Fabrication of UV-Curing Linalool-Polysiloxane Hybrid Films with High Refractive Index and Transparency

In this article,a series of high refractive indices(1.50-1.53)thiol phenyl polysiloxane(TPS)were synthesized via hydrolytic sol-gel reaction.The Fourier transform infrared spectra(FT-IR)and nuclear magnetic resonance spectra(NMR)results showed that TPS conformed to the predicted structures.Natural terpene linalool was exploited as photocrosslinker to fabricate UV-curing linalool-polysiloxane hybrid films(LPH)with TPS via photoinitiated thiol-ene reaction.LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm^(2) in 30 s,exhibiting good UV-curing properties.The optical transmittance of LPH in the wavelength of 300-800 nm was over 90%,exhibiting good optical transparency.The water contact angle and water vapor permeability results showed that the introduction of phenyl groups enhance the hydrophobicity and water vapor barrier properties of LPH.The results indicated the potential of LPHs in the applications of optical functional coatings.

Detecting High-Refractive-Index Media Using Surface Plasmon Sensor with One-Dimensional Metal Diffraction Grating

We experimentally detect high-refractive-index media (n > 1.5) using a surface plasmon resonance (SPR) sensor with a diffraction grating. While SPR sensors are generally based on the attenuated total reflection method using metal films, here, we focus on a method using a diffraction grating, which can detect relatively higher refractive-index media and is suitable for device miniaturization. In this study, we used the rigorous coupled-wave analysis method to simulate the dependence of the reflectance on an incident angle for media with refractive index values up to 1.700. In the experiment, a medium (n = 1.660 - 1.700) was successfully detected using this grating. Under the conditions of the grating (period: 600 nm, Au thickness: 40 nm) using a red laser (λ: 635 nm), a sharp decline in the reflectance and a rise in the transmittance at certain angles were confirmed, demonstrating the extraordinary transmission enabled by SPR. Because excitation angles changed with changes in the refractive index, we concluded that this method can be applied to sensors that detect high-refractive-index media.

Hybrid Long-Period Fiber Grating with Multimode Fiber Core for Refractive Index Measurement

A refractive index （RI） sensor based on hybrid long-period fiber grating （LPFG） with multimode fiber core （MMFC） is proposed and demonstrated. The surrounding RI can be determined by monitoring the separation between the resonant wavelengths of the LPFG and MMFC since the resonant wavelengths of the LPFG and MMFC will shift in opposite directions when the surrounding RI changes. Experimental results show that the sensor possesses an enhanced sensitivity of 526.92nm/RIU in the RI range of 1.387-1.394 RIU. The response to the temperature is also discussed.

A hybrid algorithm for reengineering the refractive index profile of inhomogeneous coatings from optical in-situ broadband monitoring data

Reengineering the refractive index profile of inhomogeneous coatings is a troublesome task. Multiplicity of solutions may significantly reduced by providing additional information. For this reason an in-situ broadband monitoring system was developed to measure the transmittance of the growing film directly at the rotating substrate. For characterization of these coatings, a new model was developed, which significantly reduces the number of parameters. The refractive index profile may be described by a proper number of equally spaced volume fraction values using the Bruggeman effective media approach. A good initial approximation of the refractive index profile can be generated based on deposition rates for both materials recorded with quartz crystal monitor during manufacturing. During the optimization process, a second order minimization algorithm was used to vary the refractive index profile of the whole coating and film thickness of the intermediate stages. Finally, a significantly improved accuracy of the modelled transmittance was achieved.

Atmospheric Refractive Turbulence Effect on Diffraction-Limited Infrared Coherent Lidar

This paper, based on the Kavaya-Suni format, discusses the signal-to-noise ratio equation of the diffraction-limited coherent CO 2 lidar in detail, which is applied to atmospheric turbulence. The cumulative SNR and relative SNR, which are all affected by the nonlinear effects of the diffraction-limited Gaussian beam, atmospheric molecule and atmospheric turbulence, are simulated by microcomputer. Six instructions for the optimal design of IR CO 2 Coherent Lidar System, are provided.

A COMBINED REFRACTION-DIFFRACTION-DISSIPATION MODEL OF WAVE PROPAGATION

A numerical model based on the mild-slope equation of water wave propagation over complicated bathymetry,taking into account the combined effects of refraction,diffraction and dissipation due to wavebreaking is presented.Wave breaking is simulated by modifying the wave height probability density func-tion and the wave energy dissipation mechanism is parameterized according to that of the hydraulic jumpformulation.Solutions of the wave height,phase function,and the wave direction at every grid point areobtained by finite difference approximation of the governing equations,using Gauss-Seidel Iterative Method(GSIM)row by row.Its computational convenience allows it to be applied to large coast regions tostudy the wave transformation problem.Several case studies have been made and the results compare verywell with the experiment data and other model solutions.The capability and utility of the model forreal coast areas are illustrated by application to a shallow bay of northeast Australia.

Water Wave Refraction and Diffraction over Frictional Topography

This paper considers the effect of wave energy dissipation induced by sea-bottom friction on the computational results of water wave refraction and diffraction with the parabolic equation method. The presented results show that the friction factor formula adopted in this paper is of higher numerical accuracy than that introduced by Dalrymphe (1984), and it can be used to compute wave propagation over large open areas.

Numerical Modeling of Wave Diffraction-Refraction in Water of Varying Current and Topography

A numerical model for wave diffracrion-refraction in water of varying current and topography is proposed, and time-dependent wave mild-slope equation with a dissipation term and corresponding equivalent: governing equations are presented. Two different expressions of parabolic approximations for the case of the absence of current are also given and analyzed. The influence of current on the results of simulation of waves is discussed. Some examples show that the present model is better than others in simulating wave transformation in large water areas. And they also show that the influence of current should be taken into account, on numerical modeling of wave propagation in water of strong current and coastal areas, otherwise the modeling results will be largely distorted.

Mathematical Models for Combined Refraction-Diffraction of Waves on Non-Uniform Current and Depth

Two mathematical models for combined refraction-diffraction of regular and irregular waves on non-uniform current in water of slowly varying topography are presented in this paper. Model I is derived by wave theory and variational principle separately. It has two kinds of expressions including the dissipation term. Model n is based on the energy conservation equation with energy flux through the wave crest lines in orthogonal curvilinear coordinates and the wave kinematic conservation equation. The analysis and comparison and special cases of these two models are also given.

Numerical Simulation for Refraction-Diffraction of Waves in Water of Slowly Varying Current and Topography

A new numerical finite difference iteration method for refraction-diffraction of waves ia water of slowly varying current and topography is developed in this paper. And corresponding theoretical model including the dissipation term is briefly described, together with some analysis and comparison of computational results of the model with measurements in a hydraulic scale model (Berkhoff et al., 1982). An example of practical use of the method is given, showing that the present model is useful to engineering practice.

Sensitivity Analysis of a Bioinspired Refractive Index Based Gas Sensor

It was found out that the change of refractive index of ambient gas can lead to obvious change of the color of Morpho butterfly＇s wing. Such phenomenon has been employed as a sensing principle for detecting gas. In the present study, Rigorous Coupled-Wave Analysis （RCWA） was described briefly, and the partial derivative of optical reflection efficiency with respect to the refractive index of ambient gas, i.e., sensitivity of the sensor, was derived based on RCWA. A bioinspired grating model was constructed by mimicking the nanostructure on the ground scale of Morpho didius butterfly＇s wing. The analytical sensitivity was verified and the effect of the grating shape on the reflection spectra and its sensitivity were discussed. The results show that by tuning shape parameters of the grating, we can obtain desired reflection spectra and sensitivity, which can be applied to the design of the bioinspired refractive index based gas sensor.

Computation of Wave Refraction-Diffraction with Error Vector Propagation Method

After modifying the basic computation model made by Panchang (1988), the error vector propagation (EVP) method has been adopted to compute the combined effects of water wave refraction and diffraction in the presence of reflection boundary. The results show that the present method is successful in restraining the noise in Panchang's solution. Compared to other numerical methods for the mild-slope wave equation, EVP method can both consider the influence of reflection and save computer memory and computing time.

Combined refraction and diffraction models for sea waves over complicated topography and with currents in shallow water

-Combined refraction and diffraction models in the form of linear parabolic approximation are derived through smallparameter method. More strictly theoretical basis and more accuracy in the models than Lozano's (1980) are obtained. Some theoretical defects in Liu's model (1985) with consideration of current are not only found but also eliminated. More strict and accurate models are, therefore, presented in this paper.The calculation results and analysis in applying the models to actual wave field with consideration of bottom friction will be given in the following paper.

Wave Refraction-Diffraction in the Presence of a Current

-Wave refraction-diffraction due to a large ocean structure and topography in the presence of a 'current are studied numerically. The mathematical model is the mild-slope equation developed by Kirby (1984). This equation is solved using a finite and boundary element method. The physical domain is devid-ed into two regions: a slowly varying topography region and a constant water depth region. For waves propagating in the constant water depth region, without current interfering, the mild- slope equation is then reduced to the Helmholtz equation which is solved by boundary element method. In varying topography region, this equation will be solved by finite element method. Conservation of mass and energy flux of the fluid between these two regions is required for composition of these two numerical methods. The numerical scheme proposed here is capable of dealing with water wave problems of different water depths with the main characters of these two methods.

Refraction-Diffraction Mathematical Model for Waves With Lateral Energy Transmission Mechanism and Its Verification

To solve problems concerning wave elements and wave propagation, an effective way is the wave energy balance equation, which is widely applied in oceanography and ocean dynamics for its simple computation. The present papaer advances wave energy balance equations considering lateral energy transmission and energy loss as the governing equation for the study of wave refraction-diffraction. For the mathematical model, numerical simulation is made by means of difference method, and the result is verified with two examples.

Internal modification in transparent hybrid germanium-silica plates using plasma formation induced by a femtosecond laser

The fabrication of an internal diffraction grating with photoinduced refractive index modification in planar hybrid germanium-silica plates was demonstrated using low-density plasma formation excited by a high-intensity femtosecond (150 fs) Ti:sapphire laser (λp=790 nm).The refractive index modifications with diameters ranging from 400 nm to 3 μm were photoinduced after plasma formation occurred upon irradiation with peak intensities of more than 2×1013 W/cm2.The graded refractive index profile was fabricated to be a symmetric around from the center of the point at which low-density plasma occurred.

Principle of diffraction enhanced imaging (DEI) and computed tomography based on DEI method

In the first part of this article a more general DEI equation was derived using simple concepts. Not only does the new DEI equation explain all the problems that can be done by the DEI equation proposed by Chapman, but also explains the problem that can not be explained with the old DEI equation, such as the noise background caused by the small angle scattering reflected by the analyzer. In the second part, a DEI-PI-CT formula has been proposed and the contour contrast caused by the extinction of refraction beam has been qualitatively explained, and then based on the work of Ando's group two formulae of refraction CT with DEI method has been proposed. Combining one refraction CT formula proposed by Dilmanian with the two refraction CT formulae proposed by us, the whole framework of CT algorithm can be made to reconstruct three components of the gradient of refractive index.

Powder x-ray diffraction and Rietveld analysis of (C_(2)H_(5)NH_(3))_(2)CuCl_(4)

Structural properties of the organic-inorganic hybrid(C_(2)H_(5)NH_(3))_(2)CuCl_(4) have been investigated by means of x-ray powder diffraction and Rietveld analysis. A structural phase transition from Pbca to Aba2 occurs at T_(4)= 240 K, which results in a paraelectric–ferroelectric phase transition. The release of the Jahn–Teller distortion with increasing temperature toward T_(4) is revealed by the structural analysis.

Refractive-diffractive visual system for micro-display of LCOS

One head-mounted display visual system for computer entertainment and three-dimensional display of virtual-reality was achieved, which consists of a hybrid re-fractive-diffractive eyepiece and a relay reflector. It can be used in micro-display of liquid crystal on silicon (LCOS) diagonal of 18 mm. The whole system has better performance, with 60° field of view, 10 mm exit pupil, 23 mm eye relief, and reduces weight and size.

Characterization of structural transitions and lattice dynamics of hybrid organic–inorganic perovskite CH3NH3PbI3

By combining temperature-dependent x-ray diffraction(XRD) with temperature-dependent Raman scattering, we have characterized the structural transitions and lattice dynamics of the hybrid organic–inorganic perovskite CH3NH3PbI3.The XRD measurements cover distinct phases between 15 K and 370 K and demonstrate a general positive thermal expansion.Clear anomalies are found around the transition temperatures.The temperature evolution of the lattice constants reveals that the transition at 160 K/330 K is of the first-/second-order type.Raman measurements uncover three strong lowfrequency modes, which can be ascribed to the vibration of the Pb/I atoms.The temperature evolution of the modes clearly catches these transitions at 160 K and 330 K, and confirms the transition types, which are exactly consistent with the XRD results.The present study may set an experimental basis to understand the high conversion efficiency in methylammonium lead iodide.