The Liwan Sag, with an area of 4 000 km-2, is one of the deepwater sags in the Zhujiang River(Pearl River) Mouth Basin, northern South China Sea. Inspired by the exploration success in oil and gas resources in the d...The Liwan Sag, with an area of 4 000 km-2, is one of the deepwater sags in the Zhujiang River(Pearl River) Mouth Basin, northern South China Sea. Inspired by the exploration success in oil and gas resources in the deepwater sags worldwide, we conducted the thermal modeling to investigate the tectono-thermal history of the Liwan Sag,which has been widely thought to be important to understand tectonic activities as well as hydrocarbon potential of a basin. Using the multi-stage finite stretching model, the tectonic subsidence history and the thermal history have been obtained for 12 artificial wells, which were constructed on basis of one seismic profile newly acquired in the study area. Two stages of rifting during the time periods of 49–33.9 Ma and 33.9–23 Ma can be recognized from the tectonic subsidence pattern, and there are two phases of heating processes corresponding to the rifting.The reconstructed average basal paleo-heat flow values at the end of the rifting events are -70.5 and -94.2 mW/m^2 respectively. Following the heating periods, the study area has undergone a persistent thermal attenuation phase since 23 Ma and the basal heat flow cooled down to -71.8–82.5 mW/m^2 at present.展开更多
Multi-period heat exchanger network(HEN) retrofit is usually performed by targeting and matching heat transfer areas. In this paper, based on the reverse order matching method we proposed previously, three strategies ...Multi-period heat exchanger network(HEN) retrofit is usually performed by targeting and matching heat transfer areas. In this paper, based on the reverse order matching method we proposed previously, three strategies of matching heat transfer areas are proposed to minimize the investment cost for the retrofit of HEN in multiperiod, in which replacement of heat exchangers, addition of heat exchangers and addition of heat transfer areas are performed. We demonstrate the procedures through three scenarios, including maximum number of substituted heat exchangers after retrofit, minimum additional heat transfer areas in the retrofitted HEN, and minimum investment cost for retrofit. The strategies are extended to a single period HEN retrofit problem. The results of multi-period and single period HEN retro fit problems indicate the effectiveness of the strategies. Moreover, these results are better than those reported in literature. The strategies are simple and easy to implement,which are of great benefit to large-scale HEN retrofit in practice.展开更多
To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net p...To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net power, embodying the cost/performance ratio of an ORC system, was proposed as a new indicator to judge the suitability of ORC working fluids on a given condition. The heat exchange area was computed by an improved evaporator model without fixing the minimum temperature difference between working fluid and hot fluid, and the flow pattern transition during heat exchange was also taken into account. The maximum UHEA net powers obtained show that dry organic fluids are more suitable for ORCs than wet organic fluids to recover low-temperature heat. The organic fluid 1-butene is recommended if the inlet temperature of hot fluid is 353.15-363.15 K or443.15-453.15 K, heptane is more suitable at 373.15-423.15 K, and R245 ca is a good option at 483.15-503.15 K.展开更多
It is not ethical to conduct experiments on infants regarding the thermal environment. Therefore, to examine the thermal environment of infants, experiments and simulations using a human body thermal model may be feas...It is not ethical to conduct experiments on infants regarding the thermal environment. Therefore, to examine the thermal environment of infants, experiments and simulations using a human body thermal model may be feasible by clarifying the human body coefficient values of infants. When focusing on the heat transfer area of the infant’s body coefficient values, the body surface area and solar radiation area factor have only been clarified as the standard. The essential basic data for examining the thermal environment of infants have not been sufficiently obtained. Therefore, the purpose of this study was to determine the clothing area factor for infants’ clothing in a typical season. The clothing area factor of infants clothed in summer, mid-season, and winter clothing was measured using a photographic method. The clothing area factor was 1.22, 1.42, and 1.90 for summer, mid-season, and winter clothing, respectively, indicating a significant seasonal difference. It was also found that the clothing area factor was significantly greater for infants than for adults.展开更多
This paper describes results of the fluxes of momentum , sensible heat and latent heat for the West Pacific Tropical Ocean Area ( 127 ° E - 150 ° E , 5 ° N -3 ° S ). The data were collected by the ...This paper describes results of the fluxes of momentum , sensible heat and latent heat for the West Pacific Tropical Ocean Area ( 127 ° E - 150 ° E , 5 ° N -3 ° S ). The data were collected by the small tethered balloon sounding system over this ocean area including 6 continuous stations (140 ° E. 0 ° ; 145 ° E, 0 ° ; 150 ° E, 0 ° ; 140° E, 5 ° N; 145 ° E, 5° N and 150 ° E, 5 ° N) from 11 October to 15 December, 1986 . These fluxes were calculated by the semiempirical flux-profile relationships of Monin-Obukhov similarity theory using these observed data. The results show that for this tropical ocean area the drag coefficient CD is equal to (1.53 ± 0.25) × 10 3 and the daily mean latent flux Hl is greater than its daily mean sensible flux HV by a factor of about 9.展开更多
The identification of the exact location of the heatings that occur in often inaccessible locations several hundred meters deep in goaf areas is a key to allowing effective control measures to be taken. Radon techniqu...The identification of the exact location of the heatings that occur in often inaccessible locations several hundred meters deep in goaf areas is a key to allowing effective control measures to be taken. Radon technique provides the only solution for remotely locating underground sponcom from surface. The results of Chaili mine indicated that a total area of 66 000 m2 has been surveyed and exact locations of spontaneous combustion have been detected. This has enabled the sueeessful implementation of various control measures against spontaneous combustion.展开更多
Indirect evaporative cooling(IEC)is a kind of high efficiency,energy-saving and environmental protection cooling technology,which has been widely used in data centers and other fields in recent years.In this paper,the...Indirect evaporative cooling(IEC)is a kind of high efficiency,energy-saving and environmental protection cooling technology,which has been widely used in data centers and other fields in recent years.In this paper,the optimized two-dimensional non-condensation state model of indirect evaporative cooling was proposed.Meanwhile the computer program was updated to solve the developed mathematical model under variable fresh air conditions.The optimized model was verified by the experimental data,and the maximum deviation was only 4.6%.Based on the modified model and the annual hourly meteorological parameters in Tianjin,China,it was analyzed the optimal heat transfer area of IEC used as fresh air pre-cooling unit under various air volumes to provide references for system design and equipment selection.Finally,taking an IEC-primary return air conditioning system of a gymnasium as an example,the hourly energy-saving effect of whole year was simulated by the developed IEC model.The simulation results showed that IEC could control the fresh air temperature below 27℃ and the moisture content below 18 g/kg throughout the year,and undertook 102.6% of the total fresh air cooling load.The findings are useful in future system optimization and design of IEC equipment.展开更多
The present work aims to investigate the influence of extended surfaces(fins)on the multi-objective optimization of a tubular heat exchanger network(THEN).An increase in the heat transfer area using various extended s...The present work aims to investigate the influence of extended surfaces(fins)on the multi-objective optimization of a tubular heat exchanger network(THEN).An increase in the heat transfer area using various extended surfaces(fins)to enhance the performance of the heat exchanger was used while considering the effectiveness and total heat transfer area as two objective functions.In addition to the simulation of simple fins,a new set of fins,called constructal fins,was designed based on the constructal theory.Tubular heat exchanger network design parameters were chosen as optimization variables,and optimization results were achieved in such a way as to enhance the effectiveness and decrease the total heat transfer area.The results show the importance of constructal fins in improving the objective functions of heat exchangers.For instance,the simple fins case enhances the effectiveness by up to 5.3%compared to that without fins(usual heat exchanger)while using constructal fins,in addition to the 7%increment of effectiveness,reduces the total heat transfer area by 9.47%.In order to optimize the heat exchanger,the heat transfer rate and cold fluid temperature must increase,and at the same time,the hot exiting fluid temperature should decrease at the same constant total heat transfer area,which is higher in the constructal fins case.Finally,optimized design variables were studied for different cases,and the effects of various fins were reported.展开更多
The nanoparticles of SiO2 were used in cement systems to modify the rheological behavior, to enhance the reactivity of supplementary cementitious materials, and also to improve the strength and durability. In this res...The nanoparticles of SiO2 were used in cement systems to modify the rheological behavior, to enhance the reactivity of supplementary cementitious materials, and also to improve the strength and durability. In this research, low-cost nano-SiO2 particles from natural hydrothermal solutions obtained by membrane ultrafiltration and, optionally, by cryochemical vacuum sublimation drying, were evaluated in portland cement based systems. The SiO2-rich solutions were obtained from the wells of Mutnovsky geothermal power station (Far East of Russia). The constant nano-SiO2 dosage of 0.25% (as a solid material by weight of cementitious materials) was used to compare the cement systems with different nanoparticles against a reference mortar and a commercially available nano-SiO2. Nanoparticles were characterized by X-Ray Diffraction (XRD), BET Surface Area, Scanning Electron Microscope (SEM) and Fourier Transform Infrared (FTIR) spectroscopy techniques. It was demonstrated that the addition of polycarboxylate ether superplasticizer and the dispersion treatment using an ultrasound processor can be used to facilitate the distribution ofnano-SiOz particles in the mixing water. The effect ofnano-SiO2 particles in portland cement mortars was investigated by evaluating the flow, heat of hydration and compressive strength development. It was demonstrated that the use ofnano- SiO2 particles can reduce the segregation and improve strength properties.展开更多
Based on the Scripps/NODC Joint Environmental Data Analysis Center's data of heat content in upper ocean (1955--1998) and NCEP/NCAR reanalysis data,the relationship between the heat content anomalies in the warm p...Based on the Scripps/NODC Joint Environmental Data Analysis Center's data of heat content in upper ocean (1955--1998) and NCEP/NCAR reanalysis data,the relationship between the heat content anomalies in the warm pool area of the western Pacific (WP) and onset of South China Sea summer monsoon (SCSM) is examined.The results show that the warm pool area (WP) is the place where heat content in the tropical upper layer changes with maximum range and which is most obviously influential to South China Sea summer monsoon.Onset of SCSM is very closely related to the heat content anomaly during the previous period (previous winter and spring) of the WP so that the heat content of March to April in the WP area is a very good predictor for onset of SCSM.When the heat content of the WP area is positive,convection center will be located in the South China Sea-western Pacific with strong convection,a positive anomaly of monsoon circulation and Walker circulation will take place and the subtropical high will be weaker and farther east. Positive anomalous monsoon circulation and Walker circulation will be favorable for westerly and southwesterly flows-SCSM breaks off earlier than normal.Otherwise,SCSM comes later than usual.Large-scale anomalous change of monsoon circulation and Walker circulation seems one of the important mechanisms to influence SCSM.展开更多
A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the...A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the leaching behavior of rare earth elements(REEs),and an interpretation of the interrelationship between mineralogy,decomposition process,and leaching process were provided in this study.The influences of the temperature,time of microwave heating and contents of NaO H(mass ratio of NaO H to mixed rare earth concentrate)on the decomposition of mixed rare earth concentrate were investigated.The results revealed that the temperature was the main factor affecting the decomposition process.The recovery of REEs by hydrochloric acid leaching reached 93.28% under the microwave heating conditions:140 oC,30 min and 35.35% NaO H.The BET specific surface area and SEM analysis indicated that the particles of mixed rare earth concentrate were non-hole,while the particles presented a porous structure after heating the concentrate by microwave radiation.For the microwave treated sample after water leaching,the BET specific surface area was 11.04 m^2/g,which was higher than the corresponding values(6.94 m^2/g)for the mixed rare earth concentrate.This result could be attributed to the phase changes of bastnaesite and monazite,and a number of cracks induced by thermal stress.The increase of BET specific surface area resulted in an increase of the recovery of REEs by promoting interaction within the system of acid leaching.展开更多
The microstructures of as-cast and as-solution Mg–12Gd–2Er–1Zn–0.6Zr alloys were investigated by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron microscopy(TEM), highresoluti...The microstructures of as-cast and as-solution Mg–12Gd–2Er–1Zn–0.6Zr alloys were investigated by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron microscopy(TEM), highresolution transmission electron microscopy(HRTEM)X-ray diffraction(XRD) and selected-area electron diffraction(SAED) in the present investigation. The results show that the primary eutectic phase Mg5(Gd, Er, Zn) and some flocculent features are found in the as-cast alloy; the SAED pattern indicates that these flocculent features are the dense areas of stacking faults. The 14H-LPSO structure precipitates in the temperature range of 673–793 K, and the volume fraction of 14H-LPSO structure increases with the extension of heating time; however, there is no precipitation of 14H-LPSO structure when the temperature reaches up to 803 K. In addition, the Mg5(Gd, Er, Zn) phase dissolves gradually along with the precipitation of 14H-LPSO structure.展开更多
This study assesses surface urban heat island (UHI) and its associated surface physical characteristics using remote sensing approaches. TERRA/MODIS images acquired in 2005 in three different seasons were selected to ...This study assesses surface urban heat island (UHI) and its associated surface physical characteristics using remote sensing approaches. TERRA/MODIS images acquired in 2005 in three different seasons were selected to generate land surface tem-perature and surface characteristics for the Changsha-Zhuzhou-Xiangtan metropolitan area in China. The intensity of urban heat is-land effects and its seasonal variations were examined. The result showed that UHI effects were significant both in the summer and the spring. Land surface temperatures in the city were 8 ℃ to 10℃ warmer than those in surrounding rural areas in the spring and the summer seasons. Although UHI effects exist in winter, they are not significant. Land surface temperature in the city was 4℃ warmer than that in surrounding rural areas in winter. This study uses normalized difference vegetation index (NDVI) and normal-ized difference built-up index (NDBI) as indicators of surface physical characteristics and investigates the relationship among land surface temperature (LST), NDVI and NDBI. The results from this study indicate that, while the relationship between LST and NDVI changes in different seasons, there is a strong positive linear relationship between NDBI and LST for all seasons. The amount of slope and intercept of the linear relationship between NDBI and LST can indicate the magnitude of UHI for different seasons. This finding suggests that NDBI provides an alternative physical indicator for analyzing LST quantitatively over different seasons, and therefore providing a useful way to study UHI effects using remote sensing.展开更多
基金The Program of the Key Technologies for Petroleum Exploration in Deep Oceanic Areas under contract No.2011ZX05025-006-05the Chinese Postdoc Fund,No.58 General Fund,2015 under contract No.2015M582636the National Natural Science Foundation of China under contract No.41602251
文摘The Liwan Sag, with an area of 4 000 km-2, is one of the deepwater sags in the Zhujiang River(Pearl River) Mouth Basin, northern South China Sea. Inspired by the exploration success in oil and gas resources in the deepwater sags worldwide, we conducted the thermal modeling to investigate the tectono-thermal history of the Liwan Sag,which has been widely thought to be important to understand tectonic activities as well as hydrocarbon potential of a basin. Using the multi-stage finite stretching model, the tectonic subsidence history and the thermal history have been obtained for 12 artificial wells, which were constructed on basis of one seismic profile newly acquired in the study area. Two stages of rifting during the time periods of 49–33.9 Ma and 33.9–23 Ma can be recognized from the tectonic subsidence pattern, and there are two phases of heating processes corresponding to the rifting.The reconstructed average basal paleo-heat flow values at the end of the rifting events are -70.5 and -94.2 mW/m^2 respectively. Following the heating periods, the study area has undergone a persistent thermal attenuation phase since 23 Ma and the basal heat flow cooled down to -71.8–82.5 mW/m^2 at present.
基金Supported by the National Natural Science Foundation of China(21376188,21176198)
文摘Multi-period heat exchanger network(HEN) retrofit is usually performed by targeting and matching heat transfer areas. In this paper, based on the reverse order matching method we proposed previously, three strategies of matching heat transfer areas are proposed to minimize the investment cost for the retrofit of HEN in multiperiod, in which replacement of heat exchangers, addition of heat exchangers and addition of heat transfer areas are performed. We demonstrate the procedures through three scenarios, including maximum number of substituted heat exchangers after retrofit, minimum additional heat transfer areas in the retrofitted HEN, and minimum investment cost for retrofit. The strategies are extended to a single period HEN retrofit problem. The results of multi-period and single period HEN retro fit problems indicate the effectiveness of the strategies. Moreover, these results are better than those reported in literature. The strategies are simple and easy to implement,which are of great benefit to large-scale HEN retrofit in practice.
基金Projects(U0937604,50876116)supported by the National Natural Science Foundation of ChinaProjects(2010QZZD0107,2014zzts192)supported by the Fundamental Research Funds for the Central Universities of China
文摘To improve energy conversion efficiency, optimization of the working fluids in organic Rankine cycles(ORCs) was explored in the range of low-temperature heat sources. The concept of unit-heat-exchange-area(UHEA) net power, embodying the cost/performance ratio of an ORC system, was proposed as a new indicator to judge the suitability of ORC working fluids on a given condition. The heat exchange area was computed by an improved evaporator model without fixing the minimum temperature difference between working fluid and hot fluid, and the flow pattern transition during heat exchange was also taken into account. The maximum UHEA net powers obtained show that dry organic fluids are more suitable for ORCs than wet organic fluids to recover low-temperature heat. The organic fluid 1-butene is recommended if the inlet temperature of hot fluid is 353.15-363.15 K or443.15-453.15 K, heptane is more suitable at 373.15-423.15 K, and R245 ca is a good option at 483.15-503.15 K.
文摘It is not ethical to conduct experiments on infants regarding the thermal environment. Therefore, to examine the thermal environment of infants, experiments and simulations using a human body thermal model may be feasible by clarifying the human body coefficient values of infants. When focusing on the heat transfer area of the infant’s body coefficient values, the body surface area and solar radiation area factor have only been clarified as the standard. The essential basic data for examining the thermal environment of infants have not been sufficiently obtained. Therefore, the purpose of this study was to determine the clothing area factor for infants’ clothing in a typical season. The clothing area factor of infants clothed in summer, mid-season, and winter clothing was measured using a photographic method. The clothing area factor was 1.22, 1.42, and 1.90 for summer, mid-season, and winter clothing, respectively, indicating a significant seasonal difference. It was also found that the clothing area factor was significantly greater for infants than for adults.
文摘This paper describes results of the fluxes of momentum , sensible heat and latent heat for the West Pacific Tropical Ocean Area ( 127 ° E - 150 ° E , 5 ° N -3 ° S ). The data were collected by the small tethered balloon sounding system over this ocean area including 6 continuous stations (140 ° E. 0 ° ; 145 ° E, 0 ° ; 150 ° E, 0 ° ; 140° E, 5 ° N; 145 ° E, 5° N and 150 ° E, 5 ° N) from 11 October to 15 December, 1986 . These fluxes were calculated by the semiempirical flux-profile relationships of Monin-Obukhov similarity theory using these observed data. The results show that for this tropical ocean area the drag coefficient CD is equal to (1.53 ± 0.25) × 10 3 and the daily mean latent flux Hl is greater than its daily mean sensible flux HV by a factor of about 9.
文摘The identification of the exact location of the heatings that occur in often inaccessible locations several hundred meters deep in goaf areas is a key to allowing effective control measures to be taken. Radon technique provides the only solution for remotely locating underground sponcom from surface. The results of Chaili mine indicated that a total area of 66 000 m2 has been surveyed and exact locations of spontaneous combustion have been detected. This has enabled the sueeessful implementation of various control measures against spontaneous combustion.
基金This research is financially supported by the National Natural Science Foundation of China(No.51678385).
文摘Indirect evaporative cooling(IEC)is a kind of high efficiency,energy-saving and environmental protection cooling technology,which has been widely used in data centers and other fields in recent years.In this paper,the optimized two-dimensional non-condensation state model of indirect evaporative cooling was proposed.Meanwhile the computer program was updated to solve the developed mathematical model under variable fresh air conditions.The optimized model was verified by the experimental data,and the maximum deviation was only 4.6%.Based on the modified model and the annual hourly meteorological parameters in Tianjin,China,it was analyzed the optimal heat transfer area of IEC used as fresh air pre-cooling unit under various air volumes to provide references for system design and equipment selection.Finally,taking an IEC-primary return air conditioning system of a gymnasium as an example,the hourly energy-saving effect of whole year was simulated by the developed IEC model.The simulation results showed that IEC could control the fresh air temperature below 27℃ and the moisture content below 18 g/kg throughout the year,and undertook 102.6% of the total fresh air cooling load.The findings are useful in future system optimization and design of IEC equipment.
文摘The present work aims to investigate the influence of extended surfaces(fins)on the multi-objective optimization of a tubular heat exchanger network(THEN).An increase in the heat transfer area using various extended surfaces(fins)to enhance the performance of the heat exchanger was used while considering the effectiveness and total heat transfer area as two objective functions.In addition to the simulation of simple fins,a new set of fins,called constructal fins,was designed based on the constructal theory.Tubular heat exchanger network design parameters were chosen as optimization variables,and optimization results were achieved in such a way as to enhance the effectiveness and decrease the total heat transfer area.The results show the importance of constructal fins in improving the objective functions of heat exchangers.For instance,the simple fins case enhances the effectiveness by up to 5.3%compared to that without fins(usual heat exchanger)while using constructal fins,in addition to the 7%increment of effectiveness,reduces the total heat transfer area by 9.47%.In order to optimize the heat exchanger,the heat transfer rate and cold fluid temperature must increase,and at the same time,the hot exiting fluid temperature should decrease at the same constant total heat transfer area,which is higher in the constructal fins case.Finally,optimized design variables were studied for different cases,and the effects of various fins were reported.
文摘The nanoparticles of SiO2 were used in cement systems to modify the rheological behavior, to enhance the reactivity of supplementary cementitious materials, and also to improve the strength and durability. In this research, low-cost nano-SiO2 particles from natural hydrothermal solutions obtained by membrane ultrafiltration and, optionally, by cryochemical vacuum sublimation drying, were evaluated in portland cement based systems. The SiO2-rich solutions were obtained from the wells of Mutnovsky geothermal power station (Far East of Russia). The constant nano-SiO2 dosage of 0.25% (as a solid material by weight of cementitious materials) was used to compare the cement systems with different nanoparticles against a reference mortar and a commercially available nano-SiO2. Nanoparticles were characterized by X-Ray Diffraction (XRD), BET Surface Area, Scanning Electron Microscope (SEM) and Fourier Transform Infrared (FTIR) spectroscopy techniques. It was demonstrated that the addition of polycarboxylate ether superplasticizer and the dispersion treatment using an ultrasound processor can be used to facilitate the distribution ofnano-SiOz particles in the mixing water. The effect ofnano-SiO2 particles in portland cement mortars was investigated by evaluating the flow, heat of hydration and compressive strength development. It was demonstrated that the use ofnano- SiO2 particles can reduce the segregation and improve strength properties.
基金National Climbing Project A:"South China Sea Monsoon Experiments"CAS Innovation Project (No.ZKCX2-SW-210)Project of Natural Sciences Fund of Shandong Province"A study of relationship between warm pool thermal state anomalies and summer rainfall in Shandong"
文摘Based on the Scripps/NODC Joint Environmental Data Analysis Center's data of heat content in upper ocean (1955--1998) and NCEP/NCAR reanalysis data,the relationship between the heat content anomalies in the warm pool area of the western Pacific (WP) and onset of South China Sea summer monsoon (SCSM) is examined.The results show that the warm pool area (WP) is the place where heat content in the tropical upper layer changes with maximum range and which is most obviously influential to South China Sea summer monsoon.Onset of SCSM is very closely related to the heat content anomaly during the previous period (previous winter and spring) of the WP so that the heat content of March to April in the WP area is a very good predictor for onset of SCSM.When the heat content of the WP area is positive,convection center will be located in the South China Sea-western Pacific with strong convection,a positive anomaly of monsoon circulation and Walker circulation will take place and the subtropical high will be weaker and farther east. Positive anomalous monsoon circulation and Walker circulation will be favorable for westerly and southwesterly flows-SCSM breaks off earlier than normal.Otherwise,SCSM comes later than usual.Large-scale anomalous change of monsoon circulation and Walker circulation seems one of the important mechanisms to influence SCSM.
基金Project supported by the National Basic Research Program of China(973 program,2012CBA01205)
文摘A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the leaching behavior of rare earth elements(REEs),and an interpretation of the interrelationship between mineralogy,decomposition process,and leaching process were provided in this study.The influences of the temperature,time of microwave heating and contents of NaO H(mass ratio of NaO H to mixed rare earth concentrate)on the decomposition of mixed rare earth concentrate were investigated.The results revealed that the temperature was the main factor affecting the decomposition process.The recovery of REEs by hydrochloric acid leaching reached 93.28% under the microwave heating conditions:140 oC,30 min and 35.35% NaO H.The BET specific surface area and SEM analysis indicated that the particles of mixed rare earth concentrate were non-hole,while the particles presented a porous structure after heating the concentrate by microwave radiation.For the microwave treated sample after water leaching,the BET specific surface area was 11.04 m^2/g,which was higher than the corresponding values(6.94 m^2/g)for the mixed rare earth concentrate.This result could be attributed to the phase changes of bastnaesite and monazite,and a number of cracks induced by thermal stress.The increase of BET specific surface area resulted in an increase of the recovery of REEs by promoting interaction within the system of acid leaching.
基金financially supported by the Projects of Beijing Municipal Science and Technology Commission (No. Z131100003213019)the Projects of Beijing Municipal Commission of Education (Nos. KM201110005001 and KM201310005001)Beijing Natural Science Foundation (No. 2144043)
文摘The microstructures of as-cast and as-solution Mg–12Gd–2Er–1Zn–0.6Zr alloys were investigated by optical microscopy(OM), scanning electron microscopy(SEM), transmission electron microscopy(TEM), highresolution transmission electron microscopy(HRTEM)X-ray diffraction(XRD) and selected-area electron diffraction(SAED) in the present investigation. The results show that the primary eutectic phase Mg5(Gd, Er, Zn) and some flocculent features are found in the as-cast alloy; the SAED pattern indicates that these flocculent features are the dense areas of stacking faults. The 14H-LPSO structure precipitates in the temperature range of 673–793 K, and the volume fraction of 14H-LPSO structure increases with the extension of heating time; however, there is no precipitation of 14H-LPSO structure when the temperature reaches up to 803 K. In addition, the Mg5(Gd, Er, Zn) phase dissolves gradually along with the precipitation of 14H-LPSO structure.
基金Supported by the National Natural Science Foundation of China (No.40771198)the Hunan Provincial Natural Science Foundation of China (No.08JJ6023)
文摘This study assesses surface urban heat island (UHI) and its associated surface physical characteristics using remote sensing approaches. TERRA/MODIS images acquired in 2005 in three different seasons were selected to generate land surface tem-perature and surface characteristics for the Changsha-Zhuzhou-Xiangtan metropolitan area in China. The intensity of urban heat is-land effects and its seasonal variations were examined. The result showed that UHI effects were significant both in the summer and the spring. Land surface temperatures in the city were 8 ℃ to 10℃ warmer than those in surrounding rural areas in the spring and the summer seasons. Although UHI effects exist in winter, they are not significant. Land surface temperature in the city was 4℃ warmer than that in surrounding rural areas in winter. This study uses normalized difference vegetation index (NDVI) and normal-ized difference built-up index (NDBI) as indicators of surface physical characteristics and investigates the relationship among land surface temperature (LST), NDVI and NDBI. The results from this study indicate that, while the relationship between LST and NDVI changes in different seasons, there is a strong positive linear relationship between NDBI and LST for all seasons. The amount of slope and intercept of the linear relationship between NDBI and LST can indicate the magnitude of UHI for different seasons. This finding suggests that NDBI provides an alternative physical indicator for analyzing LST quantitatively over different seasons, and therefore providing a useful way to study UHI effects using remote sensing.