A novel polyoxometalate-based hybrid modified by 3d-4d/2-ptz heterometallic organic chains[n-ptz= 5-（n-pyridyl）-tetrazolate], Ag2[Cu（2-ptz）2][β-MosO26]0.5-H20（1）[2-ptz=5-（2-pyridyl）-tetrazolate], was synthesi...A novel polyoxometalate-based hybrid modified by 3d-4d/2-ptz heterometallic organic chains[n-ptz= 5-（n-pyridyl）-tetrazolate], Ag2[Cu（2-ptz）2][β-MosO26]0.5-H20（1）[2-ptz=5-（2-pyridyl）-tetrazolate], was synthesized under hydrothermal conditions. The 3D framework structure of compound 1 was constructed from 1D novel 3d-4d heterometallic organic chains [CuAg2（2-ptz）2]2＋ as cationic complexes and [β-Mo8026]4- polyoxoanions via Cu--O and Ag--O bonds, in which each [fl-MosO26]4- polyoxoanion was surrounded by six such chains. The electrochemical and photocatalytic properties of compound I were investigated.展开更多
文摘A novel polyoxometalate-based hybrid modified by 3d-4d/2-ptz heterometallic organic chains[n-ptz= 5-（n-pyridyl）-tetrazolate], Ag2[Cu（2-ptz）2][β-MosO26]0.5-H20（1）[2-ptz=5-（2-pyridyl）-tetrazolate], was synthesized under hydrothermal conditions. The 3D framework structure of compound 1 was constructed from 1D novel 3d-4d heterometallic organic chains [CuAg2（2-ptz）2]2＋ as cationic complexes and [β-Mo8026]4- polyoxoanions via Cu--O and Ag--O bonds, in which each [fl-MosO26]4- polyoxoanion was surrounded by six such chains. The electrochemical and photocatalytic properties of compound I were investigated.
