In this work, a simulated aircraft fuel tank inerting system has been successfully estab- lished based on a model tank. Experiments were conducted to investigate the influences of different operating parameters on the...In this work, a simulated aircraft fuel tank inerting system has been successfully estab- lished based on a model tank. Experiments were conducted to investigate the influences of different operating parameters on the inerting effectiveness of the system, including flow rate of the inert gas (nitrogen-enriched air), inert gas concentration, fuel load of the tank and different inerting approaches. The experimental results show that under the same operating conditions, the time span of a complete inerting process decreased as the flow rate of inert gas was increased; the time span using the inert gas with 5% oxygen concentration was much longer than that using pure nitrogen; when the fuel tank was inerted using the ullage washing approach, the time span increased as the fuel load was decreased; the ullage washing approach showed the best inerting performance when the time span of a complete inerting process was the evaluation criterion, but when the decrease of dissolved oxygen concentration in the fuel was also considered to characterize the inerting effective- ness, the approach of ullage washing and fuel scrubbing at the same time was the most effective.展开更多
Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generati...Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generation System(GOBIGGS) is a novel technology based on flameless catalytic combustion, and owning to its simple structure and high inerting efficiency, it has received a lot of attentions. The inert gas in the GOBIGGS is mainly comprised of CO2, N2, and O2(hereinafter, Mixed Inert Gas(MIG)), while that in the On-Board Inert Gas Generation System(OBIGGS), which is one of the most widely used fuel tank inerting technologies, is NitrogenEnriched Air(NEA). The solubility of CO2 is nearly 20 times higher than that of N2 in jet fuels,so the inerting capability and performance are definitely disparate if the inert gas is selected as NEA or MIG. An inerting test bench was constructed to compare the inerting capabilities between NEA and MIG. Experimental results reveal that, if ullage washing is adopted, the variations of oxygen concentrations on the ullage and in the fuel are nearly identical no matter the inert gas is NEA or MIG. However, the ullage and dissolved oxygen concentrations of MIG scrubbing are always higher than those of NEA scrubbing.展开更多
The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component ...The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component flowing through the catalytic reactor was derived. The mathematical model of the gas concentration in the gas phase of the fuel tank was established based on the mass conservation equation, and the fuel tank model was verified by performing experiments.The results showed that the fuel type exerts a considerably higher influence on the performance of the oxygen-consuming inerting system compared to the corresponding influence on the hollow fiber membrane system, and the relative magnitude of the inerting rates of the four fuel types is RP5 > RP3 > RP6 > JP8. In addition, a higher catalytic efficiency or fuel load rate corresponds to a higher rate of decrease of the oxygen concentration in the gas phase, and the inerting time is inversely proportional to the suction flow rate of the fan. When different fuels are used, the amount of cooling gas and water released from the inerting system are different. Therefore, the influence of fuel type on the system performance should be extensively considered in the future.展开更多
The dynamic vibration absorber with inerter and grounded stiffness(IGDVA)is used to control a two-scale system subject to a weak periodic perturbation.The vibration suppression effect is remarkable.The amplitude of th...The dynamic vibration absorber with inerter and grounded stiffness(IGDVA)is used to control a two-scale system subject to a weak periodic perturbation.The vibration suppression effect is remarkable.The amplitude of the main system coupled with absorber is significantly reduced,and the high frequency vibration completely disappears.First,through the slow-fast analysis and stability theory,it is found that the stability of the autonomous system exerts a notable regulating effect on the vibration response of the non-autonomous system.After adding the dynamic vibrator absorber,the center in the autonomous system changes to an asymptotically stable focus,consequently suppressing the vibration in the non-autonomous system.Further research reveals that the parameters of the absorber affect the real parts of the eigenvalues of the autonomous system,thereby regulating the stability of the system.Transitioning from a qualitative standpoint to a quantitative approach,a comparison of the solutions before and after the introduction of the dynamic absorber reveals that,when the grounded stiffness ratio and the mass ratio of the dynamic absorber are not equal,the high-frequency part in the analytical solution disappears.As a result,this leads to a reduction in the amplitude of the trajectory,achieving a vibration reduction effect.展开更多
Composite solid-state electrolytes represent a critical pathway that balances the interface compatibility and lithium-ion conductivity in all-solid-state batteries.The quest for stable and highly ion-conductive combin...Composite solid-state electrolytes represent a critical pathway that balances the interface compatibility and lithium-ion conductivity in all-solid-state batteries.The quest for stable and highly ion-conductive combinations between polymers and fillers is vital,but blind attempts are often made due to a lack of understanding of the mechanisms involved in the interaction between polymers and fillers.Herein,we employ in-situ polymerization to prepare a polymer based on an ether-nitrile copolymer with high cathode stability as the foundation and discuss the performance enhancement mechanisms of argyrodite and nano-alumina.With 1%content of sulfide interacting with the polymer at the two-phase interface,the local enhancement of lithium-ion migration capability can be achieved,avoiding the reduction in capacity due to the low ion conductivity of the passivation layer during cycling.The capacity retention after 50cycles at 0.5 C increases from 83.5%to 94.4%.Nano-alumina,through anchoring the anions and interface inhibition functions,eventually poses an initial discharge capacity of 136.8 m A h g^(-1)at 0.5 C and extends the cycling time to 1000 h without short-circuiting in lithium metal batteries.Through the combined action of dual fillers on the composite solid-state electrolyte,promising insights are provided for future material design.展开更多
Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to...Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to enhance the dynamic performance. The X-structure is used as a mechanism to realize the nonlinear stiffness characteristic of the NES, which can realize the flexibility, adjustability, high efficiency, and easy operation of nonlinear stiffness, and is convenient to apply in the vehicle suspension, and the inerter is applied to replacing the mass of the NES based on the mass amplification characteristic. The dynamic model of the half-vehicle system coupled with the IX-NES is established with the Lagrange theory, and the harmonic balance method(HBM) and the pseudo-arc-length method(PALM) are used to obtain the dynamic response under road harmonic excitation. The corresponding dynamic performance under road harmonic and random excitation is evaluated by six performance indices, and compared with that of the original half-vehicle system to show the benefits of the IX-NES. Furthermore, the structural parameters of the IX-NES are optimized with the genetic algorithm. The results show that for road harmonic and random excitation, using the IX-NES can greatly reduce the resonance peaks and root mean square(RMS) values of the front and rear suspension deflections and the front and rear dynamic tire loads, while the resonance peaks and RMS values of the vehicle body vertical and pitching accelerations are slightly larger.When the structural parameters of the IX-NES are optimized, the vehicle body vertical and pitching accelerations of the half-vehicle system could reduce by 2.41% and 1.16%,respectively, and the other dynamic performance indices are within the reasonable ranges.Thus, the IX-NES combines the advantages of the inerter, X-structure, and NES, which improves the dynamic performance of the half-vehicle system and provides an effective option for vibration attenuation in the vehicle engineering.展开更多
In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in ...In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in serial or in parallel.The dynamic equations of TID adjacent building damping systems were derived,and the H2 norm criterion was used to optimize and adjust them,so that the system had the optimum damping performance under white noise random excitation.Taking TID frequency ratio and damping ratio as optimization parameters,the optimum analytical solutions of the displacement frequency response of the undamped structure under white noise excitation were obtained.The results showed that compared with the classic TMD,TID could obtain a better damping effect in the adjacent buildings.Comparing the TIDs composed of serial or parallel,it was found that the parallel TIDs had more significant advantages in controlling the peak displacement frequency response,while the H2 norm of the displacement frequency response of the damping system under the coupling of serial TID was smaller.Taking the adjacent building composed of two ten-story frame structures as an example,the displacement and energy collection time history analysis of the adjacent building coupled with the optimum design parameter TIDs were carried out.It was found that TID had a better damping effect in the full-time range compared with the classic TMD.This paper also studied the potential power of TID in adjacent buildings,which can be converted into available power resources during earthquakes.展开更多
建立气相色谱法测定氟苯尼考中二乙胺和三乙胺残留的方法。采用Inert Cap for Amines毛细管胺类测试柱,经惰性处理的衬管,载气为氮气,流速3.0 mL/min,分流比为5∶1,检测器为FID。结果表明:该方法中二乙胺、三乙胺与其相邻峰完全分离;对...建立气相色谱法测定氟苯尼考中二乙胺和三乙胺残留的方法。采用Inert Cap for Amines毛细管胺类测试柱,经惰性处理的衬管,载气为氮气,流速3.0 mL/min,分流比为5∶1,检测器为FID。结果表明:该方法中二乙胺、三乙胺与其相邻峰完全分离;对照峰面积RSD均小于2%;二乙胺的检测限浓度为1.84μg/mL,定量限浓度为3.67μg/mL,在3.67~13.76μg/mL浓度范围内线性相关系数r为0.995 9;三乙胺的检测限浓度为0.50μg/mL,定量限浓度为1.50μg/mL,在1.50~374.63μg/mL浓度范围内线性相关系数r为0.998 6;二乙胺的回收率90.7%~103.0%,三乙胺的回收率90.8%~97.3%;小幅改变色谱条件,耐用性良好。方法操作简单、准确度高、重复性好,适用于氟苯尼考中二乙胺、三乙胺残留的测定。展开更多
17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstruc...17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstructures and phase compositions of the as-sintered and post-electrolyzed samples were investigated. The impurity contents in the electrolyte and the cathode metal were detected in order to investigate the corrosion characteristic of the elements of Fe, Ni and Cu in the anode. A dense NiFe2O4 layer was observed on the surface of anode and thickened with prolonging the electrolysis time. In the newly formed dense ceramic layer, NiO phase disappeared as a result of being swallowed by NiFe2O4 phase, and the metal phase was oxidized during the electrolysis in which Cu element showed a higher dissolution rate than Fe and Ni elements. The formation process of the dense ceramic layer during the electrolysis was presented and explained by using the corrosion mode of the metal phase and the transformation mechanism from NiO phase to NiFe2O4 phase.展开更多
In order to study the welding process,microstructure and properties of Al-Mg-Mn-Sc-Zr alloy,comparative methods of friction stir welding(FSW) and tungsten inert gas(TIG) were applied to the two conditions of this ...In order to study the welding process,microstructure and properties of Al-Mg-Mn-Sc-Zr alloy,comparative methods of friction stir welding(FSW) and tungsten inert gas(TIG) were applied to the two conditions of this alloy,namely hot rolled plate and cold rolled-annealed plate.The relationships between microstructures and properties of the welded joints were investigated by means of optical microscopy and transmission electron microscopy.Compared with the base metal,the strength of FSW and TIG welded joints decreased,and the FSW welding coefficients were higher than the TIG welding coefficients.The loss of substructure strengthening and a very little loss of precipitation strengthening of Al3(Sc,Zr) cause the decreased strength of FSW welded joint.But for the TIG welded joint,the disappearance of both the strain hardening and most precipitation strengthening effect of Al3(Sc,Zr) particles contributed to its softening.At the same time,the grains in weld nugget zone of FSW welded joints were finer than those in the molten zone of TIG welded joints.展开更多
Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide (CeO2) were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electro...Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide (CeO2) were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electrodes and the impact of α-PbO2 as the intermediate layer. The results show that using α-PbO2 as the intermediate layer will benefit the crystallization of β-PbO2 and β-PbO2 is more suitable as the surface layer than α-PbO2. CeO2 dopants change the crystallite size and crystal structure, enhance the catalytic activity, and even change the deposition mechanism of PbO2. The doping of CeO2 in the PbO2 electrodes can enhance the electro-catalytic activity, which is helpful for oxygen evolution, and therefore reduce the cell voltage.展开更多
xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte ...xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte was studied with anodic current density of 1.0 A/cm2 in laboratory electrolysis.The substantial corrosion of metal Cu was observed,many pores appeared on the surface of anode and electrolytes infiltrated inside anodes during the electrolysis.The wear rates of 5Cu/(10NiO-NiFe2O4),10Cu/(10NiO-NiFe2O4),17Cu/(10NiO-NiFe2O4),1BaO-5Cu/(10NiO-NiFe2O4),1BaO-10Cu/(10NiO-NiFe2O4) and 1BaO-17Cu/(10NiO-NiFe2O4) are 2.15,6.50,8.30,4.88,4.70 and 4.48 cm/a,respectively.The addition of BaO to 10Cu/(10NiO-NiFe2O4) cermet and 17Cu/(10NiO-NiFe2O4) cermet is advantageous because BaO can effectively promote densification and thus improve corrosion resistance.But the addition of BaO to 5Cu/(10NiO-NiFe2O4) cermet is unfavorable to corrosion resistance because additive BaO at the grain boundary of anode accelerates possibly the corrosion of cermet.展开更多
A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rate...A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 (volume fraction) are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer (about 50 μm) is thicker than that (about 30 μm) formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe(II) in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.展开更多
2219-T8 aluminum alloys were butt welded by the double-pass tungsten inert gas (TIG) arc welding process. The transverse tensile test of the joint showed that the fracture mainly occurred in the partially melted zo...2219-T8 aluminum alloys were butt welded by the double-pass tungsten inert gas (TIG) arc welding process. The transverse tensile test of the joint showed that the fracture mainly occurred in the partially melted zone (PMZ). Effects of the PMZ on the fracture behavior were systematically studied. Continuous intergranular eutectics were observed in the PMZ close to the fusion line. Away from the fusion line, the intergranular eutectics in the PMZ became discontinuous. The fracture morphology and the microhardness distribution of the joint showed that the PMZ was gradient material with different mechanical properties, which strongly affected the fracture process. It was observed that the crack initiated in the PMZ near the front weld toe, and propagated in the PMZ away from the fusion line. Then, the crack tip was blunt when it propagated into the PMZ with higher plasticity. Finally, the rest part of the joint was shear fractured.展开更多
NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance...NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance during electrolysis in molten salt cryolite at 960 °C, but according to the analyses of phase compositions and microstructures through XRD, SEM/EDX and metallographic analysis, the metal in the anodes is preferentially corroded and many pores are produced on the anode surface after electrolysis. The preferential dissolution of Fe in the NiFe2O4 phase may lead to the non-uniform corrosion of NiFe2O4 grains. Moreover, a dense protective layer of NiFe2O4-NiAl2O4-FeAl2O4 is formed on the anode surface, which originates from the reaction of Al2O3 dissolved in the electrolyte with NiO or FeO, the annexation of NiFe2O4-NiAl2O4-FeAl2O4 to NiO and volume expansion. Thus, the dense NiFe2O4-NiAl2O4-FeAl2O4 layer inhibits the metal loss and ceramic-phase corrosion on the surface of the cermet inert anodes.展开更多
Onboard air separation devices,based on hollow fiber membranes,are traditionally used for the optimization of aircraft fuel tank inerting systems.In the present study,a set of tests have been designed and executed to ...Onboard air separation devices,based on hollow fiber membranes,are traditionally used for the optimization of aircraft fuel tank inerting systems.In the present study,a set of tests have been designed and executed to assess the air separation performances of these systems for different air inlet temperatures(70°C∼110°C),inlet pressures(0.1∼0.4 MPa),volume flow rates of nitrogen-enriched air(NEA)(30∼120 L/min)and flight altitudes(1.5∼18 km).In particular,the temperature,pressure,volume flow rate,and oxygen concentration of air,NEA and oxygen-enriched air(OEA)have been measured.The experimental results show that the oxygen concentration of NEA,air separation coefficient,and nitrogen utilization coefficient decrease with the rising of air inlet temperature,air inlet pressure,and flight altitude.The effect of air inlet pressure on the above three parameters is significant,while the influence of air inlet temperature and flight altitude is relatively small.展开更多
In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by...In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition(DPE) of PANI and WC particles with Pb2+ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy(SEM).The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2+,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.展开更多
Cold Metal Transfer technology has revolutionized the welding of dissimilar metals and thicker materials by producing improved weld bead aesthetics with controlled metal deposition and low heat-input. In this study, t...Cold Metal Transfer technology has revolutionized the welding of dissimilar metals and thicker materials by producing improved weld bead aesthetics with controlled metal deposition and low heat-input. In this study, the process, weld combinations, laser-CMT hybrid welding and applications of CMT welding are critically reviewed. Microstructure and other weld characteristics have been discussed at length for various base metal combinations. Particularly, the welding of aluminium and steel with better results has been possible with CMT Welding. The results reviewed in this article indicate that the CMT-Laser hybrid welding is more preferable to Laser or Laser hybrid welding. CMT welding has found applications in automobile industries, defence sectors and power plants as a method of additive manufacturing.展开更多
1.Introduction Artificial intelligence(AI)is a rapidly growing field of technol-ogy,which“will enliven inert objects,much as electricity did more than a century ago.Everything that we formerly electrified will now co...1.Introduction Artificial intelligence(AI)is a rapidly growing field of technol-ogy,which“will enliven inert objects,much as electricity did more than a century ago.Everything that we formerly electrified will now cognitize”[1].AI advances are constantly pushing the frontier of what machines can do.Increased attention is being placed on AI research,as well as its development and deployment by commer-cial investors,defense strategists,and policy makers[2].展开更多
Due to the serious greenhouse gas effects caused by the increasing concentration of atmospheric CO_2,carbon capture and storage(CCS) has been an important area of research and many technologies are developed within th...Due to the serious greenhouse gas effects caused by the increasing concentration of atmospheric CO_2,carbon capture and storage(CCS) has been an important area of research and many technologies are developed within this field. Molten salt CO_2 capture and electrochemical transformation(MSCC-ET) process is a desirable method due to a high CO_2 solubility, a wide potential window of molten salts and easily-controlled electrode reactions. Generally, electro-splitting CO_2 in molten salts begins with CO_2 absorption reactions to form CO_3^(2-), which is then followed by the carbon deposition at the cathode and O_2 evolution at the anode. As a result, CO_2 is electro-converted to O_2 and carbon with different morphologies, compositions, microstructures and functional properties. This report introduces the MSCC-ET process, summarizes the reactions occurring in the molten salts and at the electrode surfaces, as well as the morphological variations of the cathodic products. The inert anode materials, cost estimation and scale-up evaluation of the process are then discussed. It is presumed that with a comprehensive understanding of the electrode reactions during electrolysis and the functional properties of carbon materials obtained during CO_2 electro-splitting can provide a foundation for further developing this environmentally friendly process.展开更多
文摘In this work, a simulated aircraft fuel tank inerting system has been successfully estab- lished based on a model tank. Experiments were conducted to investigate the influences of different operating parameters on the inerting effectiveness of the system, including flow rate of the inert gas (nitrogen-enriched air), inert gas concentration, fuel load of the tank and different inerting approaches. The experimental results show that under the same operating conditions, the time span of a complete inerting process decreased as the flow rate of inert gas was increased; the time span using the inert gas with 5% oxygen concentration was much longer than that using pure nitrogen; when the fuel tank was inerted using the ullage washing approach, the time span increased as the fuel load was decreased; the ullage washing approach showed the best inerting performance when the time span of a complete inerting process was the evaluation criterion, but when the decrease of dissolved oxygen concentration in the fuel was also considered to characterize the inerting effective- ness, the approach of ullage washing and fuel scrubbing at the same time was the most effective.
基金supported by Funding of Jiangsu Innovation Program for Graduate Education of China (No.KYLX15_0231)Postgraduate Research & Practice Innovation Program of Jiangsu Province of China (No.KYCX17_0279)+1 种基金the Fundamental Research Funds for the Central Universities,Aviation Industry Corporation of China Technology Innovation Fund for Fundamental Research (No.2014D60931R)Funding of Ministry of Industry and Information Technology for Civil Aircraft
文摘Fuel tank inerting technologies are able to reduce the fire risk by injection of inert gas into the ullage or fuel, the former called ullage washing and the latter fuel scrubbing. The Green On-Board Inert Gas Generation System(GOBIGGS) is a novel technology based on flameless catalytic combustion, and owning to its simple structure and high inerting efficiency, it has received a lot of attentions. The inert gas in the GOBIGGS is mainly comprised of CO2, N2, and O2(hereinafter, Mixed Inert Gas(MIG)), while that in the On-Board Inert Gas Generation System(OBIGGS), which is one of the most widely used fuel tank inerting technologies, is NitrogenEnriched Air(NEA). The solubility of CO2 is nearly 20 times higher than that of N2 in jet fuels,so the inerting capability and performance are definitely disparate if the inert gas is selected as NEA or MIG. An inerting test bench was constructed to compare the inerting capabilities between NEA and MIG. Experimental results reveal that, if ullage washing is adopted, the variations of oxygen concentrations on the ullage and in the fuel are nearly identical no matter the inert gas is NEA or MIG. However, the ullage and dissolved oxygen concentrations of MIG scrubbing are always higher than those of NEA scrubbing.
基金supported by National Natural Science Foundation of China Civil Aviation Joint Fund (No.U1933121)Postgraduate Research & Practice Innovation Program of Jiangsu Province (No.KYCX19_0198)The Fundamental Research Funds for the Central Universities and Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘The properties of aviation fuel have a great influence on the performance of oxygenconsuming inerting systems. Based on the establishment of the catalytic inerting process, the flow relationship of each gas component flowing through the catalytic reactor was derived. The mathematical model of the gas concentration in the gas phase of the fuel tank was established based on the mass conservation equation, and the fuel tank model was verified by performing experiments.The results showed that the fuel type exerts a considerably higher influence on the performance of the oxygen-consuming inerting system compared to the corresponding influence on the hollow fiber membrane system, and the relative magnitude of the inerting rates of the four fuel types is RP5 > RP3 > RP6 > JP8. In addition, a higher catalytic efficiency or fuel load rate corresponds to a higher rate of decrease of the oxygen concentration in the gas phase, and the inerting time is inversely proportional to the suction flow rate of the fan. When different fuels are used, the amount of cooling gas and water released from the inerting system are different. Therefore, the influence of fuel type on the system performance should be extensively considered in the future.
基金Project supported by the National Natural Science Foundation of China(Nos.12172233 and U1934201)。
文摘The dynamic vibration absorber with inerter and grounded stiffness(IGDVA)is used to control a two-scale system subject to a weak periodic perturbation.The vibration suppression effect is remarkable.The amplitude of the main system coupled with absorber is significantly reduced,and the high frequency vibration completely disappears.First,through the slow-fast analysis and stability theory,it is found that the stability of the autonomous system exerts a notable regulating effect on the vibration response of the non-autonomous system.After adding the dynamic vibrator absorber,the center in the autonomous system changes to an asymptotically stable focus,consequently suppressing the vibration in the non-autonomous system.Further research reveals that the parameters of the absorber affect the real parts of the eigenvalues of the autonomous system,thereby regulating the stability of the system.Transitioning from a qualitative standpoint to a quantitative approach,a comparison of the solutions before and after the introduction of the dynamic absorber reveals that,when the grounded stiffness ratio and the mass ratio of the dynamic absorber are not equal,the high-frequency part in the analytical solution disappears.As a result,this leads to a reduction in the amplitude of the trajectory,achieving a vibration reduction effect.
基金supported by the Science and Technology Commission of Shanghai Municipality(No.19DZ2270100),China。
文摘Composite solid-state electrolytes represent a critical pathway that balances the interface compatibility and lithium-ion conductivity in all-solid-state batteries.The quest for stable and highly ion-conductive combinations between polymers and fillers is vital,but blind attempts are often made due to a lack of understanding of the mechanisms involved in the interaction between polymers and fillers.Herein,we employ in-situ polymerization to prepare a polymer based on an ether-nitrile copolymer with high cathode stability as the foundation and discuss the performance enhancement mechanisms of argyrodite and nano-alumina.With 1%content of sulfide interacting with the polymer at the two-phase interface,the local enhancement of lithium-ion migration capability can be achieved,avoiding the reduction in capacity due to the low ion conductivity of the passivation layer during cycling.The capacity retention after 50cycles at 0.5 C increases from 83.5%to 94.4%.Nano-alumina,through anchoring the anions and interface inhibition functions,eventually poses an initial discharge capacity of 136.8 m A h g^(-1)at 0.5 C and extends the cycling time to 1000 h without short-circuiting in lithium metal batteries.Through the combined action of dual fillers on the composite solid-state electrolyte,promising insights are provided for future material design.
基金Project supported by the National Natural Science Foundation of China (Nos. 12172153 and51805216)the China Postdoctoral Science Foundation (No. 2023M731668)the Major Project of Basic Science (Natural Science) of the Jiangsu Higher Education Institutions of China(No. 22KJA410001)。
文摘Inspired by the demand of improving the riding comfort and meeting the lightweight design of the vehicle, an inerter-based X-structure nonlinear energy sink(IXNES) is proposed and applied in the half-vehicle system to enhance the dynamic performance. The X-structure is used as a mechanism to realize the nonlinear stiffness characteristic of the NES, which can realize the flexibility, adjustability, high efficiency, and easy operation of nonlinear stiffness, and is convenient to apply in the vehicle suspension, and the inerter is applied to replacing the mass of the NES based on the mass amplification characteristic. The dynamic model of the half-vehicle system coupled with the IX-NES is established with the Lagrange theory, and the harmonic balance method(HBM) and the pseudo-arc-length method(PALM) are used to obtain the dynamic response under road harmonic excitation. The corresponding dynamic performance under road harmonic and random excitation is evaluated by six performance indices, and compared with that of the original half-vehicle system to show the benefits of the IX-NES. Furthermore, the structural parameters of the IX-NES are optimized with the genetic algorithm. The results show that for road harmonic and random excitation, using the IX-NES can greatly reduce the resonance peaks and root mean square(RMS) values of the front and rear suspension deflections and the front and rear dynamic tire loads, while the resonance peaks and RMS values of the vehicle body vertical and pitching accelerations are slightly larger.When the structural parameters of the IX-NES are optimized, the vehicle body vertical and pitching accelerations of the half-vehicle system could reduce by 2.41% and 1.16%,respectively, and the other dynamic performance indices are within the reasonable ranges.Thus, the IX-NES combines the advantages of the inerter, X-structure, and NES, which improves the dynamic performance of the half-vehicle system and provides an effective option for vibration attenuation in the vehicle engineering.
基金This research was funded by the Natural Science Research Project of Higher Education Institutions in Anhui Province(Grant No.2022AH040045)the Anhui Provincial Natural Science Foundation(Grant No.2008085QE245)the Project of Science and Technology Plan of Department of Housing and Urban-Rural Development of Anhui Province(Grant No.2021-YF22).
文摘In order to improve the seismic performance of adjacent buildings,two types of tuned inerter damper(TID)damping systems for adjacent buildings are proposed,which are composed of springs,inerter devices and dampers in serial or in parallel.The dynamic equations of TID adjacent building damping systems were derived,and the H2 norm criterion was used to optimize and adjust them,so that the system had the optimum damping performance under white noise random excitation.Taking TID frequency ratio and damping ratio as optimization parameters,the optimum analytical solutions of the displacement frequency response of the undamped structure under white noise excitation were obtained.The results showed that compared with the classic TMD,TID could obtain a better damping effect in the adjacent buildings.Comparing the TIDs composed of serial or parallel,it was found that the parallel TIDs had more significant advantages in controlling the peak displacement frequency response,while the H2 norm of the displacement frequency response of the damping system under the coupling of serial TID was smaller.Taking the adjacent building composed of two ten-story frame structures as an example,the displacement and energy collection time history analysis of the adjacent building coupled with the optimum design parameter TIDs were carried out.It was found that TID had a better damping effect in the full-time range compared with the classic TMD.This paper also studied the potential power of TID in adjacent buildings,which can be converted into available power resources during earthquakes.
文摘建立气相色谱法测定氟苯尼考中二乙胺和三乙胺残留的方法。采用Inert Cap for Amines毛细管胺类测试柱,经惰性处理的衬管,载气为氮气,流速3.0 mL/min,分流比为5∶1,检测器为FID。结果表明:该方法中二乙胺、三乙胺与其相邻峰完全分离;对照峰面积RSD均小于2%;二乙胺的检测限浓度为1.84μg/mL,定量限浓度为3.67μg/mL,在3.67~13.76μg/mL浓度范围内线性相关系数r为0.995 9;三乙胺的检测限浓度为0.50μg/mL,定量限浓度为1.50μg/mL,在1.50~374.63μg/mL浓度范围内线性相关系数r为0.998 6;二乙胺的回收率90.7%~103.0%,三乙胺的回收率90.8%~97.3%;小幅改变色谱条件,耐用性良好。方法操作简单、准确度高、重复性好,适用于氟苯尼考中二乙胺、三乙胺残留的测定。
基金Project (2005CB623703) supported by the National Basic Research Program of ChinaProject (50721003) supported by the National Natural Science Fund for Innovation Group of ChinaProject (2008AA030501) supported by the National High-Tech Research and Development Program of China
文摘17(Cu-10Ni)-(NiFe2O4-10NiO) cermets were prepared by cold pressing and sintering in nitrogen atmosphere, and tested as inert anode for aluminum electrolysis at 960 °C for 10 and 40 h, respectively. Microstructures and phase compositions of the as-sintered and post-electrolyzed samples were investigated. The impurity contents in the electrolyte and the cathode metal were detected in order to investigate the corrosion characteristic of the elements of Fe, Ni and Cu in the anode. A dense NiFe2O4 layer was observed on the surface of anode and thickened with prolonging the electrolysis time. In the newly formed dense ceramic layer, NiO phase disappeared as a result of being swallowed by NiFe2O4 phase, and the metal phase was oxidized during the electrolysis in which Cu element showed a higher dissolution rate than Fe and Ni elements. The formation process of the dense ceramic layer during the electrolysis was presented and explained by using the corrosion mode of the metal phase and the transformation mechanism from NiO phase to NiFe2O4 phase.
基金Project (MKPT-2005-16ZD) supported by the National Key Scientific and Technological Project of ChinaProject supported by the Postdoctoral Science Foundation of Central South University,China
文摘In order to study the welding process,microstructure and properties of Al-Mg-Mn-Sc-Zr alloy,comparative methods of friction stir welding(FSW) and tungsten inert gas(TIG) were applied to the two conditions of this alloy,namely hot rolled plate and cold rolled-annealed plate.The relationships between microstructures and properties of the welded joints were investigated by means of optical microscopy and transmission electron microscopy.Compared with the base metal,the strength of FSW and TIG welded joints decreased,and the FSW welding coefficients were higher than the TIG welding coefficients.The loss of substructure strengthening and a very little loss of precipitation strengthening of Al3(Sc,Zr) cause the decreased strength of FSW welded joint.But for the TIG welded joint,the disappearance of both the strain hardening and most precipitation strengthening effect of Al3(Sc,Zr) particles contributed to its softening.At the same time,the grains in weld nugget zone of FSW welded joints were finer than those in the molten zone of TIG welded joints.
基金Project(50964008)supported by the National Natural Science Foundation of ChinaProject(2010287)supported by Analysis and Testing Foundation of Kunming University of Science and Technology,China
文摘Al/α-PbO2/β-PbO2 composite electrodes doped with rare earth oxide (CeO2) were prepared by anodic oxidation method investigate the influence of nano-CeO2 dopants on the properties of Al/α-PbO2/β-PbO2-CeO2 electrodes and the impact of α-PbO2 as the intermediate layer. The results show that using α-PbO2 as the intermediate layer will benefit the crystallization of β-PbO2 and β-PbO2 is more suitable as the surface layer than α-PbO2. CeO2 dopants change the crystallite size and crystal structure, enhance the catalytic activity, and even change the deposition mechanism of PbO2. The doping of CeO2 in the PbO2 electrodes can enhance the electro-catalytic activity, which is helpful for oxygen evolution, and therefore reduce the cell voltage.
基金Project(2005CB623703)supported by the National Basic Research Program of ChinaProject(50721003)supported by the National Natural Science Foundation for Innovation Group of China+1 种基金Project(2008AA030501)supported by the National High-tech Research and Development Program of ChinaProject(201012200021)supported by the Basic Scientific Research Program of Central South University,China
文摘xCu/(10NiO-NiFe2O4) cermet and 1BaO-xCu/(10NiO-NiFe2O4) cermet(x=5,10,17) inert anodes were prepared as potential inert anodes for aluminum electrolysis and their corrosion resistance to traditional electrolyte was studied with anodic current density of 1.0 A/cm2 in laboratory electrolysis.The substantial corrosion of metal Cu was observed,many pores appeared on the surface of anode and electrolytes infiltrated inside anodes during the electrolysis.The wear rates of 5Cu/(10NiO-NiFe2O4),10Cu/(10NiO-NiFe2O4),17Cu/(10NiO-NiFe2O4),1BaO-5Cu/(10NiO-NiFe2O4),1BaO-10Cu/(10NiO-NiFe2O4) and 1BaO-17Cu/(10NiO-NiFe2O4) are 2.15,6.50,8.30,4.88,4.70 and 4.48 cm/a,respectively.The addition of BaO to 10Cu/(10NiO-NiFe2O4) cermet and 17Cu/(10NiO-NiFe2O4) cermet is advantageous because BaO can effectively promote densification and thus improve corrosion resistance.But the addition of BaO to 5Cu/(10NiO-NiFe2O4) cermet is unfavorable to corrosion resistance because additive BaO at the grain boundary of anode accelerates possibly the corrosion of cermet.
基金Project(51474238)supported by the National Natural Science Foundation of China
文摘A comparative study on the corrosion resistance of 17Ni/(NiFe2O4-10NiO) cermet inert anode prepared in differentsintering atmospheres was conducted in Na3AlF6-Al2O3 melt. The results indicate that the corrosion rates of NiFe2O4-based cermetanodes prepared in the vacuum and the atmosphere with oxygen content of 2×10^-3 (volume fraction) are 6.46 and 2.71 cm/a,respectively. Though there is a transition layer with lots of holes or pores, a densified layer is formed on the surface of anode due tosome reactions producing aluminates. For the anode prepared in the atmosphere with oxygen content of 2×10^-3, the thickness of thedensification layer (about 50 μm) is thicker than that (about 30 μm) formed on the surface of anode prepared in the vacuum. Thecontents of NiO and Fe(II) in NiFe2xO4-y-z increase with the decrease of oxygen content in sintering atmosphere, which reduces thecorrosion resistance of the material.
文摘2219-T8 aluminum alloys were butt welded by the double-pass tungsten inert gas (TIG) arc welding process. The transverse tensile test of the joint showed that the fracture mainly occurred in the partially melted zone (PMZ). Effects of the PMZ on the fracture behavior were systematically studied. Continuous intergranular eutectics were observed in the PMZ close to the fusion line. Away from the fusion line, the intergranular eutectics in the PMZ became discontinuous. The fracture morphology and the microhardness distribution of the joint showed that the PMZ was gradient material with different mechanical properties, which strongly affected the fracture process. It was observed that the crack initiated in the PMZ near the front weld toe, and propagated in the PMZ away from the fusion line. Then, the crack tip was blunt when it propagated into the PMZ with higher plasticity. Finally, the rest part of the joint was shear fractured.
基金Project (2012FJ6123) supported by the Project of Science and Technology of Hunan Province,ChinaProject supported by Post-Doctoral Foundation of Central South University,China+1 种基金Project (CL12100) supported the Undergraduate Innovative Training of Central South University,ChinaProject (2282013bkso13) supported by Free Exploration Plan of Central South University,China
文摘NiFe2O4-10NiO-based cermet inert anodes for aluminium electrolysis were prepared and their properties were investigated in a lab-scale electrolysis cell. The results show that the inert anodes exhibit good performance during electrolysis in molten salt cryolite at 960 °C, but according to the analyses of phase compositions and microstructures through XRD, SEM/EDX and metallographic analysis, the metal in the anodes is preferentially corroded and many pores are produced on the anode surface after electrolysis. The preferential dissolution of Fe in the NiFe2O4 phase may lead to the non-uniform corrosion of NiFe2O4 grains. Moreover, a dense protective layer of NiFe2O4-NiAl2O4-FeAl2O4 is formed on the anode surface, which originates from the reaction of Al2O3 dissolved in the electrolyte with NiO or FeO, the annexation of NiFe2O4-NiAl2O4-FeAl2O4 to NiO and volume expansion. Thus, the dense NiFe2O4-NiAl2O4-FeAl2O4 layer inhibits the metal loss and ceramic-phase corrosion on the surface of the cermet inert anodes.
基金This project is supported by the Fund of Natural Science Project of Hunan Province,China,with the Item No.2020JJ5393Education Department of Hunan Province,China,with the Item No.18C0735.
文摘Onboard air separation devices,based on hollow fiber membranes,are traditionally used for the optimization of aircraft fuel tank inerting systems.In the present study,a set of tests have been designed and executed to assess the air separation performances of these systems for different air inlet temperatures(70°C∼110°C),inlet pressures(0.1∼0.4 MPa),volume flow rates of nitrogen-enriched air(NEA)(30∼120 L/min)and flight altitudes(1.5∼18 km).In particular,the temperature,pressure,volume flow rate,and oxygen concentration of air,NEA and oxygen-enriched air(OEA)have been measured.The experimental results show that the oxygen concentration of NEA,air separation coefficient,and nitrogen utilization coefficient decrease with the rising of air inlet temperature,air inlet pressure,and flight altitude.The effect of air inlet pressure on the above three parameters is significant,while the influence of air inlet temperature and flight altitude is relatively small.
基金Project (51004056) supported by the National Natural Science Foundation of ChinaProject (KKZ6201152009) supported by the Opening Foundation of Key Laboratory of Inorganic Coating Materials, ChinaProjects (2011239, 2011240) supported by Analysis and Measurement Research Fund of Kunming University of Science and Technology,China
文摘In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI(polyaniline)-WC(tungsten carbide) composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition(DPE) of PANI and WC particles with Pb2+ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy(SEM).The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2+,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.
文摘Cold Metal Transfer technology has revolutionized the welding of dissimilar metals and thicker materials by producing improved weld bead aesthetics with controlled metal deposition and low heat-input. In this study, the process, weld combinations, laser-CMT hybrid welding and applications of CMT welding are critically reviewed. Microstructure and other weld characteristics have been discussed at length for various base metal combinations. Particularly, the welding of aluminium and steel with better results has been possible with CMT Welding. The results reviewed in this article indicate that the CMT-Laser hybrid welding is more preferable to Laser or Laser hybrid welding. CMT welding has found applications in automobile industries, defence sectors and power plants as a method of additive manufacturing.
基金supported in part by the Shanghai Municipal Science and Technology Major Project (2021SHZDZX0100)Shanghai Municipal Commission of Science and Technology Project (19511132101)National Natural Science Foundation of China (62088101, 61720106011, and 62173034)
文摘1.Introduction Artificial intelligence(AI)is a rapidly growing field of technol-ogy,which“will enliven inert objects,much as electricity did more than a century ago.Everything that we formerly electrified will now cognitize”[1].AI advances are constantly pushing the frontier of what machines can do.Increased attention is being placed on AI research,as well as its development and deployment by commer-cial investors,defense strategists,and policy makers[2].
基金funding support from the National Natural Science Foundation of China (51722404 and 51674177)
文摘Due to the serious greenhouse gas effects caused by the increasing concentration of atmospheric CO_2,carbon capture and storage(CCS) has been an important area of research and many technologies are developed within this field. Molten salt CO_2 capture and electrochemical transformation(MSCC-ET) process is a desirable method due to a high CO_2 solubility, a wide potential window of molten salts and easily-controlled electrode reactions. Generally, electro-splitting CO_2 in molten salts begins with CO_2 absorption reactions to form CO_3^(2-), which is then followed by the carbon deposition at the cathode and O_2 evolution at the anode. As a result, CO_2 is electro-converted to O_2 and carbon with different morphologies, compositions, microstructures and functional properties. This report introduces the MSCC-ET process, summarizes the reactions occurring in the molten salts and at the electrode surfaces, as well as the morphological variations of the cathodic products. The inert anode materials, cost estimation and scale-up evaluation of the process are then discussed. It is presumed that with a comprehensive understanding of the electrode reactions during electrolysis and the functional properties of carbon materials obtained during CO_2 electro-splitting can provide a foundation for further developing this environmentally friendly process.