Gypsum was used as substrate,and silica gel was mixed into substrate at a certain mass ratio to prepare humidity-controlling composites;moreover,the moisture absorption and desorption properties of gypsum-based compos...Gypsum was used as substrate,and silica gel was mixed into substrate at a certain mass ratio to prepare humidity-controlling composites;moreover,the moisture absorption and desorption properties of gypsum-based composites were compared with adding different silica gel particle size and proportion.The morphological characteristics,the isothermal equilibrium moisture content curve,moisture absorption and desorption rate,moisture absorption and desorption stability,and humidity-conditioning performance were tested and analyzed.The experimental results show that,compared with pure-gypsum,the surface structure of the gypsum-based composites is relatively loose,the quantity,density and aperture of the pores in the structure increase.The absorption and desorption capacity increase along with the increase of silica gel particle size and silica gel proportion.When 3 mm silica gel particle size is added with a mass ratio of 40%,the maximum equilibrium moisture content of humidity-controlling composites is 0.161 g/g at 98% relative humidity(RH),3.22 times that of pure-gypsum.The moisture absorption and desorption rates are increased,the equilibrium moisture absorption and desorption rates are 2.68 times and 1.61 times that of pure-gypsum at 58.5% RH,respectively.The gypsum-based composites have a good stability,which has better timely response to dynamic humidity changes and can effectively regulate indoor humidity under natural conditions.展开更多
This study aims to quantify the susceptibility of granular materials used in pavements to changes in moisture content and propose a correlation model to incorporate this susceptibility into seasonal analyses.The fines...This study aims to quantify the susceptibility of granular materials used in pavements to changes in moisture content and propose a correlation model to incorporate this susceptibility into seasonal analyses.The fines content and the percentage of fractured coarse aggregates were identified as direct indicators of the resilient modulus susceptibility to changes in water content.The results showed that the percentage of fractured coarse aggregates particles(FR)has a more significant impact on the resilient modulus(Er)of crushed granular materials used in pavement construction than the combined indicator of the fines content and sample volumetrics(nf).Crushed granular materials with a higher percentage of fractured coarse aggregates are relatively insensitive to changes in the degree of saturation,but become more sensitive as the fine fraction porosity decreases.An adjusted model was proposed based on the existing formulation,but considers a complex parameter to describe and adjust the sensitivity of base granular materials to variations in moisture content with respect to fabrication charac-teristics,fines content and volumetric properties.The model shows that the variation of Er values is below10%for fully crushed granular materials.However,it reaches approximately±12%for materials with 75%of crushed coarse aggregates andþ40%and-25%for materials with FR=50%.This model could help select good ag-gregates characteristics and adjust grain-size distribution for environments where significant moisture content variations can occur in the pavement system,such as in the Province of Quebec(Canada).As it is based on pa-rameters that can be easily determined or estimated,it also represents a valuable tool for detailed design and analysis that can consider material characteristics.展开更多
Human metabolite moisture detection is important in health monitoring and non-invasive diagnosis.However,ultra-sensitive quantitative extraction of respiration information in real-time remains a great challenge.Herein...Human metabolite moisture detection is important in health monitoring and non-invasive diagnosis.However,ultra-sensitive quantitative extraction of respiration information in real-time remains a great challenge.Herein,chemiresistors based on imine-linked covalent organic framework(COF)films with dual-active sites are fabricated to address this issue,which demonstrates an amplified humidity-sensing signal performance.By regulation of monomers and functional groups,these COF films can be pre-engineered to achieve high response,wide detection range,fast response,and recovery time.Under the condition of relative humidity ranging from 13 to 98%,the COFTAPB-DHTA film-based humidity sensor exhibits outstanding humidity sensing perfor-mance with an expanded response value of 390 times.Furthermore,the response values of the COF film-based sensor are highly linear to the relative humidity in the range below 60%,reflecting a quantitative sensing mechanism at the molecular level.Based on the dual-site adsorption of the(-C=N-)and(C-N)stretching vibrations,the revers-ible tautomerism induced by hydrogen bonding with water molecules is demonstrated to be the main intrinsic mechanism for this effective humidity detection.In addition,the synthesized COF films can be further exploited to effectively detect human nasal and oral breathing as well as fabric permeability,which will inspire novel designs for effective humidity-detection devices.展开更多
Flexible and wearable humidity sensors play a vital role in daily point-of-care diagnosis and noncontact human-machine interactions.However,achieving a facile and high-speed fabrication approach to realizing flexible ...Flexible and wearable humidity sensors play a vital role in daily point-of-care diagnosis and noncontact human-machine interactions.However,achieving a facile and high-speed fabrication approach to realizing flexible humidity sensors remains a challenge.In this work,a wearable capacitive-type Ga_(2)O_(3)/liquid metal-based humidity sensor is demonstrated by a one-step laser direct writing technique.Owing to the photothermal effect of laser,the Ga_(2)O_(3)-wrapped liquid metal particles can be selectively sintered and converted from insulative to conductive traces with a resistivity of 0.19Ω·cm,while the untreated regions serve as active sensing layers in response to moisture changes.Under 95%relative humidity,the humidity sensor displays a highly stable performance along with rapid response and recover time.Utilizing these superior properties,the Ga_(2)O_(3)/liquid metal-based humidity sensor is able to monitor human respiration rate,as well as skin moisture of the palm under different physiological states for healthcare monitoring.展开更多
The environment significantly impacts the interaction between plants and pathogens,thus remarkably affecting crop disease occurrence.However,the detailed combined mechanisms of temperature and humidity influencing thi...The environment significantly impacts the interaction between plants and pathogens,thus remarkably affecting crop disease occurrence.However,the detailed combined mechanisms of temperature and humidity influencing this interaction remain unclear.In this study,the interaction between tomato and Botrytis cinerea in various temperature and humidity conditions was analyzed by histological observation and a dual RNA-seq approach.Results showed that low humidity was not favorable for mycelial growth,resulting in infection failure.Both high and low temperatures at high humidity successfully inhibited pathogenic infection and disease incidence in the tomato plants,thus enhancing their resistance to B.cinerea.The high temperature and high humidity(HH)treatment induced the upregulation of light reaction genes,increased the net photosynthetic rate,and expanded the chloroplast morphology of infected tomatoes.The HH treatment also inhibited the expression of cell cycle-related genes of B.cinerea,interfered with conidial germination andmycelial growth,and damagedmycelial cell structure.Lowtemperature and high humidity(LH)treatment induced the expression of cell wall modification genes and remodeled the cell wall morphology of tomatoes in response to B.cinerea.In addition,the downregulated fungal catabolic genes and the abnormal increase in electron density ofmycelial cells under LH treatment subsequently reduced the infection ability of B.cinerea.These results further explain the coupled effects of temperature and humidity on plant defenses and pathogen virulence,and provide a potential means to control gray mold.展开更多
Soil quality determination and estimation is an important issue not only for terrestrial ecosystems but also for sustainable management of soils.In this study,soil quality was determined by linear and nonlinear standa...Soil quality determination and estimation is an important issue not only for terrestrial ecosystems but also for sustainable management of soils.In this study,soil quality was determined by linear and nonlinear standard scoring function methods integrated with a neutrosophic fuzzy analytic hierarchy process in the micro catchment.In addition,soil quality values were estimated using a support vector machine(SVM)in machine learning algorithms.In order to generate spatial distribution maps of soil quality indice values,different interpolation methods were evaluated to detect the most suitable semivariogram model.While the soil quality index values obtained by the linear method were determined between 0.458-0.717,the soil quality index with the nonlinear method showed variability at the levels of 0.433-0.651.There was no statistical difference between the two methods,and they were determined to be similar.In the estimation of soil quality with SVM,the normalized root means square error(NRMSE)values obtained in the linear and nonlinear method estimation were determined as 0.057 and 0.047,respectively.The spherical model of simple kriging was determined as the interpolation method with the lowest RMSE value in the actual and predicted values of the linear method while,in the nonlinear method,the lowest error in the distribution maps was determined with exponential of the simple kriging.展开更多
Humidity can affect the attenuation of MEA(membrane electrode assembly), however, the relationship between humidity and MEA decays is complex and ambiguous in realistic application. Herein, we design a simulating auto...Humidity can affect the attenuation of MEA(membrane electrode assembly), however, the relationship between humidity and MEA decays is complex and ambiguous in realistic application. Herein, we design a simulating automotive protocol, performed on five single fuel cells under RH(relative humidity) 100%,RH 80%, RH 64%, and RH 40%, RH 10%, respectively, to study the relationship of MEA decays and humidity and suggest optimized humidity range to extend the durability. With the electrochemical impedance spectroscopy, cyclic voltammetry, X-ray fluorescence, X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, the four degradation mechanisms about catalyst layer, including Pt dissolution, Pt coarsening, carbon corrosion and ionomer degradation, are observed. Pt coarsening and carbon corrosion are accelerated by higher water content at high humidity. Ionomer degradation and Pt dissolution are enhanced in low humidity. With the linear sweep voltammetry, ion chromatography,nuclear magnetic resonance, tensile test and scan electron microscope, chemical and mechanical degradation in proton exchange membrane are all observed in these five fuels. Chemical degradation, characterized by membrane thinning and more fluoride loss, occurred markedly in RH 10%. Mechanical degradation, characterized by the non-uniformity thickness and bad mechanical properties, is more pronounced in RH 100%, RH 80%, RH 64%. These two degradations are in a moderate level in RH 40%. The research suggests that the RH range from 64% to 40% is conductive to mitigate the degradation of MEAs operated in automotive applications.展开更多
Breathing is an inherent human activity;however,the composition of the air we inhale and gas exhale remains unknown to us.To address this,wearable vapor sensors can help people monitor air composition in real time to ...Breathing is an inherent human activity;however,the composition of the air we inhale and gas exhale remains unknown to us.To address this,wearable vapor sensors can help people monitor air composition in real time to avoid underlying risks,and for the early detection and treatment of diseases for home healthcare.Hydrogels with three-dimensional polymer networks and large amounts of water molecules are naturally flexible and stretchable.Functionalized hydrogels are intrinsically conductive,self-healing,self-adhesive,biocompatible,and room-temperature sensitive.Compared with traditional rigid vapor sensors,hydrogel-based gas and humidity sensors can directly fit human skin or clothing,and are more suitable for real-time monitoring of personal health and safety.In this review,current studies on hydrogel-based vapor sensors are investigated.The required properties and optimization methods of wearable hydrogel-based sensors are introduced.Subsequently,existing reports on the response mechanisms of hydrogel-based gas and humidity sensors are summarized.Related works on hydrogel-based vapor sensors for their application in personal health and safety monitoring are presented.Moreover,the potential of hydrogels in the field of vapor sensing is elucidated.Finally,the current research status,challenges,and future trends of hydrogel gas/humidity sensing are discussed.展开更多
基金Funded by the National Natural Science Foundation of China(No.51678254)。
文摘Gypsum was used as substrate,and silica gel was mixed into substrate at a certain mass ratio to prepare humidity-controlling composites;moreover,the moisture absorption and desorption properties of gypsum-based composites were compared with adding different silica gel particle size and proportion.The morphological characteristics,the isothermal equilibrium moisture content curve,moisture absorption and desorption rate,moisture absorption and desorption stability,and humidity-conditioning performance were tested and analyzed.The experimental results show that,compared with pure-gypsum,the surface structure of the gypsum-based composites is relatively loose,the quantity,density and aperture of the pores in the structure increase.The absorption and desorption capacity increase along with the increase of silica gel particle size and silica gel proportion.When 3 mm silica gel particle size is added with a mass ratio of 40%,the maximum equilibrium moisture content of humidity-controlling composites is 0.161 g/g at 98% relative humidity(RH),3.22 times that of pure-gypsum.The moisture absorption and desorption rates are increased,the equilibrium moisture absorption and desorption rates are 2.68 times and 1.61 times that of pure-gypsum at 58.5% RH,respectively.The gypsum-based composites have a good stability,which has better timely response to dynamic humidity changes and can effectively regulate indoor humidity under natural conditions.
文摘This study aims to quantify the susceptibility of granular materials used in pavements to changes in moisture content and propose a correlation model to incorporate this susceptibility into seasonal analyses.The fines content and the percentage of fractured coarse aggregates were identified as direct indicators of the resilient modulus susceptibility to changes in water content.The results showed that the percentage of fractured coarse aggregates particles(FR)has a more significant impact on the resilient modulus(Er)of crushed granular materials used in pavement construction than the combined indicator of the fines content and sample volumetrics(nf).Crushed granular materials with a higher percentage of fractured coarse aggregates are relatively insensitive to changes in the degree of saturation,but become more sensitive as the fine fraction porosity decreases.An adjusted model was proposed based on the existing formulation,but considers a complex parameter to describe and adjust the sensitivity of base granular materials to variations in moisture content with respect to fabrication charac-teristics,fines content and volumetric properties.The model shows that the variation of Er values is below10%for fully crushed granular materials.However,it reaches approximately±12%for materials with 75%of crushed coarse aggregates andþ40%and-25%for materials with FR=50%.This model could help select good ag-gregates characteristics and adjust grain-size distribution for environments where significant moisture content variations can occur in the pavement system,such as in the Province of Quebec(Canada).As it is based on pa-rameters that can be easily determined or estimated,it also represents a valuable tool for detailed design and analysis that can consider material characteristics.
基金supported by the National Key Research and Development Program of China(2022YFB3205500,and 2022YFC3104700)the National Natural Science Foundation of China(62101329 and 61971284)+4 种基金the Shanghai Sailing Program(21YF1421400)the Natural Science Foundation of Shanghai(23ZR1430100)the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University(SL2020ZD203,SL2021MS006 and SL2020MS031)Scientific Research Fund of Second Institute of Oceanography,Ministry of Natural Resources of P.R.China(SL2003)Startup Fund for Youngman Research at Shanghai Jiao Tong University.
文摘Human metabolite moisture detection is important in health monitoring and non-invasive diagnosis.However,ultra-sensitive quantitative extraction of respiration information in real-time remains a great challenge.Herein,chemiresistors based on imine-linked covalent organic framework(COF)films with dual-active sites are fabricated to address this issue,which demonstrates an amplified humidity-sensing signal performance.By regulation of monomers and functional groups,these COF films can be pre-engineered to achieve high response,wide detection range,fast response,and recovery time.Under the condition of relative humidity ranging from 13 to 98%,the COFTAPB-DHTA film-based humidity sensor exhibits outstanding humidity sensing perfor-mance with an expanded response value of 390 times.Furthermore,the response values of the COF film-based sensor are highly linear to the relative humidity in the range below 60%,reflecting a quantitative sensing mechanism at the molecular level.Based on the dual-site adsorption of the(-C=N-)and(C-N)stretching vibrations,the revers-ible tautomerism induced by hydrogen bonding with water molecules is demonstrated to be the main intrinsic mechanism for this effective humidity detection.In addition,the synthesized COF films can be further exploited to effectively detect human nasal and oral breathing as well as fabric permeability,which will inspire novel designs for effective humidity-detection devices.
基金This study was supported by the National Natural Science Foundation of China (52105593 and 62271439)STI 2030 —Major Projects(2022ZD0208601)the “Pioneer” and “Leading Goose” R&D Program of Zhejiang (2023C01051)。
文摘Flexible and wearable humidity sensors play a vital role in daily point-of-care diagnosis and noncontact human-machine interactions.However,achieving a facile and high-speed fabrication approach to realizing flexible humidity sensors remains a challenge.In this work,a wearable capacitive-type Ga_(2)O_(3)/liquid metal-based humidity sensor is demonstrated by a one-step laser direct writing technique.Owing to the photothermal effect of laser,the Ga_(2)O_(3)-wrapped liquid metal particles can be selectively sintered and converted from insulative to conductive traces with a resistivity of 0.19Ω·cm,while the untreated regions serve as active sensing layers in response to moisture changes.Under 95%relative humidity,the humidity sensor displays a highly stable performance along with rapid response and recover time.Utilizing these superior properties,the Ga_(2)O_(3)/liquid metal-based humidity sensor is able to monitor human respiration rate,as well as skin moisture of the palm under different physiological states for healthcare monitoring.
基金the National Key Research and Development Program of China[grant number 2022YFF0801303]the National Natural Science Foundation of China[grant numbers 41991284 and 42075021].
基金supported by the National Key Research and Development Program of China(No.2019YFD1002004).
文摘The environment significantly impacts the interaction between plants and pathogens,thus remarkably affecting crop disease occurrence.However,the detailed combined mechanisms of temperature and humidity influencing this interaction remain unclear.In this study,the interaction between tomato and Botrytis cinerea in various temperature and humidity conditions was analyzed by histological observation and a dual RNA-seq approach.Results showed that low humidity was not favorable for mycelial growth,resulting in infection failure.Both high and low temperatures at high humidity successfully inhibited pathogenic infection and disease incidence in the tomato plants,thus enhancing their resistance to B.cinerea.The high temperature and high humidity(HH)treatment induced the upregulation of light reaction genes,increased the net photosynthetic rate,and expanded the chloroplast morphology of infected tomatoes.The HH treatment also inhibited the expression of cell cycle-related genes of B.cinerea,interfered with conidial germination andmycelial growth,and damagedmycelial cell structure.Lowtemperature and high humidity(LH)treatment induced the expression of cell wall modification genes and remodeled the cell wall morphology of tomatoes in response to B.cinerea.In addition,the downregulated fungal catabolic genes and the abnormal increase in electron density ofmycelial cells under LH treatment subsequently reduced the infection ability of B.cinerea.These results further explain the coupled effects of temperature and humidity on plant defenses and pathogen virulence,and provide a potential means to control gray mold.
文摘Soil quality determination and estimation is an important issue not only for terrestrial ecosystems but also for sustainable management of soils.In this study,soil quality was determined by linear and nonlinear standard scoring function methods integrated with a neutrosophic fuzzy analytic hierarchy process in the micro catchment.In addition,soil quality values were estimated using a support vector machine(SVM)in machine learning algorithms.In order to generate spatial distribution maps of soil quality indice values,different interpolation methods were evaluated to detect the most suitable semivariogram model.While the soil quality index values obtained by the linear method were determined between 0.458-0.717,the soil quality index with the nonlinear method showed variability at the levels of 0.433-0.651.There was no statistical difference between the two methods,and they were determined to be similar.In the estimation of soil quality with SVM,the normalized root means square error(NRMSE)values obtained in the linear and nonlinear method estimation were determined as 0.057 and 0.047,respectively.The spherical model of simple kriging was determined as the interpolation method with the lowest RMSE value in the actual and predicted values of the linear method while,in the nonlinear method,the lowest error in the distribution maps was determined with exponential of the simple kriging.
基金supported by the National Key Research and Development Program of China (2018YFB1502502)the National Natural Science Foundation of China (22179127)。
文摘Humidity can affect the attenuation of MEA(membrane electrode assembly), however, the relationship between humidity and MEA decays is complex and ambiguous in realistic application. Herein, we design a simulating automotive protocol, performed on five single fuel cells under RH(relative humidity) 100%,RH 80%, RH 64%, and RH 40%, RH 10%, respectively, to study the relationship of MEA decays and humidity and suggest optimized humidity range to extend the durability. With the electrochemical impedance spectroscopy, cyclic voltammetry, X-ray fluorescence, X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, the four degradation mechanisms about catalyst layer, including Pt dissolution, Pt coarsening, carbon corrosion and ionomer degradation, are observed. Pt coarsening and carbon corrosion are accelerated by higher water content at high humidity. Ionomer degradation and Pt dissolution are enhanced in low humidity. With the linear sweep voltammetry, ion chromatography,nuclear magnetic resonance, tensile test and scan electron microscope, chemical and mechanical degradation in proton exchange membrane are all observed in these five fuels. Chemical degradation, characterized by membrane thinning and more fluoride loss, occurred markedly in RH 10%. Mechanical degradation, characterized by the non-uniformity thickness and bad mechanical properties, is more pronounced in RH 100%, RH 80%, RH 64%. These two degradations are in a moderate level in RH 40%. The research suggests that the RH range from 64% to 40% is conductive to mitigate the degradation of MEAs operated in automotive applications.
基金Jin Wu acknowledges financial support from the National Natural Science Foundation of China(No.61801525)the Guangdong Basic and Applied Basic Research Foundation(No.2020A1515010693)+1 种基金the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.22lgqb17)the Independent Fund of the State Key Laboratory of Optoelectronic Materials and Technologies(Sun Yat-sen University)under grant No.OEMT-2022-ZRC-05.
文摘Breathing is an inherent human activity;however,the composition of the air we inhale and gas exhale remains unknown to us.To address this,wearable vapor sensors can help people monitor air composition in real time to avoid underlying risks,and for the early detection and treatment of diseases for home healthcare.Hydrogels with three-dimensional polymer networks and large amounts of water molecules are naturally flexible and stretchable.Functionalized hydrogels are intrinsically conductive,self-healing,self-adhesive,biocompatible,and room-temperature sensitive.Compared with traditional rigid vapor sensors,hydrogel-based gas and humidity sensors can directly fit human skin or clothing,and are more suitable for real-time monitoring of personal health and safety.In this review,current studies on hydrogel-based vapor sensors are investigated.The required properties and optimization methods of wearable hydrogel-based sensors are introduced.Subsequently,existing reports on the response mechanisms of hydrogel-based gas and humidity sensors are summarized.Related works on hydrogel-based vapor sensors for their application in personal health and safety monitoring are presented.Moreover,the potential of hydrogels in the field of vapor sensing is elucidated.Finally,the current research status,challenges,and future trends of hydrogel gas/humidity sensing are discussed.