In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hy...In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.展开更多
Hydraulic-electric rock fragmentation(HERF)plays a significant role in improving the efficiency of high voltage pulse rock breaking.However,the underlying mechanism of HERF remains unclear.In this study,considering th...Hydraulic-electric rock fragmentation(HERF)plays a significant role in improving the efficiency of high voltage pulse rock breaking.However,the underlying mechanism of HERF remains unclear.In this study,considering the heterogeneity of the rock,microscopic thermodynamic properties,and shockwave time domain waveforms,based on the shockwave model,digital imaging technology and the discrete element method,the cyclic loading numerical simulations of HERF is achieved by coupling electrical,thermal,and solid mechanics under different formation temperatures,confining pressure,initial peak voltage,electrode bit diameter,and loading times.Meanwhile,the HERF discharge system is conducive to the laboratory experiments with various electrical parameters and the resulting broken pits are numerically reconstructed to obtain the geometric parameters.The results show that,the completely broken area consists of powdery rock debris.In the pre-broken zone,the mineral cementation of the rock determines the transition of type CⅠcracks to type CⅡand type CⅢcracks.Furthermore,the peak pressure of the shockwave increased with initial peak voltage but decreased with electrode bit diameter,while the wave front time reduced.Moreover,increasing well depth,formation temperature and confining pressure augment and inhibit HERF,but once confining pressure surpassed the threshold of 60 MPa for 152.40,215.90,and 228.60 mm electrode bits,and 40 MPa for 309.88 mm electrode bits,HERF is promoted.Additionally,for the same kind of rock,the volume and width of the broken pit increase with higher initial peak voltage and rock fissures will promote HERF.Eventually,the electrode drill bit with a 215.90 mm diameter is more suitable for drilling pink granite.This research contributes to a better microscopic understanding of HERF and provides valuable insights for electrode bit selection,as well as the optimization of circuit parameters for HERF technology.展开更多
This study comprehensively assessed long-term vegetation changes and forest fragmentation dynamics in the Himalayan temperate region of Pakistan from 1989 to 2019.Four satellite images,including Landsat-5 TM and Lands...This study comprehensively assessed long-term vegetation changes and forest fragmentation dynamics in the Himalayan temperate region of Pakistan from 1989 to 2019.Four satellite images,including Landsat-5 TM and Landsat-8 Operational Land Imager(OLI),were chosen for subsequent assessments in October 1989,2001,2011 and 2019.The classified maps of 1989,2001,2011 and 2019 were created using the maximum likelihood classifier.Post-classification comparison showed an overall accuracy of 82.5%and a Kappa coefficient of 0.79 for the 2019 map.Results revealed a drastic decrease in closed-canopy and open-canopy forests by 117.4 and 271.6 km^(2),respectively,and an increase in agriculture/farm cultivation by 1512.8 km^(2).The two-way ANOVA test showed statistically significant differences in the area of various cover classes.Forest fragmentation was evaluated using the Landscape Fragmentation Tool(LFT v2.0)between 1989 and 2019.The large forest core(>2.00 km^(2))decreased from 149.4 to 296.7 km^(2),and a similar pattern was observed in medium forest core(1.00-2.00 km^(2))forests.On the contrary,the small core(<1.00 km^(2))forest increased from 124.8 to 145.3 km^(2) in 2019.The perforation area increased by 296.9 km^(2),and the edge effect decreased from 458.9 to 431.7 km^(2).The frequency of patches also increased by 119.1 km^(2).The closed and open canopy classes showed a decreasing trend with an annual rate of 0.58%and 1.35%,respectively.The broad implications of these findings can be seen in the studied region as well as other global ecological areas.They serve as an imperative baseline for afforestation and reforestation operations,highlighting the urgent need for efficient management,conservation,and restoration efforts.Based on these findings,sustainable land-use policies may be put into place that support local livelihoods,protect ecosystem services,and conserve biodiversity.展开更多
Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,F...Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,Fangshan granite(FG)specimens were exposed to microwave irradiation and heat treatment.The damage of FG specimens induced by these two methods was compared using X-ray CT scanning and ultrasonic wave method.The temperatures of FG after microwave irradiation and thermal treatment were effectively evaluated using a newly proposed technique.A novelty method for precisely determining the geometric features of fragments is developed to estimate the fragmentation energy.Thus,the dynamic uniaxial compressive strength(UCS),the dynamic fragmentation characteristics,and the fragmentation energy of FG after these two pretreatment methods can be reasonably compared.The noticeable distinction of loading rate effect on the dynamic UCS of FG between these two pretreatment methods is first observed.A relationship is established between the dynamic UCS and the damage induced by microwave irradiation and heat treatment.Moreover,fragmentation energy fan analysis is introduced to accurately compare the fragmentation properties of FG after two pretreatment methods in dynamic compression tests.展开更多
Rock fragmentation plays a critical role in rock avalanches,yet conventional approaches such as classical granular flow models or the bonded particle model have limitations in accurately characterizing the progressive...Rock fragmentation plays a critical role in rock avalanches,yet conventional approaches such as classical granular flow models or the bonded particle model have limitations in accurately characterizing the progressive disintegration and kinematics of multi-deformable rock blocks during rockslides.The present study proposes a discrete-continuous numerical model,based on a cohesive zone model,to explicitly incorporate the progressive fragmentation and intricate interparticle interactions inherent in rockslides.Breakable rock granular assemblies are released along an inclined plane and flow onto a horizontal plane.The numerical scenarios are established to incorporate variations in slope angle,initial height,friction coefficient,and particle number.The evolutions of fragmentation,kinematic,runout and depositional characteristics are quantitatively analyzed and compared with experimental and field data.A positive linear relationship between the equivalent friction coefficient and the apparent friction coefficient is identified.In general,the granular mass predominantly exhibits characteristics of a dense granular flow,with the Savage number exhibiting a decreasing trend as the volume of mass increases.The process of particle breakage gradually occurs in a bottom-up manner,leading to a significant increase in the angular velocities of the rock blocks with increasing depth.The simulation results reproduce the field observations of inverse grading and source stratigraphy preservation in the deposit.We propose a disintegration index that incorporates factors such as drop height,rock mass volume,and rock strength.Our findings demonstrate a consistent linear relationship between this index and the fragmentation degree in all tested scenarios.展开更多
Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon s...Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon sequestration and the trend towards fragmentation of plantation forests.Limited studies have been conducted on changes in plantation biomass and stand structure caused by fragmentation,and the effect of fragmentation on the carbon storage of plantation forests remains unclear.This study evaluated the differences between carbon storage and stand structure in black locust forests in fragmented and continuous landscape in the Ansai District,China and discussed the effects of ecological significance of four landscape indices on carbon storage and tree density.We used structural equation modelling to explore the direct and indirect effects of fragmentation,edge,abiotic factors,and stand structure on above-ground carbon storage.Diameter at breast height(DBH)in fragmented forests was 53.3%thicker,tree density was 40.9%lower,and carbon storage was 49.8%higher than those in continuous forests;for all given DBH>10 cm,the trees in fragmented forests were shorter than those in continuous forests.The patch area had a negative impact on carbon storage,i.e.,the higher the degree of fragmentation,the lower the density of the tree;and fragmentation and distance to edge(DTE)directly increased canopy coverage.However,canopy coverage directly decreased carbon storage,and fragmentation directly increased carbon storage and tree density.In non-commercial forests,fragmentation reduces the carbon storage potential of plantation,and the influence of patch area,edge,and patchy connection on plantation should be considered when follow-up trees are planted and for the plantation management.Thus,expanding the area of plantation patches,repairing the edges of complex-shaped patches,enhancing the connectivity of similar patches,and applying nutrients to plantation forests at regular intervals are recommended in fragmented areas of the Loess Plateau.展开更多
This report provides an overall assessment of land fragmentation problems in East Africa. Many parts of East Africa have become highly fragmented, putting development systems and activities in these areas at risk of c...This report provides an overall assessment of land fragmentation problems in East Africa. Many parts of East Africa have become highly fragmented, putting development systems and activities in these areas at risk of complete collapse. Land fragmentation occurs when land gets converted for agriculture, industrialization, or urbanization, invaded by non-local plants, or enclosed for individual use and by subdividing farmlands into subsequent smaller units called parcels with varying average farm sizes. Fragmentation results from inappropriate agricultural development processes and ineffective land use planning that fails to recognize how farmland is used, and the importance of its interconnected areas. Insecurity of tenure and resource rights are key factors in making this possible. Land fragmentation is one of the key reasons why the ability of most resources in East Africa becomes scarcer, and those remaining become “privatized” by more powerful community members—keen to maintain their access to them. Such individualistic attitudes are new and disadvantage the poorest even further by affecting the traditional customary safety nets and agricultural outputs. Neither the government nor customary governance systems effectively protect resource access for the poorest. This review summary report identifies the key causes, measures, and implications, government interventions, and the common remedies to land fragmentation problems in the East African Countries of Kenya, Uganda, Rwanda, and Tanzania including neighboring Ethiopia, and the Sudan. The findings indicated from 2005 to 2015, the population kept increasing for all the named countries in East Africa with Rwanda and Uganda having a substantial increase in population density. The study review further explores the trend in the performance of agriculture by average farm sizes within the intervals of five years by highlighting their strong linkages and found that the average farm size has declined drastically, especially for Kenya. This can only mean that small farms kept becoming smaller and smaller and that there were more small-scale farmers. The results further depicted that the major and commonly cultivated food crops among the East African countries include maize, sorghum, rice, cassava, sweet potatoes, bananas, Irish potatoes, beans, peas, etc., with maize yields (Mt/ha) in 2003 for Uganda being the highest (1.79 Mt/ha) and the lowest in Rwanda (0.77 Mt/ha) respectively. Therefore, from the review results, recommendations are being made as to how the negative impacts of land fragmentation on agricultural productivity can be reduced or mitigated. One way is by community sensitization and awareness about the importance of land consolidation and its proposition on farm productivity.展开更多
Neutron-skin thickness is a key parameter for a neutron-rich nucleus;however,it is difficult to determine.In the framework of the Lanzhou Quantum Molecular Dynamics(LQMD)model,a possible probe for the neutron-skin thi...Neutron-skin thickness is a key parameter for a neutron-rich nucleus;however,it is difficult to determine.In the framework of the Lanzhou Quantum Molecular Dynamics(LQMD)model,a possible probe for the neutron-skin thickness(δ_(np))of neutron-rich ^(48)Ca was studied in the 140A MeV ^(48)Ca+^(9)Be projectile fragmentation reaction based on the parallel momentum distribution(p∥)of the residual fragments.A Fermi-type density distribution was employed to initiate the neutron density distributions in the LQMD simulations.A combined Gaussian function with different width parameters for the left side(Γ_(L))and the right side(Γ_(R))in the distribution was used to describe the p∥of the residual fragments.Taking neutron-rich sulfur isotopes as examples,Γ_(L) shows a sensitive correlation withδ_(np) of ^(48)Ca,and is proposed as a probe for determining the neutron skin thickness of the projectile nucleus.展开更多
Objective:To determine the relationship between teratozoospermia and sperm DNA fragmentation(SDF)in the human ejaculate.Methods:This retrospective study included 100 normozoospermic men as a control cohort(abnormal fo...Objective:To determine the relationship between teratozoospermia and sperm DNA fragmentation(SDF)in the human ejaculate.Methods:This retrospective study included 100 normozoospermic men as a control cohort(abnormal forms>14%),210 patients with a high level of abnormal forms(≤4%)and 65 patients presenting with a moderate level of abnormal forms(>4%to≤14%)based on the World Health Organization definitions.Sperm morphology was assessed using bright field microscopy.Sperm DNA fragmentation was assessed using the sperm chromatin dispersion assay.Non-parametric analyses were conducted to examine the relationship between abnormal sperm morphology and sperm DNA fragmentation;receiver operating characteristic(ROC)analyses were conducted to assess sensitivity and specificity of this relationship.Results:A correlation analysis revealed that the higher the proportion of abnormal spermatozoa in the ejaculate,the higher the level of SDF(Spearman's Rho=-0.230;P<0.001).Significant differences in the proportion of SDF were found when all cohorts were compared(P<0.001);these significant differences were also retained when the different cohorts were compared pairwise.ROC analysis showed a moderate but significant predictive value for SDF to differentiate patients with different levels of teratozoospemia.Conclusions:Although analysis of a more continuous range of values for teratozoospermia would help further clarify any causal relationship with SDF,there is clearly a synergistic or coincident affiliation between these variables that needs to be acknowledged by the clinician when interpreting the spermiogram.展开更多
Landscape fragmentation is generally viewed as an indicator of environmental stresses or risks,but the fragmentation intensity assessment also depends on the scale of data and the definition of spatial unit.This study...Landscape fragmentation is generally viewed as an indicator of environmental stresses or risks,but the fragmentation intensity assessment also depends on the scale of data and the definition of spatial unit.This study aimed to explore the scale-dependence of forest fragmentation intensity along a moisture gradient in Yinshan Mountain of North China,and to estimate environmental sensitivity of forest fragmentation in this semi-arid landscape.We developed an automatic classification algorithm using simple linear iterative clustering(SLIC)and Gaussian mixture model(GMM),and extracted tree canopy patches from Google Earth images(GEI),with an accuracy of 89.2%in the study area.Then we convert the tree canopy patches to forest category according to definition of forest that tree density greater than 10%,and compared it with forest categories from global land use datasets,FROM-GLC10 and GlobeLand30,with spatial resolutions of 10 m and 30 m,respectively.We found that the FROM-GLC10 and GlobeLand30 datasets underestimated the forest area in Yinshan Mountain by 16.88%and 21.06%,respectively;and the ratio of open forest(OF,10%<tree coverage<40%)to closed forest(CF,tree coverage>40%)areas in the underestimated part was 2:1.The underestimations concentrated in warmer and drier areas occupied mostly by large coverage of OFs with severely fragmented canopies.Fragmentation intensity of canopies positively correlated with spring temperature while negatively correlated with summer precipitation and terrain slope.When summer precipitation was less than 300 mm or spring temperature higher than 4℃,canopy fragmentation intensity rose drastically,while the forest area percentage kept stable.Our study suggested that the spatial configuration,e.g.,sparseness,is more sensitive to drought stress than area percentage.This highlights the importance of data resolution and proper fragmentation measurements for forest patterns and environmental interpretation,which is the base of reliable ecosystem predictions with regard to the future climate scenarios.展开更多
As edge computing services soar,the problem of resource fragmentation situation is greatly worsened in elastic optical networks(EON).Aimed to solve this problem,this article proposes the fragmentation prediction model...As edge computing services soar,the problem of resource fragmentation situation is greatly worsened in elastic optical networks(EON).Aimed to solve this problem,this article proposes the fragmentation prediction model that makes full use of the gate recurrent unit(GRU)algorithm.Based on the fragmentation prediction model,one virtual optical network mapping scheme is presented for edge computing driven EON.With the minimum of fragmentation degree all over the whole EON,the virtual network mapping can be successively conducted.Test results show that the proposed approach can reduce blocking rate,and the supporting ability for virtual optical network services is greatly improved.展开更多
Spontaneous combustion of coal increases the temperature in adjoining overburden strata of coal seams and poses a challenge when loading blastholes.This condition,known as hot-hole blasting,is dangerous due to the inc...Spontaneous combustion of coal increases the temperature in adjoining overburden strata of coal seams and poses a challenge when loading blastholes.This condition,known as hot-hole blasting,is dangerous due to the increased possibility of premature explosions in loaded blastholes.Thus,it is crucial to load the blastholes with an appropriate amount of explosives within a short period to avoid premature detonation caused by high temperatures of blastholes.Additionally,it will help achieve the desired fragment size.This study tried to ascertain the most influencial variables of mean fragment size and their optimum values adopted for blasting in a fiery seam.Data on blast design,rock mass,and fragmentation of 100 blasts in fiery seams of a coal mine were collected and used to develop mean fragmentation prediction models using soft computational techniques.The coefficient of determination(R^(2)),root mean square error(RMSE),mean absolute error(MAE),mean square error(MSE),variance account for(VAF)and coefficient of efficiency in percentage(CE)were calculated to validate the results.It indicates that the random forest algorithm(RFA)outperforms the artificial neural network(ANN),response surface method(RSM),and decision tree(DT).The values of R^(2),RMSE,MAE,MSE,VAF,and CE for RFA are 0.94,0.034,0.027,0.001,93.58,and 93.01,respectively.Multiple parametric sensitivity analyses(MPSAs)of the input variables showed that the Schmidt hammer rebound number and spacing-to-burden ratio are the most influencial variables for the blast fragment size.The analysis was finally used to define the best blast design variables to achieve optimum fragment size from blasting.The optimum factor values for RFA of S/B,ld/B and ls/ld are 1.03,1.85 and 0.7,respectively.展开更多
High-voltage pulse discharge(HVPD)rock fragmentation controls a plasma channel forming inside the rock by adjusting the electrical parameters,electrode type,etc.In this work,an HVPD rock fragmentation test platform wa...High-voltage pulse discharge(HVPD)rock fragmentation controls a plasma channel forming inside the rock by adjusting the electrical parameters,electrode type,etc.In this work,an HVPD rock fragmentation test platform was built and the test waveforms were measured.Considering the effects of temperature,channel expansion and electromagnetic radiation,the impedance model of the plasma channel in the rock was established.The parameters and initial values of the model were determined by an iterative computational process.The model calculation results can reasonably characterize the development of the plasma channel in the rock and estimate the shock wave characteristics.Based on the plasma channel impedance model,the temporal and spatial distribution characteristics of the radial stress and tangential stress in the rock were calculated,and the rock fragmentation effect of the HVPD was analyzed.展开更多
A simple finite element implementation of the Mott model for fragmentation of a thin walled ring has been implemented and used to explore the effect of local variations in fracture strain around the ring.The model has...A simple finite element implementation of the Mott model for fragmentation of a thin walled ring has been implemented and used to explore the effect of local variations in fracture strain around the ring.The model has successfully reproduced the fragment size distributions previously reported,which follow a characteristic“Mott distribution”form,providing sufficient(1000)simulations are run.It has been shown that this form is retained even when there are large differences in the random distribution of fracture strains or a different choice of function used to describe the fracture strain scatter.In these cases,the strain rate has a much stronger effect than fracture strain distribution the on the average fragment size and fragment distribution.However,for cases where there are a small number of local defects that strongly reduce the fracture strain at certain locations around the ring,the predicted fragment size distribution develops a bimodal character.This is also the case for large but gradual variations in fracture strain with position around the ring.The results have implications for cases where a small number of large pre-existing defects exist,or processing has led to macrozones in the microstructure.The utility of a simple fast running model to study these cases is discussed.展开更多
Individual hydrocarbons identified to be macrocyclic alkanes in a torbanite from the Sydney Basin(Australia)were successfully isolated from its extracts using preparative gas chromatography and analyzed by NMR.Saturat...Individual hydrocarbons identified to be macrocyclic alkanes in a torbanite from the Sydney Basin(Australia)were successfully isolated from its extracts using preparative gas chromatography and analyzed by NMR.Saturated cyclic structures were confirmed by single peaks in the NMR~1H and~(13)C spectra indicating single forms of H and C atoms exist in these biomarker molecules.This is consistent with the methylene unit in a ring system assignment of the macrocyclic alkanes and accounts for a formula of(CH2)n.The unusual molecular structures of these compounds are consistent with those that were identified from previous GC retention index data and co-injection with a standard supports the previous research.The mass spectral fragmentation behaviors of representative cyclic alkanes were further investigated by comparing them with the mass spectra of isolated individual macrocyclic alkanes.The characteristic fragment ions in the macrocyclic alkanes of(M–28)+and base peaks of m/z 97,111,125,etc.,can be assigned as being generated by simple a-/i-cleavage and hydrogen rearrangement.These fragmentation pathways combined with retention indices should assist in differentiating these compounds from monounsaturated alkenes and alkylated monocyclics having similar mass spectral characteristics in other geological samples.展开更多
The hilly area of red soil in the central subtropical region of China has a long history of severe soil erosion due to its abundance of water,heat,and intense agricultural and forestry activities.The Sandshale red soi...The hilly area of red soil in the central subtropical region of China has a long history of severe soil erosion due to its abundance of water,heat,and intense agricultural and forestry activities.The Sandshale red soil area is hot and rainy,the local land utilization rate and replanting index are high,and the soil easily weathers and erodes,resulting in infertile and sandy soils,extensive soil erosion and large erosion,with far-reaching impacts.In this study,the stability of soil aggregates was studied by the wet sieving method and Le Bissonais(LB)method in six land use patterns in the Sandshale red soil area,including natural forest(NF),Pinus massoniana(PM),Eucalyptus urophylla×E.grandis(EU),orchard(OR),wasteland(WL)and arable land(AL).The transport damage characteristics of the soil aggregates under concentrated water flow were analyzed by using the soil aggregates to simulate the soil surface roughness in the field using a steel scouring flume with a variable slope.The results showed that:(1)the total soil porosity of the natural forest was the highest,with 56.51%in A layer,which was 4.99%higher than the B layer,and the organic matter content ranged from 10.69 to 29.94 g.kg-1 and was highest in NF and lowest in AL;(2)the maximum mean weight diameter(MWD)obtained by the wet sieving method was 4.81 mm for natural forest,and the MWD was the lowest in OR and AL at 2.45-2.77mm.The MWD measured by the LB method was also highest in NF and lowest in AL.The contents of Fed and Ald have a strong correlation with the stability parameters of soil aggregates;(3)the Wr/Wi results for the six land use patterns were NF>PM>EU>WL>OR>AL;the NF had the strongest soil aggregate stability,followed by WL,PM and EU,and AL and OR had the weakest;the stability of soil aggregates gradually weakened as the soil depth increased.Comprehensive analysis shows that forest land has high soil stability and obvious advantages in soil erosion resistance.Strengthening the construction of artificial forests can be an important means to reduce soil erosion in red soil hilly region.展开更多
This study investigated the failure mechanism associated with the rock mass structure and the dynamic fragmentation process of blocky rocks of the 2018 Daanshan rockslide that occurred on 11 August,2018.It was found t...This study investigated the failure mechanism associated with the rock mass structure and the dynamic fragmentation process of blocky rocks of the 2018 Daanshan rockslide that occurred on 11 August,2018.It was found that the initially collapsed rock of this rockslide was partitioned along the unconformity and strata interfaces.We analyzed how the unique rock mass structure,coupled with the road cut and the antecedent rainfall,jointly resulted in its failure.Based on the rock types and geological structures,the initial stratified configuration of a discrete element model was setup to reveal the influences of the local structure.The numerical model was divided into three parts.Part 1 is the basalt of the Nandaling Formation,the normal and shear stiffnesses of the basalt particles are set as 80 MPa and 40 MPa.Parts 2 and 3 are the sandstones interbedded with mudstone and sandstone of the Shihezi Formation,and the normal and shear stiffnesses of these parts were set as 6 MPa and 10 MPa,respectively.The dynamic process of the rockslide,particularly the rock fragmentation process,was numerically analyzed using a 3D discrete element method.The numerical results were compared with real-time videos and field investigations.The results show that the rock fragmentation and the final deposition range match well with the real disaster phenomenon,and the calculation accuracy of the rockslide reaches 82.41%.Moreover,a parameter sensitivity analysis was conducted,and classical uniform models under different bonding forces were established;the stratified model can better restore the true state of the fragmentation,movement,and deposition processes of rockslides.Therefore,for complicated rocks with significant differences in lithology,clarifying the rock mass stratigraphy is essential for an accurate reconstruction of the dynamic process of rockslides.展开更多
Virginia Woolf’s seventh novel,The Waves,first published by the Hogarth Press in 1931,is widely regarded as her most experimental piece of writing.The complex and elusive structure of the work,the least representatio...Virginia Woolf’s seventh novel,The Waves,first published by the Hogarth Press in 1931,is widely regarded as her most experimental piece of writing.The complex and elusive structure of the work,the least representational among Woolf’s novels,challenges the reader’s assumptions about the inner and the outer world.In the absence of a substantial story,of a convincing plot and well-defined characters,the reader is called upon to search for a deeper coherence and more profound meanings.Indeed,in The Waves the modernist writer strives for a fresh way of expressing a vision of wholeness in a broken world.The present article attempts to reread Woolf’s self-conscious novel in the double perspective of separation and reunion,of dispersal and recomposition.A close reading of selected passages will show how the poetics of fragmentation and the poetics of wholeness coexist in Woolf’s narrative,pervading the imagery and the symbols of the text.In more than one sense,the dialectic between division and unity,fragmentation and wholeness can be identified as the structuring force of the novel;most tellingly,this textual dynamism is reflected in the oscillatory motion of the waves,continuously breaking and merging.展开更多
An in-depth understanding of the fracture behavior and mechanism of metallic shells under internal explosive loading can help develop material designs for warheads and regulate the quantity and mass distribution of th...An in-depth understanding of the fracture behavior and mechanism of metallic shells under internal explosive loading can help develop material designs for warheads and regulate the quantity and mass distribution of the fragments formed.This study investigated the fragmentation performance of a new high-carbon silicon-manganese(HCSiMn)steel cylindrical shell through fragment recovery experiments.Compared with the conventional 45Cr steel shell,the number of small mass fragments produced by the HCSi Mn steel shell was significantly increased with a scale parameter of 0.57 g fitted by the Weibull distribution model.The fragmentation process of the HCSi Mn shell exhibited more brittle tensile fracture characteristics,with the microcrack damage zone on the outer surface being the direct cause of its high fragmentation.On the one hand,the doping of alloy elements resulted in grain refinement by forming metallographic structure of tempered sorbite,so that microscopic intergranular fracture reduces the characteristic mass of the fragments;on the other hand,the distribution of alloy carbides can exert a"pinning"effect on the substrate grains,causing more initial cracks to form and propagate along the brittle carbides,further improving the shell fragmentation.Although the killing power radius for light armored vehicles was slightly reduced by about 6%,the dense killing radius of HCSiMn steel projectile against personnel can be significantly increased by about 26%based on theoretical assessment.These results provided an experimental basis for high fragmentation warhead design,and to some extent,revealed the correlation mechanism between metallographic structure and shell fragmentation.展开更多
Transfer RNA-derived small RNAs(tsRNAs)have been shown to be involved in early embryo development and repression of endogenous retroelements in embryos and stem cells.However,it is unknown whether tsRNAs also regulate...Transfer RNA-derived small RNAs(tsRNAs)have been shown to be involved in early embryo development and repression of endogenous retroelements in embryos and stem cells.However,it is unknown whether tsRNAs also regulate embryo hatching.In this study,we mined the sequencing data of a previous experiment in which we demonstrated that the microRNA(miRNA)cargo of preimplantation embryonic extracellular vesicles(EVs)influences embryo development.We thus profiled the tsRNA cargo of EVs secreted by blastocysts and non-blastocysts.The majority of tsRNAs was identified as tRNA halves originating from the 5'ends of tRNAs.Among the 148 differentially expressed tsRNAs,the 19 nt tRNA fragment(tRF)tDR-14:32-Glu-CTC-1 was found to be significantly up-regulated in EVs derived from non-blastocysts.RT-qPCR assays confirmed its significant up-regulation in non-blastocyst embryos and their conditioned medium compared to the blastocyst group(P<0.05).Inhibition of tDR-14:32-Glu-CTC-1 by supplementing antagomirs to the conditioned medium improved embryo hatching(P<0.05).Transcriptomic analysis of embryos treated with tDR-14:32-Glu-CTC-1 antagomirs further showed differential expression of genes that are associated with embryo hatching and implantation.In summary,tDR-14:32-Glu-CTC-1 is up-regulated in non-blastocyst embryos and their secretions,and inhibition of tDR-14:32-Glu-CTC-1 promotes embryo hatching,while influencing embryo implantation-related genes and pathways.These results indicate that embryonic EVs containing specific tRFs may regulate preimplantation embryo development.展开更多
基金Projects(42177164,52474121)supported by the National Science Foundation of ChinaProject(PBSKL2023A12)supported by the State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,China。
文摘In the mining industry,precise forecasting of rock fragmentation is critical for optimising blasting processes.In this study,we address the challenge of enhancing rock fragmentation assessment by developing a novel hybrid predictive model named GWO-RF.This model combines the grey wolf optimization(GWO)algorithm with the random forest(RF)technique to predict the D_(80)value,a critical parameter in evaluating rock fragmentation quality.The study is conducted using a dataset from Sarcheshmeh Copper Mine,employing six different swarm sizes for the GWO-RF hybrid model construction.The GWO-RF model’s hyperparameters are systematically optimized within established bounds,and its performance is rigorously evaluated using multiple evaluation metrics.The results show that the GWO-RF hybrid model has higher predictive skills,exceeding traditional models in terms of accuracy.Furthermore,the interpretability of the GWO-RF model is enhanced through the utilization of SHapley Additive exPlanations(SHAP)values.The insights gained from this research contribute to optimizing blasting operations and rock fragmentation outcomes in the mining industry.
基金supported by the National Natural Science Foundation of China(Nos.52034006,52004229,52225401,and 52274231)the Regional Innovation Cooperation Project of Sichuan Province(No.2022YFQ0059)+3 种基金Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(No.2020CX040301)Natural Science Foundation of Sichuan Province(No.2023NSFSC0431)Science and Technology Strategic Cooperation Project between Nanchong City and Southwest Petroleum University(No.SXHZ004)Research and innovation Fund for Graduate Students of Southwest Petroleum University(No.2022KYCX058).
文摘Hydraulic-electric rock fragmentation(HERF)plays a significant role in improving the efficiency of high voltage pulse rock breaking.However,the underlying mechanism of HERF remains unclear.In this study,considering the heterogeneity of the rock,microscopic thermodynamic properties,and shockwave time domain waveforms,based on the shockwave model,digital imaging technology and the discrete element method,the cyclic loading numerical simulations of HERF is achieved by coupling electrical,thermal,and solid mechanics under different formation temperatures,confining pressure,initial peak voltage,electrode bit diameter,and loading times.Meanwhile,the HERF discharge system is conducive to the laboratory experiments with various electrical parameters and the resulting broken pits are numerically reconstructed to obtain the geometric parameters.The results show that,the completely broken area consists of powdery rock debris.In the pre-broken zone,the mineral cementation of the rock determines the transition of type CⅠcracks to type CⅡand type CⅢcracks.Furthermore,the peak pressure of the shockwave increased with initial peak voltage but decreased with electrode bit diameter,while the wave front time reduced.Moreover,increasing well depth,formation temperature and confining pressure augment and inhibit HERF,but once confining pressure surpassed the threshold of 60 MPa for 152.40,215.90,and 228.60 mm electrode bits,and 40 MPa for 309.88 mm electrode bits,HERF is promoted.Additionally,for the same kind of rock,the volume and width of the broken pit increase with higher initial peak voltage and rock fissures will promote HERF.Eventually,the electrode drill bit with a 215.90 mm diameter is more suitable for drilling pink granite.This research contributes to a better microscopic understanding of HERF and provides valuable insights for electrode bit selection,as well as the optimization of circuit parameters for HERF technology.
基金This research was supported by project number(RSP2024R384)King Saud University,Riyadh,Saudi Arabia.
文摘This study comprehensively assessed long-term vegetation changes and forest fragmentation dynamics in the Himalayan temperate region of Pakistan from 1989 to 2019.Four satellite images,including Landsat-5 TM and Landsat-8 Operational Land Imager(OLI),were chosen for subsequent assessments in October 1989,2001,2011 and 2019.The classified maps of 1989,2001,2011 and 2019 were created using the maximum likelihood classifier.Post-classification comparison showed an overall accuracy of 82.5%and a Kappa coefficient of 0.79 for the 2019 map.Results revealed a drastic decrease in closed-canopy and open-canopy forests by 117.4 and 271.6 km^(2),respectively,and an increase in agriculture/farm cultivation by 1512.8 km^(2).The two-way ANOVA test showed statistically significant differences in the area of various cover classes.Forest fragmentation was evaluated using the Landscape Fragmentation Tool(LFT v2.0)between 1989 and 2019.The large forest core(>2.00 km^(2))decreased from 149.4 to 296.7 km^(2),and a similar pattern was observed in medium forest core(1.00-2.00 km^(2))forests.On the contrary,the small core(<1.00 km^(2))forest increased from 124.8 to 145.3 km^(2) in 2019.The perforation area increased by 296.9 km^(2),and the edge effect decreased from 458.9 to 431.7 km^(2).The frequency of patches also increased by 119.1 km^(2).The closed and open canopy classes showed a decreasing trend with an annual rate of 0.58%and 1.35%,respectively.The broad implications of these findings can be seen in the studied region as well as other global ecological areas.They serve as an imperative baseline for afforestation and reforestation operations,highlighting the urgent need for efficient management,conservation,and restoration efforts.Based on these findings,sustainable land-use policies may be put into place that support local livelihoods,protect ecosystem services,and conserve biodiversity.
基金supported by the National Natural Science Foundation of China(Nos.51879184 and 12172253).
文摘Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,Fangshan granite(FG)specimens were exposed to microwave irradiation and heat treatment.The damage of FG specimens induced by these two methods was compared using X-ray CT scanning and ultrasonic wave method.The temperatures of FG after microwave irradiation and thermal treatment were effectively evaluated using a newly proposed technique.A novelty method for precisely determining the geometric features of fragments is developed to estimate the fragmentation energy.Thus,the dynamic uniaxial compressive strength(UCS),the dynamic fragmentation characteristics,and the fragmentation energy of FG after these two pretreatment methods can be reasonably compared.The noticeable distinction of loading rate effect on the dynamic UCS of FG between these two pretreatment methods is first observed.A relationship is established between the dynamic UCS and the damage induced by microwave irradiation and heat treatment.Moreover,fragmentation energy fan analysis is introduced to accurately compare the fragmentation properties of FG after two pretreatment methods in dynamic compression tests.
基金support from the National Key R&D plan(Grant No.2022YFC3004303)the National Natural Science Foundation of China(Grant No.42107161)+3 种基金the State Key Laboratory of Hydroscience and Hydraulic Engineering(Grant No.2021-KY-04)the Open Research Fund Program of State Key Laboratory of Hydroscience and Engineering(sklhse-2023-C-01)the Open Research Fund Program of Key Laboratory of the Hydrosphere of the Ministry of Water Resources(mklhs-2023-04)the China Three Gorges Corporation(XLD/2117).
文摘Rock fragmentation plays a critical role in rock avalanches,yet conventional approaches such as classical granular flow models or the bonded particle model have limitations in accurately characterizing the progressive disintegration and kinematics of multi-deformable rock blocks during rockslides.The present study proposes a discrete-continuous numerical model,based on a cohesive zone model,to explicitly incorporate the progressive fragmentation and intricate interparticle interactions inherent in rockslides.Breakable rock granular assemblies are released along an inclined plane and flow onto a horizontal plane.The numerical scenarios are established to incorporate variations in slope angle,initial height,friction coefficient,and particle number.The evolutions of fragmentation,kinematic,runout and depositional characteristics are quantitatively analyzed and compared with experimental and field data.A positive linear relationship between the equivalent friction coefficient and the apparent friction coefficient is identified.In general,the granular mass predominantly exhibits characteristics of a dense granular flow,with the Savage number exhibiting a decreasing trend as the volume of mass increases.The process of particle breakage gradually occurs in a bottom-up manner,leading to a significant increase in the angular velocities of the rock blocks with increasing depth.The simulation results reproduce the field observations of inverse grading and source stratigraphy preservation in the deposit.We propose a disintegration index that incorporates factors such as drop height,rock mass volume,and rock strength.Our findings demonstrate a consistent linear relationship between this index and the fragmentation degree in all tested scenarios.
基金supported by the National Natural Science Foundation of China(32201429)the College of Landscape Architecture and Art,Northwest A&F University,China.
文摘Tree plantation and forest restoration are the major strategies for enhancing terrestrial carbon sequestration and mitigating climate change.The Grain for Green Project in China has positively impacted global carbon sequestration and the trend towards fragmentation of plantation forests.Limited studies have been conducted on changes in plantation biomass and stand structure caused by fragmentation,and the effect of fragmentation on the carbon storage of plantation forests remains unclear.This study evaluated the differences between carbon storage and stand structure in black locust forests in fragmented and continuous landscape in the Ansai District,China and discussed the effects of ecological significance of four landscape indices on carbon storage and tree density.We used structural equation modelling to explore the direct and indirect effects of fragmentation,edge,abiotic factors,and stand structure on above-ground carbon storage.Diameter at breast height(DBH)in fragmented forests was 53.3%thicker,tree density was 40.9%lower,and carbon storage was 49.8%higher than those in continuous forests;for all given DBH>10 cm,the trees in fragmented forests were shorter than those in continuous forests.The patch area had a negative impact on carbon storage,i.e.,the higher the degree of fragmentation,the lower the density of the tree;and fragmentation and distance to edge(DTE)directly increased canopy coverage.However,canopy coverage directly decreased carbon storage,and fragmentation directly increased carbon storage and tree density.In non-commercial forests,fragmentation reduces the carbon storage potential of plantation,and the influence of patch area,edge,and patchy connection on plantation should be considered when follow-up trees are planted and for the plantation management.Thus,expanding the area of plantation patches,repairing the edges of complex-shaped patches,enhancing the connectivity of similar patches,and applying nutrients to plantation forests at regular intervals are recommended in fragmented areas of the Loess Plateau.
文摘This report provides an overall assessment of land fragmentation problems in East Africa. Many parts of East Africa have become highly fragmented, putting development systems and activities in these areas at risk of complete collapse. Land fragmentation occurs when land gets converted for agriculture, industrialization, or urbanization, invaded by non-local plants, or enclosed for individual use and by subdividing farmlands into subsequent smaller units called parcels with varying average farm sizes. Fragmentation results from inappropriate agricultural development processes and ineffective land use planning that fails to recognize how farmland is used, and the importance of its interconnected areas. Insecurity of tenure and resource rights are key factors in making this possible. Land fragmentation is one of the key reasons why the ability of most resources in East Africa becomes scarcer, and those remaining become “privatized” by more powerful community members—keen to maintain their access to them. Such individualistic attitudes are new and disadvantage the poorest even further by affecting the traditional customary safety nets and agricultural outputs. Neither the government nor customary governance systems effectively protect resource access for the poorest. This review summary report identifies the key causes, measures, and implications, government interventions, and the common remedies to land fragmentation problems in the East African Countries of Kenya, Uganda, Rwanda, and Tanzania including neighboring Ethiopia, and the Sudan. The findings indicated from 2005 to 2015, the population kept increasing for all the named countries in East Africa with Rwanda and Uganda having a substantial increase in population density. The study review further explores the trend in the performance of agriculture by average farm sizes within the intervals of five years by highlighting their strong linkages and found that the average farm size has declined drastically, especially for Kenya. This can only mean that small farms kept becoming smaller and smaller and that there were more small-scale farmers. The results further depicted that the major and commonly cultivated food crops among the East African countries include maize, sorghum, rice, cassava, sweet potatoes, bananas, Irish potatoes, beans, peas, etc., with maize yields (Mt/ha) in 2003 for Uganda being the highest (1.79 Mt/ha) and the lowest in Rwanda (0.77 Mt/ha) respectively. Therefore, from the review results, recommendations are being made as to how the negative impacts of land fragmentation on agricultural productivity can be reduced or mitigated. One way is by community sensitization and awareness about the importance of land consolidation and its proposition on farm productivity.
基金the National Natural Science Foundation of China(Nos.12375123,11975091,and 12305130)the Natural Science Foundation of Henan Province(No.242300421048)+1 种基金China Postdoctoral Science Foundation(No.2023M731016)Henan Postdoctoral Foundation(No.HN2022164).
文摘Neutron-skin thickness is a key parameter for a neutron-rich nucleus;however,it is difficult to determine.In the framework of the Lanzhou Quantum Molecular Dynamics(LQMD)model,a possible probe for the neutron-skin thickness(δ_(np))of neutron-rich ^(48)Ca was studied in the 140A MeV ^(48)Ca+^(9)Be projectile fragmentation reaction based on the parallel momentum distribution(p∥)of the residual fragments.A Fermi-type density distribution was employed to initiate the neutron density distributions in the LQMD simulations.A combined Gaussian function with different width parameters for the left side(Γ_(L))and the right side(Γ_(R))in the distribution was used to describe the p∥of the residual fragments.Taking neutron-rich sulfur isotopes as examples,Γ_(L) shows a sensitive correlation withδ_(np) of ^(48)Ca,and is proposed as a probe for determining the neutron skin thickness of the projectile nucleus.
文摘Objective:To determine the relationship between teratozoospermia and sperm DNA fragmentation(SDF)in the human ejaculate.Methods:This retrospective study included 100 normozoospermic men as a control cohort(abnormal forms>14%),210 patients with a high level of abnormal forms(≤4%)and 65 patients presenting with a moderate level of abnormal forms(>4%to≤14%)based on the World Health Organization definitions.Sperm morphology was assessed using bright field microscopy.Sperm DNA fragmentation was assessed using the sperm chromatin dispersion assay.Non-parametric analyses were conducted to examine the relationship between abnormal sperm morphology and sperm DNA fragmentation;receiver operating characteristic(ROC)analyses were conducted to assess sensitivity and specificity of this relationship.Results:A correlation analysis revealed that the higher the proportion of abnormal spermatozoa in the ejaculate,the higher the level of SDF(Spearman's Rho=-0.230;P<0.001).Significant differences in the proportion of SDF were found when all cohorts were compared(P<0.001);these significant differences were also retained when the different cohorts were compared pairwise.ROC analysis showed a moderate but significant predictive value for SDF to differentiate patients with different levels of teratozoospemia.Conclusions:Although analysis of a more continuous range of values for teratozoospermia would help further clarify any causal relationship with SDF,there is clearly a synergistic or coincident affiliation between these variables that needs to be acknowledged by the clinician when interpreting the spermiogram.
基金the Natural Science Foundation of China(Grant No.41790425).
文摘Landscape fragmentation is generally viewed as an indicator of environmental stresses or risks,but the fragmentation intensity assessment also depends on the scale of data and the definition of spatial unit.This study aimed to explore the scale-dependence of forest fragmentation intensity along a moisture gradient in Yinshan Mountain of North China,and to estimate environmental sensitivity of forest fragmentation in this semi-arid landscape.We developed an automatic classification algorithm using simple linear iterative clustering(SLIC)and Gaussian mixture model(GMM),and extracted tree canopy patches from Google Earth images(GEI),with an accuracy of 89.2%in the study area.Then we convert the tree canopy patches to forest category according to definition of forest that tree density greater than 10%,and compared it with forest categories from global land use datasets,FROM-GLC10 and GlobeLand30,with spatial resolutions of 10 m and 30 m,respectively.We found that the FROM-GLC10 and GlobeLand30 datasets underestimated the forest area in Yinshan Mountain by 16.88%and 21.06%,respectively;and the ratio of open forest(OF,10%<tree coverage<40%)to closed forest(CF,tree coverage>40%)areas in the underestimated part was 2:1.The underestimations concentrated in warmer and drier areas occupied mostly by large coverage of OFs with severely fragmented canopies.Fragmentation intensity of canopies positively correlated with spring temperature while negatively correlated with summer precipitation and terrain slope.When summer precipitation was less than 300 mm or spring temperature higher than 4℃,canopy fragmentation intensity rose drastically,while the forest area percentage kept stable.Our study suggested that the spatial configuration,e.g.,sparseness,is more sensitive to drought stress than area percentage.This highlights the importance of data resolution and proper fragmentation measurements for forest patterns and environmental interpretation,which is the base of reliable ecosystem predictions with regard to the future climate scenarios.
基金Supported by the National Key Research and Development Program of China(No.2021YFB2401204)。
文摘As edge computing services soar,the problem of resource fragmentation situation is greatly worsened in elastic optical networks(EON).Aimed to solve this problem,this article proposes the fragmentation prediction model that makes full use of the gate recurrent unit(GRU)algorithm.Based on the fragmentation prediction model,one virtual optical network mapping scheme is presented for edge computing driven EON.With the minimum of fragmentation degree all over the whole EON,the virtual network mapping can be successively conducted.Test results show that the proposed approach can reduce blocking rate,and the supporting ability for virtual optical network services is greatly improved.
文摘Spontaneous combustion of coal increases the temperature in adjoining overburden strata of coal seams and poses a challenge when loading blastholes.This condition,known as hot-hole blasting,is dangerous due to the increased possibility of premature explosions in loaded blastholes.Thus,it is crucial to load the blastholes with an appropriate amount of explosives within a short period to avoid premature detonation caused by high temperatures of blastholes.Additionally,it will help achieve the desired fragment size.This study tried to ascertain the most influencial variables of mean fragment size and their optimum values adopted for blasting in a fiery seam.Data on blast design,rock mass,and fragmentation of 100 blasts in fiery seams of a coal mine were collected and used to develop mean fragmentation prediction models using soft computational techniques.The coefficient of determination(R^(2)),root mean square error(RMSE),mean absolute error(MAE),mean square error(MSE),variance account for(VAF)and coefficient of efficiency in percentage(CE)were calculated to validate the results.It indicates that the random forest algorithm(RFA)outperforms the artificial neural network(ANN),response surface method(RSM),and decision tree(DT).The values of R^(2),RMSE,MAE,MSE,VAF,and CE for RFA are 0.94,0.034,0.027,0.001,93.58,and 93.01,respectively.Multiple parametric sensitivity analyses(MPSAs)of the input variables showed that the Schmidt hammer rebound number and spacing-to-burden ratio are the most influencial variables for the blast fragment size.The analysis was finally used to define the best blast design variables to achieve optimum fragment size from blasting.The optimum factor values for RFA of S/B,ld/B and ls/ld are 1.03,1.85 and 0.7,respectively.
基金support of National Natural Science Foundation of China(No.52177144)。
文摘High-voltage pulse discharge(HVPD)rock fragmentation controls a plasma channel forming inside the rock by adjusting the electrical parameters,electrode type,etc.In this work,an HVPD rock fragmentation test platform was built and the test waveforms were measured.Considering the effects of temperature,channel expansion and electromagnetic radiation,the impedance model of the plasma channel in the rock was established.The parameters and initial values of the model were determined by an iterative computational process.The model calculation results can reasonably characterize the development of the plasma channel in the rock and estimate the shock wave characteristics.Based on the plasma channel impedance model,the temporal and spatial distribution characteristics of the radial stress and tangential stress in the rock were calculated,and the rock fragmentation effect of the HVPD was analyzed.
基金funding through the LightForm program grant EP/R001715/1
文摘A simple finite element implementation of the Mott model for fragmentation of a thin walled ring has been implemented and used to explore the effect of local variations in fracture strain around the ring.The model has successfully reproduced the fragment size distributions previously reported,which follow a characteristic“Mott distribution”form,providing sufficient(1000)simulations are run.It has been shown that this form is retained even when there are large differences in the random distribution of fracture strains or a different choice of function used to describe the fracture strain scatter.In these cases,the strain rate has a much stronger effect than fracture strain distribution the on the average fragment size and fragment distribution.However,for cases where there are a small number of local defects that strongly reduce the fracture strain at certain locations around the ring,the predicted fragment size distribution develops a bimodal character.This is also the case for large but gradual variations in fracture strain with position around the ring.The results have implications for cases where a small number of large pre-existing defects exist,or processing has led to macrozones in the microstructure.The utility of a simple fast running model to study these cases is discussed.
基金the financial support from The Strategic Priority Research Program of the Chinese Academy of Sciences(XDA14010102)Chinese National Science Foundation grants(4197306941673045)。
文摘Individual hydrocarbons identified to be macrocyclic alkanes in a torbanite from the Sydney Basin(Australia)were successfully isolated from its extracts using preparative gas chromatography and analyzed by NMR.Saturated cyclic structures were confirmed by single peaks in the NMR~1H and~(13)C spectra indicating single forms of H and C atoms exist in these biomarker molecules.This is consistent with the methylene unit in a ring system assignment of the macrocyclic alkanes and accounts for a formula of(CH2)n.The unusual molecular structures of these compounds are consistent with those that were identified from previous GC retention index data and co-injection with a standard supports the previous research.The mass spectral fragmentation behaviors of representative cyclic alkanes were further investigated by comparing them with the mass spectra of isolated individual macrocyclic alkanes.The characteristic fragment ions in the macrocyclic alkanes of(M–28)+and base peaks of m/z 97,111,125,etc.,can be assigned as being generated by simple a-/i-cleavage and hydrogen rearrangement.These fragmentation pathways combined with retention indices should assist in differentiating these compounds from monounsaturated alkenes and alkylated monocyclics having similar mass spectral characteristics in other geological samples.
基金financial support for the research provided by the National Natural Science Foundation of China(No.42107350)the Special Projects of the Central Government Guiding Local Science and Technology Development in China(Guike.ZY21195022)the National Natural Science Foundation of China(No.42007055)。
文摘The hilly area of red soil in the central subtropical region of China has a long history of severe soil erosion due to its abundance of water,heat,and intense agricultural and forestry activities.The Sandshale red soil area is hot and rainy,the local land utilization rate and replanting index are high,and the soil easily weathers and erodes,resulting in infertile and sandy soils,extensive soil erosion and large erosion,with far-reaching impacts.In this study,the stability of soil aggregates was studied by the wet sieving method and Le Bissonais(LB)method in six land use patterns in the Sandshale red soil area,including natural forest(NF),Pinus massoniana(PM),Eucalyptus urophylla×E.grandis(EU),orchard(OR),wasteland(WL)and arable land(AL).The transport damage characteristics of the soil aggregates under concentrated water flow were analyzed by using the soil aggregates to simulate the soil surface roughness in the field using a steel scouring flume with a variable slope.The results showed that:(1)the total soil porosity of the natural forest was the highest,with 56.51%in A layer,which was 4.99%higher than the B layer,and the organic matter content ranged from 10.69 to 29.94 g.kg-1 and was highest in NF and lowest in AL;(2)the maximum mean weight diameter(MWD)obtained by the wet sieving method was 4.81 mm for natural forest,and the MWD was the lowest in OR and AL at 2.45-2.77mm.The MWD measured by the LB method was also highest in NF and lowest in AL.The contents of Fed and Ald have a strong correlation with the stability parameters of soil aggregates;(3)the Wr/Wi results for the six land use patterns were NF>PM>EU>WL>OR>AL;the NF had the strongest soil aggregate stability,followed by WL,PM and EU,and AL and OR had the weakest;the stability of soil aggregates gradually weakened as the soil depth increased.Comprehensive analysis shows that forest land has high soil stability and obvious advantages in soil erosion resistance.Strengthening the construction of artificial forests can be an important means to reduce soil erosion in red soil hilly region.
基金funded by the Strategic Priority Research Program of CAS(Grant No.XDA23090303)the NSFC(Grant No.42022054)+1 种基金Sichuan Science and Technology Program(Grant No.2022YFS0543)the Science Foundation for Distinguished Young Scholars of Sichuan Province(Grant No.2020JDJQ0044)State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Independent Research Project(SKLGP2019Z013).
文摘This study investigated the failure mechanism associated with the rock mass structure and the dynamic fragmentation process of blocky rocks of the 2018 Daanshan rockslide that occurred on 11 August,2018.It was found that the initially collapsed rock of this rockslide was partitioned along the unconformity and strata interfaces.We analyzed how the unique rock mass structure,coupled with the road cut and the antecedent rainfall,jointly resulted in its failure.Based on the rock types and geological structures,the initial stratified configuration of a discrete element model was setup to reveal the influences of the local structure.The numerical model was divided into three parts.Part 1 is the basalt of the Nandaling Formation,the normal and shear stiffnesses of the basalt particles are set as 80 MPa and 40 MPa.Parts 2 and 3 are the sandstones interbedded with mudstone and sandstone of the Shihezi Formation,and the normal and shear stiffnesses of these parts were set as 6 MPa and 10 MPa,respectively.The dynamic process of the rockslide,particularly the rock fragmentation process,was numerically analyzed using a 3D discrete element method.The numerical results were compared with real-time videos and field investigations.The results show that the rock fragmentation and the final deposition range match well with the real disaster phenomenon,and the calculation accuracy of the rockslide reaches 82.41%.Moreover,a parameter sensitivity analysis was conducted,and classical uniform models under different bonding forces were established;the stratified model can better restore the true state of the fragmentation,movement,and deposition processes of rockslides.Therefore,for complicated rocks with significant differences in lithology,clarifying the rock mass stratigraphy is essential for an accurate reconstruction of the dynamic process of rockslides.
文摘Virginia Woolf’s seventh novel,The Waves,first published by the Hogarth Press in 1931,is widely regarded as her most experimental piece of writing.The complex and elusive structure of the work,the least representational among Woolf’s novels,challenges the reader’s assumptions about the inner and the outer world.In the absence of a substantial story,of a convincing plot and well-defined characters,the reader is called upon to search for a deeper coherence and more profound meanings.Indeed,in The Waves the modernist writer strives for a fresh way of expressing a vision of wholeness in a broken world.The present article attempts to reread Woolf’s self-conscious novel in the double perspective of separation and reunion,of dispersal and recomposition.A close reading of selected passages will show how the poetics of fragmentation and the poetics of wholeness coexist in Woolf’s narrative,pervading the imagery and the symbols of the text.In more than one sense,the dialectic between division and unity,fragmentation and wholeness can be identified as the structuring force of the novel;most tellingly,this textual dynamism is reflected in the oscillatory motion of the waves,continuously breaking and merging.
基金funded by the National Natural Science Foundation of China (Grant Nos.12302444 and 12202349)。
文摘An in-depth understanding of the fracture behavior and mechanism of metallic shells under internal explosive loading can help develop material designs for warheads and regulate the quantity and mass distribution of the fragments formed.This study investigated the fragmentation performance of a new high-carbon silicon-manganese(HCSiMn)steel cylindrical shell through fragment recovery experiments.Compared with the conventional 45Cr steel shell,the number of small mass fragments produced by the HCSi Mn steel shell was significantly increased with a scale parameter of 0.57 g fitted by the Weibull distribution model.The fragmentation process of the HCSi Mn shell exhibited more brittle tensile fracture characteristics,with the microcrack damage zone on the outer surface being the direct cause of its high fragmentation.On the one hand,the doping of alloy elements resulted in grain refinement by forming metallographic structure of tempered sorbite,so that microscopic intergranular fracture reduces the characteristic mass of the fragments;on the other hand,the distribution of alloy carbides can exert a"pinning"effect on the substrate grains,causing more initial cracks to form and propagate along the brittle carbides,further improving the shell fragmentation.Although the killing power radius for light armored vehicles was slightly reduced by about 6%,the dense killing radius of HCSiMn steel projectile against personnel can be significantly increased by about 26%based on theoretical assessment.These results provided an experimental basis for high fragmentation warhead design,and to some extent,revealed the correlation mechanism between metallographic structure and shell fragmentation.
基金supported by Ghent University(Grant:Bijzonder Onderzoeksfonds Geconcerteerde Onderzoeksactie 2018000504[GOA030-18 BOF])supported by Ghent University:BOF.STG.2022.02.0034.01+1 种基金supported by China Scholarship Council:Grant 202006910034supported by Fonds Wetenschappelijk Onderzoek:Grant 1228821N and 12A2H24N。
文摘Transfer RNA-derived small RNAs(tsRNAs)have been shown to be involved in early embryo development and repression of endogenous retroelements in embryos and stem cells.However,it is unknown whether tsRNAs also regulate embryo hatching.In this study,we mined the sequencing data of a previous experiment in which we demonstrated that the microRNA(miRNA)cargo of preimplantation embryonic extracellular vesicles(EVs)influences embryo development.We thus profiled the tsRNA cargo of EVs secreted by blastocysts and non-blastocysts.The majority of tsRNAs was identified as tRNA halves originating from the 5'ends of tRNAs.Among the 148 differentially expressed tsRNAs,the 19 nt tRNA fragment(tRF)tDR-14:32-Glu-CTC-1 was found to be significantly up-regulated in EVs derived from non-blastocysts.RT-qPCR assays confirmed its significant up-regulation in non-blastocyst embryos and their conditioned medium compared to the blastocyst group(P<0.05).Inhibition of tDR-14:32-Glu-CTC-1 by supplementing antagomirs to the conditioned medium improved embryo hatching(P<0.05).Transcriptomic analysis of embryos treated with tDR-14:32-Glu-CTC-1 antagomirs further showed differential expression of genes that are associated with embryo hatching and implantation.In summary,tDR-14:32-Glu-CTC-1 is up-regulated in non-blastocyst embryos and their secretions,and inhibition of tDR-14:32-Glu-CTC-1 promotes embryo hatching,while influencing embryo implantation-related genes and pathways.These results indicate that embryonic EVs containing specific tRFs may regulate preimplantation embryo development.