In this paper the main sources causing the scatter of the experimental results of the material parameters are discussed. They can be divided into two parts: one is the experimental errors which are introduced because ...In this paper the main sources causing the scatter of the experimental results of the material parameters are discussed. They can be divided into two parts: one is the experimental errors which are introduced because of the inaccuracy of experimental equipment, the experimental techniques, etc., and the form of the scatter caused by this source is called external distribution. The other is due to the irregularity and inhomogeneity of the material structure and the randomness of deformation process. The scatter caused by this source is inherent and then this form of the scatter is called internal distribution. Obviously the experimental distribution of material parameters combines these two distributions in some way; therefore, it is a sum distribution of the external distribution and the internal distribution. In view of this , a general method used to analyse the influence of the experimental errors on the experimental results is presented, and three criteria used to value this influence are defined. An example in which the fracture toughness KIC is analysed shows that this method is reasonable, convenient and effective.展开更多
Two new metal-organic frameworks, {[Cd2CI（HL）（H20）2＂0.5H20]}n （1） and {[Cd2L（H20）2]＇H20}n （2）, have been hydrothermally synthesized with designed ligand H4L （HaL = 1,3,5-triazine-2-iminodiacetic acid-4,6-...Two new metal-organic frameworks, {[Cd2CI（HL）（H20）2＂0.5H20]}n （1） and {[Cd2L（H20）2]＇H20}n （2）, have been hydrothermally synthesized with designed ligand H4L （HaL = 1,3,5-triazine-2-iminodiacetic acid-4,6-biglycine） under the same condition except for different pH values. Single-crystal X-ray determination shows that they are 3-D frameworks. Complex 1 crystallizes in monoclinic, space group P21/n. Complex 2 crystallizes in triclinic, space group Pi. The photoluminescence properties of those two complexes have been investigated in solid state. Complexes 2 exhibited remarkable blue luminescence emissions with high quantum yield of 40.3% On the other hand, complexes 1 featured weak quantum yields of 13.7%.展开更多
文摘In this paper the main sources causing the scatter of the experimental results of the material parameters are discussed. They can be divided into two parts: one is the experimental errors which are introduced because of the inaccuracy of experimental equipment, the experimental techniques, etc., and the form of the scatter caused by this source is called external distribution. The other is due to the irregularity and inhomogeneity of the material structure and the randomness of deformation process. The scatter caused by this source is inherent and then this form of the scatter is called internal distribution. Obviously the experimental distribution of material parameters combines these two distributions in some way; therefore, it is a sum distribution of the external distribution and the internal distribution. In view of this , a general method used to analyse the influence of the experimental errors on the experimental results is presented, and three criteria used to value this influence are defined. An example in which the fracture toughness KIC is analysed shows that this method is reasonable, convenient and effective.
基金supported the National Ministry of Science and Technology of China(2012CB821702)the National Science Foundation of China(21073192,21203194 and 21233009)the Science Foundation of CAS and Fujian Province(KJCX2-YW-H20)
文摘Two new metal-organic frameworks, {[Cd2CI（HL）（H20）2＂0.5H20]}n （1） and {[Cd2L（H20）2]＇H20}n （2）, have been hydrothermally synthesized with designed ligand H4L （HaL = 1,3,5-triazine-2-iminodiacetic acid-4,6-biglycine） under the same condition except for different pH values. Single-crystal X-ray determination shows that they are 3-D frameworks. Complex 1 crystallizes in monoclinic, space group P21/n. Complex 2 crystallizes in triclinic, space group Pi. The photoluminescence properties of those two complexes have been investigated in solid state. Complexes 2 exhibited remarkable blue luminescence emissions with high quantum yield of 40.3% On the other hand, complexes 1 featured weak quantum yields of 13.7%.
