Underground fires are characterized by smouldering combustion with a slow rate of spread rate and without flames.Although smouldering combustion releases large amounts of gaseous pollutants,it is difficult to discover...Underground fires are characterized by smouldering combustion with a slow rate of spread rate and without flames.Although smouldering combustion releases large amounts of gaseous pollutants,it is difficult to discover by today's forest fire monitoring technologies.Carbon monoxide(CO),nitrogen oxides(NO_(x))and sulfur dioxide(SO_(2))were identified as high concentration marker gases of smouldering combustion-easily-be monitored.According to a two-way ANOVA,combustion time had a significant impact on CO and NO_(x) emissions;smoldering-depth also had a significant impact on NO_(x) emissions but not on CO emissions.Gas emission equations were established by multiple linear regression,C_(co)=156.989-16.626 t and C_(NOx)=3.637-0.252 t-0.039 h.展开更多
The influence of three different Al2O3 powder art self-flowing alumina castabie was studied , Max-imum compaction of sample wascomputed by An-dresen Equation . The result showed that the Al2O3 powder, which has much s...The influence of three different Al2O3 powder art self-flowing alumina castabie was studied , Max-imum compaction of sample wascomputed by An-dresen Equation . The result showed that the Al2O3 powder, which has much smaller particle size, could improve the microstructure and the mechanical properties of castabie under room temperature and high temperature. With the same powder size, the room temperature strength of the castabie added with Al2O3 powder properties of which were altered by adding mineralizing agent, was higher than that of the castabie added with common Al2O3 powder, but the flowability of these three different castabie was almost thesame.展开更多
The synthesis process of conventional Mn-based denitrification catalysts is relatively complex and expensive.In this paper,a resource application of chlorella was proposed,and a Chlorella@Mn composite denitrification ...The synthesis process of conventional Mn-based denitrification catalysts is relatively complex and expensive.In this paper,a resource application of chlorella was proposed,and a Chlorella@Mn composite denitrification catalyst was innovatively synthesized by electrostatic interaction.The Chlorella@Mn composite denitrification catalyst prepared under the optimal conditions(0.54 g/L Mn^(2+)concentration,20 million chlorellas/mL concentration,450℃ calcination temperature)exhibited a well-developed pore structure and large specific surface area(122 m^(2)/g).Compared with MnOx alone,the Chlorella@Mn composite catalyst achieved superior performance,with~100%NH_(3)selective catalytic reduction(NH_(3)-SCR)denitrification activity at 100-225℃.The results of NH_(3)temperature-programmed desorption(NH_(3)-TPD)and H_(2)temperature-programmed reduction(H_(2)-TPR)showed that the catalyst had strong acid sites and good redox properties.Zeta potential testing showed that the electronegativity of the chlorella cell surface could be used to enrich with Mn^(2+).X-ray photoelectron spectroscopy(XPS)confirmed that Chlorella@Mn had a high content of Mn^(3+)and surface chemisorbed oxygen.In-situ diffuse refectance infrared Fourier transform spectroscopy(in-situ DRIFTS)experimental results showed that both Langmuir-Hinshelwood(L-H)and Eley-Rideal(E-R)mechanisms play a role in the denitrification process on the surface of the Chlorella@Mn catalyst,where the main intermediate nitrate species is monodentate nitrite.The presence of SO_(2)promoted the generation and strengthening of Bronsted acid sites,but also generated more sulfate species on the surface,thereby reducing the denitrification activity of the Chlorella@Mn catalyst.The Chlorella@Mn composite catalyst had the characteristics of short preparation time,simple process and low cost,making it promising for industrial application.展开更多
Strain Energy of the structure can be changed with the damage at the damage location.The accurate detection of the damage location using this index in a force system is dependent on the degree of accuracy in determini...Strain Energy of the structure can be changed with the damage at the damage location.The accurate detection of the damage location using this index in a force system is dependent on the degree of accuracy in determining the structure deformation function before and after damage.The use of modal-based methods to identify damage in complex bridges is always associated with problems due to the need to consider the effects of higher modes and the adverse effct of operational conditions on the extraction of structural modal parameters.In this paper,the deformation of the structure was determined by the concept of influence line using the Betti-Maxwell theory.Then two damage detection indicators were developed based on strain energy variations.These indices were presented separately for bending and torsion changes.Finite element analysis of a five-span concrete curved bridge was done to validate the stated methods.Damage was simulated by decreasing stiffness at different sections of the deck.The response regarding displacement ofa point on the deck was measured along each span by passing a moving load on the bridge at very low speeds.Indicators of the strain energy extracted from displacement influence line and the strain energy extracted from the rotational displacement influence line(SERIL)were calculated for the studied bridge.The results show that the proposed methods have well identified the location of the damage by significantly reducing the number of sensors required to record the response.Also,the location of symmetric damages is detected with high resolution using SERIL.展开更多
基金supported financially by the National Key Research and Development Plan(2018YFD0600205)the National Natural Science Foundation of China(31971669)。
文摘Underground fires are characterized by smouldering combustion with a slow rate of spread rate and without flames.Although smouldering combustion releases large amounts of gaseous pollutants,it is difficult to discover by today's forest fire monitoring technologies.Carbon monoxide(CO),nitrogen oxides(NO_(x))and sulfur dioxide(SO_(2))were identified as high concentration marker gases of smouldering combustion-easily-be monitored.According to a two-way ANOVA,combustion time had a significant impact on CO and NO_(x) emissions;smoldering-depth also had a significant impact on NO_(x) emissions but not on CO emissions.Gas emission equations were established by multiple linear regression,C_(co)=156.989-16.626 t and C_(NOx)=3.637-0.252 t-0.039 h.
文摘The influence of three different Al2O3 powder art self-flowing alumina castabie was studied , Max-imum compaction of sample wascomputed by An-dresen Equation . The result showed that the Al2O3 powder, which has much smaller particle size, could improve the microstructure and the mechanical properties of castabie under room temperature and high temperature. With the same powder size, the room temperature strength of the castabie added with Al2O3 powder properties of which were altered by adding mineralizing agent, was higher than that of the castabie added with common Al2O3 powder, but the flowability of these three different castabie was almost thesame.
基金supported by the National Natural Science Foundation of China (No.U20A20130)the Fundamental Research Funds for the Central Universities (No.FRF-TP-20-03B)。
文摘The synthesis process of conventional Mn-based denitrification catalysts is relatively complex and expensive.In this paper,a resource application of chlorella was proposed,and a Chlorella@Mn composite denitrification catalyst was innovatively synthesized by electrostatic interaction.The Chlorella@Mn composite denitrification catalyst prepared under the optimal conditions(0.54 g/L Mn^(2+)concentration,20 million chlorellas/mL concentration,450℃ calcination temperature)exhibited a well-developed pore structure and large specific surface area(122 m^(2)/g).Compared with MnOx alone,the Chlorella@Mn composite catalyst achieved superior performance,with~100%NH_(3)selective catalytic reduction(NH_(3)-SCR)denitrification activity at 100-225℃.The results of NH_(3)temperature-programmed desorption(NH_(3)-TPD)and H_(2)temperature-programmed reduction(H_(2)-TPR)showed that the catalyst had strong acid sites and good redox properties.Zeta potential testing showed that the electronegativity of the chlorella cell surface could be used to enrich with Mn^(2+).X-ray photoelectron spectroscopy(XPS)confirmed that Chlorella@Mn had a high content of Mn^(3+)and surface chemisorbed oxygen.In-situ diffuse refectance infrared Fourier transform spectroscopy(in-situ DRIFTS)experimental results showed that both Langmuir-Hinshelwood(L-H)and Eley-Rideal(E-R)mechanisms play a role in the denitrification process on the surface of the Chlorella@Mn catalyst,where the main intermediate nitrate species is monodentate nitrite.The presence of SO_(2)promoted the generation and strengthening of Bronsted acid sites,but also generated more sulfate species on the surface,thereby reducing the denitrification activity of the Chlorella@Mn catalyst.The Chlorella@Mn composite catalyst had the characteristics of short preparation time,simple process and low cost,making it promising for industrial application.
文摘Strain Energy of the structure can be changed with the damage at the damage location.The accurate detection of the damage location using this index in a force system is dependent on the degree of accuracy in determining the structure deformation function before and after damage.The use of modal-based methods to identify damage in complex bridges is always associated with problems due to the need to consider the effects of higher modes and the adverse effct of operational conditions on the extraction of structural modal parameters.In this paper,the deformation of the structure was determined by the concept of influence line using the Betti-Maxwell theory.Then two damage detection indicators were developed based on strain energy variations.These indices were presented separately for bending and torsion changes.Finite element analysis of a five-span concrete curved bridge was done to validate the stated methods.Damage was simulated by decreasing stiffness at different sections of the deck.The response regarding displacement ofa point on the deck was measured along each span by passing a moving load on the bridge at very low speeds.Indicators of the strain energy extracted from displacement influence line and the strain energy extracted from the rotational displacement influence line(SERIL)were calculated for the studied bridge.The results show that the proposed methods have well identified the location of the damage by significantly reducing the number of sensors required to record the response.Also,the location of symmetric damages is detected with high resolution using SERIL.