Thin wall samples of high density polyethylene （HDPE） were prepared via injection molding with different injection speeds ranging from 100 mm/s to 1200 mm/s. A significant decrease in the tensile strength and Young...Thin wall samples of high density polyethylene （HDPE） were prepared via injection molding with different injection speeds ranging from 100 mm/s to 1200 mm/s. A significant decrease in the tensile strength and Young＇s modulus was observed with increasing injection speed. In order to investigate the mechanism behind this decrease, the orientation, molecular weight, molecular weight distribution, melt flow rate, crystallinity and crystal morphology of HDPE were characterized using two-dimensional wide-angle X-ray diffraction （2D-WAXD）, gel permeation chromatography （GPC）, capillary rheometry and differential scanning calorimetry （DSC）, respectively. It is demonstrated that the orientation, molecular weight, molecular weight distribution, melt flow rate and crystallinity have no obvious change with increasing injection speed. Nevertheless, the content of extended chain crystals or large folded chain crystals was found to decrease with increasing injection speed. Therefore, it is concluded that the decrease in tensile properties is mainly contributed by the reduced content of extended chain crystals or large folded chain crystals. This study provides industry with valuable information for the application of high speed injection molding.展开更多
Based on the oil,gas and water distribution characteristics of Khasib reservoir in Halfaya oilfield,Iraq,a core displacement experiment is designed to evaluate the influence of different displacement methods and displ...Based on the oil,gas and water distribution characteristics of Khasib reservoir in Halfaya oilfield,Iraq,a core displacement experiment is designed to evaluate the influence of different displacement methods and displacement parameters on oil displacement efficiency.The research shows that,in the displacement method with water injected from the edge of the reservoir,early depletion production is conducive to the elastic expansion of the gas cap,forming the three-dimensional displacement of"upper pressure and lower pushing",and the oil displacement effect is good.When gas injection at the top and water injection at the edge are used for synergistic displacement,the injection timing has different influences on the oil displacement effects of high and low parts.Considering the overall oil displacement efficiency,the injection pressure should be greater than the bubble point pressure of crude oil.Two displacement methods are recommended with the reasonable injection time at 20–25 MPa.The injection speed has the same influence on different injection media.Appropriately reducing the injection speed is conducive to the stability of the displacement front,delaying the breakthrough of injection media and improving the oil displacement effect.The reasonable injection rate of water flooding is 0.075 mL/min,the reasonable injection rates of water and gas are 0.15 mL/min and 0.10 mL/min,respectively in gas-water synergistic displacement.Gas-water synergistic displacement is conducive to the production of crude oil at high position,and has crude oil recovery 5.0%–14.8%higher than water flooding from the edge,so it is recommended as the development mode of Khasib reservoir at the middle and late stages.展开更多
基金supported by the National Natural Science Foundation of China(No.51073111)
文摘Thin wall samples of high density polyethylene （HDPE） were prepared via injection molding with different injection speeds ranging from 100 mm/s to 1200 mm/s. A significant decrease in the tensile strength and Young＇s modulus was observed with increasing injection speed. In order to investigate the mechanism behind this decrease, the orientation, molecular weight, molecular weight distribution, melt flow rate, crystallinity and crystal morphology of HDPE were characterized using two-dimensional wide-angle X-ray diffraction （2D-WAXD）, gel permeation chromatography （GPC）, capillary rheometry and differential scanning calorimetry （DSC）, respectively. It is demonstrated that the orientation, molecular weight, molecular weight distribution, melt flow rate and crystallinity have no obvious change with increasing injection speed. Nevertheless, the content of extended chain crystals or large folded chain crystals was found to decrease with increasing injection speed. Therefore, it is concluded that the decrease in tensile properties is mainly contributed by the reduced content of extended chain crystals or large folded chain crystals. This study provides industry with valuable information for the application of high speed injection molding.
基金Supported by the Scientific Research and Technology Development Project of CNPC(2019D-4410)。
文摘Based on the oil,gas and water distribution characteristics of Khasib reservoir in Halfaya oilfield,Iraq,a core displacement experiment is designed to evaluate the influence of different displacement methods and displacement parameters on oil displacement efficiency.The research shows that,in the displacement method with water injected from the edge of the reservoir,early depletion production is conducive to the elastic expansion of the gas cap,forming the three-dimensional displacement of"upper pressure and lower pushing",and the oil displacement effect is good.When gas injection at the top and water injection at the edge are used for synergistic displacement,the injection timing has different influences on the oil displacement effects of high and low parts.Considering the overall oil displacement efficiency,the injection pressure should be greater than the bubble point pressure of crude oil.Two displacement methods are recommended with the reasonable injection time at 20–25 MPa.The injection speed has the same influence on different injection media.Appropriately reducing the injection speed is conducive to the stability of the displacement front,delaying the breakthrough of injection media and improving the oil displacement effect.The reasonable injection rate of water flooding is 0.075 mL/min,the reasonable injection rates of water and gas are 0.15 mL/min and 0.10 mL/min,respectively in gas-water synergistic displacement.Gas-water synergistic displacement is conducive to the production of crude oil at high position,and has crude oil recovery 5.0%–14.8%higher than water flooding from the edge,so it is recommended as the development mode of Khasib reservoir at the middle and late stages.
