针对无线传感器网络中存在的安全问题,提出了基于Q-Learning的分簇无线传感网信任管理机制(Q-learning based trust management mechanism for clustered wireless sensor networks,QLTMM-CWSN).该机制主要考虑通信信任、数据信任和能...针对无线传感器网络中存在的安全问题,提出了基于Q-Learning的分簇无线传感网信任管理机制(Q-learning based trust management mechanism for clustered wireless sensor networks,QLTMM-CWSN).该机制主要考虑通信信任、数据信任和能量信任3个方面.在网络运行过程中,基于节点的通信行为、数据分布和能量消耗,使用Q-Learning算法更新节点信任值,并选择簇内信任值最高的节点作为可信簇头节点.当簇中主簇头节点的信任值低于阈值时,可信簇头节点代替主簇头节点管理簇内成员节点,维护正常的数据传输.研究结果表明,QLTMM-CWSN机制能有效抵御通信攻击、伪造本地数据攻击、能量攻击和混合攻击.展开更多
Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficien...Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficiency.Herein,we explore an economic and environmentally friendly method for synthesizing hierarchical NaX zeolite that exhibits improved catalytic performance in the Knoevenagel condensation reaction for producing the useful fine chemical 2-cyano-3-phenylacrylate.The synthesis was achieved via a low-temperature activation of kaolinite and subsequent in-situ transformation strategy without any template or seed.Systematic characterizations reveal that the synthesized NaX zeolite has both intercrystalline and intra-crystalline mesopores,smaller crystal size,and larger external specific surface area compared to commercial NaX zeolite.Detailed mechanism investigations show that the inter-crystalline mesopores are generated by stacking smaller crystals formed from in-situ crystallization of the depolymerized kaolinite,and the intra-crystalline mesopores are inherited from the pores in the depolymerized kaolinite.This synthesis strategy provides an energy-saving and effective way to construct hierarchical zeolites,which may gain wide applications in fine chemical manufacturing.展开更多
Printed micro-supercapacitors(MSCs)have shown broad prospect in flexible and wearable electronics.Most of previous studies focused on printing the electrochemically active materials paying less attention to other key ...Printed micro-supercapacitors(MSCs)have shown broad prospect in flexible and wearable electronics.Most of previous studies focused on printing the electrochemically active materials paying less attention to other key components like current collectors and electrolytes.This study presents an allprinting strategy to fabricate in-plane flexible and substrate-free MSCs with hierarchical encapsulation.This new type of“all-in-one”MSC is constructed by encapsulating the in-plane interdigital current collectors and electrodes within the polyvinyl-alcohol-based hydrogel electrolyte via sequential printing.The bottom electrolyte layer of this fully printed MSCs helps protect the device from the limitation of conventional substrate,showing excellent flexibility.The MSCs maintain a high capacitance retention of 96.84%even in a completely folded state.An optimal electrochemical performance can be achieved by providing ample and shorter transport paths for ions.The MSCs using commercial activated carbon as the active material are endowed with a high specific areal capacitance of 1892.90 mF cm^(-2)at a current density of 0.3 mA cm^(-2),and an outstanding volumetric energy density of 9.20 mWh cm^(-3)at a volumetric power density of 6.89 mW cm^(-3).For demonstration,a thermo-hygrometer is stably powered by five MSCs which are connected in series and wrapped onto a glass rod.This low-cost and versatile all-printing strategy is believed to diversify the application fields of MSCs with high capacitance and excellent flexibility.展开更多
Materials exhibiting high-performance electromagnetic wave absorption have garnered considerable scientific and technological attention,yet encounter significant challenges.Developing new materials and innovative stru...Materials exhibiting high-performance electromagnetic wave absorption have garnered considerable scientific and technological attention,yet encounter significant challenges.Developing new materials and innovative structural design concepts is crucial for expanding the application field of electromagnetic wave absorption.Particularly,hierarchical structure engineering has emerged as a promising approach to enhance the physical and chemical properties of materials,providing immense potential for creating versatile electromagnetic wave absorption materials.Herein,an exceptional multi-dimensional hierarchical structure was meticulously devised,unleashing the full microwave attenuation capabilities through in situ growth,selfreduction,and multi-heterogeneous interface integration.The hierarchical structure features a three-dimensional carbon framework,where magnetic nanoparticles grow in situ on the carbon skeleton,creating a necklace-like structure.Furthermore,magnetic nanosheets assemble within this framework.Enhanced impedance matching was achieved by precisely adjusting component proportions,and intelligent integration of diverse interfaces bolstered dielectric polarization.The obtain Fe_(3)O_(4)-Fe nanoparticles/carbon nanofibers/Al-Fe_(3)O_(4)-Fe nanosheets composites demonstrated outstanding performance with a minimum reflection loss(RLmin)value of−59.3 dB and an effective absorption bandwidth(RL≤−10 dB)extending up to 5.6 GHz at 2.2 mm.These notable accomplishments offer fresh insights into the precision design of high-efficient electromagnetic wave absorption materials.展开更多
Silicon oxide(SiO_(x),0<x≤2)has been recognized as a prominent anode material in lithium-ion batteries and sodium-ion batteries due to its high theoretical capacity,suitable electrochemical potential,and earth abu...Silicon oxide(SiO_(x),0<x≤2)has been recognized as a prominent anode material in lithium-ion batteries and sodium-ion batteries due to its high theoretical capacity,suitable electrochemical potential,and earth abundance.However,it is intrinsically poor electronic conductivity and excessive volume expansion during potassiation/depotassiation process hinder its application in potassium-ion batteries.Herein,we reported a hierarchical porous C/SiO_(x)potassium-ion batteries anode using lignite as raw material via a one-step carbonization and activation method.The amorphous C skeleton around SiO_(x)particles can effectively buffer the volume expansion,and improve the ionic/electronic conductivity and structural integrity,achieving outstanding rate capability and cyclability.As expected,the obtained C/SiO_(x)composite delivers a superb specific capacity of 370 mAh g^(-1)at 0.1 A g^(-1)after 100 cycles as well as a highly reversible capacity of 208 mAh g^(-1)after 1200 cycles at 1.0 A g^(-1).Moreover,the potassium ion storage mechanism of C/SiO_(x)electrodes was investigated by ex-situ X-ray diffraction and transmission electron microscopy,revealing the formation of reversible products of K_(6.8)Si_(45.3)and K_(4)SiO_(4),accompanied by generation of irreversible K2O after the first cycle.This work sheds light on designing low-cost Si-based anode materials for high-performance potassium-ion batteries and beyond.展开更多
The flow shop scheduling problem is important for the manufacturing industry.Effective flow shop scheduling can bring great benefits to the industry.However,there are few types of research on Distributed Hybrid Flow S...The flow shop scheduling problem is important for the manufacturing industry.Effective flow shop scheduling can bring great benefits to the industry.However,there are few types of research on Distributed Hybrid Flow Shop Problems(DHFSP)by learning assisted meta-heuristics.This work addresses a DHFSP with minimizing the maximum completion time(Makespan).First,a mathematical model is developed for the concerned DHFSP.Second,four Q-learning-assisted meta-heuristics,e.g.,genetic algorithm(GA),artificial bee colony algorithm(ABC),particle swarm optimization(PSO),and differential evolution(DE),are proposed.According to the nature of DHFSP,six local search operations are designed for finding high-quality solutions in local space.Instead of randomselection,Q-learning assists meta-heuristics in choosing the appropriate local search operations during iterations.Finally,based on 60 cases,comprehensive numerical experiments are conducted to assess the effectiveness of the proposed algorithms.The experimental results and discussions prove that using Q-learning to select appropriate local search operations is more effective than the random strategy.To verify the competitiveness of the Q-learning assistedmeta-heuristics,they are compared with the improved iterated greedy algorithm(IIG),which is also for solving DHFSP.The Friedman test is executed on the results by five algorithms.It is concluded that the performance of four Q-learning-assisted meta-heuristics are better than IIG,and the Q-learning-assisted PSO shows the best competitiveness.展开更多
Intelligent traffic control requires accurate estimation of the road states and incorporation of adaptive or dynamically adjusted intelligent algorithms for making the decision.In this article,these issues are handled...Intelligent traffic control requires accurate estimation of the road states and incorporation of adaptive or dynamically adjusted intelligent algorithms for making the decision.In this article,these issues are handled by proposing a novel framework for traffic control using vehicular communications and Internet of Things data.The framework integrates Kalman filtering and Q-learning.Unlike smoothing Kalman filtering,our data fusion Kalman filter incorporates a process-aware model which makes it superior in terms of the prediction error.Unlike traditional Q-learning,our Q-learning algorithm enables adaptive state quantization by changing the threshold of separating low traffic from high traffic on the road according to the maximum number of vehicles in the junction roads.For evaluation,the model has been simulated on a single intersection consisting of four roads:east,west,north,and south.A comparison of the developed adaptive quantized Q-learning(AQQL)framework with state-of-the-art and greedy approaches shows the superiority of AQQL with an improvement percentage in terms of the released number of vehicles of AQQL is 5%over the greedy approach and 340%over the state-of-the-art approach.Hence,AQQL provides an effective traffic control that can be applied in today’s intelligent traffic system.展开更多
Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,...Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,posing a major obstacle.Herein,we prepared the kinetically favorable Zn_(x)Ni_(1−x)O electrode in situ growth on carbon felt(Zn_(x)Ni_(1−x)O@CF)through constraining the rate of OH^(−)generation in the hydrothermal method.Zn_(x)Ni_(1−x)O@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores,benefitting the ion transport/electron transfer.And tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites,actual activity of redox-active Ni species,and lower adsorption energy,promoting the adsorption kinetic and thermodynamic of the Zn_(0.2)Ni_(0.8)O@CF.Benefitting from the kinetic-thermodynamic facilitation mechanism,Zn_(0.2)Ni_(0.8)O@CF achieved ultrahigh desalination capacity(128.9 mgNaCl g^(-1)),ultra-low energy consumption(0.164 kW h kgNaCl^(-1)),high salt removal rate(1.21 mgNaCl g^(-1) min^(-1)),and good cyclability.The thermodynamic facilitation and Na^(+)intercalation mechanism of Zn_(0.2)Ni_(0.8)O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring,respectively.This research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping,which is redox-inert,is essential for enhancing the electrochemical performance of CDI electrodes.展开更多
The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) a...The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) and thecorrelation of each sub fuzzy system, the uncertainty of the HFS’s deep structure increases. For the HFS, a largenumber of studies mainly use fixed structures, which cannot be selected automatically. To solve this problem, thispaper proposes a novel approach for constructing the incremental HFS. During system design, the deep structureand the rule base of the HFS are encoded separately. Subsequently, the deep structure is adaptively mutated basedon the fitness value, so as to realize the diversity of deep structures while ensuring reasonable competition amongthe structures. Finally, the differential evolution (DE) is used to optimize the deep structure of HFS and theparameters of antecedent and consequent simultaneously. The simulation results confirm the effectiveness of themodel. Specifically, the root mean square errors in the Laser dataset and Friedman dataset are 0.0395 and 0.0725,respectively with rule counts of rules is 8 and 12, respectively.When compared to alternative methods, the resultsindicate that the proposed method offers improvements in accuracy and rule counts.展开更多
Conducting polymers(CPs),including poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS),are promising coating materials for neural electrodes.However,the weak adhesion of CP coatings to substrates such a...Conducting polymers(CPs),including poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS),are promising coating materials for neural electrodes.However,the weak adhesion of CP coatings to substrates such as platinum-iridium is a significant challenge that limits their practical application.To address this issue,we used femtosecond laser-prepared hierarchical structures on platinum-iridium(Pt-Ir)substrates to enhance the adhesion of PEDOT:PSS coatings.Next,we used cyclic voltammetry(CV)stress and accelerated aging tests to evaluate the stability of both drop cast and electrodeposited PEDOT:PSS coatings on Pt-Ir substrates,both with and without hierarchical structures.Our results showed that after 2000 CV cycles or five weeks of aging at 60℃,the morphology and electrochemical properties of the coatings on the Pt-Ir substrates with hierarchical structures remained relatively stable.In contrast,we found that smooth Pt-Ir substrate surfaces caused delamination of the PEDOT:PSS coating and exhibited both decreased charge storage capacity and increased impedance.Overall,enhancing the stability of PEDOT:PSS coatings used on common platinum-iridium neural electrodes offers great potential for improving their electrochemical performance and developing new functionalities.展开更多
Hierarchical networks are frequently encountered in animal groups,gene networks,and artificial engineering systems such as multiple robots,unmanned vehicle systems,smart grids,wind farm networks,and so forth.The struc...Hierarchical networks are frequently encountered in animal groups,gene networks,and artificial engineering systems such as multiple robots,unmanned vehicle systems,smart grids,wind farm networks,and so forth.The structure of a large directed hierarchical network is often strongly influenced by reverse edges from lower-to higher-level nodes,such as lagging birds’howl in a flock or the opinions of lowerlevel individuals feeding back to higher-level ones in a social group.This study reveals that,for most large-scale real hierarchical networks,the majority of the reverse edges do not affect the synchronization process of the entire network;the synchronization process is influenced only by a small part of these reverse edges along specific paths.More surprisingly,a single effective reverse edge can slow down the synchronization of a huge hierarchical network by over 60%.The effect of such edges depends not on the network size but only on the average in-degree of the involved subnetwork.The overwhelming majority of active reverse edges turn out to have some kind of“bunching”effect on the information flows of hierarchical networks,which slows down synchronization processes.This finding refines the current understanding of the role of reverse edges in many natural,social,and engineering hierarchical networks,which might be beneficial for precisely tuning the synchronization rhythms of these networks.Our study also proposes an effective way to attack a hierarchical network by adding a malicious reverse edge to it and provides some guidance for protecting a network by screening out the specific small proportion of vulnerable nodes.展开更多
文摘针对无线传感器网络中存在的安全问题,提出了基于Q-Learning的分簇无线传感网信任管理机制(Q-learning based trust management mechanism for clustered wireless sensor networks,QLTMM-CWSN).该机制主要考虑通信信任、数据信任和能量信任3个方面.在网络运行过程中,基于节点的通信行为、数据分布和能量消耗,使用Q-Learning算法更新节点信任值,并选择簇内信任值最高的节点作为可信簇头节点.当簇中主簇头节点的信任值低于阈值时,可信簇头节点代替主簇头节点管理簇内成员节点,维护正常的数据传输.研究结果表明,QLTMM-CWSN机制能有效抵御通信攻击、伪造本地数据攻击、能量攻击和混合攻击.
基金The financial supports from the National Natural Science Foundation of China (22178059, 22208054 and 22072019)Natural Science Foundation of Fujian Province, China (2020J01513)+1 种基金Sinochem Quanzhou Energy Technology Co., Ltd. (ZHQZKJ-19-F-ZS0076)Qingyuan Innovation Laboratory (00121002)
文摘Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficiency.Herein,we explore an economic and environmentally friendly method for synthesizing hierarchical NaX zeolite that exhibits improved catalytic performance in the Knoevenagel condensation reaction for producing the useful fine chemical 2-cyano-3-phenylacrylate.The synthesis was achieved via a low-temperature activation of kaolinite and subsequent in-situ transformation strategy without any template or seed.Systematic characterizations reveal that the synthesized NaX zeolite has both intercrystalline and intra-crystalline mesopores,smaller crystal size,and larger external specific surface area compared to commercial NaX zeolite.Detailed mechanism investigations show that the inter-crystalline mesopores are generated by stacking smaller crystals formed from in-situ crystallization of the depolymerized kaolinite,and the intra-crystalline mesopores are inherited from the pores in the depolymerized kaolinite.This synthesis strategy provides an energy-saving and effective way to construct hierarchical zeolites,which may gain wide applications in fine chemical manufacturing.
基金financially supported by National Natural Science Foundation of China(Nos.U22A20193 and 51975218)Fundamental Research Funds for the Central Universities(No.2022ZYGXZR101)
文摘Printed micro-supercapacitors(MSCs)have shown broad prospect in flexible and wearable electronics.Most of previous studies focused on printing the electrochemically active materials paying less attention to other key components like current collectors and electrolytes.This study presents an allprinting strategy to fabricate in-plane flexible and substrate-free MSCs with hierarchical encapsulation.This new type of“all-in-one”MSC is constructed by encapsulating the in-plane interdigital current collectors and electrodes within the polyvinyl-alcohol-based hydrogel electrolyte via sequential printing.The bottom electrolyte layer of this fully printed MSCs helps protect the device from the limitation of conventional substrate,showing excellent flexibility.The MSCs maintain a high capacitance retention of 96.84%even in a completely folded state.An optimal electrochemical performance can be achieved by providing ample and shorter transport paths for ions.The MSCs using commercial activated carbon as the active material are endowed with a high specific areal capacitance of 1892.90 mF cm^(-2)at a current density of 0.3 mA cm^(-2),and an outstanding volumetric energy density of 9.20 mWh cm^(-3)at a volumetric power density of 6.89 mW cm^(-3).For demonstration,a thermo-hygrometer is stably powered by five MSCs which are connected in series and wrapped onto a glass rod.This low-cost and versatile all-printing strategy is believed to diversify the application fields of MSCs with high capacitance and excellent flexibility.
基金funded by the National Natural Science Foundation of China(No.51873004).
文摘Materials exhibiting high-performance electromagnetic wave absorption have garnered considerable scientific and technological attention,yet encounter significant challenges.Developing new materials and innovative structural design concepts is crucial for expanding the application field of electromagnetic wave absorption.Particularly,hierarchical structure engineering has emerged as a promising approach to enhance the physical and chemical properties of materials,providing immense potential for creating versatile electromagnetic wave absorption materials.Herein,an exceptional multi-dimensional hierarchical structure was meticulously devised,unleashing the full microwave attenuation capabilities through in situ growth,selfreduction,and multi-heterogeneous interface integration.The hierarchical structure features a three-dimensional carbon framework,where magnetic nanoparticles grow in situ on the carbon skeleton,creating a necklace-like structure.Furthermore,magnetic nanosheets assemble within this framework.Enhanced impedance matching was achieved by precisely adjusting component proportions,and intelligent integration of diverse interfaces bolstered dielectric polarization.The obtain Fe_(3)O_(4)-Fe nanoparticles/carbon nanofibers/Al-Fe_(3)O_(4)-Fe nanosheets composites demonstrated outstanding performance with a minimum reflection loss(RLmin)value of−59.3 dB and an effective absorption bandwidth(RL≤−10 dB)extending up to 5.6 GHz at 2.2 mm.These notable accomplishments offer fresh insights into the precision design of high-efficient electromagnetic wave absorption materials.
基金the National Natural Science Foundation of China(nos.21968022 and 51962027)the Fundamental Research Funds for Inner Mongolia University of Science&Technology(no.2023QNJS052)the Natural Science Foundation of Inner Mongolia(no.2019BS02002)
文摘Silicon oxide(SiO_(x),0<x≤2)has been recognized as a prominent anode material in lithium-ion batteries and sodium-ion batteries due to its high theoretical capacity,suitable electrochemical potential,and earth abundance.However,it is intrinsically poor electronic conductivity and excessive volume expansion during potassiation/depotassiation process hinder its application in potassium-ion batteries.Herein,we reported a hierarchical porous C/SiO_(x)potassium-ion batteries anode using lignite as raw material via a one-step carbonization and activation method.The amorphous C skeleton around SiO_(x)particles can effectively buffer the volume expansion,and improve the ionic/electronic conductivity and structural integrity,achieving outstanding rate capability and cyclability.As expected,the obtained C/SiO_(x)composite delivers a superb specific capacity of 370 mAh g^(-1)at 0.1 A g^(-1)after 100 cycles as well as a highly reversible capacity of 208 mAh g^(-1)after 1200 cycles at 1.0 A g^(-1).Moreover,the potassium ion storage mechanism of C/SiO_(x)electrodes was investigated by ex-situ X-ray diffraction and transmission electron microscopy,revealing the formation of reversible products of K_(6.8)Si_(45.3)and K_(4)SiO_(4),accompanied by generation of irreversible K2O after the first cycle.This work sheds light on designing low-cost Si-based anode materials for high-performance potassium-ion batteries and beyond.
基金partially supported by the Guangdong Basic and Applied Basic Research Foundation(2023A1515011531)the National Natural Science Foundation of China under Grant 62173356+2 种基金the Science and Technology Development Fund(FDCT),Macao SAR,under Grant 0019/2021/AZhuhai Industry-University-Research Project with Hongkong and Macao under Grant ZH22017002210014PWCthe Key Technologies for Scheduling and Optimization of Complex Distributed Manufacturing Systems(22JR10KA007).
文摘The flow shop scheduling problem is important for the manufacturing industry.Effective flow shop scheduling can bring great benefits to the industry.However,there are few types of research on Distributed Hybrid Flow Shop Problems(DHFSP)by learning assisted meta-heuristics.This work addresses a DHFSP with minimizing the maximum completion time(Makespan).First,a mathematical model is developed for the concerned DHFSP.Second,four Q-learning-assisted meta-heuristics,e.g.,genetic algorithm(GA),artificial bee colony algorithm(ABC),particle swarm optimization(PSO),and differential evolution(DE),are proposed.According to the nature of DHFSP,six local search operations are designed for finding high-quality solutions in local space.Instead of randomselection,Q-learning assists meta-heuristics in choosing the appropriate local search operations during iterations.Finally,based on 60 cases,comprehensive numerical experiments are conducted to assess the effectiveness of the proposed algorithms.The experimental results and discussions prove that using Q-learning to select appropriate local search operations is more effective than the random strategy.To verify the competitiveness of the Q-learning assistedmeta-heuristics,they are compared with the improved iterated greedy algorithm(IIG),which is also for solving DHFSP.The Friedman test is executed on the results by five algorithms.It is concluded that the performance of four Q-learning-assisted meta-heuristics are better than IIG,and the Q-learning-assisted PSO shows the best competitiveness.
文摘Intelligent traffic control requires accurate estimation of the road states and incorporation of adaptive or dynamically adjusted intelligent algorithms for making the decision.In this article,these issues are handled by proposing a novel framework for traffic control using vehicular communications and Internet of Things data.The framework integrates Kalman filtering and Q-learning.Unlike smoothing Kalman filtering,our data fusion Kalman filter incorporates a process-aware model which makes it superior in terms of the prediction error.Unlike traditional Q-learning,our Q-learning algorithm enables adaptive state quantization by changing the threshold of separating low traffic from high traffic on the road according to the maximum number of vehicles in the junction roads.For evaluation,the model has been simulated on a single intersection consisting of four roads:east,west,north,and south.A comparison of the developed adaptive quantized Q-learning(AQQL)framework with state-of-the-art and greedy approaches shows the superiority of AQQL with an improvement percentage in terms of the released number of vehicles of AQQL is 5%over the greedy approach and 340%over the state-of-the-art approach.Hence,AQQL provides an effective traffic control that can be applied in today’s intelligent traffic system.
基金supported by The National Natural Science Foundation of China(22276137,52170087)the Fundamental Research Funds for the Central Universities(XJEDU2023Z009).
文摘Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,posing a major obstacle.Herein,we prepared the kinetically favorable Zn_(x)Ni_(1−x)O electrode in situ growth on carbon felt(Zn_(x)Ni_(1−x)O@CF)through constraining the rate of OH^(−)generation in the hydrothermal method.Zn_(x)Ni_(1−x)O@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores,benefitting the ion transport/electron transfer.And tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites,actual activity of redox-active Ni species,and lower adsorption energy,promoting the adsorption kinetic and thermodynamic of the Zn_(0.2)Ni_(0.8)O@CF.Benefitting from the kinetic-thermodynamic facilitation mechanism,Zn_(0.2)Ni_(0.8)O@CF achieved ultrahigh desalination capacity(128.9 mgNaCl g^(-1)),ultra-low energy consumption(0.164 kW h kgNaCl^(-1)),high salt removal rate(1.21 mgNaCl g^(-1) min^(-1)),and good cyclability.The thermodynamic facilitation and Na^(+)intercalation mechanism of Zn_(0.2)Ni_(0.8)O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring,respectively.This research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping,which is redox-inert,is essential for enhancing the electrochemical performance of CDI electrodes.
基金the Sichuan Science and Technology Program(2021ZYD0016).
文摘The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) and thecorrelation of each sub fuzzy system, the uncertainty of the HFS’s deep structure increases. For the HFS, a largenumber of studies mainly use fixed structures, which cannot be selected automatically. To solve this problem, thispaper proposes a novel approach for constructing the incremental HFS. During system design, the deep structureand the rule base of the HFS are encoded separately. Subsequently, the deep structure is adaptively mutated basedon the fitness value, so as to realize the diversity of deep structures while ensuring reasonable competition amongthe structures. Finally, the differential evolution (DE) is used to optimize the deep structure of HFS and theparameters of antecedent and consequent simultaneously. The simulation results confirm the effectiveness of themodel. Specifically, the root mean square errors in the Laser dataset and Friedman dataset are 0.0395 and 0.0725,respectively with rule counts of rules is 8 and 12, respectively.When compared to alternative methods, the resultsindicate that the proposed method offers improvements in accuracy and rule counts.
基金supported by the National Key Research and Development Program of China(No.2021YFC2400201)the National Natural Science Foundation of China(No.81830033)+1 种基金the Natural Science Foundation of Fujian Province,China(No.2023J05097)the Young and Middle-aged Teacher Education Research Project of the Education Department of Fujian Province,China(No.JAT220004)。
文摘Conducting polymers(CPs),including poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS),are promising coating materials for neural electrodes.However,the weak adhesion of CP coatings to substrates such as platinum-iridium is a significant challenge that limits their practical application.To address this issue,we used femtosecond laser-prepared hierarchical structures on platinum-iridium(Pt-Ir)substrates to enhance the adhesion of PEDOT:PSS coatings.Next,we used cyclic voltammetry(CV)stress and accelerated aging tests to evaluate the stability of both drop cast and electrodeposited PEDOT:PSS coatings on Pt-Ir substrates,both with and without hierarchical structures.Our results showed that after 2000 CV cycles or five weeks of aging at 60℃,the morphology and electrochemical properties of the coatings on the Pt-Ir substrates with hierarchical structures remained relatively stable.In contrast,we found that smooth Pt-Ir substrate surfaces caused delamination of the PEDOT:PSS coating and exhibited both decreased charge storage capacity and increased impedance.Overall,enhancing the stability of PEDOT:PSS coatings used on common platinum-iridium neural electrodes offers great potential for improving their electrochemical performance and developing new functionalities.
基金supported in part by the National Natural Science Foundation of China(62225306,U2141235,52188102,and 62003145)the National Key Research and Development Program of China(2022ZD0119601)+1 种基金Guangdong Basic and Applied Research Foundation(2022B1515120069)the Science and Technology Project of State Grid Corporation of China(5100-202199557A-0-5-ZN).
文摘Hierarchical networks are frequently encountered in animal groups,gene networks,and artificial engineering systems such as multiple robots,unmanned vehicle systems,smart grids,wind farm networks,and so forth.The structure of a large directed hierarchical network is often strongly influenced by reverse edges from lower-to higher-level nodes,such as lagging birds’howl in a flock or the opinions of lowerlevel individuals feeding back to higher-level ones in a social group.This study reveals that,for most large-scale real hierarchical networks,the majority of the reverse edges do not affect the synchronization process of the entire network;the synchronization process is influenced only by a small part of these reverse edges along specific paths.More surprisingly,a single effective reverse edge can slow down the synchronization of a huge hierarchical network by over 60%.The effect of such edges depends not on the network size but only on the average in-degree of the involved subnetwork.The overwhelming majority of active reverse edges turn out to have some kind of“bunching”effect on the information flows of hierarchical networks,which slows down synchronization processes.This finding refines the current understanding of the role of reverse edges in many natural,social,and engineering hierarchical networks,which might be beneficial for precisely tuning the synchronization rhythms of these networks.Our study also proposes an effective way to attack a hierarchical network by adding a malicious reverse edge to it and provides some guidance for protecting a network by screening out the specific small proportion of vulnerable nodes.