The sequential oxidation-Horner-Wadsworth-Emmons reaction of alcohols to prepare α-Halo-α,β-unsaturated esters （halo =F, Cl） with middle to excellent （Z）-selectivity was developed.
The properties of N = 7, 8, 9 isotones with Z = 4 - 8 are studied in the framework of the single-particle shell model. A tentative orbit-orbit coupling is introduced in the average nuclear potential. Calculations give...The properties of N = 7, 8, 9 isotones with Z = 4 - 8 are studied in the framework of the single-particle shell model. A tentative orbit-orbit coupling is introduced in the average nuclear potential. Calculations give a unified description of the structures of N- 7, 8, 9 isotones. The neutron level inversion in N = 7 and N = 9 isotones is discussed. The ground-state level inversion in 11Be and ^15C is reproduced. The inversion between 2s1/2 and 1d5/2 neutron levels in 14B and 13Be is predicted. The possible halo structures in N = 7 and N = 9 isotones are analysed. The numerical results confirm the one-neutron halo structures in ^11Be（2s1/2）, ^11 Be（1p1/2）, ^12B（2s1/2）, ^133C（2s1/2）, ^14B（2s1/2） and ^15C（2s1/2）. The study implies that the attempt of considering orbit orbit interaction in the shell model may be a feasible way to explain the anomalous properties of exotic light nuclei.展开更多
文摘The sequential oxidation-Horner-Wadsworth-Emmons reaction of alcohols to prepare α-Halo-α,β-unsaturated esters （halo =F, Cl） with middle to excellent （Z）-selectivity was developed.
基金Supported by the National Natural Science Foundation of China under Grant Nos 10125521 and 10535010, and the National Major State Basic Research and Development Programme of China under Grant No C2000077400.
文摘The properties of N = 7, 8, 9 isotones with Z = 4 - 8 are studied in the framework of the single-particle shell model. A tentative orbit-orbit coupling is introduced in the average nuclear potential. Calculations give a unified description of the structures of N- 7, 8, 9 isotones. The neutron level inversion in N = 7 and N = 9 isotones is discussed. The ground-state level inversion in 11Be and ^15C is reproduced. The inversion between 2s1/2 and 1d5/2 neutron levels in 14B and 13Be is predicted. The possible halo structures in N = 7 and N = 9 isotones are analysed. The numerical results confirm the one-neutron halo structures in ^11Be（2s1/2）, ^11 Be（1p1/2）, ^12B（2s1/2）, ^133C（2s1/2）, ^14B（2s1/2） and ^15C（2s1/2）. The study implies that the attempt of considering orbit orbit interaction in the shell model may be a feasible way to explain the anomalous properties of exotic light nuclei.
