Thermal runaway evolution of a 280 Ah lithium-ion battery with LiFePO_(4) as the cathode for different heat transfer modes constructed by mechanical abuse

Lithium iron phosphate batteries have been increasingly utilized in recent years because their higher safety performance can improve the increasing trend of recurring thermal runaway accidents.However,the safety performance and mechanism of high-capacity lithium iron phosphate batteries under internal short-circuit challenges remain to be explored.This work analyzes the thermal runaway evolution of high-capacity LiFePO_(4) batteries under different internal heat transfer modes,which are controlled by different penetration modes.Two penetration cases involving complete penetration and incomplete penetration were detected during the test,and two modes were performed incorporating nails that either remained or were removed after penetration to comprehensively reveal the thermal runaway mechanism.A theoretical model of microcircuits and internal heat conduction is also established.The results indicated three thermal runaway evolution processes for high-capacity batteries,which corresponded to the experimental results of thermal equilibrium,single thermal runaway,and two thermal runaway events.The difference in heat distribution in the three phenomena is determined based on the microstructure and material structure near the pinhole.By controlling the heat dissipation conditions,the time interval between two thermal runaway events can be delayed from 558 to 1417 s,accompanied by a decrease in the concentration of in-situ gas production during the second thermal runaway event.

Performance analysis of heat pump based on a new solar air-source heat pump heating system

To further improve the utilization efficiency of solar energy and the performance of solar heat pump heating systems,a new heating mode of a solar air-source heat pump（SASHP）is proposed,and the characteristics and performance of the heat pump part of this new heating system are studied.Based on a SASHP with 10 kW,the mathematical model of this system is built,and the characteristics and performance are concluded from the simulation analysis at different environmental temperatures and output water temperatures.The results show that the performance of heat pumps can be greatly improved based on the new SASHP.When the environmental temperature is 7 ℃,the coefficient of performance（COP）of the air-source heat pump（ASHP）can be increased by 26% at most.This paper sets up a base for further study on the heating system with this new SASHP in the heating season.

Exploring heating performance of gas engine heat pump with heat recovery

In order to evaluate the heating performance of gas engine heat pump（GEHP） for air-conditioning and hot water supply, a test facility was developed and experiments were performed over a wide range of engine speed（1400-2600 r/min）, ambient air temperature（2.4-17.8 ℃） and condenser water inlet temperature（30-50℃）. The results show that as engine speed increases from 1400 r/min to 2600 r/min, the total heating capacity and energy consumption increase by about 30% and 89%, respectively; while the heat pump coefficient of performance（COP） and system primary energy ratio（PER） decrease by 44% and 31%, respectively. With the increase of ambient air temperature from 2.4 ℃ to 17.8 ℃, the heat pump COP and system PER increase by 32% and 19%, respectively. Moreover, the heat pump COP and system PER decrease by 27% and 15%, respectively, when the condenser water inlet temperature changes from 30 ℃ to 50 ℃. So, it is obvious that the effect of engine speed on the performance is more significant than the effects of ambient air temperature and condenser water inlet temperature.

Effect of variable heat treatment modes on microstructures of Fe-Cr-Bcast iron alloy

The effect of heat treatment mode on the microstructure of Fe-Cr-B cast iron alloys was investigated inthis paper by comparing the difference of precipitation patterns of secondary particles after thermal cycling treatment(TCT) with those after normal heat treatment (NHT). No obvious differences were found in precipitation patterns ofsecondary particles between TCT and NHT when experimental temperature was below Ar1. However, whentemperature was over Ar1, there were significant differences, with secondary particles prominently segregated at thegrain boundaries under TCT, while the particles evenly distributed in the matrix under NHT. The reason for themicrostructure differences could be associated with the development of non-equilibrium segregation of boron duringTCT.

Finite element analysis of keyhole plasma arc welding based on an adaptive heat source mode

An adaptive heat source mode is proposed to account for the keyhole effect and the characteristics of volumetric distribution along the direction of the workpiece thickness. Finite element analysis of the temperature field in keyhole plasma arc welding is conducted and the weld geometry is obtained. The predicted results are in agreement with the measured ones.

Heat Transfer and Mode Transition for Laser Ablation Subjected to Supersonic Airflow

When laser ablation is subjected to supersonic flow, the influence mechanism of airflow on laser ablation behavior is still unclear. A coupled thermal-fluid-structure model is presented to investigate the influence of supersonic airflow on the development of a laser ablation pit. Results show that the aerodynamic convection cooling effect not only reduces the ablation velocity but also changes the symmetry morphology of the ablation pit due to the non-uniform convective heat transfer. Flow mode transition is also observed when the pit becomes deeper, and significant change in flow pattern and heat transfer behavior are found when the open mode is transformed into the closed mode.

A comprehensive comparison on vibration and heat transfer of two elastic heat transfer tube bundles

Elastic heat transfer tube bundles are widely used in the field of flow-induced vibration heat transfer enhancement. Two types of mainly used tube bundles, the planar elastic tube bundle and the conical spiral tube bundle were comprehensively compared in the condition of the same shell side diameter. The natural mode characteristics, the effect of fluid-structure interaction, the stress distribution, the comprehensive heat transfer performance and the secondary fluid flow of the two elastic tube bundles were all concluded and compared. The results show that the natural frequency and the critical velocity of vibration buckling of the planar elastic tube bundle are larger than those of the conical spiral tube bundle, while the stress distribution and the comprehensive heat transfer performance of the conical spiral tube bundle are relatively better.

Study and Design of a High-Frequency Interaction Cavity for a 140 GHz Megawatts Gyrotron

The gyrotron is one of the most promising high-power millimeter-wave sources for electron cyclotron resonance heating（ECRH） in controlled thermal nuclear fusion experiments.In this paper,the design of a high-frequency interaction cavity of a 1 MW/140 GHz gyrotron is described in detail.The cavity is designed by using eigen mode analysis and radio frequency（RF） behavior calculation.Rounded transitions at the input and output tapers are designed for reducing mode conversion.With the obtained cavity structure,non-linear self-consistent equations are adopted to calculate its output power and efficiency.A particle-in-cell（PIC） method is used to simulate the beam-wave interaction process for obtaining the resonant frequency and output power of the cavity.The PIC simulation results match considerably well with the results obtained by the non-linear self-consistent calculation.The cavity is currently under construction and will be integrated with other components for overall testing.

Study of High Power ICRF Antenna Design in LHD

In large helical device （LHD）, antenna loadings are different for minority ion cyclotron heating （MICH with 38.47 MHz） and mode-converted ion Bernstein wave heating （MC-IBW with 28.4 MHz）, and it is necessary to improve antenna loading with low heating efficiency to avoid arching on transmission line. To design a new ion cyclotron range of frequencies （ICRF） antenna in LHD, calculation for a simple antenna model is conducted using three-dimensional electrical magnetic code （high frequency structure simulator, HFSS） for an water loading as an imaginary plasma with low heating efficiency. At resonant frequencies, antenna loading is sensitive to strap width, and resonant frequencies are strongly related to strap height. There is no differences of RF current profile on the strap surface between resonant frequency and non-resonant frequency. The strap should be perpendicularly placed against the magnetic field line, since Faraday-shield angle will lead to a decrease in the effective antenna height.

Temperature distribution of fluids in a two-section two-phase closed thermosyphon wellbore

Compared with a conventional single section two-phase closed thermosyphon （TPCT） wellbore, a two-section TPCT wellbore has better heat transfer performance, which may improve the temperature distribution of fluid in wellbores, increase the temperature of fluid in wellheads and even more effectively reduce the failure rate of conventional TPCT wellbores. Heat transfer performance of two-section TPCT wellbores is affected by working medium, combination mode and oil flow rate. Different working media are introduced into the upper and lower TPCTs, which may achieve a better match between the working medium and the temperature field in the wellbores. Interdependence exists between the combination mode and the flow rate of the oil, which affects the heat transfer performance of a two-section TPCT wellbore. The experimental results show that a two-section TPCT wellbore, with equal upper and lower TPCTs respectively filled with Freon and methanol, has the best heat transfer performance when the oil flow rate is 200 L/h.

First principles study and comparison of vibrational and thermodynamic properties of XBi(X=In,Ga,B,Al)

In the present work, vibrational and thermodynamic properties of XBi（X = B, Al, Ga, In） compounds are compared and investigated. The calculation is carried out using density functional theory（DFT） within the generalized gradient approximation（GGA） in a plane wave basis, with ultrasoft pseudopotentials. The lattice dynamical properties are calculated using density functional perturbation theory（DFPT） as implemented in Quantum ESPRESSO（QE） code. Thermodynamic properties involving phonon density of states（DOS） and specific heat at constant volume are investigated using quasiharmonic approximation（QHA） package within QE. The phonon dispersion diagrams for InBi, GaBi, BBi, and AlBi indicate that there is no imaginary phonon frequency in the entire Brillouin zone, which proves the dynamical stability of these materials. BBi has the highest thermal conductivity and InBi has the lowest thermal conductivity. AlBi has the largest and GaBi has the smallest reststrahlen band which somehow suggests the polar property of XBi materials. The phonon gaps for InBi, GaBi, BBi and AlBi are about 160 cm^-1, 150 cm^-1, 300 cm^-1, and 150 cm^-1, respectively. For all compounds,the three acoustic modes near the gamma point have a linear behavior. C_V is a function of T-3 at low temperatures while for higher temperatures it asymptotically tends to a constant as expected.

Anomalous low-temperature heat capacity in antiperovskite compounds

The low-temperature heat capacities are studied for antiperovskite compounds AX M_3（A = Al, Ga, Cu, Ag, Sn, X = C,N, M = Mn, Fe, Co）. A large peak in（C- γ T）/T^3 versus T is observed for each of a total of 18 compounds investigated,indicating an existence of low-energy phonon mode unexpected by Debye T^3 law. Such a peak is insensitive to the external magnetic field up to 80 k Oe（1 Oe = 79.5775 A·m-1）. For compounds with smaller lattice constant, the peak shifts towards higher temperatures with a reduction of peak height. This abnormal peak in（C- γ T）/T^3 versus T of antiperovskite compound may result from the strongly dispersive acoustic branch due to the heavier A atoms and the optical-like mode from the dynamic rotation of X M_6 octahedron. Such a low-energy phonon mode may not contribute negatively to the normal thermal expansion in AX M_3 compounds, while it is usually concomitant with negative thermal expansion in open-structure material（e.g., ZrW_2O_8, Sc F_3）.

Energy Efficiency Assessment of Building Wall with PCM Layers in the Hot Summer Locations

This manuscript addresses the futuristic energy savings by impregnating building elements with PCM formations. Two structured gypsum building walls were monitored under the transient heat mode in the conducted experiments. One wall included (phase-change material) spheres, integrated into one styrofoam layer, installed at different positions, from 1 to 5, from the outside to the inside of the room. The other wall included one styrofoam insulation layer, perforated with holes, with changeable positions, from 1 to 5, from the outside to the inside of the room. The temperatures in the experiment corresponded to high summer temperatures in the tropical or subtropical zones. The obtained experimental results were further analyzed, while HVAC is off, for an indoor thermal comfort range, from 20˚C to 25˚C. This manuscript has analyzed the thermal comfort, effectiveness and optimal position of PCM spheres, incorporated in styrofoam thermal insulation, for a previously determined temperature range. The wall with integrated PCM should not be thick, (in total), but rather slender so that PCM can show its effectiveness. The farthermost position of the PCM layer should be the third because PCM combined with a lot of thermal insulation is not so effective and the thermal insulation has a buffer effect. The honeycomb or hollow-core thermal insulations should be avoided to put alone, because of natural air convection in them, which raises the heat flow. The monthly monetary saving, for a PCM-integrated wall, is calculated and amounts to 55.5 $, which shows that the integration of PCM in building walls, in hot summer locations, is very beneficial.

Sensitivity analysis of borehole thermal energy storage: examining key factors for system optimization

Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the precise design and operation of BTES systems.This study conducts a sensitivity analysis of BTES modeling by employing a comparative investigation of five distinct parameters on a wedge-shaped model,with implications extendable to a cylindrical configuration.The parameters examined included two design factors(well spacing and grout thermal conductivity),two operational variables(charging and discharging rates),and one geological attribute(soil thermal conductivity).Finite element simulations were carried out for the sensitivity analysis to evaluate the round-trip efficiency,both on a per-cycle basis and cumulatively over three years of operation,serving as performance metrics.The results showed varying degrees of sensitivity across different models to changes in these parameters.In particular,the round-trip efficiency exhibited a greater sensitivity to changes in spacing and volumetric flow rate.Furthermore,this study underscores the importance of considering the impact of the soil and grout-material thermal conductivities on the BTES-system performance over time.An optimized scenario is modelled and compared with the base case,over a comparative assessment based on a 10-year simulation.The analysis revealed that,at the end of the 10-year period,the optimized BTES model achieved a cycle efficiency of 83.4%.This sensitivity analysis provides valuable insights into the merits and constraints of diverse BTES modeling methodologies,aiding in the selection of appropriate modeling tools for BTES system design and operation.

Mixed convection of alumina-water nanofluid inside a concentric annulus considering nanoparticle migration

A theoretical investigation was conducted of laminar fully developed mixed convection of alumina-water nanofluid through a vertical annulus, to improve its heating/cooling performance. We focused on con- trolling the nanoparticle migration and studying how it affected the heat transfer rate and pressure drop. Because the nanoparticles have very small dimensions, we only considered Brownian motion and ther- mophoretic diffusivity as the main causes of nanoparticle migration. Because thermophoresis is very sensitive to temperature gradients, we imposed various temperature gradients using asymmetric heat- ing. Considering hydrodynamically and thermally fully developed flow, the governing equations were reduced to two-point ordinary boundary value differential equations and were solved numerically. The imposed thermal asymmetry changed the direction of nanoparticle migration and distorted the velocity, temperature, and nanoparticle concentration profiles. Moreover, we found optimum values for the radius ratio （ζ） and heat flux ratio （ε）; with these optimum values, the nanofluid enhanced the efficacy of the system.