Hydrocarbon accumulation and orderly distribution of whole petroleum system in marine carbonate rocks of Sichuan Basin,SW China

Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbon accumulation elements,especially the source rock.The hydrocarbon accumulation characteristics of each whole petroleum system are analyzed,the patterns of integrated conventional and unconventional hydrocarbon accumulation are summarized,and the favorable exploration targets are proposed.Under the control of multiple extensional-convergent tectonic cycles,the marine carbonate rocks of the Sichuan Basin contain three sets of regional source rocks and three sets of regional cap rocks,and can be divided into the Cambrian,Silurian and Permian whole petroleum systems.These whole petroleum systems present mainly independent hydrocarbon accumulation,containing natural gas of affinity individually.Locally,large fault zones run through multiple whole petroleum systems,forming a fault-controlled complex whole petroleum system.The hydrocarbon accumulation sequence of continental shelf facies shale gas accumulation,marginal platform facies-controlled gas reservoirs,and intra-platform fault-and facies-controlled gas reservoirs is common in the whole petroleum system,with a stereoscopic accumulation and orderly distribution pattern.High-quality source rock is fundamental to the formation of large gas fields,and natural gas in a whole petroleum system is generally enriched near and within the source rocks.The development and maintenance of large-scale reservoirs are essential for natural gas enrichment,multiple sources,oil and gas transformation,and dynamic adjustment are the characteristics of marine petroleum accumulation,and good preservation conditions are critical to natural gas accumulation.Large-scale marginal-platform reef-bank facies zones,deep shale gas,and large-scale lithological complexes related to source-connected faults are future marine hydrocarbon exploration targets in the Sichuan Basin.

Differences in hydrocarbon accumulation and controlling factors of slope belt in graben basin: A case study of Pinghu Slope Belt in the Xihu sag of the east China Sea Shelf basin(ECSSB)

The Pinghu slope belt in the Xihu sag of the East China Sea Shelf Basin(ECSSB) is a crucial hydrocarbon production area in eastern China. However, due to the complex geological conditions, publications have lacked comprehensive research on the spatial-temporal coupling relationships of primary factors that impact hydrocarbon accumulation in the Pinghu slope belt. Furthermore, the hydrocarbon distribution patterns and the controlling factors across different study areas within the same slope belt are not yet fully understood. This study extensively utilized three-dimensional seismic data, well logging data,geochemical analysis, fluorescence analysis, and oil testing and production data to address these issues.Following a “stratification and differentiation” approach, the study identified seven distinct hydrocarbon migration and accumulation units(HMAU) in the Pinghu slope area based on the structural morphology characteristics, hydrocarbon source-reservoir-cap rock patterns, hydrocarbon migration pathways, and hydrocarbon supply range. Detailed analysis was conducted to examine the hydrocarbon distribution patterns and controlling factors within each migration and accumulation unit across different structural units, including high, medium, and low structural components. All data sources support a “southern-northern sub-area division, eastern-western sub-belt division, and variations in hydrocarbon accumulation” pattern in the Pinghu slope belt. The degree of hydrocarbon accumulation is controlled by the factors of structural morphology, hydrocarbon generation potential of source rocks, the spatial position of source slopes, fault sealing capacity, and sand body distribution. Furthermore, different coupling patterns of faults and sand bodies play a pivotal role in governing hydrocarbon enrichment systems across various migration and accumulation units. These observations indicate that three hydrocarbon accumulation patterns have been established within the slope belt, including near-source to far-source gentle slope with multiple hydrocarbon kitchens in the XP1-XP4 zones, near-source to middle-source gentle slope with dual-hydrocarbon kitchens in the XP5 zone, and near-source steep slope with a single hydrocarbon kitchen in the XP6-XP7 zones. These findings contribute to enhancing the theoretical system of hydrocarbon accumulation in the slope belt.

Genetic source,migration and accumulation of helium under deep thermal fluid activities:A case study of Ledong diapir area in Yinggehai Basin,South China Sea

Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid activities.The average content of mantle-derived He is only 0.0014%,the ^(3)He/^(4)He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir area.The crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/g.These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions.The ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10^(−11) cm^(3)/J,and the heat contribution from the deep mantle(X_(M))accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 He.The primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation.From deep to shallow layers,the CO_(2/3) He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has escaped.Under the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pressure balance and sealing capability.

Characteristics and hydrocarbon accumulation model of Paleogene whole petroleum system in western depression of Qaidam Basin,NW China

Based on the oil and gas exploration in western depression of the Qaidam Basin,NW China,combined with the geochemical,seismic,logging and drilling data,the basic geological conditions,oil and gas distribution characteristics,reservoir-forming dynamics,and hydrocarbon accumulation model of the Paleogene whole petroleum system(WPS)in the western depression of the Qaidam Basin are systematically studied.A globally unique ultra-thick mountain-style WPS is found in the western depression of the Qaidam Basin.Around the source rocks of the upper member of the Paleogene Lower Ganchaigou Formation,the structural reservoir,lithological reservoir,shale oil and shale gas are laterally distributed in an orderly manner and vertically overlapped from the edge to the central part of the lake basin.The Paleogene WPS in the western depression of the Qaidam Basin is believed unique in three aspects.First,the source rocks with low organic matter abundance are characterized by low carbon and rich hydrogen,showing a strong hydrocarbon generating capacity per unit mass of organic carbon.Second,the saline lake basinal deposits are ultra-thick,with mixed deposits dominating the center of the depression,and strong vertical and lateral heterogeneity of lithofacies and storage spaces.Third,the strong transformation induced by strike-slip compression during the Himalayan resulted in the heterogeneous enrichment of oil and gas in the mountain-style WPS.As a result of the coordinated evolution of source-reservoir-caprock assemblage and conducting system,the Paleogene WPS has the characteristics of“whole process”hydrocarbon generation of source rocks which are low-carbon and hydrogen-rich,“whole depression”ultra-thick reservoir sedimentation,“all direction”hydrocarbon adjustment by strike-slip compressional fault,and“whole succession”distribution of conventional and unconventional oil and gas.Due to the severe Himalayan tectonic movement,the western depression of the Qaidam Basin evolved from depression to uplift.Shale oil is widely distributed in the central lacustrine basin.In the sedimentary system thicker than 2000 m,oil and gas are continuous in the laminated limy-dolomites within the source rocks and the alga limestones neighboring the source kitchen,with intercrystalline pores,lamina fractures in dolomites and fault-dissolution bodies serving as the effective storage space.All these findings are helpful to supplement and expand the WPS theory in the continental lake basins in China,and provide theoretical guidance and technical support for oil and gas exploration in the Qaidam Basin.

Research advances on the mechanisms of reservoir formation and hydrocarbon accumulation and the oil and gas development methods of deep and ultra-deep marine carbonates

Based on the new data of drilling, seismic, logging, test and experiments, the key scientific problems in reservoir formation, hydrocarbon accumulation and efficient oil and gas development methods of deep and ultra-deep marine carbonate strata in the central and western superimposed basin in China have been continuously studied.(1) The fault-controlled carbonate reservoir and the ancient dolomite reservoir are two important types of reservoirs in the deep and ultra-deep marine carbonates. According to the formation origin, the large-scale fault-controlled reservoir can be further divided into three types:fracture-cavity reservoir formed by tectonic rupture, fault and fluid-controlled reservoir, and shoal and mound reservoir modified by fault and fluid. The Sinian microbial dolomites are developed in the aragonite-dolomite sea. The predominant mound-shoal facies, early dolomitization and dissolution, acidic fluid environment, anhydrite capping and overpressure are the key factors for the formation and preservation of high-quality dolomite reservoirs.(2) The organic-rich shale of the marine carbonate strata in the superimposed basins of central and western China are mainly developed in the sedimentary environments of deep-water shelf of passive continental margin and carbonate ramp. The tectonic-thermal system is the important factor controlling the hydrocarbon phase in deep and ultra-deep reservoirs, and the reformed dynamic field controls oil and gas accumulation and distribution in deep and ultra-deep marine carbonates.(3) During the development of high-sulfur gas fields such as Puguang, sulfur precipitation blocks the wellbore. The application of sulfur solvent combined with coiled tubing has a significant effect on removing sulfur blockage. The integrated technology of dual-medium modeling and numerical simulation based on sedimentary simulation can accurately characterize the spatial distribution and changes of the water invasion front.Afterward, water control strategies for the entire life cycle of gas wells are proposed, including flow rate management, water drainage and plugging.(4) In the development of ultra-deep fault-controlled fractured-cavity reservoirs, well production declines rapidly due to the permeability reduction, which is a consequence of reservoir stress-sensitivity. The rapid phase change in condensate gas reservoir and pressure decline significantly affect the recovery of condensate oil. Innovative development methods such as gravity drive through water and natural gas injection, and natural gas drive through top injection and bottom production for ultra-deep fault-controlled condensate gas reservoirs are proposed. By adopting the hierarchical geological modeling and the fluid-solid-thermal coupled numerical simulation, the accuracy of producing performance prediction in oil and gas reservoirs has been effectively improved.

Hydrocarbon migration and accumulation along the fault intersection zone-a case study on the reef-flat systems of the No.1 slope break zone in the Tazhong area, Tarim Basin

Understanding hydrocarbon migration and accumulation mechanisms is one of the key scientif ic problems that should be solved for effective hydrocarbon exploration in the superimposed basins developed in northwest China. The northwest striking No.1 slope break zone, which is a representative of superimposed basins in the Tarim Basin, can be divided into five parts due to the intersection of the northeast strike-slip faults. Controlled by the tectonic framework, the types and properties of reservoirs and the hydrocarbon compositions can also be divided into five parts from east to west. Anomalies of all the parameters were found on the fault intersection zone and weakened up-dip along the structural ridge away from it. Thus, it can be inferred that the intersection zone is the hydrocarbon charging position. This new conclusion differs greatly from the traditional viewpoint, which believes that the hydrocarbon migrates and accumulates along the whole plane of the No.1 slope break zone. The viewpoint is further supported by the evidence from the theory of main pathway systems, obvious improvement of the reservoir quality （2-3 orders of magnitude at the intersection zone） and the formation mechanisms of the fault intersection zone. Differential hydrocarbon migration and entrapment exists in and around the strike- slip faults. This is controlled by the internal structure of faults. It is concluded that the more complicated the fault structure is, the more significant the effects will be. If there is a deformation band, it will hinder the cross fault migration due to the common feature of two to four orders of magnitude reduction in permeability. Otherwise, hydrocarbons tend to accumulate in the up-dip structure under the control of buoyancy. Further research on the internal fault structure should be emphasized.

Dynamic Field Division of Hydrocarbon Migration,Accumulation and Hydrocarbon Enrichment Rules in Sedimentary Basins

Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much lower in the deep parts of basins： at a depth of 7000 m, hydrocarbons can accumulate only in rocks with porosity less than 5%. However, in the shallow parts of basins （i.e., depths of around 1000 m）, hydrocarbon can accumulate in rocks only when porosity is over 20%. Second, hydrocarbon reservoirs tend to exhibit negative pressures after hydrocarbon accumulation at depth, with a pressure coefficient less than 0.7. However, hydrocarbon reservoirs at shallow depths tend to exhibit high pressure after hydrocarbon accumulation. Third, deep reservoirs tend to exhibit characteristics of oil （-gas）-water inversion, indicating that the oil （gas） accumulated under the water. However, the oil （gas） tends to accumulate over water in shallow reservoirs. Fourth, continuous unconventional tight hydrocarbon reservoirs are distributed widely in deep reservoirs, where the buoyancy force is not the primary dynamic force and the caprock is not involved during the process of hydrocarbon accumulation. Conversely, the majority of hydrocarbons in shallow regions accumulate in traps with complex structures. The results of this study indicate that two dynamic boundary conditions are primarily responsible for the above phenomena： a lower limit to the buoyancy force and the lower limit of hydrocarbon accumulation overall, corresponding to about 10%-12% porosity and irreducible water saturation of 100%, respectively. These two dynamic boundary conditions were used to divide sedimentary basins into three different dynamic fields of hydrocarbon accumulation： the free fluid dynamic field, limit fluid dynamic field, and restrain fluid dynamic field. The free fluid dynamic field is located between the surface and the lower limit of the buoyancy force, such that hydrocarbons in this field migrate and accumulate under the influence of, for example, the buoyancy force, pressure, hydrodynamic force, and capillary force. The hydrocarbon reservoirs formed are characterized as ＂four high,＂ indicating that they accumulate in high structures, are sealed in high locations, migrate into areas of high porosity, and are stored in reservoirs at high pressure. The basic features of distribution and accumulation in this case include hydrocarbon migration as a result of the buoyancy force and formation of a reservoir by a caprock. The limit fluid dynamic field is located between the lower limit of the buoyancy force and the lower limit of hydrocarbon accumulation overall; the hydrocarbon migrates and accumulates as a result of, for example, the molecular expansion force and the capillary force. The hydrocarbon reservoirs formed are characterized as ＂four low,＂ indicating that hydrocarbons accumulate in low structures, migrate into areas of low porosity, and accumulate in reservoirs with low pressure, and that oil（-gas）-water inversion occurs at low locations. Continuous hydrocarbon accumulation over a large area is a basic feature of this field. The restrain fluid dynamic field is located under the bottom of hydrocarbon accumulation, such that the entire pore space is filled with water. Hydrocarbons migrate as a result of the molecular diffusion force only. This field lacks many of the basic conditions required for formation of hydrocarbon reservoirs： there is no effective porosity, movable fluid, or hydrocarbon accumulation, and potential for hydrocarbon exploration is low. Many conventional hydrocarbon resources have been discovered and exploited in the free fluid dynamic field of shallow reservoirs, where exploration potential was previously considered to be low. Continuous unconventional tight hydrocarbon resources have been discovered in the limit fluid dynamic field of deep reservoirs; the exploration potential of this setting is thought to be tremendous, indicating that future exploration should be focused primarily in this direction.

A Study of the Migration and Accumulation Efficiency and the Genesis of Hydrocarbon Natural Gas in the Xujiaweizi Fault Depression

In order to investigate the migration and accumulation efficiency of hydrocarbon natural gas in the Xujiaweizi fault depression, and to provide new evidence for the classification of its genesis, a source rock pyrolysis experiment in a closed system was designed and carried out. Based on this, kinetic models for describing gas generation from organic matter and carbon isotope fractionation during this process were established, calibrated and then extrapolated to geologic conditions by combining the thermal history data of the Xushen-1 Well. The results indicate that the coal measures in the Xujiaweizi fault depression are typical ＂high-efficiency gas sources＂, the natural gas generated from them has a high migration and accumulation efficiency, and consequently a large-scale natural gas accumulation occurred in the area. The highly/over matured coal measures in the Xujiaweizi fault depression generate coaliferous gas with a high δ^13C1 value （〉 -20‰） at the late stage, making the carbon isotope composition of organic alkane gases abnormally heavy. In addition, the mixing and dissipation through the caprock of natural gas can result in the negative carbon isotope sequence （δ^13C1 〉δ^13C2 〉δ^13C3 〉δ^13C4） of organic alkane gases, and the dissipation can also lead to the abnormally heavy carbon isotope composition of organic alkane gases. As for the discovery of inorganic nonhydrocarbon gas reservoirs, it can only serve as an accessorial evidence rather than a direct evidence that the hydrocarbon gas is inorganic. As a result, it needs stronger evidence to classify the hydrocarbon natural gas in the Xujiaweizi fault depression as inorganic gas.

Features and dynamic mechanisms of Cenozoic tectonic migration and its impact on the hydrocarbon accumulation in the northern South China Sea

The northern continental margin of the South China Sea （SCS） is located within the tectonic system of Southeast Asia, an area with a great deal of tectonic migration due to the regional tectonic movements. The available geological and geophysical data of the area are comprehensively analyzed in order to demonstrate the typical migration patterns of the Cenozoic tectonics in the northern SCS caused by the episodes of the Cenozoic tectonic movement. Furthermore, the lateral variation characteristics of the strata and the differ- ent evolution patterns of the main basins＇ features are assessed. It primarily focus on： （1） the Cenozoic epi- sodic rifting from north to south in the continental margin of the northern SCS; （2） the rifting and depression time of the main basins progressively become younger as one goes from north to south, signifying that the migration of both the tectonics and the sediments within the northern SCS travelled from north to south during the Cenozoic; and （3） the lateral tectonic migration on the direction of EW is not regular in total, but in some local areas the trending of the tectonic migration is from west to east. The analysis of the tectonic migration features of the northern SCS, in combination with the regional tectonic evolution background, indicates that the observed remote lagging effect, resulted from the India-Eurasia plate collision, is the main dynamic mechanism involved in the tectonic migration within the northern SCS. The tectonic migration has significant influence on both the organization of petroleum deposits and on the hydrocarbon accumulation within the basins in the northern SCS; comprehensive understanding of this dynamic system is of great reference value in predicting the hydrocarbon accumulation and has the potential to have an enormous impact in discovering new deep reservoirs for the future oil-gas exploration.

Study on fault-controlled hydrocarbon migration and accumulation process and models in Zhu I Depression

Through the analysis of the faults and their internal structure in Zhu I Depression,it is found that the internal structure of the late fault is obviously segmented vertically.It develops unitary structure(simple fault plane)in shallow layers,binary structure(induced fracture zone in hanging wall and sliding fracture zone in footwall)in middle,layers and ternary structure(induced fracture zone in hanging wall and sliding fracture zone in middle,and induced fracture zone in footwall)in deep layers.Because the induced fracture zone is a high porosity and permeability zone,and the sliding fracture zone is a low porosity and ultra-low permeability zone,the late fault in middle layers has the character of"transporting while sealing".The late fault can transport hydrocarbon by its induced fracture zone in the side of the hanging wall and seal hydrocarbon by its sliding fracture zone in the side of the footwall.In deep layers,the late fault has the character of"dual-transportation",induced fracture zones in both sides of hanging wall and footwall can transport hydrocarbon.The early fault that only developed in the deep layers is presumed to be unitary structure,which plays a completely sealing role in the process of hydrocarbon migration and accumulation due to inactivity during the hydrocarbon filling period.Controlled by hydrocarbon source,early/late faults,sand bodies and traps,two reservoir-forming models of"inverted L"and"stereo-spiral"can be proposed in middle layers,while two reservoir-forming models of"cross fault"and"lateral fault sealing"are developed in the deep layers of Zhu I Depression.

Artificial Neural Network Model of Hydrocarbon Migration and Accumulation

Based on the dynamic simulation of the 3 D structure the sedimentary modeling, the unit entity model has been adopted to transfer the heterogeneous complex passage system into limited simple homogeneous entity, and then the traditional dynamic simulation has been used to calculate the phase and the drive forces of the hydrocarbon , and the artificial neural network(ANN) technology has been applied to resolve such problems as the direction, velocity and quantity of the hydrocarbon migration among the unit entities. Through simulating of petroleum migration and accumulation in Zhu Ⅲ depression, the complex mechanism of hydrocarbon migration and accumulation has been opened out.

Mesh model building and migration and accumulation simulation of 3D hydrocarbon carrier system

Migration and accumulation simulation of oil and gas in carrier systems has always been a difficult subject in the quantitative study of petroleum geology. In view of the fact that the traditional geological modeling technology can not establish the interrelation of carriers in three dimensional space, we have proposed a hybrid-dimensional mesh modeling technology consisting of body(stratum), surfaces(faults and unconformities), lines and points, which provides an important research method for the description of geometry of sand bodies, faults and unconformities, the 3 D geological modeling of complex tectonic areas, and the simulation of hydrocarbon migration and accumulation. Furthermore, we have advanced a 3 D hydrocarbon migration pathway tracking method based on the hybrid-dimensional mesh of the carrier system. The application of this technology in western Luliang Uplift of Junggar Basin shows that the technology can effectively characterize the transport effect of fault planes, unconformities and sand bodies, indicate the hydrocarbon migration pathways, simulate the process of oil accumulation, reservoir adjustment and secondary reservoir formation, predict the hydrocarbon distribution. It is found through the simulation that the areas around the paleo-oil reservoir and covered by migration pathways are favorable sites for oil and gas distribution.

Hydrocarbon Migration and Accumulation in Dongying Basin

ＨｙｄｒｏｃａｒｂｏｎＭｉｇｒａｔｉｏｎａｎｄＡｃｃｕｍｕｌａｔｉｏｎｉｎＤｏｎｇｙｉｎｇＢａｓｉｎＬｉＣｈｕｎｇｕａｎｇ（ＳｅｎｉｏｒＥｎｇｉｎｅｅｒ，ＧｅｏｌｏｇｉｃａｌＳｃｉｅｎｔｉｆｉｃＲｅｓｅａｒｃｈＩｎｓｔｉｔｕｔｅ，ＳｈｅｎｇｌｉＰｅｔ...

Hydrocarbon accumulation in deep ancient carbonate-evaporite assemblages

The Ediacaran–Ordovician strata within three major marine basins(Tarim,Sichuan,and Ordos)in China are analyzed.Based on previous studies focusing on the characteristics of the Neoproterozoic–Cambrian strata within the three major basins(East Siberian,Oman,and Officer in Australia)overseas,the carbonate–evaporite assemblages in the target interval are divided into three types:intercalated carbonate and gypsum salt,interbedded carbonate and gypsum salt,and coexisted carbonate,gypsum salt and clastic rock.Moreover,the concept and definition of the carbonate-evaporite assemblage are clarified.The results indicate that the oil and gas in the carbonate-evaporite assemblage are originated from two types of source rocks:shale and argillaceous carbonate,and confirmed the capability of gypsum salt in the saline environment to drive the source rock hydrocarbon generation.The dolomite reservoirs are classified in two types:gypseous dolomite flat,and grain shoal&microbial mound.This study clarifies that the penecontemporaneous or epigenic leaching of atmospheric fresh water mainly controlled the large-scale development of reservoirs.Afterwards,burial dissolution transformed and reworked the reservoirs.The hydrocarbon accumulation in carbonate-evaporite assemblage can be categorized into eight sub-models under three models(sub-evaporite hydrocarbon accumulation,supra-evaporite hydrocarbon accumulation,and inter-evaporite hydrocarbon accumulation).As a result,the Cambrian strata in the Tazhong Uplift North Slope,Maigaiti Slope and Mazatag Front Uplift Zone of the Tarim Basin,the Cambrian strata in the eastern-southern area of the Sichuan Basin,and the inter-evaporite Ma-4 Member of Ordovician in the Ordos Basin,China,are defined as favorable targets for future exploration.

Geochemical identification of a source rock affected by migrated hydrocarbons and its geological significance:Fengcheng Formation,southern Mahu Sag,Junggar Basin,NW China

The Fengcheng Formation is a crucial source rock and the primary reservoir for oil accumulation in the Mahu Sag.Crude oils are distributed throughout the Fengcheng Formation,ranging from the edge to the interior of the sag in the southern Mahu Sag.These crude oils originate from in-situ source rocks in shallowly buried areas and the inner deep sag.During migration,the crude oil from the inner deep sag affects the source rocks close to carrier beds,leading to changes in the organic geochemical characteristics of the source rocks.These changes might alter source rock evaluations and oil-source correlation.Based on data such as total organic carbon(TOC),Rock-Eval pyrolysis of source rocks,and gas chromatography-mass spectrometry(GC-MS)of the saturated fraction,and considering the geological characteristics of the study area,we define the identification characteristics of source rock affected by migrated hydrocarbons and establish the various patterns of influence that migrated hydrocarbons have on the source rock of the Fengcheng Formation in the southern Mahu Sag.The source rocks of the Fengcheng Formation are mostly fair to good,containing mainly Type II organic matter and being thermally mature enough to generate oil.Source rocks affected by migrated hydrocarbons exhibit relatively high hydrocarbon contents(S1/TOC>110 mg HC/g TOC,Extract/TOC>30%,HC:hydrocarbon),relatively low Rock-Eval Tmax values,and relatively high tricyclic terpane contents with a descending and mountain-shaped distribution.Furthermore,biomarker composition parameters indicate a higher thermal maturity than in-situ source rocks.Through a comparison of the extract biomarker fingerprints of adjacent reservoirs and mudstones in different boreholes,three types of influence patterns of migrated hydrocarbons are identified:the edge-influence of thin sandstone-thick mudstone,the mixed-influence of sandstone-mudstone interbedded,and the full-influence of thick sandstone-thin mudstone.This finding reminds us that the influence of migrated hydrocarbons must be considered when evaluating source rocks and conducting oil-source correlation.

Petroleum geology features and research developments of hydrocarbon accumulation in deep petroliferous basins

As petroleum exploration advances and as most of the oil-gas reservoirs in shallow layers have been explored, petroleum exploration starts to move toward deep basins, which has become an inevitable choice. In this paper, the petroleum geology features and research progress on oil-gas reservoirs in deep petroliferous basins across the world are characterized by using the latest results of worldwide deep petroleum exploration. Research has demonstrated that the deep petroleum shows ten major geological features. （1） While oil-gas reservoirs have been discovered in many different types of deep petroliferous basins, most have been discovered in low heat flux deep basins. （2） Many types of petroliferous traps are developed in deep basins, and tight oil-gas reservoirs in deep basin traps are arousing increasing attention. （3） Deep petroleum normally has more natural gas than liquid oil, and the natural gas ratio increases with the burial depth. （4） The residual organic matter in deep source rocks reduces but the hydrocarbon expulsion rate and efficiency increase with the burial depth. （5） There are many types of rocks in deep hydrocarbon reservoirs, and most are clastic rocks and carbonates. （6） The age of deep hydrocarbon reservoirs is widely different, but those recently discovered are pre- dominantly Paleogene and Upper Paleozoic. （7） The porosity and permeability of deep hydrocarbon reservoirs differ widely, but they vary in a regular way with lithology and burial depth. （8） The temperatures of deep oil-gas reservoirs are widely different, but they typically vary with the burial depth and basin geothermal gradient. （9） The pressures of deep oil-gas reservoirs differ significantly, but they typically vary with burial depth, genesis, and evolu- tion period. （10） Deep oil-gas reservoirs may exist with or without a cap, and those without a cap are typically of unconventional genesis. Over the past decade, six major steps have been made in the understanding of deep hydrocarbon reservoir formation. （1） Deep petroleum in petroliferous basins has multiple sources and many dif- ferent genetic mechanisms. （2） There are high-porosity, high-permeability reservoirs in deep basins, the formation of which is associated with tectonic events and subsurface fluid movement. （3） Capillary pressure differences inside and outside the target reservoir are the principal driving force of hydrocarbon enrichment in deep basins. （4） There are three dynamic boundaries for deep oil-gas reservoirs; a buoyancy-controlled threshold, hydrocarbon accumulation limits, and the upper limit of hydrocarbon generation. （5） The formation and distribution of deep hydrocarbon res- ervoirs are controlled by free, limited, and bound fluid dynamic fields. And （6） tight conventional, tight deep, tight superimposed, and related reconstructed hydrocarbon reservoirs formed in deep-limited fluid dynamic fields have great resource potential and vast scope for exploration. Compared with middle-shallow strata, the petroleum geology and accumulation in deep basins are more complex, which overlap the feature of basin evolution in different stages. We recommend that further study should pay more attention to four aspects： （1） identification of deep petroleum sources and evaluation of their relative contributions; （2） preservation conditions and genetic mechanisms of deep high-quality reservoirs with high permeability and high porosity; （3） facies feature and transformation of deep petroleum and their potential distribution; and （4） economic feasibility evaluation of deep tight petroleum exploration and development.

A hydrocarbon enrichment model and prediction of favorable accumulation areas in complicated superimposed basins in China

The geologic conditions of superimposed basins in China are very complicated. This is mainly shown by multi-phase structural evolution, multiple sets of source-reservoir-cap rock combinations, multiple stages of hydrocarbon generation and expulsion from source rocks, multi-cycle hydrocarbon enrichment and accumulation, and multi-phase reservoir adjustment and reconstruction. The enrichment, accumulation and distribution of hydrocarbon is mainly controlled by the source rock kitchen, paleo- anticline, regional cap rock and intensity of tectonic movement. In this paper, the T-BCMS model has been developed to predict favorable areas of hydrocarbon accumulation in complicated superimposed basins according to time and spatial relationships among five key factors. The five factors include unconformity surface representing tectonic balancing （B）, regional cap rock representing hydrocarbon protection （C）, paleo-anticline representing hydrocarbon migration and accumulation （M）, source rock kitchen representing hydrocarbon generation and expulsion （S） and geological time （T）. There are three necessary conditions to form favorable areas of hydrocarbon accumulation. First, four key factors BCMS should be strictly in the order of BCMS from top to bottom. Second, superimposition of four key factors BCMS in the same area is the most favorable for hydrocarbon accumulation. Third, vertically ordered combination and superimposition in the same area of BCMS should occur at the same geological time. The model has been used to predict the most favorable exploration areas in Ordovician in the Tarim Basin in the main hydrocarbon accumulation periods. The result shows that 95% of the discovered Ordovician hydrocarbon reservoirs are located in the predicted areas, which indicates the feasibility and reliability of the key factor matching T-BCMS model for hydrocarbon accumulation and enrichment.

Paleoporosity and critical porosity in the accumulation period and their impacts on hydrocarbon accumulation—A case study of the middle Es3 member of the Paleogene formation in the Niuzhuang Sag, Dongying Depression, Southeastern Bohai Bay Basin, East Chi

Similar reservoir sandbodies and fault conduit systems in the sandstone reservoirs in the middle Es3 member of the Niuzhuang Sag have been problematic for a long time. The following problems remain unsolved： 1） The distribution of sandstone porosity is inconsistent with the hydrocarbon accumulation. The oil sandstones have low porosity instead of high porosity. 2） Sandstones, which have the same properties, have different levels of oiliness, and the sandstones with almost the same properties show different degrees of oil-bearing capacity. This study analyzes the condition of reservoirs in the research area during the accumulation period in terms of paleoporosity estimation and discusses the critical porosity of the sandstone reservoirs during the same period. The following conclusions can be drawn from the results. 1） Although reservoir properties are low at present and some reservoirs have become tight, the paleoporosity ranging from 18% to 25% is greater than the critical porosity of 13.9%. As the： loss of porosity is different in terms of burial history, the present porosity cannot reflect porosity during the accumulation period. Similar/y, high porosity during the accumulation period does not indicate that tbe present porosity is high. 2） The present reservoir location is consistent with the distribution of high paleoporosity during the accumulation period. This result indicates that high porosity belts are prone to hydrocarbon accumulation because of the dominant migration pathways generated as a result of property discrepancies under similar fault conduit conditions. Consequently, the hydrocarbon mainly accumulates in high porosity belts. Paleoporosity during the accumulation period is found to be a vital controlling factor. Therefore, high paleoporosity sandstones in the middle Es3 member of the Niuzhuang Sag have great potential for future exploration.

The Cretaceous tectonic event in the Qiangtang Basin and its implications for hydrocarbon accumulation

The tectonic event during Cretaceous and its relationship with hydrocarbon accumulation in the Qiangtang Basin is discussed based on zircon U-Pb dating and the study of deformation, thermochronology and hydrocarbon formation. LA-ICPMS zircon U-Pb dating indicates that the tectonic event took place during the Early-Late Cretaceous （125-75Ma）. The event not only established the framework and the styles of structural traps in the basin, but also led to the cessation of the first hydrocarbon formation and the destruction of previous oil pools. The light crude oil in the basin was formed during the second hydrocarbon formation stage in the Cenozoic, and ancient structural traps formed during the Cretaceous event are promising targets for oil and gas exploration.

Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances（gases and aqueous solutions） as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO2, CH4, H2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO2 reservoirs have been discovered. The CO2 content is up to 99%, with δ-（13）C（CO2） values ranging from-4.1‰ to-0.37‰ and -3He/-4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ-（13）CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ-（13）C（CH4）δ-（13）C（C2H6）δ-（13）C（C3H8）δ-（13）C（C4H10）. According to laboratory experiments, introducing external H2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic -（87）Sr. Due to CO2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at -6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO2. Many reservoirs containing both supercritical CO2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO2 are dominated by low molecular weight saturated hydrocarbons.