As one of the most important elements in linear transformer driver(LTD) based systems, the gas pressurized closing switches are required to operate with a very low prefire probability during the DC-charging process to...As one of the most important elements in linear transformer driver(LTD) based systems, the gas pressurized closing switches are required to operate with a very low prefire probability during the DC-charging process to ensure reliable operation and stable output of the whole pulsed power system. The most direct and effective way to control the prefire probability is to select a suitable working coefficient. The study of the development characteristics of the initially generated electrons is useful for optimizing the working coefficient and improving the prefire characteristic of the switches. In this paper an ultraviolet pulsed laser is used to generate initial electrons inside the gap volume. A current measuring system is used to measure the time-dependent current generated by the growth of the initial electrons so as to study the development characteristics of the electrons under different working coefficients. Experimental results show that the development characteristics of the initial electrons are influenced obviously by the working coefficient. With the increase of the working coefficient, the development degree of the electrons increases consequently. At the same times, there is a threshold of working coefficient which produces the effect of ionization on electrons. The range of the threshold has a slow growth but remains close to 65% with the gas pressure increase. When the working coefficient increases further, γ processes are starting to be generated inside the gap volume. In addition, an optimal working coefficient beneficial for improving the prefire characteristic is indicated and further tested.展开更多
We theoretically investigate the effects of different electronic states as the initial state on the vortex patterns in photoelectron momentum distributions(PMDs)from numerical solutions of the two-dimensional(2D)time-...We theoretically investigate the effects of different electronic states as the initial state on the vortex patterns in photoelectron momentum distributions(PMDs)from numerical solutions of the two-dimensional(2D)time-dependent Schrodinger equation(TDSE)of He^(+)with a pair of counter-rotating circularly polarized attosecond pulses.It is found that the number of spiral arms in vortex patterns is equal to the number of the absorbed photons when the initial state is the ground state.However,the number of spiral arms in vortex patterns is always two more than the number of the absorbed photons when the initial state is the excited state.This sensitivity is attributed to the initial electron density distribution.In addition,we have demonstrated the PMDs for different initial electronic states with the same wavelengths and analyzed their corresponding physical mechanisms.It is illustrated that the method presented can be employed to effectively control the distribution of the electron vortices.展开更多
Objective:In this study,we try to establish an initial electron beam model by combining Monte Carlo simulation method with particle dynamic calculation(TRSV)for the single 6 MV X-ray accelerating waveguide of BJ-6 med...Objective:In this study,we try to establish an initial electron beam model by combining Monte Carlo simulation method with particle dynamic calculation(TRSV)for the single 6 MV X-ray accelerating waveguide of BJ-6 medical linac.Methods and Materials:1.We adapted the treatment head configuration of BJ-6 medical linac made by Beijing Medical Equipment Institute(BMEI)as the radiation system for this study.2.Use particle dynamics calculation code called TRSV to drive out the initial electron beam parameters of the energy spectrum,the spatial intensity distribution,and the beam incidence angle.3.Analyze the 6 MV X-ray beam characteristics of PDDc,OARc in a water phantom by using Monte Carlo simulation(BEAMnrc,DOSXYZnrc)for a preset of the initial electron beam parameters which have been determined by TRSV,do the comparisons of the measured results of PDDm,OARm in a real water phantom,and then use the deviations of calculated and measured results to slightly modify the initial electron beam model back and forth until the deviations meet the error less than 2%.Results:The deviations between the Monte Carlo simulation results of percentage depth doses at PDDc and off-axis ratios OARc and the measured results of PDDm and OARm in a water phantom were within 2%.Conclusion:When doing the Monte Carlo simulation to determine the parameters of an initial electron beam for a particular medical linac like BJ-6,modifying some parameters based on the particle dynamics calculation code would give some more reasonable and more acceptable results.展开更多
Purpose: To model the ELEKTA COMPACT accelerator head by using EGSnrc/BEAMnrc/DOSXYZnrc and to validatethe simulation according to the depth-dose and lateral profiles of different radiation fields measured by the...Purpose: To model the ELEKTA COMPACT accelerator head by using EGSnrc/BEAMnrc/DOSXYZnrc and to validatethe simulation according to the depth-dose and lateral profiles of different radiation fields measured by the water phantom. Methods: IBA Blue Water Phantom2 and CC13 Ionization Chamber were used to measure the depth-dose curves at 10 cm × 10 cm field and profile curves at 10 cm depth underwater. In BEAMnrc, the main components of accelerator head and the initial electron beam are established based on the specifications file, and the phase space file containing the photon beam information is generated. In DOXYZnrc, phase space files were used to irradiate a homogeneous water phantom of the same size as the IBA water phantom, and the simulated percentage depth dose curves and lateral profiles were outputted. The accuracy of the model was evaluated by mean square error (MSE) compared with the measured data. PDD curves are used to determine the energy of the initial electron beam. Dose profile curves are used to adjust the flattening filter. The penumbra on lateral profiles is used to adjust the full-width half-maximum (FWHM) of the electron source. Result: The electron energy of 5.8 MeV was considered the best match after comparing the PDD curves of 5.6 - 6.2 MeV electron beams. The flattening filter can only be adjusted by trial. In the final result, the maximum fluctuation of profile curve within 80% of the maximum field size is less than 3%, which meets the requirements of field flatness. The optimum FWHM for different fields is not consistent due to the Transmission penumbra. But a match can be approached by adjusting the FWHM every 10 cm field size.展开更多
The geometric structure, mechanism of detonation initiation and stability of transition metal carbohydrazide (CHZ) nitrates are investigated via density functional theory. The obtained results show that the Heyd-Scu...The geometric structure, mechanism of detonation initiation and stability of transition metal carbohydrazide (CHZ) nitrates are investigated via density functional theory. The obtained results show that the Heyd-Scuseria-Ernzerhof (HSE) functional yields the most accurate geometry. The initiating reaction of detonation in [Mn(CHZ)3](NO3)2 and [Zn(CHZ)3](NO3)2 is the formation of NO3 radicals. The calculated heat of formation and energy gap predict that the Mn and Zn complexes, which have the half-filled (3d5) and full-filled (3d10) electron configurations for the transition metal ions, respectively are more stable than the Co, Ni and Cu complexes. This indicates that the electron configuration of transition metal ion plays an important role in the stabilities of these energetic complexes.展开更多
Sodium perfluoroalkanesulfinates [Cl(CF_2)n SO_2 Na (1), a, n=4; b, n=6; c, n=8] with the reduction potentials about 0.95-1.00V could be oxidized readily with various oxidizing agents such as Mn (OAc)_3·2H_2O, Ce...Sodium perfluoroalkanesulfinates [Cl(CF_2)n SO_2 Na (1), a, n=4; b, n=6; c, n=8] with the reduction potentials about 0.95-1.00V could be oxidized readily with various oxidizing agents such as Mn (OAc)_3·2H_2O, Ce(SO_4)_2, HgSO_4 and Co_2O_3 to generate perfluoroalkyl radicals which added to the olefins RCH=CHR′to give two kinds of adducts, namely RCH (R_f) CHXR′(3, X=H; 4, X=OAc), with good yields depending upon the solvent system used. Different oxidizing agents showed slight variation on the yields of the adducts. The reaction time could be greatly shortened at higher temperature. Thus, this reaction provides a new way for introducing a perfluoroalkyl group into olefinic compounds.展开更多
基金supported by the Foundation of State Key Laboratory of Intense Pulsed Radiation Simulation and Effect (No. SKLIPR1601)
文摘As one of the most important elements in linear transformer driver(LTD) based systems, the gas pressurized closing switches are required to operate with a very low prefire probability during the DC-charging process to ensure reliable operation and stable output of the whole pulsed power system. The most direct and effective way to control the prefire probability is to select a suitable working coefficient. The study of the development characteristics of the initially generated electrons is useful for optimizing the working coefficient and improving the prefire characteristic of the switches. In this paper an ultraviolet pulsed laser is used to generate initial electrons inside the gap volume. A current measuring system is used to measure the time-dependent current generated by the growth of the initial electrons so as to study the development characteristics of the electrons under different working coefficients. Experimental results show that the development characteristics of the initial electrons are influenced obviously by the working coefficient. With the increase of the working coefficient, the development degree of the electrons increases consequently. At the same times, there is a threshold of working coefficient which produces the effect of ionization on electrons. The range of the threshold has a slow growth but remains close to 65% with the gas pressure increase. When the working coefficient increases further, γ processes are starting to be generated inside the gap volume. In addition, an optimal working coefficient beneficial for improving the prefire characteristic is indicated and further tested.
基金Project supported by the National Natural Science Foundation of China(Grant No.12074142)the Natural Science Foundation of Jilin Province of China(Grant No.20180101225JC)the Graduate Innovation Fund of Jilin University,China(Grant No.101832020CX337)。
文摘We theoretically investigate the effects of different electronic states as the initial state on the vortex patterns in photoelectron momentum distributions(PMDs)from numerical solutions of the two-dimensional(2D)time-dependent Schrodinger equation(TDSE)of He^(+)with a pair of counter-rotating circularly polarized attosecond pulses.It is found that the number of spiral arms in vortex patterns is equal to the number of the absorbed photons when the initial state is the ground state.However,the number of spiral arms in vortex patterns is always two more than the number of the absorbed photons when the initial state is the excited state.This sensitivity is attributed to the initial electron density distribution.In addition,we have demonstrated the PMDs for different initial electronic states with the same wavelengths and analyzed their corresponding physical mechanisms.It is illustrated that the method presented can be employed to effectively control the distribution of the electron vortices.
文摘Objective:In this study,we try to establish an initial electron beam model by combining Monte Carlo simulation method with particle dynamic calculation(TRSV)for the single 6 MV X-ray accelerating waveguide of BJ-6 medical linac.Methods and Materials:1.We adapted the treatment head configuration of BJ-6 medical linac made by Beijing Medical Equipment Institute(BMEI)as the radiation system for this study.2.Use particle dynamics calculation code called TRSV to drive out the initial electron beam parameters of the energy spectrum,the spatial intensity distribution,and the beam incidence angle.3.Analyze the 6 MV X-ray beam characteristics of PDDc,OARc in a water phantom by using Monte Carlo simulation(BEAMnrc,DOSXYZnrc)for a preset of the initial electron beam parameters which have been determined by TRSV,do the comparisons of the measured results of PDDm,OARm in a real water phantom,and then use the deviations of calculated and measured results to slightly modify the initial electron beam model back and forth until the deviations meet the error less than 2%.Results:The deviations between the Monte Carlo simulation results of percentage depth doses at PDDc and off-axis ratios OARc and the measured results of PDDm and OARm in a water phantom were within 2%.Conclusion:When doing the Monte Carlo simulation to determine the parameters of an initial electron beam for a particular medical linac like BJ-6,modifying some parameters based on the particle dynamics calculation code would give some more reasonable and more acceptable results.
文摘Purpose: To model the ELEKTA COMPACT accelerator head by using EGSnrc/BEAMnrc/DOSXYZnrc and to validatethe simulation according to the depth-dose and lateral profiles of different radiation fields measured by the water phantom. Methods: IBA Blue Water Phantom2 and CC13 Ionization Chamber were used to measure the depth-dose curves at 10 cm × 10 cm field and profile curves at 10 cm depth underwater. In BEAMnrc, the main components of accelerator head and the initial electron beam are established based on the specifications file, and the phase space file containing the photon beam information is generated. In DOXYZnrc, phase space files were used to irradiate a homogeneous water phantom of the same size as the IBA water phantom, and the simulated percentage depth dose curves and lateral profiles were outputted. The accuracy of the model was evaluated by mean square error (MSE) compared with the measured data. PDD curves are used to determine the energy of the initial electron beam. Dose profile curves are used to adjust the flattening filter. The penumbra on lateral profiles is used to adjust the full-width half-maximum (FWHM) of the electron source. Result: The electron energy of 5.8 MeV was considered the best match after comparing the PDD curves of 5.6 - 6.2 MeV electron beams. The flattening filter can only be adjusted by trial. In the final result, the maximum fluctuation of profile curve within 80% of the maximum field size is less than 3%, which meets the requirements of field flatness. The optimum FWHM for different fields is not consistent due to the Transmission penumbra. But a match can be approached by adjusting the FWHM every 10 cm field size.
基金supported by the National Natural Science Foundation of China(No.20471008)the Natural Science Foundation of Chongqing(No.cstc2011jjA50013)the Chongqing Municipal Commission of Education(No.KJ111310)
文摘The geometric structure, mechanism of detonation initiation and stability of transition metal carbohydrazide (CHZ) nitrates are investigated via density functional theory. The obtained results show that the Heyd-Scuseria-Ernzerhof (HSE) functional yields the most accurate geometry. The initiating reaction of detonation in [Mn(CHZ)3](NO3)2 and [Zn(CHZ)3](NO3)2 is the formation of NO3 radicals. The calculated heat of formation and energy gap predict that the Mn and Zn complexes, which have the half-filled (3d5) and full-filled (3d10) electron configurations for the transition metal ions, respectively are more stable than the Co, Ni and Cu complexes. This indicates that the electron configuration of transition metal ion plays an important role in the stabilities of these energetic complexes.
文摘Sodium perfluoroalkanesulfinates [Cl(CF_2)n SO_2 Na (1), a, n=4; b, n=6; c, n=8] with the reduction potentials about 0.95-1.00V could be oxidized readily with various oxidizing agents such as Mn (OAc)_3·2H_2O, Ce(SO_4)_2, HgSO_4 and Co_2O_3 to generate perfluoroalkyl radicals which added to the olefins RCH=CHR′to give two kinds of adducts, namely RCH (R_f) CHXR′(3, X=H; 4, X=OAc), with good yields depending upon the solvent system used. Different oxidizing agents showed slight variation on the yields of the adducts. The reaction time could be greatly shortened at higher temperature. Thus, this reaction provides a new way for introducing a perfluoroalkyl group into olefinic compounds.