In order to study reasonable tree structure parameters of Y-shaped pear orchards in natural conditions and at management technical level of Tai'an area, the tree structure and population structure of high-quality ...In order to study reasonable tree structure parameters of Y-shaped pear orchards in natural conditions and at management technical level of Tai'an area, the tree structure and population structure of high-quality and high-yielding Y-shaped pear orchards were investigated. The results showed that when the yield of Y-shaped 'Oshu' was 2 550 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was about 54 000, and the number of short branches was the largest, accounting for 80.1% of total number of branches, followed by middle branches, long branches and developmental branches. As the yield of Y-shaped 'Qiuyue' was 2 875 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was 51 000, and the number of short branches was the largest, accounting for 75.6% of total number of branches, followed by middle branches, long branches and developmental branches. When the yield of Y-shaped 'Niitaka' was 3 000 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was 43 000, and the number of short branches was the largest, accounting for 82.0% of total number of branches, followed by long branches, middle branches and developmental branches.展开更多
Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was ...Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was put forward.The supporting principlesof high stress engineering soft rock roadway (high resistance and yielding support,timelysupport,high strength and high stiffness supports) were proposed,which were applied inengineering practices,and obtained better achievements.展开更多
Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G* level.Isomers 1 and 2 are of D2h and D2d symmetry, res...Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G* level.Isomers 1 and 2 are of D2h and D2d symmetry, respectively. Heats of formation for the two C4N12O4 isomers have been estimated in this paper, indicating they would be reasonable candidates for high energy density materials.展开更多
Worldwide, scarce water resources and substantial food demands require efficient water use and high yield.This study investigated whether irrigation frequency can be used to adjust soil moisture to increase grain yiel...Worldwide, scarce water resources and substantial food demands require efficient water use and high yield.This study investigated whether irrigation frequency can be used to adjust soil moisture to increase grain yield and water use efficiency(WUE) of high-yield maize under conditions of mulching and drip irrigation.A field experiment was conducted using three irrigation intervals in 2016: 6, 9, and 12 days(labeled D6, D9, and D12) and five irrigation intervals in 2017: 3, 6, 9, 12, and 15 days(D3, D6, D9, D12, and D15).In Xinjiang, an optimal irrigation quota is 540 mm for high-yield maize.The D3, D6, D9, D12, and D15 irrigation intervals gave grain yields of 19.7, 19.1–21.0, 18.8–20.0, 18.2–19.2, and 17.2 Mg ha^-1 and a WUE of 2.48, 2.53–2.80, 2.47–2.63, 2.34–2.45, and 2.08 kg m-3, respectively.Treatment D6 led to the highest soil water storage, but evapotranspiration and soil-water evaporation were lower than other treatments.These results show that irrigation interval D6 can help maintain a favorable soil-moisture environment in the upper-60-cm soil layer, reduce soilwater evaporation and evapotranspiration, and produce the highest yield and WUE.In this arid region and in other regions with similar soil and climate conditions, a similar irrigation interval would thus be beneficial for adjusting soil moisture to increase maize yield and WUE under conditions of mulching and drip irrigation.展开更多
Structural intervention involves the restoration and/or upgrading of the mechanical performances of structures. In addition to concrete and steel, which are typical materials for concrete structures, various ber-reinf...Structural intervention involves the restoration and/or upgrading of the mechanical performances of structures. In addition to concrete and steel, which are typical materials for concrete structures, various ber-reinforced polymers (FRPs), cementitious materials with bers, polymers, and adhesives are often applied for structural intervention. In order to predict structural performance, it is necessary to develop a generic method that is applicable to not only to steel, but also to other materials. Such a generic model could provide information on the mechanical properties required to improve the structural performance. External bonding, which is a typical scheme for structural intervention, is not applied for new structures. It is necessary to clarify material properties and structural details in order to achieve better bonding strength at the interface between the substrate concrete and an externally bonded material. This paper presents the mechanical properties of substrate concrete and relevant intervention material for the fol- lowing purposes: ① to achieve better shear strength and ultimate deformation of a member after struc- tural intervention;and ② to achieve better debonding strength for external bonding. This paper concludes that some of the mechanical properties and structural details for intervention materials that are necessary for improvement in mechanical performance in structures with structural intervention are new, and differ from those of structures without intervention. For example, high strength and stiff- ness are important properties for materials in structures without structural intervention, whereas high fracturing strain and low stiffness are important properties for structural intervention materials.展开更多
In order to understand the structure-property correlation and explore the application of metal nanoclusters, it is important and intriguing to determine their crystal structure and obtain high-yield. At the same time,...In order to understand the structure-property correlation and explore the application of metal nanoclusters, it is important and intriguing to determine their crystal structure and obtain high-yield. At the same time, this is also a challenge in nanoscience and technology. Here, we report the highly efficient synthesis of Pt1Ag28 nanocluster via one-pot chemical wet method. The crystal structure of Pt1Ag28 nanocluster was determined by X-ray crystallography to be a face centered cubic (FCC) kernel. This novel structure is the structural isomerization of Pt1Ag28 nanocluster reported before. This phenomenon is first discovered in the synthesis of alloy nanoclusters. In addition, Pt1Ag28 nanocluster has high yield and exhibits potential optics in the near infrared (NIR) fluorescent imaging. The time-dependent density functional theory (TD-DFT) calculation implied that the optical property of Pt1Ag28 was sensitive to its structure. This work provides a simple method to synthesize alloy nanoclusters with structural isomerization.展开更多
Hierarchical porous zeolitic imidazolate frameworks (ZIFs) have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly des...Hierarchical porous zeolitic imidazolate frameworks (ZIFs) have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly desirable for large-scale industrial production. Here, we developed a green and versatile method using organic amines as supramolecular templates (organic amine-template) to rapidly synthesize hierarchical porous ZIFs (ZIF-8, ZIF-61 and ZIF-90) at room temperature and pressure. The synthesis time was reduced dramatically to within 1 min, and the resulting ZIFs had multimodal hierarchical porous structures with mesopores/ macropores interconnected with micropores. Notably, the space-time yield (STY) of hierarchical porous ZIF-8 was up to 1.29×10^4 kg m^-3 d^-1, which is more than three times higher than that reported using other methods. Furthermore, the morphologies and porosities of the produced ZIFs could be readily tuned by controlling the synthesis time or type of organic amine. The organic amine played two roles in the synthesis: (1) a protonation agent to deprotonate organic ligands, facilitating the formation of ZIF crystals, and (2) an structure directing agent to direct mesopore/macropore formation. The resulting hierarchical porous ZIF-8 exhibited enhanced uptake capacities and diffusion rates for guest molecules relative to its microporous counterpart. This work provides a new direction for the green and efficient synthesis of various hierarchical porous ZIFs with high STYs for a wide range of applications.展开更多
An advance Li-sphere possessing a definitely regular morphology in Li deposition enables a well-defined more robust structure and superior solid-electrolyte interphase(SEI)to achieve high-efficiency long-term cycles i...An advance Li-sphere possessing a definitely regular morphology in Li deposition enables a well-defined more robust structure and superior solid-electrolyte interphase(SEI)to achieve high-efficiency long-term cycles in Li metal anode.Here,a new sight of high Li^(+)cluster-like solvation sheaths coordinated in a localized high-concentration NO_(3)^(-)(LH-LiNO_(3))electrolyte fully clarifies for depositing advanced Li spheres.Moreover,we elucidate a critical amorphouscrystalline phase transition in the nanostructure evolution of Li-sphere deposits during the nucleation and growth.Li-sphere anode exhibits ultrastable structural engineering for suppressing Li dendrite growths and rendering ultralong life of 4000 cycles in symmetrical cells at 2 mAcm^(-2).The as-constructed Li spheres/3DCMjLiFePO_(4)(LFP)full cell delivers a high capacity retention of 90.5%at 1 C after 1000 cycles,and a robust dendrite-free structure also stably exists in Li-sphere anode.Combined with high-loading LFP cathodes(6.6 and 10.9 mg cm^(-2)),superb capacity retentions are up to 96.5%and 92.5%after 800 cycles at 1 C,respectively.Cluster-like solvation sheaths with high Li^(+)coordination exert significant influence on depositing a highquality Li-sphere anode.展开更多
基金Supported by Special Project for Construction of National Pear Industry Technology System(CARS-28-36)National Natural Science Foundation of China(31601708)+3 种基金Agricultural Seed Improvement Project of Shandong Province,China(2016LZGC034)Foundation for Young Scholars of Shandong Academy of Agricultural Sciences(2015YQN40)National Science and Technology Plan of Rural Areas in the"12th Five-year Plan"Period of China(2014BAD16B03-4)Agricultural Science and Technology Innovation Project of Shandong Academy of Agricultural Sciences(CXGC2016B07)
文摘In order to study reasonable tree structure parameters of Y-shaped pear orchards in natural conditions and at management technical level of Tai'an area, the tree structure and population structure of high-quality and high-yielding Y-shaped pear orchards were investigated. The results showed that when the yield of Y-shaped 'Oshu' was 2 550 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was about 54 000, and the number of short branches was the largest, accounting for 80.1% of total number of branches, followed by middle branches, long branches and developmental branches. As the yield of Y-shaped 'Qiuyue' was 2 875 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was 51 000, and the number of short branches was the largest, accounting for 75.6% of total number of branches, followed by middle branches, long branches and developmental branches. When the yield of Y-shaped 'Niitaka' was 3 000 kg/667 m^2 in the early fully fruiting period, the quantity of the branches per 667 m^2 was 43 000, and the number of short branches was the largest, accounting for 82.0% of total number of branches, followed by long branches, middle branches and developmental branches.
基金Supported by the National Natural Science Fundation of China (50674045)the National "973" Planning Project(2007CB209403)
文摘Through the description of the deformational features of the surrounding rockaround high stress engineering soft rock roadways,the coupling stabilization principle ofinner and outer structures in surrounding rock was put forward.The supporting principlesof high stress engineering soft rock roadway (high resistance and yielding support,timelysupport,high strength and high stiffness supports) were proposed,which were applied inengineering practices,and obtained better achievements.
基金This work was supported by the Natural Science Foundation of Shandong Province (Y2002G11)
文摘Geometries, energies, and vibrational frequencies for two C4N12O4 isomers with pagodane- and isopagodane-like structures have been calculated at the B3LYP/6-31G* level.Isomers 1 and 2 are of D2h and D2d symmetry, respectively. Heats of formation for the two C4N12O4 isomers have been estimated in this paper, indicating they would be reasonable candidates for high energy density materials.
基金research support from the National Key Research and Development Program of China (2016YFD0300110, 2016YFD0300101)the National Basic Research Program of China (2015CB150401)+2 种基金the National Natural Science Foundation of China (31360302)the Science and Technology Program of the Sixth Division of Xinjiang Construction Corps in China (1703)the Agricultural Science and Technology Innovation Program for financial support.
文摘Worldwide, scarce water resources and substantial food demands require efficient water use and high yield.This study investigated whether irrigation frequency can be used to adjust soil moisture to increase grain yield and water use efficiency(WUE) of high-yield maize under conditions of mulching and drip irrigation.A field experiment was conducted using three irrigation intervals in 2016: 6, 9, and 12 days(labeled D6, D9, and D12) and five irrigation intervals in 2017: 3, 6, 9, 12, and 15 days(D3, D6, D9, D12, and D15).In Xinjiang, an optimal irrigation quota is 540 mm for high-yield maize.The D3, D6, D9, D12, and D15 irrigation intervals gave grain yields of 19.7, 19.1–21.0, 18.8–20.0, 18.2–19.2, and 17.2 Mg ha^-1 and a WUE of 2.48, 2.53–2.80, 2.47–2.63, 2.34–2.45, and 2.08 kg m-3, respectively.Treatment D6 led to the highest soil water storage, but evapotranspiration and soil-water evaporation were lower than other treatments.These results show that irrigation interval D6 can help maintain a favorable soil-moisture environment in the upper-60-cm soil layer, reduce soilwater evaporation and evapotranspiration, and produce the highest yield and WUE.In this arid region and in other regions with similar soil and climate conditions, a similar irrigation interval would thus be beneficial for adjusting soil moisture to increase maize yield and WUE under conditions of mulching and drip irrigation.
文摘Structural intervention involves the restoration and/or upgrading of the mechanical performances of structures. In addition to concrete and steel, which are typical materials for concrete structures, various ber-reinforced polymers (FRPs), cementitious materials with bers, polymers, and adhesives are often applied for structural intervention. In order to predict structural performance, it is necessary to develop a generic method that is applicable to not only to steel, but also to other materials. Such a generic model could provide information on the mechanical properties required to improve the structural performance. External bonding, which is a typical scheme for structural intervention, is not applied for new structures. It is necessary to clarify material properties and structural details in order to achieve better bonding strength at the interface between the substrate concrete and an externally bonded material. This paper presents the mechanical properties of substrate concrete and relevant intervention material for the fol- lowing purposes: ① to achieve better shear strength and ultimate deformation of a member after struc- tural intervention;and ② to achieve better debonding strength for external bonding. This paper concludes that some of the mechanical properties and structural details for intervention materials that are necessary for improvement in mechanical performance in structures with structural intervention are new, and differ from those of structures without intervention. For example, high strength and stiff- ness are important properties for materials in structures without structural intervention, whereas high fracturing strain and low stiffness are important properties for structural intervention materials.
基金the National Natural Science Foundation of China (No. 21601178)the "Strategic Priority Research Program” of the Chinese Academy of Sciences (No. XDA09030103).
文摘In order to understand the structure-property correlation and explore the application of metal nanoclusters, it is important and intriguing to determine their crystal structure and obtain high-yield. At the same time, this is also a challenge in nanoscience and technology. Here, we report the highly efficient synthesis of Pt1Ag28 nanocluster via one-pot chemical wet method. The crystal structure of Pt1Ag28 nanocluster was determined by X-ray crystallography to be a face centered cubic (FCC) kernel. This novel structure is the structural isomerization of Pt1Ag28 nanocluster reported before. This phenomenon is first discovered in the synthesis of alloy nanoclusters. In addition, Pt1Ag28 nanocluster has high yield and exhibits potential optics in the near infrared (NIR) fluorescent imaging. The time-dependent density functional theory (TD-DFT) calculation implied that the optical property of Pt1Ag28 was sensitive to its structure. This work provides a simple method to synthesize alloy nanoclusters with structural isomerization.
基金supported by the National Natural Science Foundation of China (21576094)SRFDP (20130172110012)the Fundamental Research Funds for the Central Universities (2015ZM046)
文摘Hierarchical porous zeolitic imidazolate frameworks (ZIFs) have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly desirable for large-scale industrial production. Here, we developed a green and versatile method using organic amines as supramolecular templates (organic amine-template) to rapidly synthesize hierarchical porous ZIFs (ZIF-8, ZIF-61 and ZIF-90) at room temperature and pressure. The synthesis time was reduced dramatically to within 1 min, and the resulting ZIFs had multimodal hierarchical porous structures with mesopores/ macropores interconnected with micropores. Notably, the space-time yield (STY) of hierarchical porous ZIF-8 was up to 1.29×10^4 kg m^-3 d^-1, which is more than three times higher than that reported using other methods. Furthermore, the morphologies and porosities of the produced ZIFs could be readily tuned by controlling the synthesis time or type of organic amine. The organic amine played two roles in the synthesis: (1) a protonation agent to deprotonate organic ligands, facilitating the formation of ZIF crystals, and (2) an structure directing agent to direct mesopore/macropore formation. The resulting hierarchical porous ZIF-8 exhibited enhanced uptake capacities and diffusion rates for guest molecules relative to its microporous counterpart. This work provides a new direction for the green and efficient synthesis of various hierarchical porous ZIFs with high STYs for a wide range of applications.
基金National Key Research and Development Program of China,Grant/Award Numbers:2021YFB2400401,2017YFA0204702National Natural Science Foundation of China,Grant/Award Numbers:21673008,21927901,21821004。
文摘An advance Li-sphere possessing a definitely regular morphology in Li deposition enables a well-defined more robust structure and superior solid-electrolyte interphase(SEI)to achieve high-efficiency long-term cycles in Li metal anode.Here,a new sight of high Li^(+)cluster-like solvation sheaths coordinated in a localized high-concentration NO_(3)^(-)(LH-LiNO_(3))electrolyte fully clarifies for depositing advanced Li spheres.Moreover,we elucidate a critical amorphouscrystalline phase transition in the nanostructure evolution of Li-sphere deposits during the nucleation and growth.Li-sphere anode exhibits ultrastable structural engineering for suppressing Li dendrite growths and rendering ultralong life of 4000 cycles in symmetrical cells at 2 mAcm^(-2).The as-constructed Li spheres/3DCMjLiFePO_(4)(LFP)full cell delivers a high capacity retention of 90.5%at 1 C after 1000 cycles,and a robust dendrite-free structure also stably exists in Li-sphere anode.Combined with high-loading LFP cathodes(6.6 and 10.9 mg cm^(-2)),superb capacity retentions are up to 96.5%and 92.5%after 800 cycles at 1 C,respectively.Cluster-like solvation sheaths with high Li^(+)coordination exert significant influence on depositing a highquality Li-sphere anode.