Forty soils from top layer (0-20 cm) were sampled in different regions of China and Kjeldahl, HF-Kjeldahl and double treatment methods were used to determine total N, total N plus fixed ammonium, and total N and the r...Forty soils from top layer (0-20 cm) were sampled in different regions of China and Kjeldahl, HF-Kjeldahl and double treatment methods were used to determine total N, total N plus fixed ammonium, and total N and the residual fixed ammonium left in soil after determination of total N, respectively, to evaluate if Kjeldahl’s method could include the fixed N by soil minerals. The fixed N by soil minerals was measured by Silva-Bremner procedure to make comparison. Results showed that total N determined by Kjeldahl’s method averaged 1.622 g kg-1, while that by HF- Kjeldahl’s method 1.633 g kg-1, and that by double procedure 1.666 g kg-1. Obviously results obtained by the last two methods, particularly the double treatment method, were higher than Kjeldahl’s, showing that Kjeldahl’s method could not or not fully release N fixed by 2:1 minerals in soil, and therefore the determined results would not be the true “total N” for soils that contained large amount of the fixed N. The mineral fixedN averaged 166 mg kg-1, accounting for 10.1% of the total N while the residual fixed N amounted to 30.4 mg kg-1, equivalent to 1.9% of the total N or 18.3% of the total fixed N. The residual fixed N was correlated neither to organic matter nor to total N, but closely related to the total fixed N with a correlation coefficient of 0.598 (n=40), showing that the fixed N was the sole source of the residues. Soils having high residues of the fixed N were just those containing high fixed N, and soils containing high fixed N were just those containing high amount of 2:1 minerals. As a result, Kjeldahl’s method could not give a true value of the total N for such soils. However, for those containing small or little amount of 2:1 minerals, there was no significant difference in results measured by these methods.展开更多
Hydraulic fracturing （HF） technique has been extensively used for the exploitation of unconventional oiland gas reservoirs. HF enhances the connectivity of less permeable oil and gas-bearing rock formationsby fluid ...Hydraulic fracturing （HF） technique has been extensively used for the exploitation of unconventional oiland gas reservoirs. HF enhances the connectivity of less permeable oil and gas-bearing rock formationsby fluid injection, which creates an interconnected fracture network and increases the hydrocarbonproduction. Meanwhile, microseismic （MS） monitoring is one of the most effective approaches to evaluatesuch stimulation process. In this paper, the combined finite-discrete element method （FDEM） isadopted to numerically simulate HF and associated MS. Several post-processing tools, includingfrequency-magnitude distribution （b-value）, fractal dimension （D-value）, and seismic events clustering,are utilized to interpret numerical results. A non-parametric clustering algorithm designed specificallyfor FDEM is used to reduce the mesh dependency and extract more realistic seismic information.Simulation results indicated that at the local scale, the HF process tends to propagate following the rockmass discontinuities; while at the reservoir scale, it tends to develop in the direction parallel to themaximum in-situ stress. 2014 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting byElsevier B.V. All rights reserved.展开更多
基金the National Natural Sci。ence Foundation of China(30230230,30070429 , 40201028)
文摘Forty soils from top layer (0-20 cm) were sampled in different regions of China and Kjeldahl, HF-Kjeldahl and double treatment methods were used to determine total N, total N plus fixed ammonium, and total N and the residual fixed ammonium left in soil after determination of total N, respectively, to evaluate if Kjeldahl’s method could include the fixed N by soil minerals. The fixed N by soil minerals was measured by Silva-Bremner procedure to make comparison. Results showed that total N determined by Kjeldahl’s method averaged 1.622 g kg-1, while that by HF- Kjeldahl’s method 1.633 g kg-1, and that by double procedure 1.666 g kg-1. Obviously results obtained by the last two methods, particularly the double treatment method, were higher than Kjeldahl’s, showing that Kjeldahl’s method could not or not fully release N fixed by 2:1 minerals in soil, and therefore the determined results would not be the true “total N” for soils that contained large amount of the fixed N. The mineral fixedN averaged 166 mg kg-1, accounting for 10.1% of the total N while the residual fixed N amounted to 30.4 mg kg-1, equivalent to 1.9% of the total N or 18.3% of the total fixed N. The residual fixed N was correlated neither to organic matter nor to total N, but closely related to the total fixed N with a correlation coefficient of 0.598 (n=40), showing that the fixed N was the sole source of the residues. Soils having high residues of the fixed N were just those containing high fixed N, and soils containing high fixed N were just those containing high amount of 2:1 minerals. As a result, Kjeldahl’s method could not give a true value of the total N for such soils. However, for those containing small or little amount of 2:1 minerals, there was no significant difference in results measured by these methods.
基金supported by the Natural Sciences and Engineering Research Council of Canada through Discovery Grant 341275 (G. Grasselli) and Engage EGP 461019-13
文摘Hydraulic fracturing （HF） technique has been extensively used for the exploitation of unconventional oiland gas reservoirs. HF enhances the connectivity of less permeable oil and gas-bearing rock formationsby fluid injection, which creates an interconnected fracture network and increases the hydrocarbonproduction. Meanwhile, microseismic （MS） monitoring is one of the most effective approaches to evaluatesuch stimulation process. In this paper, the combined finite-discrete element method （FDEM） isadopted to numerically simulate HF and associated MS. Several post-processing tools, includingfrequency-magnitude distribution （b-value）, fractal dimension （D-value）, and seismic events clustering,are utilized to interpret numerical results. A non-parametric clustering algorithm designed specificallyfor FDEM is used to reduce the mesh dependency and extract more realistic seismic information.Simulation results indicated that at the local scale, the HF process tends to propagate following the rockmass discontinuities; while at the reservoir scale, it tends to develop in the direction parallel to themaximum in-situ stress. 2014 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting byElsevier B.V. All rights reserved.
