Star-shaped oligothiophenes with hexakis（fluoren-2-yl）benzene （HFB） as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipp...Star-shaped oligothiophenes with hexakis（fluoren-2-yl）benzene （HFB） as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.展开更多
基金supported by the National Science Fund for Distinguished Young Scholars of China(No. 51125013)
文摘Star-shaped oligothiophenes with hexakis（fluoren-2-yl）benzene （HFB） as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.
