Microstructure control and hot cracking behavior of the new Ni-Co based superalloy prepared by electron beam smelting layered solidification technology

The prevention of hot cracking formation is of utmost importance in the production of the new Ni-Co based superalloys through the utilization of the electron beam smelting layered solidification technique(EBSL),as it ensures exceptional homogeneity and dependable consistency of the specimens.In contrast to previous studies that focused on minimizing the liquid film and solidification range,our methodology adopts a distinct approach.In this research,a novel methodology was employed to mitigate internal stresses through the implementation of equiaxed grain layers via an alternately reduced cooling method.This ultimately resulted in the elimination of hot cracking.To be more specific,the transition from a columnar to an equiaxed structure was observed during the layer-by-layer construction process in the fabrication of the new Ni-Co based superalloy in EBSL.The EBSL-Ni-Co superalloy,when subjected to the alternating reduction cooling method,exhibited an internal stress of 49 MPa.This value represents a significant reduction of 83.8%compared to the internal stress observed when employing the linear reduction cooling method.Additionally,the solvus temperature of theγ-γ’eutectic phases in EBSL-Ni-Co superalloys produced by the alternating reduction cooling method is significantly higher.Intriguingly,the Nth layer of the EBSL-Ni-Co based superalloys produced by EBSL simultaneously heats treated with the preceding layers.And the low melting point phase gradually dissolved back into the matrix.The implementation of an alternating reduced cooling method successfully mitigated the formation of the liquid film in theγ-γ’eutectic phase and the buildup of internal stresses in the EBSL-Ni-Co superalloy during its manufacturing process.These discoveries open up a novel preparation procedure pathway for the manufacture of crack-free superalloys with superior mechanical characteristics using EBSL.

Hot cracking susceptibility of AlSi7MgCu alloys and effects of alloying elements magnesium and copper

Hot cracking during solidification can be a serious problem in aluminium casting alloys under certain conditions.This feature is well known,but still insuffi ciently investigated in shape casting.This study gives a brief overview of the factors inf luencing hot cracking during shape casting.Five different AlSi7MgCu alloys with varying Mg and Cu contents were examined.Theoretical models,including the cracking susceptibility coeffi cient(CSC)from Clyne and Davies,were considered.Thermodynamic calculations(terminal freezing range,TFR)of the behavior of the solid fraction during solidif ication were compared to an experimentbased hot cracking indexing(HCI)method.Scanning electron microscopy(SEM)was used to compare the existing microstructure and precipitated thermodynamic phases using the software ThermoCalc Classic(TCC).Furthermore,SEM was used to investigate crack surfaces initiated by a dog-bone shaped mold during casting.A good correlation between theoretical models and the experimental hot cracking index method was observed.

Hot cracking susceptibility research in BTW1 austenitic high-manganese wear-resistant steel

Baosteel’s first BTW1 austenitic high-manganese wear-resistant steel exhibits strong deformation-induced hardening characteristics.Compared with common low-alloy martensitic wear-resistant steels in the market, it has improved impact wear resistance, hard abrasive wear, erosion wear performance, and impact toughness.The metallurgical properties of such austenitic wear-resistant steel lead to the risk of failure because of hot cracking defects in the welded structure.In wear-resistant applications, evaluating hot cracking susceptibility is necessary to avoid the effect of welding defects.In this study, the Varestraint test is used to quantitatively analyze and evaluate the hot cracking susceptibility of BTW1 austenitic high-manganese wear-resistant steel.The test results show that by controlling the content of impurity elements and grain refinement, BTW1 austenitic high-manganese wear-resistant steel effectively reduces hot cracking tendency and has a low incidence of hot cracking under small strain conditions.The developed matching welding process can effectively avoid the influence of hot cracking susceptibility.

Hot cracking tendency test and simulation of 7075 semi-solid aluminium alloy

The hot cracking tendency of 7075 semi-solid alloy under different conditions was studied by critical diameter method.The experiment and simulation results show that the dendrite arms of the rod grow from the edge to the center.The smaller the diameter of the rod is,the more obvious the directional growth of dendrite is,and the greater the tendency of hot cracking is.Compared with ordinary melt,for semi-solid slurry,increasing mould temperature or decreasing pouring temperature can significantly decrease hot cracking tendency of 7075 alloy,decreasing hot cracking grade from 256 to 100 mm^2.Furthermore,based on the RDG criterion,the effects of solidification conditions on the hot cracking tendency were discussed combined with simulation.At the same time,the application and development of RDG criterion were also researched.

Effect of Rare Earths on Hot Cracking Resistant Property of Mg-Al Alloys

The effect of rare earths （RE） ranging from 0.1% to 1.2%（mass fraction） on hot cracking resistant property of Mg-Al alloys was investigated. The results show that hot cracking resistant property of Mg-Al alloys remarkably declines with an increase of RE addition. The causes of the decline are as follows： First, grain coarsening of Mg-Al alloys caused by RE addition reduces the fracture strain required for hot crack initiation. Second, RE reduces the eutectic microstructure of Mg- Al alloys, and as a result, shortens the time that the feeding channel remains open, making it difficult to feed the alloy. Furthermore, RE elevates the eutectic reaction temperature, which leads to the decrease in the strength of the interdendritic liquid film at the late stage of solidification. Third, when a-Mg dendrites form continuous skeletons, the interdendritic Al11 RE3 phase tends to block the feeding channels and increases the difficulty of feeding. Last, the shrinkage ratio discrepancy between Al11RE3 phases and α-Mg matrix is prone to cause shrinkage stress and promote hot crack initiation.

Susceptibility to Hot Cracking and Weldment Heat Treatment of Haynes 230 Superalloy

This study investigates the susceptibility of hot cracking and weldment heat treatment of Haynes 230 superalloy. The Varestriant test was conducted to evaluate this susceptibility. Welding was performed by gas tungsten arc welding （GTAW） and plasma arc welding （PAW） with stress relief heat treatment and solid solution heat treatment. A tensile test is then performed to measure the changes in the mechanical properties of the heattreated material. The results indicate that the number of thermal cycles does not affect the susceptibility of Haynes 230 superalloy to hot cracking. However, it does increase the strain. In weldment of heat treatment, stress relief annealing increases the yield strength and tensile strength of the welded parts. The section of the tensile specimens shows fibrous fractures on the welded parts, regardless of whether they are heat-treated.

A new method--the inverse strain method(ISM)for preventing welding hot cracking of high strength aluminium alloy LY12CZ

In this paper a new method for preventing welding hot cracking—the inverse strain method(ISM)is developed on the principle of welding mechan- ics.Effectiveness and feasiblity of method in preventing welding hot cracking of high strength aluminum alloy LY12CZ by synchronous rolling during welding (SRDW)along both sides of the weld at a suitable distance behind the welding arc are examined.Experimental resulte indicate that welding hot cracking of LY12CY can be effectively prevented and the mechanical properties of welded joint can also be improved by the method.It is an important new solution for preventing hot cracking in welding of sheet metal.

Solidification behaviour and hot cracking susceptibility of a novel Ni-based superalloy

A novel Ni-based superalloy GH4151,with a γ′ volume fraction of about 55%and a service temperature capability up to 8oo oC,was investigated.Due to the different cooling conditions of various regions during the solidification of ingots,significant cooling rate variations may lead to the occurrence of hot cracking.Conventional scanning laser microscope was utilised to investigate the solidification process and phase precipitation behaviour of the GH4151 under wide range cooling rates.The characteristics of L→γ transformation were analysed,and the growth rates of at each stage were calculated.The segregation behaviour was predicted using the Scheil equation,and the predicted results match well with the experimental results.The sensitivity coefficient for hot cracking was modified,and cracking sensitivity coefficient values for the alloy under different cooling rates were computed,revealing that the alloy is most susceptible to hot cracking at 10℃/min cooling rate.Therefore,controlling the cooling rate can reduce the possibility of hot cracking in ingot.

A Hot Cracking Initiation Criterion Based on Solidification Liquid Film Characteristic and Microstructure

Herein,a hot cracking initiation criterion based on the characteristics of solidification liquid film and the microstructure was proposed,which integrated both the mechanical and non-mechanical factors during solidification.The criterion also took the effect of the shrinkage volume of the solid-liquid two-phase in the mushy zone,the flow behavior of the liquid film and the microstructure on the feeding behavior into account.Meanwhile,the effect factors of hot cracking initiation such as alloy composition,microstructure,mold design and process condition were included in this criterion,and it could quantitatively calculate whether hot cracks occurred under a certain state or not during solidification.The criterion was utilized to predict whether hot cracks occurred in Al-4.0 wt%Cu alloy in different initial solidification states or not,which was consistent with the experimental results and verified its reliability.According to the criterion expression,Vfeeding*was related with five effect factors includingη,ΔP*,l*,r*and n,in which r*and n were in positive correlation with Vfeeding*whileη,ΔP*and l*were in negative correlation with that,which provided a good instructive significance for mold design,process optimization and composition and microstructure regulation of alloys and simultaneously further enriched the mechanism and influencing factors of hot cracking initiation.Furthermore,a multiscale simulation method for calculating the characteristic parameters of hot tearing behavior during solidification was also provided in this study.

Infuence of Liquid Film Characteristics on Hot Cracking Initiation in Al–Cu Alloys at the End of Solidifcation

In this study,Al–4Cu alloy specimens with spherical grains and liquid flms were obtained by isothermal reheating treatment.The hot cracking of the solidifcation process was determined using a modifed constrained rod casting experimental apparatus,and the efect of liquid flm characteristics at the end of solidifcation on hot cracking initiation of Al–4Cu alloys was systematically investigated by combining molecular dynamics simulations and other methods.With the extension of soaking time,the liquid fraction(liquid flm fraction at the end of solidifcation)and grain shape factor increased with higher isothermal reheating temperatures.Additionally,the widened flling channel decreased the hot cracking initiation temperature and the critical hot cracking shrinkage stress was found to increase,thus reducing the hot cracking severity in Al–4Cu alloys.Molecular dynamics simulations revealed that with the extension of soaking time,the composition of the liquid flm changed at diferent isothermal reheating temperatures,but the short-range structure and atomic ordering of the liquid flm remained the same.The activity of the liquid flm increased in equilibrium,leading to a decrease in viscosity and an increase in fuidity,which contributed to the flling behaviour.After isothermal reheating at 640℃for 60 min,the liquid fraction reached the maximum,and the viscosity of the liquid flm was the minimum.In addition,almost no hot cracks were found.

Spreading Behavior and Hot Cracking Mechanism of Single Tracks in High Strength Al–Cu–Mg–Mn Alloy Fabricated by Laser Powder Bed Fusion

Laser powder bed fusion(LPBF)technology is a high-precision metal additive manufacturing(AM)technology.Due to the high specific strength of high strength aluminum alloys,high strength aluminum alloys fabricated by LPBF have broad application prospects in the field of light weighting.However,high strength aluminum alloys have high hot cracking susceptibility.In this study,an analysis of the hot cracking susceptibility as a function of processing parameters is presented for single tracks of LPBF processed(LPBFed)high strength Al–Cu–Mg–Mn alloy.The hot cracking in single tracks of LPBFed Al–Cu–Mg–Mn alloy is solidification cracking based on the experimental observations of microstructure.Combining Rosenthal simulations and spreading behavior of a single droplet,the critical scanning speed of single track with balling phenomenon was obtained.It was found that when the laser power was 200 W,the scanning speed exceeded 440.1 mm/s,the droplet will not be able to spread completely,which is consistent with the experimental result of 500 mm/s.Through the calculation and analysis of the microstructure and the existence time of the molten pool,it was pointed out that the reduction in the liquid phase caused by the high scanning speed,the shortening of the solidification time and the high stress caused by the high-temperature gradient promoted the generation of hot cracking.In summary,this work contains a practical guide to optimize processing parameters of LPBFed Al–Cu–Mg–Mn alloys,which provides a basis for fabricating thin walls and cubic samples without hot cracking.

Hot cracking behavior of large size GH4742 superalloy vacuum induction melting ingot

The developing of large size superalloy vacuum induction melting(VIM)ingots is limited owing to hot cracking,The hot cracking behavior of the large size GH4742 superalloy VIM ingot was investigated via experiment and simulation.The microstructure was examined by optical microscopy,and element segregation was investigated by electron probe microanalysis.The solidification temperature range and yield strength at high temperature(YSHT)were calculated by JMatPro software.The results show that the variations of microstructure and element segregation in different locations are caused by different cooling rates.Moreover,the larger secondary dendrite arm spacing and serious element segregation of Nb accelerate hot cracking of the VIM ingot.In addition,the solidification temperature range is wider,and YSHT is lower in center than at edge of the ingot.Therefore,the hot cracking susceptibility is the highest in the center of the GH4742 superalloy VIM ingot.The critical criterion of element segregation for hot cracking is that the partition coeffcient of Nb should be larger than 0.5.

Design and application of a multichannel"cross"hot tearing tendency device:A study on hot tearing tendency of Al alloys

Hot tearing is one of the most serious defects during the casting solidification process.In this study,a new type of multichannel"cross"hot tearing device was designed.The hot cracks initiation and propagation were predicted by the relationship between temperature,shrinkage force and solidification time during the casting solidification process.The reliability and practicability of the multichannel"cross"hot tearing device were verified by casting experiments and numerical simulations.The theoretical calculation based on Clyne-Davies model and numerical simulation results show that the hot tearing tendency decreases in the order:2024 Al alloy>Al-Cu alloy>Al-Si alloy at a pouring temperature of 670°C and a mold temperature of 25°C.Feeding of liquid films at the end of solidification plays an important role in the propagation process of hot tearing.The decrease of hot tearing tendency is attributed to the feeding of liquid film and intergranular bridging.

Impact of Rare Earth Element La on Microstructure and Hot Crack Resistance of ADC12 Alloy

The impact of rare earth element La on the microstructure and hot crack resistance of ADC12 alloy was analyzed. The additive amount of La was 0%, 0.3 wt%, 0.6 wt% and 0.9 wt%, respectively. The results showed that, with the increase of the additive amount from 0% to 0.6 wt%, the grain shape of α-Al gradually varied from developed dendritic crystal into fine dendritic crystal, equiaxed crystal and spheroidal crystal; eutectic silicon varied from needle-like or tabular shape into fine rod like shape; the hot crack force of the alloy also gradually decreased. However, when the additive amount of La reached 0.9 wt%, the excessive amount of rare earth elements was segregated within grain boundary area, forming intermetallic compounds. Therefore, the grain size of α-Al, eutectic silicon and the hot crack force of the alloy all increased. In the case that the additive amount of La reached 0.6 wt%, the best metamorphism effect and most excellent hot cracking resistance capacity of alloy were presented. The poisoning effect of rare earth element on eutectic silicon and the constitutional supercooling caused by rare earth element were the major causes for alloy modification, alloy refinement, and the main reasons for the increased hot cracking resistance.

Controlling of weld hot cracks of aluminum alloy sheets by transverse pre-stressing

A new ideological and theoretical model—a technology to control weld hot cracks by transverse compressive pre-stress in the welding of aluminum alloy was put forward,which was further proved by the subsequent self-designed test setup.Experiments are conducted on the fishbone shaped specimen under conventional welding and welding with various pre-stress values.The experimental results turn out that,the initiation rate of the weld hot cracks decreases with increasing values of the compressive pre-stress.When the pre-stress reaches 0.3-0.4 of the yield stress,the cracks even disappear.In mechanical viewpoint,the researches here develop a new way to control weld cracks.

Mechanism of biaxial pre-stress method on welding residual stress and hot cracks controlling

Based on the conventional uniaxial pre-tensile stress method during welding, this study presents a new method of welding with biaxial pre-stress. With the help of numerical simulation, experiments were carried out on the self-designed device. Except for the control on residual stress and distortion us-welded, the experimental results also show its effect on the prevention of hot cracks, thus this method can make up for the disadvantage of the conventional pre-stress method. Hot cracks disappear when the value of pre-stress surpasses 0. 2 σs（yield limit）. Welded thin plates with low-level residual stress, little distortion and no hot cracks are obtained with longitudinal pre-tensile stress level between 0. 6σsand 0. 7σs and precompressive stress between 0. 2 σs and 0. 3 σs in transverse direction.

Study on Hot Deformation Cracks of Steel D2 Using Processing Map

The hot deformation behaviors of steel D2 in the range of 900 ℃ to 1 160 ℃ and strain rate range of 0.01 s -1 to 10 s -1 have been studied by using Processing Map developed on the basis of dynamic materials model. The efficiency of energy dissipation η is taken as a function of temperature and strain rate to obtain a Processing Map. In the Processing Map of steel D2, there are two zones of cracking susceptivity with high dissipation efficiency η of 46 % and 63 % respectively. One zone is in the range of 900 ℃ to 980 ℃ and the strain rate range of 0.01 s -1 to 0.06 s -1 , and the other from 1 140 ℃ to 1 160 ℃ and 8 s -1 to 10 s -1 . The experiment proves that there are microstructural brittle transgranular fractures and macroscopic thermal cracks in the two zones respectively. The map also revealed that deformation in these two zones is of instable flowing , so these two zones should be avoided when choosing hot deformation conditions.

Comparative study of extrudability, microstructure, and mechanical properties of AZ80 and BA53 alloys

The extrudability,microstructural characteristics,and tensile properties of the Mg–5Bi–3Al(BA53)alloy are investigated herein by comparing them with those of a commercial Mg–8Al–0.5 Zn(AZ80)alloy.When AZ80 is extruded at 400℃,severe hot cracking occurs at exit speeds of 4.5 m/min or more.In contrast,BA53 is successfully extruded without any surface cracking at 400℃ and at high exit speeds of 21–40 m/min.When extruded at 3 m/min(AZ80–3)and 40 m/min(BA53–40),both AZ80 and BA53 exhibited completely recrystallized microstructures with a<10–10>basal texture.However,BA53–40 has a coarser grain structure owing to grain growth promoted by the high temperature in the deformation zone.AZ80–3 contains a continuous network of Mg_(17)Al_(12) particles along the grain boundaries,which form via static precipitation during natural air-cooling after the material exits the extrusion die.BA53–40 contains coarse Mg_(3)Bi_(2) particles aligned parallel to the extrusion direction along with numerous uniformly distributed fine Mg_(3)Bi_(2) particles.AZ80–3 has higher tensile strength than BA53–40 because the relatively finer grains and larger number of solute atoms in AZ80–3 result in stronger grain-boundary and solid-solution hardening effects,respectively.Although BA53 is extruded at a high temperature and extrusion speed of 400℃ and 40 m/min,respectively,the extruded material has a high tensile yield strength of 188 MPa.This can be primarily attributed to the large particle hardening effect resulting from the numerous fine Mg_(3)Bi_(2) particles.

Effects of the Process Parameters on Austenitic Stainless Steel by TIG-Flux Welding

The effects of the process parameters of TIG （tungsten inset gas）-flux welding on the welds morphology, angular distortion, ferrite content and hot cracking in austenitic stainless steel were investigated. Autogenous TIG welding process was applied to the type 304 stainless steel through a thin layer of activating flux to produce a bead on plate welded joint. TiO2, SiO2, Fe2O3, Cr2O3, ZnO and MnO2 were used as the activating fluxes. The experimental results indicated that the TIG-flux welding can increase the weld depth/width ratio and reduce the HAZ （heat affected zone） range, and therefore the angular distortion of the weldment can be reduced. It was also found that the retained ferrite content within the TIG-flux welds is increased, and has a beneficial effect in reducing hot cracking tendency for stainless steels of the austenitic type weld metals. A plasma column constriction increases the current density at the anode spot and then a substantial increase in penetration of the TIG-flux welds can be obtained.

Transverse stress-strain evolution during welding of thin aluminum alloy plate

The FE simulation results of transverse stresses and strains during welding of thin aluminum alloy plate are presented. The results indicate that restraint condition is the main factor that determines whether or not hot cracking will occur. With rigid restraint hot cracking (crater cracking) will occur at the arc-stopping end, and such cracking usually will not occur without external restraint. But under restraint-free condition it is easy for terminal cracks to occur.