A Novel Three-stage Tectonic Model for Mississippi Valleytype Zn-Pb Deposits in Orogenic Fold-and-Thrust Belts

Mississippi Valley-type(MVT) Zn-Pb deposits predominantly form within both orogenic forelands and fold-andthrust belts, yet the mineralization process within the latter tectonic setting remains inadequately understood. This study, through a comprehensive review of MVT deposits across global fold-and-thrust belts, introduces a novel model elucidating the mineralization process in the context of tectonic belt evolution. It is demonstrated that during the stage Ⅰ, regional compression is introduced by early stages of plate convergence, causing the folding and thrusting and creating structural or lithological traps such as evaporite diapirs and unconformity-related carbonate dissolution-collapse structures. Thereafter, in stage Ⅱ, hydrocarbons begin to migrate and accumulate within these traps, where reduced sulfur is generated through thermochemical or bacterial sulfate reduction concurrent with or preceding Zn-Pb mineralization. In the subsequent stage Ⅲ, as plate convergence persists, the regional stress transitions from compression to transpression or extension. Under these conditions, steeply-dipping extensional faults are generated, facilitating the ascent of metalliferous brines into early-formed structural or lithological traps. Precipitation of Zn and Pb sulfides occurs through the mixing of Zn-Pb-transporting fluids with pre-existing reduced sulfur or by interaction with hydrocarbons.

Trace Elements in Sphalerite from the Dadongla Zn-Pb Deposit, Western Hunan-Eastern Guizhou Zn-Pb Metallogenic Belt, South China

The western Hunan-eastern Guizhou Zn-Pb metallogenic belt is one of the important Zn-Pb mineralization regions in China.The Dadongla deposit,located in the northeast of Guizhou Province,is one of the typical Zn-Pb deposits in the region and has estimated resources more than 12 million metric tons(Mt)with an average grade of 4.11 wt%Zn+Pb.Its orebodies are hosted in the lower Cambrian Aoxi Formation dolomite,occurring as bedded,para-bedded in shape,and in conformity with the wall rock.The ore mineral assemblage is simple,dominated by sphalerite with minor pyrite and galena,and the gangue minerals are composed of dolomite,calcite with minor bitumen and barite.In view of the lack of geological and geochemical researches,the genesis of Zn-Pb ore is still unclear.Laser ablation-inductively coupled plasma mass spectrometry(LA-ICPMS)spot and mapping analyses were used to obtain sphalerite trace element chemistry in the Dadongla Zn-Pb deposit in Guizhou,China,aiming to constrain its ore genesis.The results show that sphalerite is characterized by the enrichment of Cd,Fe,Ge and Hg,corresponding with that of typical MVT deposits.Four zones were identified in the sphalerite crystal from Dadongla from the center to margin according to the color bands.in which the zone in the center,representing the early ore-stage sphalerite,is characterized by enrichment of Cd relatively,while the zone forming at late ore-stage is enriched in Ge and Hg relatively.The finding was controlled by differential leached metals content in ore-forming fluid from its source rock.Notably,critical element Ge trends to be enriched at the late ore-stage and follows a substitution of 2 Zn^2+(?)Ge^4++□(vacancy).Moreover,the calculated ore-forming temperature ranges from 79.9℃to 177.6℃by the empirical formula,which is similar to that of typical Mississippi Valley-type(MVT)deposits.Compared with the features of trace elements in sphalerite from different types of deposits,together with the geology,the Dadongla deposit belongs to an MVT Zn-Pb deposit.

Metallogenic Regularities and Deposit Type of Rich(Ge-Ag)-Zn-Pb Deposits in the Sichuan-Yunnan-Guizhou Triangle(SYGT)Area,China

1 Introduction The well-known1 Sichuan-Yunnan-Guizhou Triangle(SYGT)area of poly-metallic Zn-Pb deposits,southwest China is located at the south-western margin of the Yangtze Block in the transition area of the Tethys Belt and the Circum-Pacific Metallogenic Belt,and is composed of the Northeastern Yunnan,Northwestern

Relationship Between Organic Matters and Zn-Pb Mineralization in the Giant Jinding Zn-Pb Deposit,SW China

The Jinding Zn-Pb deposit,Yunnan Province, southwestern China,represents the youngest,only continental sediment-hosted giant Zn-Pb deposit in the world.Various kinds of organic matters,such as the kerogen,light-and heavy-oil,hydrocarbon gas, bitumen of different occurrences and maturation,have been observed in recent underground and open pit mining.Oil-gas traces and oil-and methane-in-

Metallogenic Processes:Evidencesfrom Zoning Patterns of Mineralization and alteration and fluid inclusion geochemistryin the Lehong Zn-Pb Deposit in Northeastern Yunnan, China

1 Introduction The large clusters of Zn-Pb deposits in northeastern Yunnan,located in the southwestern margin of the Yangtze Block,are an important part of the Sichuan-YunnanGuizhou Pb-Zn Poly-metallic Metallogenic Triangle Area

Giant Mineral Deposits and Their Geodynamic Setting in the Lanping Basin, Yunnan, China

There are giant mineral deposits, including the Jinding Zn-Pb and Baiyangping Ag-Co-Cu, and otherimportant mineral deposits (e.g., Baiyangchang Ag-Cu, Jinman Cu deposits, etc.) in the Lanping Mesozoic-Cenozoic Basin, Yunnan Province, China. The tabular ore-bodies and some veins hosted in terrestrial clastic rocks of the Mesozoic-Cenozoic age and no outcropping of igneous rocks in the giant deposits lead to the proposal of syngenetic origin, but the giant mineral deposits are not stratabound (e.g. MVT, sandstone- and Sedex-type). They formed in a continental red basin with intense crust movement. The mineralization is controlled by structures and lithology and occurs in different strata, and no sedimentary nature and no exhalative sediments are identified in the deposits. The deposits show some relations with organic matter (now asphalt and petroleum) and evaporates (gypsum). The middle-low-temperature (mainly 110℃ to 280℃) mineralization took place at a depth of about 0.9 km to 3.1 km during the early Himalayan (58 to 67 Ma). The salinity of ore-forming fluids is surprisingly low (1.6% to 18.0 wt% (NaCl)eq). Affected by the collision of the Indian and Eurasian plates, the mantle is disturbed under the Lanping Basin. The large-scale mineralization is closely linked with the geodynamics of the crust movement, the mantle and mantle-flux upwelling and igneous activity. Giant mineral deposits and their geodynamic setting are unique in the Lanping Basin.

The mixing of multi-source fluids in the Wusihe Zn–Pb ore deposit in Sichuan Province, Southwestern China

The Sichuan-Yunnan-Guizhou(SYG)metallogenic province of southwest China is one of the most important Zn-Pb ore zones in China,with^200 Mt ZnPb ores at mean grades of 10 wt.%Zn and 5 wt.%Pb.The source and mechanism of the regional Zn-Pb mineralization remain controversial despite many investigations that have been conducted.The Wusihe Zn-Pb deposit is a representative large-scale Zn-Pb deposit in the northern SYG,which mainly occurs in the Dengying Formation and yields Zn-Pb resources of^3.7 Mt.In this paper,Zn and S isotopes,and Fe and Cd contents of sphalerite from the Wusihe deposit were investigated in an attempt to constrain the controls on Zn and S isotopic variations,the potential sources of ore-forming components,and the possible mineralization mechanisms.Both theδ66Zn andδ34S values in sphalerite from the Wusihe deposit increase systematically from the bottom to the top of the strata-bound orebodies.Such spatial evolution inδ66Zn andδ34S values of sphalerite can be attributed to isotopic Rayleigh fractionation during sphalerite precipitation with temperature variations.The strong correlations between the Zn-S isotopic compositions and Fe-Cd concentrations in sphalerite suggest that their variations were dominated by a similar mechanism.However,the Rayleigh fractionation mechanism cannot explain the spatial variations of Fe and Cd concentrations of sphalerite in this deposit.It is noted that the bottom and top sphalerites from the strata-bound orebodies document contrasting Zn and S isotopic compositions which correspond to the Zn and S isotopic characteristics of basement rocks and host rocks,respectively.Therefore,the mixing of two-source fluids with distinct Zn-S isotopic signatures was responsible for the spatial variations of Zn-S isotopic compositions of sphalerite from the Wusihe deposit.The fluids from basement rocks are characterized by relatively lighter Zn(~0.2‰)and S(~5‰)isotopic compositions while the fluids from host rocks are marked by relatively heavier Zn(~0.6‰)and S(~15‰)isotopic compositions.

Timing of the formation of the Baiyinnuo'er skarn Zn–Pb deposit,NE China:evidence from sulfide Rb–Sr dating

The Baiyinnuo’er deposit in northern China is located in the south section of the Great Xing’an Range,and it is the largest skarn Zn–Pb deposit in the region.Skarn and Zn–Pb orebodies mainly occur between the different units of the Permian Huanggangliang Formation,or within the contact zone between the intrusive rocks and the marble.Although Baiyinnuo’er has been well investigated previously,the timing of the Zn–Pb mineralization is still controversial,largely due to the lack of appropriate ore or alteration minerals that could be directly used for isotopic dating.In this study,we report the results of Rb–Sr isotopic analysis for sphalerite and pyrite samples from the Baiyinnuo’er orebodies,which yielded two isochron ages of 137.4±3.4 and 140.0±7.8 Ma,respectively,constraining the Zn–Pb mineralization time of the deposit as the Early Cretaceous.The data are also consistent with the age of the granitoids in the mining area,indicating a potential genetic relationship between the Early Cretaceous magmatism and mineralization.Many other intrusion-related hydrothermal deposits(including the two typical skarns,Huanggang and Haobugao)in the southern Great Xing’an Range also share similar mineralization ages(i.e.,140–130 Ma).Together,these data suggest an Early Cretaceous mineralization event in this region,and this largescale mineralization could be related to the regional tectonic regime transition from compression to extension as a result of the rollback of the subducted Paleo-Pacific plate.The initial87 Sr/86 Sr ratios of the sphalerite and pyrite samples are 0.70569 and 0.70616,respectively,implying that the ore-forming material could have a significant contribution from the mantle components.The current study shows that sulfide Rb–Sr dating could be used in deciphering the timing of skarn deposit formation.

青海虎头崖铅锌多金属矿床物化探综合找矿方法研究

虎头崖矿床位于青海省祁漫塔格地区东部,区内矿产丰富、矿种多样、组合复杂,找矿潜力巨大。本研究针对该区域高寒山区的特殊地质条件,聚焦解决隐伏有色金属矿产勘探难题,以期高效、准确地识别并定位高寒环境下隐伏矿体的空间分布。设计并实施了基于物化探综合找矿方法的试验研究,采用双频激电扫面技术,结合高频大地电磁测深方法,以获取深部地质结构的电性特征,有效区分矿化与非矿化异常。同时,结合原生晕和次生晕地球化学找矿手段,通过多元素地球化学异常分析,进一步预测矿化作用的空间分布。上述综合探测技术的应用,在青海虎头崖地区取得了较好的试验效果,圈定了潜在矿化带,探索了适用于高寒山区的隐伏有色金属矿产的找矿技术方法,该工作方法可为周边勘查区及高寒山区隐伏地层找矿工作提供借鉴。

青海祁漫塔格虎头崖铅锌矿床流体包裹体、同位素地球化学及矿床成因

青海虎头崖铅锌矿床位于东昆仑祁漫塔格地区西段,铅锌矿体受蓟县纪狼牙山组控制,矿体多呈层状、似层状产出,部分为透镜状、脉状,成矿分为2个阶段。金属硫化物电子探针分析表明,闪锌矿中Fe含量为2.255%~5.579%,贫Ga、Ge,Zn/Cd值为146~198,方铅矿中Ag含量为0.015%~0.038%,具有岩浆热液有关金属硫化物的特征。方解石内流体包裹体δD值为-92.7‰^-76‰,δ18OH2O值为-11.58‰^-2.27‰,多数位于大气降水范围,但部分位于大气降水和岩浆水之间,且早阶段成矿流体含有CO2、CH4、N2、H2等地幔流体或岩浆流体成分,表明早期成矿流体为岩浆热液,后期不断加入大气降水。早阶段成矿流体具中低温、高盐度、中等密度的特征,晚阶段随着大气降水的不断混入,盐度和密度显著降低。金属硫化物的δ34SV-CDT值为1.6‰~9.9‰,具有岩浆硫与围岩硫混合来源特征;金属硫化物的206Pb/204Pb值为18.533~18.580,207Pb/204Pb值为15.606~15.669,208Pb/204Pb值为38.344~38.522,主要来源于区内深源岩浆活动,有部分地壳铅的混染。综合分析认为,虎头崖铅锌矿床为与印支期岩浆作用有关的层控夕卡岩型铅锌矿床。

青海虎头崖铅锌矿床闪锌矿化学成分特征研究

青海虎头崖铅锌矿床是祁漫塔格成矿带矽卡岩型多金属矿的典型代表之一,该矿区岩浆活动强烈,具有Fe、Cu、Mo、Pb、Zn等多金属成矿元素组合.本文通过电子探针对该矿床中闪锌矿化学成分标型特征进行了详细研究,探讨其中Fe、Cd等元素的分布状态和富集规律.研究表明,矿床中闪锌矿可分为3个世代,从早到晚闪锌矿颜色由黑色逐渐变为浅黄色,矿物组合由闪锌矿-（方铅矿-黄铜矿）-黄铁矿-磁黄铁矿→闪锌矿-方铅矿-黄铜矿-黄铁矿-（磁黄铁矿）→闪锌矿-方铅矿-方解石或石英.早阶段形成的闪锌矿以富Fe贫Zn和Cd为特征,而晚阶段形成的闪锌矿相对贫Fe,富Zn和Cd.通过闪锌矿中的FeS含量估算获得成矿温度范围为148～262℃.随着成矿阶段的演化,3个世代闪锌矿中FeS含量逐渐降低,表明对应成矿温度的不断降低,分别为262～258、260～200、248～148℃.结合Zn/Cd含量比值变化范围,认为虎头崖铅锌矿床应属于中温热液矿床.在空间分布上,沿着热液流动方向,闪锌矿中Zn含量逐渐增加,Fe含量逐渐减少,Zn/Cd变化范围增大,指示矿床中热液流动方向为由北西西到南东东,由深部到浅部,与矿体走向一致.通过与国内其他不同类型铅锌矿床的对比,发现虎头崖铅锌矿床闪锌矿中Zn、Fe、Mn、Cd等化学成分具有典型中温矽卡岩型矿床中闪锌矿化学成分的特征,明显不同于层控型矿床、喷流沉积型矿床等其他类型矿床闪锌矿.结合该矿床地质特征和成矿作用过程,我们认为虎头崖铅锌矿床为矽卡岩型矿床.

东昆仑祁漫塔格虎头崖铅锌多金属矿成矿时代及其地质意义——黑云二长花岗岩地球化学特征和锆石U-Pb年龄证据

虎头崖铅锌多金属矿床位于东昆仑祁漫塔格地区,矿区内中酸性侵入岩体广泛发育,且与成矿关系密切。通过高精度LA-ICP-MS锆石微区原位U-Pb同位素测年,获得与矿化、矽卡岩化关系密切的黑云二长花岗岩锆石的^(206)Pb/^(238)U年龄加权平均值为234.2±1.5Ma。地球化学分析表明,黑云二长花岗岩具有高Al_2O_3、K_2O,低TiO_2、Na_2O的特征,稀土和微量元素显示其富集轻稀土元素、Rb、Th和部分高场强元素,Nb、Sr、Zr相对亏损,稀土元素表现为LREE/HREE明显分离的配分模式,总体表现为I型花岗岩的特征。在(Y+Nb)-Rb图解中落入后碰撞花岗岩区,在R1-R2因子判别图上落入造山晚期和同碰撞花岗岩重叠区,显示其可能形成于碰撞-后碰撞构造阶段。虎头崖铅锌多金属矿区Ⅵ矿带具有强烈的矽卡岩化,结合矿石组构、脉石矿物、围岩蚀变等特征,认为其具有矽卡岩型矿床的特征,形成于234.2±1.5Ma(中—晚三叠世)。

青海虎头崖—肯德可克矿区地球化学特征及其喷流成矿作用

虎头崖—肯德可克矿区地处柴达木南缘东昆仑祁漫塔格成矿带中,矿床产出的大地构造背景为晚古生代的弧后扩张盆地,矿床类型为Sedex型。对虎头崖—肯德可克矿区中的虎头崖铅锌矿、肯德可克多金属矿、北沟铁矿和景仁铜矿进行现场调查,并对具有代表性的火山岩及矿石进行岩矿鉴定、化学全分析、稀土、微量元素分析及全岩硫同位素分析。结果表明:矿区火山岩基本属于含钾高的亚碱性系列,总体表现为亲弧裂谷特征,火山喷发喷流成矿作用具有多旋回的特点;矿石稀土元素、微量元素分析说明热水喷流成矿作用的存在,与Sedex型喷流成矿特征和弧后伸展盆地大地构造环境相符合。虎头崖—肯德可克矿区具有如下成矿特点:以层控矿床为主,主要为海西期弧后盆地成矿;具有多个层位成矿、以多元素成矿为主、具有由深源到浅源的成岩成矿作用的演化特征。

祁漫塔格矿带虎头崖多金属矿矿床特征和成矿作用分析

虎头崖多金属矿是青海省祁漫塔格成矿带重要的多金属矿床之一,区域内矿产丰富,矿种多样,主要以铁、铜、铅、锌的多金属为主。本文结合前人研究成果和项目组对虎头崖多金属矿床的现场调查和室内多元信息的综合分析,从虎头崖矿区地层、地质构造、岩浆活动等方面探讨了该矿床的成矿地质条件;重点分析了该矿床的矿体形态产状特征、矿石组成,矿床成因、矿床特征,并分析了成矿作用的分期活动过程和成矿机制;通过综合分析,本文认为可从现有Ⅰ、Ⅱ矿带由北西向南东的侧列方向及平行F1、F2、F3等断裂带追索寻找深部隐伏盲矿体,并可根据物探异常找隐伏岩体,根据化探Cu、Pb、Zn组合异常找隐伏矿化破碎带,我们已探明虎头崖的金属矿产储量在原有基础上有了很大的提高,取得了重大找矿突破。

青海祁漫塔格虎头崖铅锌多金属矿区年代学研究及地质意义

虎头崖铅锌多金属矿是青海祁漫塔格地区较为典型的兼具正接触带矽卡岩亚型和外接触带矽卡岩亚型的接触交代型矿床。笔者对其开展了详细的地质特征解剖和高精度成岩成矿年代学研究,结果表明:矿区金属成矿元素组合复杂,矿化主要产于侵入体与围岩接触带、不同时代地层间的断裂带或不整合面及不同岩性界面,自成矿岩体内部向外具有明显的金属矿化与蚀变分带。利用锆石LA-ICP-MS和SHRIMP U-Pb法,获得成矿花岗闪长岩体和二长花岗岩体的成岩年龄分别为(235.4±1.8)Ma(n=24,MSWD=1.7)和(219.2±1.4)Ma(n=11,MSWD=0.83);利用辉钼矿Re-Os法,获得矽卡岩型铜钼多金属矿石和矽卡岩型钼矿石的等时线年龄分别为(225.0±4.0)Ma(n=7,MSWD=0.24)和(230.1±4.7)Ma(n=5,MSWD=0.12),厘定矿区成岩成矿时代为中—晚三叠世。综合青海祁漫塔格地区已有年代学资料和区域地质构造演化特征,认为该区印支期大规模岩浆侵入活动和多金属成矿作用形成于后碰撞构造阶段,为区域东昆仑造山带晚古生代—早中生代构造旋回的产物。

虎头崖铅锌多金属矿床矿体三维空间变化结构及分布规律

文章利用Vulcan和Datamine三维可视化软件建立了虎头崖铅锌多金属矿床矿体的三维实体模型、块体模型及地层三维实体模型;运用地质统计学方法分析了虎头崖矿区67线以东和117线以西矿体的Pb,Zn品位空间变化结构,得出搜索椭球体,实现了虎头崖铅锌多金属矿床矿体、地层形态和铅锌品位变化形态的空间分布展示;结合三维建模结果和铅锌矿体空间变化结构,总结出矿体空间分布规律,并用三维可视化软件对矿体分布规律进行显示,指导隐伏矿体的预测,寻找有利的找矿部位。

青海虎头崖铜铅锌多金属矿床硫、铅同位素组成及成因意义

青海虎头崖铜铅锌多金属矿是东昆仑祁漫塔格成矿带内多金属矿床的典型代表之一。本文对该矿床硫、铅同位素组成进行详细研究,探讨了成矿物质来源和矿床成因。结果表明,该矿床黄铜矿、方铅矿、闪锌矿、黄铁矿等硫化物的δ34S值变化于+0.6‰～+8.3‰,平均+4.4‰,反映成矿流体中的硫为海水硫酸盐的地层硫和深源岩浆硫的混合硫,而不同矿带硫同位素均值的差别,可能与围岩地层硫的差异及参与程度有关。矿石矿物铅同位素组成总体变化较小(206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.476～18.688、15.560～15.688和38.261～38.599),主要分布于造山带和上地壳铅演化线范围内,为岩浆作用导致的上地壳和地幔混合成因。由于赋矿层位及主控矿因素不同,各矿带的矿石铅同位素出现一定的差异。比如滩间山群内6号铜多金属矿点207Pb/204Pb值和产于岩体与缔敖苏组接触带上的Ⅱ矿带207Pb/204Pb值相比,后者的上地壳铅参与程度较高,进一步证明壳幔混合作用对本矿区的影响。该矿床为与岩浆侵入活动密切相关的矽卡岩型铜铅锌多金属矿床。

青海虎头崖矽卡岩型多金属矿床蚀变矿化分带特征研究

虎头崖铜铅锌多金属矿床位于东昆仑西段祁漫塔格成矿亚带内。矿化带产于岩体与围岩接触蚀变带、不同岩性地层接触界面或地层中断裂破碎带内,兼有正接触带和外接触带2种蚀变矿化带。由岩体→接触带→碳酸盐岩地层,金属成矿元素分别为W-Mo→Fe-Sn-Cu→Cu-(Pb-Zn)→Pb-Zn-Ag,蚀变类型由岩体自变质的钾化、硅化、云英岩化过渡为正接触带附近的符山石化、绿帘石化、透辉石化,再到外接触带围岩的石榴子石化、透辉石化,以及晚期的绿泥石化、碳酸盐化。主量元素分析结果显示,地层中的CaO等向岩浆岩内扩散,岩体中的SiO2、Al2O3等则向碳酸盐岩扩散,而且,与花岗岩相比,矽卡岩中FeO、MnO、MgO更为富集,这表明接触渗滤作用与接触交代作用同时存在。成矿元素分析结果显示,W、Mo元素在岩体内含量较高,而Fe、Cu、Pb、Zn主要在矽卡岩带内富集,各成矿元素在未蚀变大理岩中的含量均较低。笔者认为,矿化蚀变的明显分带性是岩体和地层成矿差异性及矽卡岩带内微裂隙系统发育的不均匀性所致。

青海祁漫塔格地区虎头崖矿床Ⅵ矿带花岗岩的成岩时代、地球化学特征和成因

利用LA-ICP-MS锆石U-Pb法,测得与成矿有关的青海祁漫塔格地区虎头崖矿床Ⅵ矿带花岗岩的成岩年龄为(233.6±1.8)Ma(MSWD=1.2,n=17)。地球化学特征显示:花岗岩属高钾钙碱性、弱过铝质花岗岩;样品的稀土元素组成以总体右倾,轻、重稀土分异明显和具明显的负铕异常为特征;微量元素具有富集Rb、Th、U、La、Nd等大离子亲石元素,亏损Ba、Sr、Nb、P、Ti等元素的特点。Sr-Nd同位素组成特征显示,花岗岩的源区可能是富集岩石圈地幔。初步研究认为,虎头崖矿床Ⅵ矿带花岗岩可能形成于中、晚三叠世碰撞-后碰撞的构造背景下。

虎头崖多金属矿床成矿物质来源及演化

虎头崖矿床是祁漫塔格成矿带中一个典型的铅锌多金属矿床。依据野外矿床地质调查和室内光薄片鉴定工作将该矿床划分为4个成矿期,7个成矿阶段。16件具代表性硫化物矿石单矿物硫、铅同位素测试显示,硫、铅同位素具有如下特征:δ(34S)变化范围为+0.6×10-3^+9.8×10-3,平均值为+5.2×10-3,从岩体边部至远离岩体处硫同位素含量呈逐渐增大趋势;铅同位素变化范围小,208Pb/204Pb为38.717~38.261,207Pb/204Pb为15.718~15.560,206Pb/204Pb为19.502~18.476。结合矿床地质特征和前人研究成果,分析硫、铅同位素特征,估算地幔、地壳中各组分,获得地幔、地壳中Pb组分分别为0.07~0.22、0.78~0.93,并推断矿床成矿物质来源为以地壳成分为主、含地幔成分的岩浆岩。成矿物质演化为在靠近岩体处S主要来源于岩体,远离岩体处地层物质含量逐渐增加,但主要为岩浆成分。