Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the s...Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational.展开更多
In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and proper...In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and properties of the alloy were investigated in detail.The results showed that the samples deformed by the combination of cryogenic equal channel angular pressing(ECAP)and rolling had good comprehensive properties after aging at 400℃.The tensile strength of the peak-aged and over-aged samples was 1120 MPa and 940 MPa,with their corresponding electrical conductivity of 14.7%IACS and 22.1%IACS,respectively.ECAP and cryogenic rolling introduced high density dislocations,leading to the inhibition of the softening effects and refinement of the grains.After a long time aging at 400℃,the alloy exhibited ultra-high strength with obvious increasing electrical conductivity.The high strength was attributed to the synergistic effect of work hardening,grain refinement strengthening and precipitation strengthening.The precipitation of a large amount of Ti atoms from the matrix led to the high electrical conductivity of the over-aged sample.展开更多
To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃w...To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted.展开更多
Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic s...Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic stirring,end electromagnetic stirring,casting speed and soft reduction)for the smelting of high-strength antisulfur pipes.The microstructures of continuous-casting billets and hot-rolled or tempered pipes were analyzed using a metallographic microscope and scanning electron microscope.The mechanism and evolution law regarding the inner-wall band segregation of high-strength antisulfur pipes were studied,and the influence of different casting processes was explored.展开更多
The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to eval...The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed.展开更多
The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted ...The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted to studying the anisotropic strength,deformation and failure behavior of gneiss granite from the deep boreholes of a railway tunnel that suffers from high tectonic stress and ground temperature in the eastern tectonic knot in the Tibet Plateau.High-temperature true triaxial compression tests are performed on the samples using a self-developed testing device with five different loading directions and three temperature values that are representative of the geological conditions of the deep underground tunnels in the region.Effect of temperature and loading direction on the strength,elastic modulus,Poisson’s ratio,and failure mode are analyzed.The method for quantitative identification of anisotropic failure is also proposed.The anisotropic mechanical behaviors of the gneiss granite are very sensitive to the changes in loading direction and temperature under true triaxial compression,and the high temperature seems to weaken the inherent anisotropy and stress-induced deformation anisotropy.The strength and deformation show obvious thermal degradation at 200℃due to the weakening of friction between failure surfaces and the transition of the failure pattern in rock grains.In the range of 25℃ 200℃,the failure is mainly governed by the loading direction due to the inherent anisotropy.This study is helpful to the in-depth understanding of the thermal-mechanical behavior of anisotropic rocks in deep underground projects.展开更多
With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are desi...With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are designed to meet the requirements of high strength and high toughness of spring flat steel,through the test,the product surface quality and internal quality all meet the national standards,the performance indicators to meet user requirements.展开更多
Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying alloys.In this study,Ti–6.5Al–2Zr–Mo–V(TA15)titaniu...Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying alloys.In this study,Ti–6.5Al–2Zr–Mo–V(TA15)titanium alloy plates were prepared by cold press-ing sintering combined with high-temperature hot rolling.The microstructure and mechanical properties under different process paramet-ers were investigated.Optical microscope,electron backscatter diffraction,and others were applied to characterize the microstructure evolution and mechanical properties strengthening mechanism.The results showed that the chemical compositions were uniformly dif-fused without segregation during sintering,and the closing of the matrix craters was accelerated by increasing the sintering temperature.The block was hot rolled at 1200℃ with an 80%reduction under only two passes without annealing.The strength and elongation of the plate at 20–25℃ after solution and aging were 1247 MPa and 14.0%,respectively,which were increased by 24.5%and 40.0%,respect-ively,compared with the as-sintered alloy at 1300℃.The microstructure was significantly refined by continuous dynamic recrystalliza-tion,which was completed by the rotation and dislocation absorption of the substructure surrounded by low-angle grain boundaries.After hot rolling combined with heat treatment,the strength and plasticity of PM-TA15 were significantly improved,which resulted from the dense,uniform,and fine recrystallization structure and the synergistic effect of multiple slip systems.展开更多
Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass...Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass loadings crucial for practical use.The root of these challenges lies in the mechanical instability of the material,which subsequently leads to the structural failure of the electrode.Here,we present a novel synthesis of a composite combining expanded graphite and silicon nanoparticles.This composite features a unique interlayer-bonded graphite structure,achieved through the application of a modified spark plasma sintering method.Notably,this innovative structure not only facilitates efficient ion and electron transport but also provides exceptional mechanical strength(Vickers hardness:up to658 MPa,Young's modulus:11.6 GPa).This strength effectively accommodates silicon expansion,resulting in an impressive areal capacity of 2.9 mA h cm^(-2)(736 mA h g^(-1)) and a steady cycle life(93% after 100cycles).Such outsta nding performance is paired with features appropriate for large-scale industrial production of silicon batteries,such as active mass loading of at least 3.9 mg cm^(-2),a high-tap density electrode material of 1.68 g cm^(-3)(secondary clusters:1.12 g cm^(-3)),and a production yield of up to 1 kg per day.展开更多
The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate...The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing fillers.The interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW materials.Compared to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded steel.And 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of propellants.Despite the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic activity.This strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.展开更多
Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial...Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial AZ31 alloy in extrudability,but also have superior mechanical properties,especially in terms of yield strength(YS).The excellent extrudability is related to less coarse second-phase particles and high initial melting point of the two as-cast alloys.The high strength-ductility mainly comes from the formation of fine grains,nano-spaced submicron/nano precipitates,and weak texture.Moreover,it is worth noting that the YS of the two alloys can maintain above 160 MPa at elevated temperature of 250°C,significantly higher than that of AZ31 alloy(YS:45 MPa).The Zn/Ca solute segregation at grain boundaries,the improved heat resistance of matrix due to addition of RE,and the high melting points of strengthening particles(Mn,MgZn_(2),and Mg-Zn-RE/Mg-Zn-RE-Ca)are mainly responsible for the excellent high-temperature strength.展开更多
In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sour...In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.展开更多
Mg-1.0Al-1.0Ca-0.4Mn(AXM1104, wt.%) low alloy was extruded at 200 ℃ with an extrusion ratio of 25 and different ram speeds from 1.0 to 7.0 mm/s. The influence of extrusion rate on microstructure and mechanical proper...Mg-1.0Al-1.0Ca-0.4Mn(AXM1104, wt.%) low alloy was extruded at 200 ℃ with an extrusion ratio of 25 and different ram speeds from 1.0 to 7.0 mm/s. The influence of extrusion rate on microstructure and mechanical properties of the AXM1104 alloy was systematically studied. With the increasing of extrusion rate, the mean dynamically recrystallized(DRXed) grain size of the low alloy and average particles diameter of precipitate second phases were increased, while the degree of grain boundary segregation and the intensity of the basal fiber texture were decreased. With the rising of extrusion rate from 1.0 to 7.0 mm/s, the tensile yield strength(TYS) of the as-extruded AXM1104 alloy was decreased from 445 MPa to 249 MPa, while the elongation to failure(EL) was increased from 5.0% to 17.6%. The TYS, ultimate tensile strength(UTS) and EL of the AXM1104 alloy extruded at the ram speed of 1.5 mm/s was 412 MPa, 419 MPa and 12.0%, respectively,exhibiting comprehensive tensile mechanical properties with ultra-high strength and excellent plasticity. The ultra-high TYS of 412 MPa was mainly due to the strengthening from ultra-fine DRXed grains with segregation of solute atoms at grain boundaries. The strain hardening rate is increase slightly with increasing extrusion speed, which may be ascribed to the increasing mean DRXed grain size with rising extrusion speed. The higher strain hardening rate contributes to the higher EL of these AXM1104 samples extruded at higher ram speed.展开更多
The present work investigates copper slag as a substitute for river sand in high-strength concrete.The concrete mixtures were manufactured with 10%,30%,50%,70%,and 100%of copper slag to evaluate the mechanical and dur...The present work investigates copper slag as a substitute for river sand in high-strength concrete.The concrete mixtures were manufactured with 10%,30%,50%,70%,and 100%of copper slag to evaluate the mechanical and durability properties.The experimental results indicate that replacing copper slag above 50%affects the performance characteristics of the concrete due to its high angularity and lower water absorption characteristics.The strength of concrete with 50%copper slag is improved by 5.6%,whereas the strength of concrete with 100%copper slag is reduced by 2.75%at 28 days.However,increased curing to 90days improves the strength of the former by 7.16%and reduces the latter by only 0.23%.The water absorption,porosity,and rapid chloride penetration of the concrete mixtures with 100%copper slag are increased by 10.44%,13.20%,and 19.56%compared to control concrete.Micro-structural investigations through SEM infer higher replacement of copper results in higher void formation due to its reduced water absorption.展开更多
The ongoing effort to create methods for detecting and quantifying fatigue damage is motivated by the high levels of uncertainty in present fatigue-life prediction approaches and the frequently catastrophic nature of ...The ongoing effort to create methods for detecting and quantifying fatigue damage is motivated by the high levels of uncertainty in present fatigue-life prediction approaches and the frequently catastrophic nature of fatigue failure.The fatigue life of high strength aluminum alloy 2090-T83 is predicted in this study using a variety of artificial intelligence and machine learning techniques for constant amplitude and negative stress ratios(R?1).Artificial neural networks(ANN),adaptive neuro-fuzzy inference systems(ANFIS),support-vector machines(SVM),a random forest model(RF),and an extreme-gradient tree-boosting model(XGB)are trained using numerical and experimental input data obtained from fatigue tests based on a relatively low number of stress measurements.In particular,the coefficients of the traditional force law formula are found using relevant numerical methods.It is shown that,in comparison to traditional approaches,the neural network and neuro-fuzzy models produce better results,with the neural network models trained using the boosting iterations technique providing the best performances.Building strong models from weak models,XGB helps to predict fatigue life by reducing model partiality and variation in supervised learning.Fuzzy neural models can be used to predict the fatigue life of alloys more accurately than neural networks and traditional methods.展开更多
The accurate prediction of the strength of rocks after high-temperature treatment is important for the safety maintenance of rock in deep underground engineering.Five machine learning(ML)techniques were adopted in thi...The accurate prediction of the strength of rocks after high-temperature treatment is important for the safety maintenance of rock in deep underground engineering.Five machine learning(ML)techniques were adopted in this study,i.e.back propagation neural network(BPNN),AdaBoost-based classification and regression tree(AdaBoost-CART),support vector machine(SVM),K-nearest neighbor(KNN),and radial basis function neural network(RBFNN).A total of 351 data points with seven input parameters(i.e.diameter and height of specimen,density,temperature,confining pressure,crack damage stress and elastic modulus)and one output parameter(triaxial compressive strength)were utilized.The root mean square error(RMSE),mean absolute error(MAE)and correlation coefficient(R)were used to evaluate the prediction performance of the five ML models.The results demonstrated that the BPNN shows a better prediction performance than the other models with RMSE,MAE and R values on the testing dataset of 15.4 MPa,11.03 MPa and 0.9921,respectively.The results indicated that the ML techniques are effective for accurately predicting the triaxial compressive strength of rocks after different high-temperature treatments.展开更多
Corrosion is a primary cause of the slippage of friction⁃type high⁃strength bolted(FHSB)T⁃stub connections.This paper attempts to quantify the residual capacity of FHSB T⁃stub connections with corroded nuts.Firstly,co...Corrosion is a primary cause of the slippage of friction⁃type high⁃strength bolted(FHSB)T⁃stub connections.This paper attempts to quantify the residual capacity of FHSB T⁃stub connections with corroded nuts.Firstly,corrosion simulation tests were conducted on 48 manually cut nuts to find out the relationship between the damage degree of nut section and the residual clamping force(RCF)of bolt.Then,static load tests were carried out on 24 FHSB T⁃stub connections with nuts of different degrees of damage to obtain the failure modes.By finite⁃element(FE)models,a comparative analysis was performed on the initial friction load(IFL)and ultimate strength(US)of each connection with corroded nuts.Finally,the parameters of 96 FE models for FHSB T⁃stub connections were analyzed and used to derive the calculation formulas for the degree of damage for each nut and the IFL and US of each connection.The results show that the RCF decay of a bolt is a quadratic function of the equivalent radius loss ratio and the shear failure after nut corrosion;the IFL of each connection had a clear linear correlation with the RCF of the corresponding bolts,and the correlation depends on the applied load and static friction on connecting plate interface induced by the clamping force;the static friction had little impact on the US of the connection;the proposed IFL and US formulas can effectively derive the residual anti⁃slip capacity of FHSB T⁃stub connections from the degree of damage of the corroded nut section.The research results provide a scientific basis for the replacement and maintenance of corroded bolts of FHSB T⁃stub connections.展开更多
High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-p...High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-proof alloy design.This article concludes the factors influencing the ignition resistance of Mg alloys from oxide film and substrate microstructure,and also the mechanisms of alloying elements improving the ignition resistance.The low strength is another reason restricting the development of Mg alloys.Therefore,at the last section,Mg alloys with the combination of high strength and good ignition-proof performance are summarized,including Mg-Al-Ca based alloys,SEN(Mg-Al-Zn-Ca-Y)alloys as well as Mg-Y and Mg-Gd based alloys.Besides,the shortages and the future focus of theses alloys are also reviewed.The aim of this article is to promote the understanding of oxidation and ignition mechanisms of Mg alloys and to provide reference for the development of Mg alloys with high strength and excellent ignition-proof performance at the same time.展开更多
The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high ...The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.展开更多
Layered rock mass is a type of engineering rock mass with sound mechanical anisotropy,which is generally unfavorable to the stability of underground works.To investigate the strength anisotropy of layered rock,the Moh...Layered rock mass is a type of engineering rock mass with sound mechanical anisotropy,which is generally unfavorable to the stability of underground works.To investigate the strength anisotropy of layered rock,the Mohr-Coulomb and Hoek-Brown criteria are introduced to establish the two transverse isotropic strength criteria based on Jaeger's single weak plane theory and maximum axial strain theory,and parameter determination methods.Furthermore,the sensitivity of strength parameters(K 1,K 2,and K 3)that are used to characterize the anisotropy strength of non-sliding failure involved in the strength criteria and confining pressure are investigated.The results demonstrate that strength parameters K 1 and K 2 affect the strength of layered rock samples at all bedding angles except for the bedding angle of 90°and the angle range that can cause the shear sliding failure along the bedding plane.The strength of samples at any bedding angle decreases with increasing K 1,whereas the opposite is for K 2.Except for bedding angles of 0°and 90°and the bedding angle range that can cause the shear sliding along the bedding plane,K 3 has an impact on the strength of rock samples with other bedding angles that the specimens'strength increases with increase of K 3.In addition,the strength of the rock sample increases as confining pressure rises.Furthermore,the uniaxial and triaxial tests of chlorite schist samples were carried out to verify and evaluate the strength criteria proposed in the paper.It shows that the predicted strength is in good agreement with the experimental results.To test the applicability of the strength criterion,the strength data of several types of rock in the literature are compared.Finally,a comparison is made between the fitting effects of the two strength criteria and other available criteria for layered rocks.展开更多
基金Financial support for this work was provided by the General Program and Youth Fund Program of the National Natural Science Foundation of China(Grant Nos.42377175 and 42002292).
文摘Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational.
基金Project(U2202255)supported by the National Natural Science Foundation of ChinaProject(2024JJ2076)supported by the Hunan Provincial Natural Science Foundation of ChinaProject(2023Z092)supported by the Key Technology Research Program of Ningbo,China。
文摘In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and properties of the alloy were investigated in detail.The results showed that the samples deformed by the combination of cryogenic equal channel angular pressing(ECAP)and rolling had good comprehensive properties after aging at 400℃.The tensile strength of the peak-aged and over-aged samples was 1120 MPa and 940 MPa,with their corresponding electrical conductivity of 14.7%IACS and 22.1%IACS,respectively.ECAP and cryogenic rolling introduced high density dislocations,leading to the inhibition of the softening effects and refinement of the grains.After a long time aging at 400℃,the alloy exhibited ultra-high strength with obvious increasing electrical conductivity.The high strength was attributed to the synergistic effect of work hardening,grain refinement strengthening and precipitation strengthening.The precipitation of a large amount of Ti atoms from the matrix led to the high electrical conductivity of the over-aged sample.
基金Funded by the National Key Research and Development Program of China(No.2021YFB2601200)the Natural Science Foundations of Hebei Province(No.E2022210103)。
文摘To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted.
文摘Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic stirring,end electromagnetic stirring,casting speed and soft reduction)for the smelting of high-strength antisulfur pipes.The microstructures of continuous-casting billets and hot-rolled or tempered pipes were analyzed using a metallographic microscope and scanning electron microscope.The mechanism and evolution law regarding the inner-wall band segregation of high-strength antisulfur pipes were studied,and the influence of different casting processes was explored.
文摘The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed.
基金This work was supported by Natural Science Foundation of China(Grant No.52278333)the Fundamental Research Funds for the Central Universities(Grant No.N2101021)The work is under the framework of the 111 Project(Grant No.B17009)and Sino-Franco Joint Research Laboratory on Multiphysics and Multiscale Rock Mechanics.
文摘The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted to studying the anisotropic strength,deformation and failure behavior of gneiss granite from the deep boreholes of a railway tunnel that suffers from high tectonic stress and ground temperature in the eastern tectonic knot in the Tibet Plateau.High-temperature true triaxial compression tests are performed on the samples using a self-developed testing device with five different loading directions and three temperature values that are representative of the geological conditions of the deep underground tunnels in the region.Effect of temperature and loading direction on the strength,elastic modulus,Poisson’s ratio,and failure mode are analyzed.The method for quantitative identification of anisotropic failure is also proposed.The anisotropic mechanical behaviors of the gneiss granite are very sensitive to the changes in loading direction and temperature under true triaxial compression,and the high temperature seems to weaken the inherent anisotropy and stress-induced deformation anisotropy.The strength and deformation show obvious thermal degradation at 200℃due to the weakening of friction between failure surfaces and the transition of the failure pattern in rock grains.In the range of 25℃ 200℃,the failure is mainly governed by the loading direction due to the inherent anisotropy.This study is helpful to the in-depth understanding of the thermal-mechanical behavior of anisotropic rocks in deep underground projects.
文摘With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are designed to meet the requirements of high strength and high toughness of spring flat steel,through the test,the product surface quality and internal quality all meet the national standards,the performance indicators to meet user requirements.
基金supported by the National Natural Science Foundation of China(No.52274359)Guangdong Basic and Applied Basic Research Foundation,China(No.2022A1515110406)+3 种基金Beijing Natural Science Foundation,China(No.2212035)the Fundamental Research Funds for the Central Universities,China(Nos.FRF-TP-19005C1Z and 00007718)the Aeroengine Group University Research Cooperation Project,China(No.HFZL2021CXY021)the State Key Lab of Advanced Metals and Materials,University of Science and Technology Beijing,China(Nos.2021Z-03 and 2022Z-14).
文摘Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying alloys.In this study,Ti–6.5Al–2Zr–Mo–V(TA15)titanium alloy plates were prepared by cold press-ing sintering combined with high-temperature hot rolling.The microstructure and mechanical properties under different process paramet-ers were investigated.Optical microscope,electron backscatter diffraction,and others were applied to characterize the microstructure evolution and mechanical properties strengthening mechanism.The results showed that the chemical compositions were uniformly dif-fused without segregation during sintering,and the closing of the matrix craters was accelerated by increasing the sintering temperature.The block was hot rolled at 1200℃ with an 80%reduction under only two passes without annealing.The strength and elongation of the plate at 20–25℃ after solution and aging were 1247 MPa and 14.0%,respectively,which were increased by 24.5%and 40.0%,respect-ively,compared with the as-sintered alloy at 1300℃.The microstructure was significantly refined by continuous dynamic recrystalliza-tion,which was completed by the rotation and dislocation absorption of the substructure surrounded by low-angle grain boundaries.After hot rolling combined with heat treatment,the strength and plasticity of PM-TA15 were significantly improved,which resulted from the dense,uniform,and fine recrystallization structure and the synergistic effect of multiple slip systems.
基金supported by the National Research Foundation, Prime Minister’s Office, Singapore, under its Competitive Research Programme (CRP award number NRF-CRP22-2019-008)Medium-Sized Centre Programme (CA2DM)+1 种基金the Ministry of Education of Singapore, under its Research Centre of Excellence award to the Institute for Functional Intelligent Materials (I-FIM, Project No. EDUNC-33-18-279-V12)by the EDB Singapore, under its Space Technology Development Programme (S2219013-STDP)。
文摘Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass loadings crucial for practical use.The root of these challenges lies in the mechanical instability of the material,which subsequently leads to the structural failure of the electrode.Here,we present a novel synthesis of a composite combining expanded graphite and silicon nanoparticles.This composite features a unique interlayer-bonded graphite structure,achieved through the application of a modified spark plasma sintering method.Notably,this innovative structure not only facilitates efficient ion and electron transport but also provides exceptional mechanical strength(Vickers hardness:up to658 MPa,Young's modulus:11.6 GPa).This strength effectively accommodates silicon expansion,resulting in an impressive areal capacity of 2.9 mA h cm^(-2)(736 mA h g^(-1)) and a steady cycle life(93% after 100cycles).Such outsta nding performance is paired with features appropriate for large-scale industrial production of silicon batteries,such as active mass loading of at least 3.9 mg cm^(-2),a high-tap density electrode material of 1.68 g cm^(-3)(secondary clusters:1.12 g cm^(-3)),and a production yield of up to 1 kg per day.
基金the support of the instrument and equipment fund of the Key Laboratory of Special Energy,Ministry of Education,Nanjing University of Science and Technology,China.
文摘The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing fillers.The interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW materials.Compared to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded steel.And 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of propellants.Despite the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic activity.This strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.
基金supported by the National Natural Science Foundation of China(Nos.52071093 and 51871069)the Key Laboratory of Micro-Systems and Micro-Structures Manufacturing(HIT)+2 种基金Ministry of Education(No.2020 KM009)the Student Research and Innovation Fund of the Fundamental Research Funds for the Central Universities(No.3072022GIP1004)the Science and Technology Innovation Major Project of Ningbo City,China(No.2019B10103).
文摘Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial AZ31 alloy in extrudability,but also have superior mechanical properties,especially in terms of yield strength(YS).The excellent extrudability is related to less coarse second-phase particles and high initial melting point of the two as-cast alloys.The high strength-ductility mainly comes from the formation of fine grains,nano-spaced submicron/nano precipitates,and weak texture.Moreover,it is worth noting that the YS of the two alloys can maintain above 160 MPa at elevated temperature of 250°C,significantly higher than that of AZ31 alloy(YS:45 MPa).The Zn/Ca solute segregation at grain boundaries,the improved heat resistance of matrix due to addition of RE,and the high melting points of strengthening particles(Mn,MgZn_(2),and Mg-Zn-RE/Mg-Zn-RE-Ca)are mainly responsible for the excellent high-temperature strength.
基金Financial support comes from China National Natural Science Foundation(Grant No.51974352)as well as from China University of Petroleum(East China)(Grant Nos.2018000025 and 2019000011)。
文摘In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.
基金supported by National Natural Science Foundation of China (No. 51971076 and No. 51771062)。
文摘Mg-1.0Al-1.0Ca-0.4Mn(AXM1104, wt.%) low alloy was extruded at 200 ℃ with an extrusion ratio of 25 and different ram speeds from 1.0 to 7.0 mm/s. The influence of extrusion rate on microstructure and mechanical properties of the AXM1104 alloy was systematically studied. With the increasing of extrusion rate, the mean dynamically recrystallized(DRXed) grain size of the low alloy and average particles diameter of precipitate second phases were increased, while the degree of grain boundary segregation and the intensity of the basal fiber texture were decreased. With the rising of extrusion rate from 1.0 to 7.0 mm/s, the tensile yield strength(TYS) of the as-extruded AXM1104 alloy was decreased from 445 MPa to 249 MPa, while the elongation to failure(EL) was increased from 5.0% to 17.6%. The TYS, ultimate tensile strength(UTS) and EL of the AXM1104 alloy extruded at the ram speed of 1.5 mm/s was 412 MPa, 419 MPa and 12.0%, respectively,exhibiting comprehensive tensile mechanical properties with ultra-high strength and excellent plasticity. The ultra-high TYS of 412 MPa was mainly due to the strengthening from ultra-fine DRXed grains with segregation of solute atoms at grain boundaries. The strain hardening rate is increase slightly with increasing extrusion speed, which may be ascribed to the increasing mean DRXed grain size with rising extrusion speed. The higher strain hardening rate contributes to the higher EL of these AXM1104 samples extruded at higher ram speed.
基金Part by a Grant from Sona College of TechnologySalem。
文摘The present work investigates copper slag as a substitute for river sand in high-strength concrete.The concrete mixtures were manufactured with 10%,30%,50%,70%,and 100%of copper slag to evaluate the mechanical and durability properties.The experimental results indicate that replacing copper slag above 50%affects the performance characteristics of the concrete due to its high angularity and lower water absorption characteristics.The strength of concrete with 50%copper slag is improved by 5.6%,whereas the strength of concrete with 100%copper slag is reduced by 2.75%at 28 days.However,increased curing to 90days improves the strength of the former by 7.16%and reduces the latter by only 0.23%.The water absorption,porosity,and rapid chloride penetration of the concrete mixtures with 100%copper slag are increased by 10.44%,13.20%,and 19.56%compared to control concrete.Micro-structural investigations through SEM infer higher replacement of copper results in higher void formation due to its reduced water absorption.
文摘The ongoing effort to create methods for detecting and quantifying fatigue damage is motivated by the high levels of uncertainty in present fatigue-life prediction approaches and the frequently catastrophic nature of fatigue failure.The fatigue life of high strength aluminum alloy 2090-T83 is predicted in this study using a variety of artificial intelligence and machine learning techniques for constant amplitude and negative stress ratios(R?1).Artificial neural networks(ANN),adaptive neuro-fuzzy inference systems(ANFIS),support-vector machines(SVM),a random forest model(RF),and an extreme-gradient tree-boosting model(XGB)are trained using numerical and experimental input data obtained from fatigue tests based on a relatively low number of stress measurements.In particular,the coefficients of the traditional force law formula are found using relevant numerical methods.It is shown that,in comparison to traditional approaches,the neural network and neuro-fuzzy models produce better results,with the neural network models trained using the boosting iterations technique providing the best performances.Building strong models from weak models,XGB helps to predict fatigue life by reducing model partiality and variation in supervised learning.Fuzzy neural models can be used to predict the fatigue life of alloys more accurately than neural networks and traditional methods.
基金We acknowledge the funding support from the National Natural Science Foundation of China(Grant No.51778575)Postdoctoral Science Foundation of China(Grant No.2021M692481)Fundamental Research Funds for the Central Universities of China(Grant No.2042021kf0055).The authors would like to thank the anonymous reviewers and editors for their constructive suggestions which greatly improve the quality of this paper.The authors are also grateful for the permission from Elsevier.
文摘The accurate prediction of the strength of rocks after high-temperature treatment is important for the safety maintenance of rock in deep underground engineering.Five machine learning(ML)techniques were adopted in this study,i.e.back propagation neural network(BPNN),AdaBoost-based classification and regression tree(AdaBoost-CART),support vector machine(SVM),K-nearest neighbor(KNN),and radial basis function neural network(RBFNN).A total of 351 data points with seven input parameters(i.e.diameter and height of specimen,density,temperature,confining pressure,crack damage stress and elastic modulus)and one output parameter(triaxial compressive strength)were utilized.The root mean square error(RMSE),mean absolute error(MAE)and correlation coefficient(R)were used to evaluate the prediction performance of the five ML models.The results demonstrated that the BPNN shows a better prediction performance than the other models with RMSE,MAE and R values on the testing dataset of 15.4 MPa,11.03 MPa and 0.9921,respectively.The results indicated that the ML techniques are effective for accurately predicting the triaxial compressive strength of rocks after different high-temperature treatments.
文摘Corrosion is a primary cause of the slippage of friction⁃type high⁃strength bolted(FHSB)T⁃stub connections.This paper attempts to quantify the residual capacity of FHSB T⁃stub connections with corroded nuts.Firstly,corrosion simulation tests were conducted on 48 manually cut nuts to find out the relationship between the damage degree of nut section and the residual clamping force(RCF)of bolt.Then,static load tests were carried out on 24 FHSB T⁃stub connections with nuts of different degrees of damage to obtain the failure modes.By finite⁃element(FE)models,a comparative analysis was performed on the initial friction load(IFL)and ultimate strength(US)of each connection with corroded nuts.Finally,the parameters of 96 FE models for FHSB T⁃stub connections were analyzed and used to derive the calculation formulas for the degree of damage for each nut and the IFL and US of each connection.The results show that the RCF decay of a bolt is a quadratic function of the equivalent radius loss ratio and the shear failure after nut corrosion;the IFL of each connection had a clear linear correlation with the RCF of the corresponding bolts,and the correlation depends on the applied load and static friction on connecting plate interface induced by the clamping force;the static friction had little impact on the US of the connection;the proposed IFL and US formulas can effectively derive the residual anti⁃slip capacity of FHSB T⁃stub connections from the degree of damage of the corroded nut section.The research results provide a scientific basis for the replacement and maintenance of corroded bolts of FHSB T⁃stub connections.
基金the financial supports from the National Key Research and Development Plan(Grant No.2021YFB3701100)the National Natural Science Foundation of China(Grant No.U2241231,No.52071206)。
文摘High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-proof alloy design.This article concludes the factors influencing the ignition resistance of Mg alloys from oxide film and substrate microstructure,and also the mechanisms of alloying elements improving the ignition resistance.The low strength is another reason restricting the development of Mg alloys.Therefore,at the last section,Mg alloys with the combination of high strength and good ignition-proof performance are summarized,including Mg-Al-Ca based alloys,SEN(Mg-Al-Zn-Ca-Y)alloys as well as Mg-Y and Mg-Gd based alloys.Besides,the shortages and the future focus of theses alloys are also reviewed.The aim of this article is to promote the understanding of oxidation and ignition mechanisms of Mg alloys and to provide reference for the development of Mg alloys with high strength and excellent ignition-proof performance at the same time.
基金The authors gratefully acknowledge financial support from the National Natural Science Foundation of China(52103090)the Natural Science Foundation of Guangdong Province(2022A1515011780)Autonomous deployment project of China National Key Laboratory of Materials for Integrated Circuits(NKLJC-Z2023-B03).
文摘The remarkable properties of carbon nanotubes(CNTs)have led to promising applications in the field of electromagnetic inter-ference(EMI)shielding.However,for macroscopic CNT assemblies,such as CNT film,achieving high electrical and mechanical properties remains challenging,which heavily depends on the tube-tube interac-tions of CNTs.Herein,we develop a novel strategy based on metal-organic decomposition(MOD)to fabricate a flexible silver-carbon nanotube(Ag-CNT)film.The Ag particles are introduced in situ into the CNT film through annealing of MOD,leading to enhanced tube-tube interactions.As a result,the electrical conductivity of Ag-CNT film is up to 6.82×10^(5) S m^(-1),and the EMI shielding effectiveness of Ag-CNT film with a thickness of~7.8μm exceeds 66 dB in the ultra-broad frequency range(3-40 GHz).The tensile strength and Young’s modulus of Ag-CNT film increase from 30.09±3.14 to 76.06±6.20 MPa(~253%)and from 1.12±0.33 to 8.90±0.97 GPa(~795%),respectively.Moreover,the Ag-CNT film exhibits excellent near-field shield-ing performance,which can effectively block wireless transmission.This innovative approach provides an effective route to further apply macroscopic CNT assemblies to future portable and wearable electronic devices.
基金the financial support from the National Natural Science Foundation of China(Grant No.51979008)the National Natural Science Foundation of China(Grant No.51779018)the Innovation team of Changjiang River Scientific Research Institute(Grant No.CKSF2021715/YT).
文摘Layered rock mass is a type of engineering rock mass with sound mechanical anisotropy,which is generally unfavorable to the stability of underground works.To investigate the strength anisotropy of layered rock,the Mohr-Coulomb and Hoek-Brown criteria are introduced to establish the two transverse isotropic strength criteria based on Jaeger's single weak plane theory and maximum axial strain theory,and parameter determination methods.Furthermore,the sensitivity of strength parameters(K 1,K 2,and K 3)that are used to characterize the anisotropy strength of non-sliding failure involved in the strength criteria and confining pressure are investigated.The results demonstrate that strength parameters K 1 and K 2 affect the strength of layered rock samples at all bedding angles except for the bedding angle of 90°and the angle range that can cause the shear sliding failure along the bedding plane.The strength of samples at any bedding angle decreases with increasing K 1,whereas the opposite is for K 2.Except for bedding angles of 0°and 90°and the bedding angle range that can cause the shear sliding along the bedding plane,K 3 has an impact on the strength of rock samples with other bedding angles that the specimens'strength increases with increase of K 3.In addition,the strength of the rock sample increases as confining pressure rises.Furthermore,the uniaxial and triaxial tests of chlorite schist samples were carried out to verify and evaluate the strength criteria proposed in the paper.It shows that the predicted strength is in good agreement with the experimental results.To test the applicability of the strength criterion,the strength data of several types of rock in the literature are compared.Finally,a comparison is made between the fitting effects of the two strength criteria and other available criteria for layered rocks.