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Transient multi-physics behavior of an insert high temperature superconducting no-insulation coil in hybrid superconducting magnets with inductive coupling 被引量:1
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作者 Xiang KANG Yujin TONG +1 位作者 Wei WU Xingzhe WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第2期255-272,共18页
A transient multi-physics model incorporated with an electromagneto-thermomechanical coupling is developed to capture the multi-field behavior of a single-pancake(SP)insert no-insulation(NI)coil in a hybrid magnet dur... A transient multi-physics model incorporated with an electromagneto-thermomechanical coupling is developed to capture the multi-field behavior of a single-pancake(SP)insert no-insulation(NI)coil in a hybrid magnet during the charging and discharging processes.The coupled problem is resolved by means of the finite element method(FEM)for the magneto-thermo-elastic behaviors and the Runge-Kutta method for the transient responses of the electrical circuits of the hybrid superconducting magnet system.The results reveal that the transient multi-physics responses of the insert NI coil primarily depend on the charging/discharging procedure of the hybrid magnet.Moreover,a reverse azimuthal current and a compressive hoop stress are induced in the insert NI coil during the charging process,while a forward azimuthal current and a tensile hoop stress are observed during the discharging process.The induced voltages in the insert NI coil can drive the currents flowing across the radial turns where the contact resistance exists.Therefore,it brings forth significant Joule heat,causing a temperature rise and a uniform distribution of this heat in the coil turns.Accordingly,a thermally/mechanically unstable or quenching event may be encountered when a high operating current is flowing in the insert NI coil.It is numerically predicted that a quick charging will induce a compressive hoop stress which may bring a risk of buckling instability in the coil,while a discharging will not.The simulations provide an insight of hybrid superconducting magnets under transient start-up or shutdown phases which are inevitably encountered in practical applications. 展开更多
关键词 hybrid superconducting magnet high temperature superconducting(HTS)no-insulation(NI)coil inductive coupling multi-physics field thermal stability
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Electromagnetic interference assessment of a train-network-pipeline coupling system based on a harmonic transmission model
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作者 Minwu Chen Jinyu Zhao +2 位作者 Zongyou Liang Xin Gong Yu Cao 《Railway Engineering Science》 2023年第4期396-410,共15页
The harmonics and resonance of traction power supply systems(TPSSs)aggravate the electromagnetic interference(EMI)to adjacent metallic pipelines(MPs),which has aroused widespread concern.In this paper,an evaluation me... The harmonics and resonance of traction power supply systems(TPSSs)aggravate the electromagnetic interference(EMI)to adjacent metallic pipelines(MPs),which has aroused widespread concern.In this paper,an evaluation method on pipeline interference voltage under harmonic induction is presented.The results show that the Carson integral formula is more accurate in calculating the mutual impedance at higher frequencies.Then,an integrated train-network-pipeline model is established to estimate the influences of harmonic distortion and resonance on an MP.It is revealed that the higher the harmonic cur-rent distortion rate of the traction load,the larger the interference voltage on an MP.Particularly,the interference voltage is amplified up to 7 times when the TPSS resonates,which is worthy of attention.In addition,the parameters that affect the variation and sensitivity of the interference voltage are studied,namely,the pipeline coating material,locomotive position,and soil resistivity,indicating that soil resistivity and 3PE(3-layer polyethylene)anticorrosive coating are more sensitive to harmonic induction.Field test results show that the harmonic distortion can make the interference voltage more serious,and the protective measures are optimized. 展开更多
关键词 Induced voltage Inductive coupling Conductive coupling Harmonic resonance Electromagnetic interference
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Effect of coil and chamber structure on plasma radial uniformity in radio frequency inductively coupled plasma
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作者 赵洋 周晓华 +2 位作者 高升荣 宋莎莎 赵玉真 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期58-66,共9页
Enhancing plasma uniformity can be achieved by modifying coil and chamber structures in radio frequency inductively coupled plasma(ICP)to meet the demand for large-area and uniformly distributed plasma in industrial m... Enhancing plasma uniformity can be achieved by modifying coil and chamber structures in radio frequency inductively coupled plasma(ICP)to meet the demand for large-area and uniformly distributed plasma in industrial manufacturing.This study utilized a two-dimensional self-consistent fluid model to investigate how different coil configurations and chamber aspect ratios affect the radial uniformity of plasma in radio frequency ICP.The findings indicate that optimizing the radial spacing of the coil enhances plasma uniformity but with a reduction in electron density.Furthermore,optimizing the coil within the ICP reactor,using the interior point method in the Interior Point Optimizer significantly enhances plasma uniformity,elevating it from 56%to 96%within the range of the model sizes.Additionally,when the chamber aspect ratio k changes from 2.8 to 4.7,the plasma distribution changes from a center-high to a saddleshaped distribution.Moreover,the plasma uniformity becomes worse.Finally,adjusting process parameters,such as increasing source power and gas pressure,can enhance plasma uniformity.These findings contribute to optimizing the etching process by improving plasma radial uniformity. 展开更多
关键词 inductively coupled plasma fluid simulation optimized coil chamber aspect ratio plasma uniformity
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Power transfer efficiency in an air-breathing radio frequency ion thruster
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作者 黄高煌 李宏 +1 位作者 高飞 王友年 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第7期430-438,共9页
Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit mission... Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit missions due to its high specific impulse and efficiency. In this paper, the power transfer efficiency of the radio frequency ion thruster with different gas compositions is studied experimentally, which is obtained by measuring the radio frequency power and current of the antenna coil with and without discharge operation. The results show that increasing the turns of antenna coils can effectively improve the radio frequency power transfer efficiency, which is due to the improvement of Q factor. In pure N_2 discharge,with the increase of radio frequency power, the radio frequency power transfer efficiency first rises rapidly and then exhibits a less steep increasing trend. The radio frequency power transfer efficiency increases with the increase of gas pressure at relatively high power, while declines rapidly at relatively low power. In N_(2)/O_(2) discharge, increasing the N_(2) content at high power can improve the radio frequency power transfer efficiency, but the opposite was observed at low power. In order to give a better understanding of these trends, an analytic solution in limit cases is utilized, and a Langmuir probe was employed to measure the electron density. It is found that the evolution of radio frequency power transfer efficiency can be well explained by the variation of plasma resistance, which is related to the electron density and the effective electron collision frequency. 展开更多
关键词 radio frequency ion thruster inductively coupled plasma power transfer efficiency analytic solution
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ICP-MS测定黄豆中26种无机元素
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作者 段鹏雪 王思媛 +1 位作者 王婷婷 齐刚 《现代食品》 2024年第9期133-137,共5页
本文利用微波消解对黄豆进行前处理,采用电感耦合等离子体质谱法(Inductively Coupled Plasma Mass Spectrometer,ICP-MS)对消解液中26种元素的含量进行测定,对方法的线性、精密度、准确度及质控样品进行验证。结果表明,各元素标准曲线... 本文利用微波消解对黄豆进行前处理,采用电感耦合等离子体质谱法(Inductively Coupled Plasma Mass Spectrometer,ICP-MS)对消解液中26种元素的含量进行测定,对方法的线性、精密度、准确度及质控样品进行验证。结果表明,各元素标准曲线的相关系数均≥0.9990,线性关系良好,检出限为0.000583~0.453000 mg·kg^(-1),相对标准偏差≤5.513%,加标回收率为77%~113%,说明该方法能准确检测黄豆中无机元素,满足日常监测需求。 展开更多
关键词 电感耦合等离子体质谱仪(Inductively Coupled Plasma-Mass Spectrometer ICP-MS) 黄豆 微波消解 无机元素
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Design Method of an Ocean Induction Coupling Chain Communication System that Resists the Multipath Effect of a Seawater Channel
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作者 ZHENG Yu LU Yanfang +1 位作者 FEI Chen LI Hongzhi 《Journal of Ocean University of China》 SCIE CAS CSCD 2021年第1期87-93,共7页
In this study,a mathematical model of multipath channels is established,and the delay parameters of 10-path models are calculated at 300 m.A multipath-channel hardware simulator based on a field programmable gate arra... In this study,a mathematical model of multipath channels is established,and the delay parameters of 10-path models are calculated at 300 m.A multipath-channel hardware simulator based on a field programmable gate array(FPGA)is designed and verified at 100 k Hz,200 k Hz,500 k Hz,1 MHz,and 24 MHz transmission frequencies.According to the characteristics of the ocean induction coupling chain channel,the orthogonal frequency-division multiplexing(OFDM)algorithm parameters are designed by referring to the wireless communication protocol.The appropriate length cyclic prefix(CP)is added in the OFDM symbol to resist the multipath effect of the seawater channel,and the FPGA hardware transceiver based on the OFDM algorithm is realized.The hardware platform of the ocean induction coupling chain communication system is developed to resist the multipath effect of the seawater channel and tested at 24 MHz.The experimental results show that 800 ns is the best CP length for the developed system,which can effectively resist the multipath effect,with a signal-to-noise ratio above 24 d B and a bit error rate below 1%.This study provides a hardware simulation test platform and an effective method to resist the multipath effect of a seawater channel and improve the transmission performance of the seawater channel. 展开更多
关键词 ocean induction coupling chain communication system multipath-channel hardware simulator OFDM FPGA hardware platform
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Numerical simulation and experimental validation of multiphysics field coupling mechanisms for a high power ICP wind tunnel
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作者 喻明浩 王哲 +2 位作者 邱泽洋 吕博 郑博睿 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第6期390-400,共11页
We take the established inductively coupled plasma(ICP) wind tunnel as a research object to investigate the thermal protection system of re-entry vehicles. A 1.2-MW high power ICP wind tunnel is studied through numeri... We take the established inductively coupled plasma(ICP) wind tunnel as a research object to investigate the thermal protection system of re-entry vehicles. A 1.2-MW high power ICP wind tunnel is studied through numerical simulation and experimental validation. The distribution characteristics and interaction mechanism of the flow field and electromagnetic field of the ICP wind tunnel are investigated using the multi-field coupling method of flow, electromagnetic, chemical, and thermodynamic field. The accuracy of the numerical simulation is validated by comparing the experimental results with the simulation results. Thereafter, the wind tunnel pressure, air velocity, electron density, Joule heating rate, Lorentz force, and electric field intensity obtained using the simulation are analyzed and discussed. The results indicate that for the 1.2-MW ICP wind tunnel, the maximum values of temperature, pressure, electron number density, and other parameters are observed during coil heating. The influence of the radial Lorentz force on the momentum transfer is stronger than that of the axial Lorentz force. The electron number density at the central axis and the amplitude and position of the Joule heating rate are affected by the radial Lorentz force. Moreover, the plasma in the wind tunnel is constantly in the subsonic flow state, and a strong eddy flow is easily generated at the inlet of the wind tunnel. 展开更多
关键词 inductively coupled plasma multiphysics field coupling mechanism simulation and experiment
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Inductively Coupling Plasma(ICP) Treatment of Propylene(PP) Surface and Adhesion Improvement
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作者 刘彦君 傅彦培 《Plasma Science and Technology》 SCIE EI CAS CSCD 2009年第6期704-708,共5页
Study on increasing the roughness of the polymer substrate surface to enhance the adhesion with the copper layer in an inductively coupling plasma (ICP) process was carried out. The microstructure of the polymer sub... Study on increasing the roughness of the polymer substrate surface to enhance the adhesion with the copper layer in an inductively coupling plasma (ICP) process was carried out. The microstructure of the polymer substrate surfaces, which were exposed to different kinds of plasma treatment, was identified by scanning electron microscopy(SEM) analysis, peel strength of the copper coating and water surface contact angle. The adhesion of the substrate was largely enhanced by plasma treatment and the copper deposited coating reached a value of 7.68 kgf/m in verifying the adhesion of the copper coating with polymer material. The quality of the line/space 50/50 μm produced in the laboratory was examined by the pressure cooker test and proved to meet the requirement. 展开更多
关键词 inductively coupling plasma (ICP) water contact angle peel strength
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Orthogonal Frequency Division Multiplexing Adaptive Technology for Multinode Users of Seawater Channel Based on Inductively Coupled Mooring Chain
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作者 ZHENG Yu LIU Yingjie +3 位作者 REN Yuanhong FEI Chen ZHANG Shijiang LI Hongzhi 《Journal of Ocean University of China》 SCIE CAS CSCD 2023年第5期1243-1252,共10页
As an important part of buoy-type ocean monitoring systems,the inductively coupled mooring chain solves the problem of data cotransmission through the multinode sensors that it carries,which is significant for the rap... As an important part of buoy-type ocean monitoring systems,the inductively coupled mooring chain solves the problem of data cotransmission through the multinode sensors that it carries,which is significant for the rapid acquisition of fish,hydrology,and other information.This paper is based on a seawater channel transmission model with a depth of 300 m and a bandwidth of 2 MHz.An orthogonal frequency division multiplexing(OFDM)technology is used to overcome the multipath effect of signal transmission on a seawater medium.The adaptive technology is integrated into the OFDM,and an improved joint subcarrier and bit power allocation algorithm is proposed.This algorithm solves the problem of dynamic subcarrier allocation during the cotransmission of underwater multinode user data in seawater channels.The results show that the algorithm complexity can be reduced by 0.18126×10^(-2)s during one complete OFDM system data transmission by the improved greedy algorithm,and a total of 216 bits are transmitted by the OFDM.The normalized channel capacity can be improved by 0.012 bit s^(-1)Hz^(-1).At the bit error ratio(BER)of 10^(-3),the BER performance can be improved by approximately 6 d B.When the numbers of users are 4 and 8,the improved algorithm increases the channel capacity,and the higher the number of users,the more evident the channel capacity improvement effect is.The results of this paper have an important reference value for enhancing the transmission performance of inductively coupled mooring chain underwater multinode data. 展开更多
关键词 inductively coupled mooring chain seawater channel multinode users OFDM adaptive technology
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Fluid simulation of the effect of a dielectric window with high temperature on plasma parameters in inductively coupled plasma
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作者 李娜 韩道满 +3 位作者 张权治 刘旭辉 王英杰 王友年 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第3期51-61,共11页
To maintain the high-density plasma source in inductively coupled plasma(ICP),very high radiofrequency power is often delivered to the antenna,which can heat the dielectric windows near the antenna to high temperature... To maintain the high-density plasma source in inductively coupled plasma(ICP),very high radiofrequency power is often delivered to the antenna,which can heat the dielectric windows near the antenna to high temperature.This high temperature can modulate the plasma characteristics to a large degree.We thus study the effect of dielectric window temperature on plasma parameters in two different ICP structures based on COMSOL software.The distributions of various plasma species are examined at different dielectric window temperatures.The concentration of neutral gas is found to be largely modulated at high dielectric window temperature,which further affects the electron collision probability with neutrals and the electron temperature.However,the electron density profiles are barely affected by the dielectric window temperature,which is mainly concentrated at the center of the reactor due to the fixed power input and pressure. 展开更多
关键词 fluid simulation metastable argon dielectric window temperature inductively coupled plasma
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Mg/Ca,Ba/Ca,and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep,South China Sea
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作者 Jingya CAO Shengxiong YANG +2 位作者 Danling TANG Junxi FENG Jinqiang LIANG 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第2期660-672,共13页
Bivalve shell fossils,cemented by authigenic carbonates,are widely spread in the Haima cold seep,Qiongdongnan Basin of the South China Sea(SCS).In this study,we examined an element profile of Gigantidas platifrons in ... Bivalve shell fossils,cemented by authigenic carbonates,are widely spread in the Haima cold seep,Qiongdongnan Basin of the South China Sea(SCS).In this study,we examined an element profile of Gigantidas platifrons in the Haima cold seeps at a water depth of 1381 m.Based on the scanning electron microscope(SEM)analyses,the prismatic layer and nacreous layer were identified,which are characterized by prismatic structure and stratified structure,respectively.In addition,the profile can be subdivided into two parts:altered and unaltered zones.Laser inductively coupled plasma mass spectrometry(LA-ICP-MS)mapping shows that the element concentrations of the altered zones were influenced by the authigenic carbonate rocks,whereas the element concentrations of unaltered zones remain stable.In-situ X-ray diffraction(XRD)analyses show that the mineral constituent of the prismatic layer is mainly composed of aragonite.Along with the growth profile,Mg/Ca ratios of unaltered zones have minor variations,ranging 0.72-0.97 mmol/mol(mean=0.87 mmol/mol),with estimated temperatures of 3.8-4.1℃,indicating that the temperature of the surrounding seawater remains constant and agree with the measured data of 3.9℃which was conducted by a conductivity-temperature-depth system(CTD).The minor variations of Ba/Ca ratios(0.01-0.06 mmol/mol;mean=0.04 mmol/mol)indicate a relatively stabilized salinity of the surrounding seawater.S/Ca ratios show large variations of 0.04-4.15 mmol/mol(mean=1.37 mmol/mol).S/Ca ratios have regular variations which generally correspond to the variations of the Mg/Ca ratios,highlighting that the S/Ca ratios of bivalve shells show the potential to reflect the growth rate of the Gigantides.However,further studies should be carried out on the understanding of the links between the S/Ca ratios and seepage intensity of cold-seep fluids. 展开更多
关键词 Mg/Ca Ba/Ca and S/Ca ratios laser inductively coupled plasma mass spectrometry(LA-ICPMS) Gigantidas platifrons Haima cold seep South China Sea
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Subcellular Distribution and Chemical Forms of Cadmium in the Medicine Food Homology Plant Platycodon grandiflorum(Jacq.)A.DC.
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作者 Jia An Xiang Wang +7 位作者 Yajiang Jing Jianping Huang Qilong Wang Gang Zhang Jing Gao Liang Peng Wenli Huang Yonggang Yan 《Phyton-International Journal of Experimental Botany》 SCIE 2023年第5期1405-1420,共16页
Although Platycodon grandiflorum(Jacq.)A.DC.is a renowned medicine food homology plant,reports of excessive cadmium(Cd)levels are common,which affects its safety for clinical use and food consumption.To enable its Cd ... Although Platycodon grandiflorum(Jacq.)A.DC.is a renowned medicine food homology plant,reports of excessive cadmium(Cd)levels are common,which affects its safety for clinical use and food consumption.To enable its Cd levels to be regulated or reduced,it is necessary to first elucidate the mechanism of Cd uptake and accumulation in the plant,in addition to its detoxification mechanisms.This present study used inductively couple plasma-mass-spectrometry to analyze the subcellular distribution and chemical forms of Cd in different tissues of P.grandiflorum.The experimental results showed that Cd was mainly accumulated in the roots[predominantly in the cell wall(50.96%-61.42%)],and it was found primarily in hypomobile and hypotoxic forms.The proportion of Cd in the soluble fraction increased after Cd exposure,and the proportion of insoluble phosphate Cd and oxalate Cd increased in roots and leaves,with a higher increase in oxalate Cd.Therefore,it is likely that root retention mechanisms,cell wall deposition,vacuole sequestration,and the formation of low mobility and low toxicity forms are tolerance strategies for Cd detoxification used by P.grandiflorum.The results of this study provide a theoretical grounding for the study of Cd accumulation and detoxification mechanisms in P.grandiflorum,and they can be used as a reference for developing Cd limits and standards for other medicine food homology plants. 展开更多
关键词 CADMIUM Platycodon grandiflorum inductively coupled plasma-mass-spectrometry subcellular distribution chemical forms heavy metal tolerance medicine food homology
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Influence of vacuoles with gas–liquid inclusions on the thermobaric destruction conditions of natural quartz under dynamic heating in an RF-TICP torch system
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作者 苗龙 聂明卿 +7 位作者 Yuri Mihailovich GRISHIN 王晓宇 朱政羲 宋家辉 梁福文 何梓豪 田丰 王宁飞 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第4期138-147,共10页
In the present work,the turbulent mixing process of a polydisperse quartz particle flow with a plasma stream generated by a radio-frequency(RF)inductively coupled plasma torch was numerically studied.The thermobaric s... In the present work,the turbulent mixing process of a polydisperse quartz particle flow with a plasma stream generated by a radio-frequency(RF)inductively coupled plasma torch was numerically studied.The thermobaric stress in the quartz particles under dynamic heating in a heterogeneous plasma flow was determined by a two-stage approximation approach.The effect of the presence of vacuoles in natural quartz on the particle thermobaric destruction conditions was studied.It was found that the equivalent thermal and baric stresses in quartz particles may significantly increase in the presence of vacuoles within a small gas volume fraction.The influence of the regime and energetic working conditions of an RF inductively coupled plasma torch system on the particle thermobaric destruction conditions was examined,and a recommendation was given to promote the degree of thermobaric destruction of quartz particles,which is of substantial importance for improving the overall enrichment efficiency of quartz concentrates. 展开更多
关键词 high purity quartz dynamic heating vacuole with gas–liquid inclusions thermobaric destruction radio-frequency inductively coupled plasma torch
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A fast hybrid simulation approach of ion energy and angular distributions in biased inductively coupled Ar plasmas
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作者 赵明亮 张钰如 +1 位作者 高飞 王友年 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第7期61-71,共11页
In this work,a two-dimensional hybrid model,which consists of a bulk fluid module,a sheath module and an ion Monte-Carlo module,is developed to investigate the modulation of ion energy and angular distributions at dif... In this work,a two-dimensional hybrid model,which consists of a bulk fluid module,a sheath module and an ion Monte-Carlo module,is developed to investigate the modulation of ion energy and angular distributions at different radial positions in a biased argon inductively coupled plasma.The results indicate that when the bias voltage amplitude increases or the bias frequency decreases,the ion energy peak separation width becomes wider.Besides,the widths of the ion energy peaks at the edge of the substrate are smaller than those at the center due to the lower plasma density there,indicating the nonuniformity of the ion energy distribution function(IEDF)along the radial direction.As the pressure increases from 1 to 10 Pa,the discrepancy of the IEDFs at different radial positions becomes more obvious,i.e.the IEDF at the radial edge is characterized by multiple low energy peaks.When a dual frequency bias source is applied,the IEDF exhibits three or four peaks,and it could be modulated efficiently by the relative phase between the two bias frequencies.The results obtained in this work could help to improve the radial uniformity of the IEDF and thus the etching process. 展开更多
关键词 biased inductively coupled plasma 2D hybrid model IEADs
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Application and Development Trends of Spectral Analysis in Draft of Non-Ferrous Metal Standards in China
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作者 Lijun Kuai Huachang Li +1 位作者 Jiemin Liu Shufang Tang 《American Journal of Analytical Chemistry》 2023年第6期239-273,共35页
Spectral analysis was a method of identifying substances, determining their chemical composition and calculating their content based on their spectral characteristics. This paper mainly discussed the application of va... Spectral analysis was a method of identifying substances, determining their chemical composition and calculating their content based on their spectral characteristics. This paper mainly discussed the application of various spectroscopic techniques, mainly including atomic absorption spectrometry (AAS) inductively coupled plasma emission spectrometry (ICP-AES) X-ray fluorescence spectroscopy (XRF) atomic fluorescence spectroscopy (AFS) direct reading spectroscopy (OES) glow discharge emission spectroscopy (GD-OSE) laser-induced breakdown spectroscopy (LIBS), in the formulation of non-ferrous metal standards in China. The AAS method was the most widely used single-element microanalysis method among the non-ferrous metal standards. The ICP-AES method was good at significant advantages in the simultaneous detection of multiple elements. The XRF method was increasingly used in the determination of primary and secondary trace elements due to its simple sample preparation and high efficiency. The AFS was mostly detected by single-element trace analysis. OES GD-OES and LIBS were playing an increasingly important role in the new demand area for non-ferrous metals. This paper discussed matrix elimination, sample digestion, sample preparation, instrument categories and other aspects of some standards, and summarized the advantages of spectral analysis and traditional chemical analysis methods. The new methods of future spectroscopic technology had been illustrated in the process of developing non-ferrous metal standards. 展开更多
关键词 Atomic Absorption Spectroscopy Inductively Coupled Plasma Emission Spectroscopy X-Ray Fluorescence Spectroscopy Atomic Fluorescence Spectroscopy Direct Reading Spectroscopy Glow Discharge Emission Spectroscopy Laser-Induced Breakdown Spectroscopy Non-Ferrous Metals Standard Methods Were Formulated
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不同预处理方法对饲料中微量元素含量测定的影响 被引量:2
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作者 葛亚明 宁红梅 +4 位作者 李敬玺 刘俊伟 安志兴 魏继涛 侯向红 《Animal Husbandry and Feed Science》 CAS 2009年第3期15-18,共4页
[ Objective] To study the effects of different pretreatment methods on determination of microelement in feed and thus find the best pre treatment method for each microetement, t Method] The samples (concentrated feed... [ Objective] To study the effects of different pretreatment methods on determination of microelement in feed and thus find the best pre treatment method for each microetement, t Method] The samples (concentrated feeding stuff and fodder) were pretreated through throe methods, that is, dry incineration method, HNOs HCIO, wetdecomposition method and microwave digestion method. Then the content of seven kinds of mi croelement (AI, Ca, Cu, Fe, Mn, Se and Zn) was determined by inductively coupled plasma atomic emission spectrometer (ICPAES). I Result] These three methods were all suitable for the determination of Cu, Mn and Zn in concentrated feeding stuff and the determination of Cu and Ca in fodder. The content of Cu and Ca was higher in fodder detected by HNO3 HCIO, wetdecomposition method. The microwave digestion method was suitable for the determination of AI and Ca in concentrated feeding stuff and the determination of AI, Fe, Mn and Zn in fodder. The dry incinera tion method was fit for the determination of Fe in concentrated feeding stuff. [ Condusionl The content of different microelements should be deter mined after the feed is treated with different Ioretreatment methods. 展开更多
关键词 Pretreatment methods Determination of microelements Inductively coupled plasma atomic emission spectrometry
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用电感耦合等离子体质谱法测定中草药中的重金属元素 被引量:13
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作者 缪恩铭 张艳红 +3 位作者 王森 施红林 陈章玉 杨光宇 《分析测试学报》 CAS CSCD 北大核心 2007年第z1期184-186,共3页
In this paper,the determination of six heavy metal ions (arsenic,lead,cadmium,chromium,mercury and nickel) in the Chinese Herb by inductively coupled plasma-mass spectrometry (ICP-MS) was studied.The samples were dige... In this paper,the determination of six heavy metal ions (arsenic,lead,cadmium,chromium,mercury and nickel) in the Chinese Herb by inductively coupled plasma-mass spectrometry (ICP-MS) was studied.The samples were digested by nitric acid and hydrogen peroxide in a microwave oven.The Sc,Y,In,Bi were added as internal standards to eliminate the matrix interferences.The results show that most of the relative standard deviations of these trace elements were below 3.5%,the standard recoveries of these elements were in the range of 91%-107%,and the detection limits were in the range of 0.001-0.006 μg·L-1. This method is accurate,rapid,convenience,and can be applied to the determination of arsenic,lead,cadmium,chromium,mercury and nickel in Chinese Herb with good results. 展开更多
关键词 Chinese Herb Heavy metal element Inductively coupled plasma-mass spectrometry
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A Survey of 16 Rare Earth Elements in the Major Foods in China 被引量:29
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作者 JIANG Ding Guo YANG Jie +1 位作者 ZHANG Shuo YANG Da Jin 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2012年第3期267-271,共5页
Objective The aim of this survey was to investigate the level of contamination of the most consumed foods in China with 26 rare earth elements (REEs), and to provide the basic data for establishing and revising food... Objective The aim of this survey was to investigate the level of contamination of the most consumed foods in China with 26 rare earth elements (REEs), and to provide the basic data for establishing and revising food safety standards for REEs. Methods Sixteen REEs in foods were measured by inductively coupled plasma-mass spectrometry (ICP-MS) in the labs of the Centers for Disease Control and Prevention of four provinces and two municipalities, during 2009-2020. Results 2 231 samples were analyzed and 29 221 concentration data of 16 REEs were collected. The REEs levels in the investigated foods varied significantly. The concentrations of cerium (Ce), dysprosium (Dy), yttrium (Y), lanthanum (La), and neodymium (Nd) were relatively high, while the remaining eleven REEs were at low levels. The mean values of total rare earth element oxides (REOs) in cereals, fresh vegetables, fresh aquatic products, fresh meats and eggs varied from 0.052 mg/kg to 0.337 mg/kg. Conclusion 16 REEs in the major foods were at very low contamination levels in the investigated regions. 展开更多
关键词 Rare earth elements FOOD Inductively coupled plasma-mass spectrometry (ICP-MS) China
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电感耦合等离子体质谱测定大气铅污染物
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作者 郑永红 于水 +3 位作者 赵法 宋占军 刘丽萍 郭志英 《分析测试学报》 CAS CSCD 北大核心 2007年第z1期191-192,共2页
Inductively coupled plasma mass spectrometry(ICP-MS) was used to determine the concentration of Pb in atmospheric particulate samples,and the enrichment factor was calculated.The causes of the results were also discus... Inductively coupled plasma mass spectrometry(ICP-MS) was used to determine the concentration of Pb in atmospheric particulate samples,and the enrichment factor was calculated.The causes of the results were also discussed. 展开更多
关键词 Inductively coupled plasma mass spectrometry(ICP-MS) Microwave digestion Enrichment factor
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Quantification of trace amounts of impurities in high purity cobalt by high resolution inductively coupled plasma mass spectrometry 被引量:10
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作者 XIE Hualin HUANG Kelong +1 位作者 NIE Xidu TANG Yougen 《Rare Metals》 SCIE EI CAS CSCD 2007年第3期286-291,共6页
A An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, ... A An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn Sb, Ba, Pt, Au, and Pb) in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCI. The matrix effects because of the presence of excess HCI and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 ].tg·g^-1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results. 展开更多
关键词 high resolution inductively coupled plasma mass spectrometry high purity cobalt trace impurities matrix effect standard addition method
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