiantai Sect’s thought of“Three Truths as a Unity”(三諦圓融),discussing“the Truth of the First Mea...This paper discusses Master Tanxu’s Thought of Middle Way from three aspects:interpreting the Middle Way with the Tiantai Sect’s thought of“Three Truths as a Unity”(三諦圓融),discussing“the Truth of the First Meaning of the Middle Way”(中道第一義諦)from the relationship between“the One Mind”and the Middle Way,and discussing gradations of practice of the Middle Way.展开更多
Skilled talents are the main support for the strategic development of science and technology in China.The quality of talents is an important guarantee for the transformation and upgrading of national industries.By ana...Skilled talents are the main support for the strategic development of science and technology in China.The quality of talents is an important guarantee for the transformation and upgrading of national industries.By analyzing and studying Huang Yanpei’s thought on vocational education,this paper focuses on the cultivation of students’craftsmanship in vocational schools.First,we analyze the results of previous research and then elaborate on the connotations of Huang Yanpei’s education thought and craftsmanship spirit.Lastly,we propose five suggestions for the cultivation of craftsmanship.Our research work carries certain reference value to the study of craftsmanship cultivation in Huang Yanpei’s education thought.展开更多
基金the financial support of the National Natural Science Foundation of China(52002079,22378074,22179025 and U20A20340)the Guangdong Basic and Applied Basic Research Foundation(2022A1515140085)+2 种基金the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology(FC202209)the Guangzhou Hongmian Project(HMJH-20200012)the Foshan Introducing Innovative and Entrepreneurial Teams(1920001000108)。
文摘The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs.
基金supported by National Natural Science Foundation of China (Nos. 11975068 and 11925501)the National Key R&D Program of China (No. 2022YFE03090000)the Fundamental Research Funds for the Central Universities (No. DUT22ZD215)。
文摘The classical Pauli particle(CPP) serves as a slow manifold, substituting the conventional guiding center dynamics. Based on the CPP, we utilize the averaged vector field(AVF) method in the computations of drift orbits. Demonstrating significantly higher efficiency, this advanced method is capable of accomplishing the simulation in less than one-third of the time of directly computing the guiding center motion. In contrast to the CPP-based Boris algorithm, this approach inherits the advantages of the AVF method, yielding stable trajectories even achieved with a tenfold time step and reducing the energy error by two orders of magnitude. By comparing these two CPP algorithms with the traditional RK4 method, the numerical results indicate a remarkable performance in terms of both the computational efficiency and error elimination. Moreover, we verify the properties of slow manifold integrators and successfully observe the bounce on both sides of the limiting slow manifold with deliberately chosen perturbed initial conditions. To evaluate the practical value of the methods, we conduct simulations in non-axisymmetric perturbation magnetic fields as part of the experiments,demonstrating that our CPP-based AVF method can handle simulations under complex magnetic field configurations with high accuracy, which the CPP-based Boris algorithm lacks. Through numerical experiments, we demonstrate that the CPP can replace guiding center dynamics in using energy-preserving algorithms for computations, providing a new, efficient, as well as stable approach for applying structure-preserving algorithms in plasma simulations.
基金This article is the research result of the Education and Teaching Reform Research Project(No.2022JGB038)of Central South University and supported by the Scientific Research Fund of Hunan Provincial Education Department(No.23B0953).
文摘The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of Advanced Geochemistry has effectively stimulated students’interest in learning and further improved their scientific thinking and research innovation skills through the implementation of“Guiding Interactive”teaching reform measures,which has important theoretical significance and practical value.
文摘Through analyzing Marx's agricultural intensive management thought,this paper points out that the existence and development of agricultural management mode experience historical course and the development of agricultural intensification depends on many objective conditions.On the basis of this,it discusses the guiding significance of Marx's agricultural intensive management thought to China's agricultural development.It is required to fully realize basic current situations of China's agriculture,widely popularize agricultural mechanization and electrification,speed up artificial transformation of soil structure,promote chemical application of agriculture,make rational use of water resource,and spread improved seeds.
基金supported by National Natural Science Foundation of China(Nos.11901564,11775222 and 12171466)Geo-Algorithmic Plasma Simulator(GAPS)Project。
文摘We develop two types of adaptive energy preserving algorithms based on the averaged vector field for the guiding center dynamics,which plays a key role in magnetized plasmas.The adaptive scheme is applied to the Gauss Legendre’s quadrature rules and time stepsize respectively to overcome the energy drift problem in traditional energy-preserving algorithms.These new adaptive algorithms are second order,and their algebraic order is carefully studied.Numerical results show that the global energy errors are bounded to the machine precision over long time using these adaptive algorithms without massive extra computation cost.
文摘The essay has two main purposes.The first consists of discussing some literary and philosophical thoughts on the epistemological value of science by one of the most famous and celebrated poets in Italian literature,Giacomo Leopardi.The poet firmly believes in the cognitive power of science,capable of revealing false beliefs with the light of reason.However,in his mature reflections,what will radically change will not be the value of scientific activity itself,always admirably accepted,but rather its true salvific force.Leopardi was not a scientist,but he used the scientific culture of his time to critically address the great existential themes of man concerning nature and the universe.He had amply demonstrated a scientific culture since his youthful'History of Astronomy',which would reappear in many of his other literary works.His deep and meditative reflections on the nature of finite and infinite space and time are a clear and fruitful testimony to this.However,Giacomo writes icastically,reason alone is not enough;it needs imagination.The second concerns a first reconstruction of the influence that the philosophy of Enlightenment had on Leopardi’s thought especially in relation to these topics:atheism,rejection of providentialism and anthropocentrism,the conception of nature,the question of the relationship between human and animal intelligence,the rejection of metaphysics,the importance of scientific knowledge.
基金国家社科基金一般项目-中国思想史上的中观学研究,Serial Number 20BZJ012辽宁省社会科学规划基金一般项目-中国古代中道哲学的时代价值研究,Serial Number L22BZX001+1 种基金辽宁大学本科教学改革研究项目-哲学专业本科生《宗教学纲要》课程教学改革初探,Serial Number JG2021PTXM0342023年度辽宁大学亚洲研究中心一般项目-中国古代中道哲学与人类命运共同体构建.
文摘This paper discusses Master Tanxu’s Thought of Middle Way from three aspects:interpreting the Middle Way with the Tiantai Sect’s thought of“Three Truths as a Unity”(三諦圓融),discussing“the Truth of the First Meaning of the Middle Way”(中道第一義諦)from the relationship between“the One Mind”and the Middle Way,and discussing gradations of practice of the Middle Way.
基金The Project of China Vocational Education Association(Project Number:ZJS2022YB024)The Project of Innovation and Development Center of Ideological and Political Work(Beijing Polytechnic),Ministry of Education(Project Number:2022X305-SXZC).
文摘Skilled talents are the main support for the strategic development of science and technology in China.The quality of talents is an important guarantee for the transformation and upgrading of national industries.By analyzing and studying Huang Yanpei’s thought on vocational education,this paper focuses on the cultivation of students’craftsmanship in vocational schools.First,we analyze the results of previous research and then elaborate on the connotations of Huang Yanpei’s education thought and craftsmanship spirit.Lastly,we propose five suggestions for the cultivation of craftsmanship.Our research work carries certain reference value to the study of craftsmanship cultivation in Huang Yanpei’s education thought.