The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and heal...The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and health communication.This study employs a comprehensive framework based on the five elements of the mass communication model:information source,communication subject,communication object,message content,and post-communication feedback.Additionally,it incorporates the interactive ritual chain theory to examine the evolving dynamics and developmental trajectory of research in the social history of medicine during the new media era.Conclusively,this paper acknowledges the existing interaction gaps in the interaction between health communication and the social history of medicine research while outlining the challenges for fostering collaboration and proposing strategic optimizations for effective integration.展开更多
Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and hei...Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and heightening TB mortality. Determining interaction mechanism between HIV and Mycobacterium tuberculosis can lead to development of effective treatments. This study summarizes prevalence status of AIDS and TB coinfection and research advances concerning their interaction mechanism.展开更多
A systematic analysis has been carried out to investigate the fields of application and interaction mechanism of polymeric carbohydrate, i.e. polysaccharides (including starch, dextrin, cellulose and cellulosic deriva...A systematic analysis has been carried out to investigate the fields of application and interaction mechanism of polymeric carbohydrate, i.e. polysaccharides (including starch, dextrin, cellulose and cellulosic derivatives) on various oxides and salt-type minerals in the article, interaction mechanisms of electrostatic, of hydrogen bonding, and of chemical interaction between polymeric carbohydrate and these minerals are put forward.展开更多
Semi-metal friction material was applied widely in brake process of traffic and dynamical system. The friction materials with rare earth additive were manufactured by heating press molding process. The effects of diff...Semi-metal friction material was applied widely in brake process of traffic and dynamical system. The friction materials with rare earth additive were manufactured by heating press molding process. The effects of different reinforcing fibers and adhesives on the properties of the materials were studied by changing the formula. The results showed that the friction materials with YSM resin adhesive and hybrid fibers (Kevlar pulp and steel fiber) had higher and more stable friction coefficient and lower wear rate. Semi-metal friction materials with rare earths formed iron-rich surface layer in the worn surface, and the mechanisms of wear had obvious differences at typical temperature ranges.展开更多
ESR measurements using spin trapping technique were carried out for β-carotene-halobenzene system under UV light irradiation.The ESR spectra observed in the presence and in the absence of β-carotene are markedly dif...ESR measurements using spin trapping technique were carried out for β-carotene-halobenzene system under UV light irradiation.The ESR spectra observed in the presence and in the absence of β-carotene are markedly different.The possible scheme of β-carotene interacting with halogen atom was proposed.展开更多
The electronic structure and bonding nature of adsorbing bonding complexes which consist of Amphoteric Collector-I and Mg^(2+), Ca^(2+), MgPO_4^-, CaPO_^-4, CaCO_3, as well aa MgCO_3, are studied using quantum chemist...The electronic structure and bonding nature of adsorbing bonding complexes which consist of Amphoteric Collector-I and Mg^(2+), Ca^(2+), MgPO_4^-, CaPO_^-4, CaCO_3, as well aa MgCO_3, are studied using quantum chemistry CNDO/2, It is predicted that magnesium salts are more liable to form adsorbing chelates with Amphoteric Collector-I than calcium salts, and all results coincide with that obtained in flotation.展开更多
In the actual complex environment,the recognition accuracy of crop leaf disease is often not high.Inspired by the brain parallel interaction mechanism,a two-stream parallel interactive convolutional neural network(TSP...In the actual complex environment,the recognition accuracy of crop leaf disease is often not high.Inspired by the brain parallel interaction mechanism,a two-stream parallel interactive convolutional neural network(TSPI-CNN)is proposed to improve the recognition accuracy.TSPI-CNN includes a two-stream parallel network(TSP-Net)and a parallel interactive network(PI-Net).TSP-Net simulates the ventral and dorsal stream.PI-Net simulates the interaction between two pathways in the process of human brain visual information transmission.A large number of experiments shows that the proposed TSPI-CNN performs well on MK-D2,PlantVillage,Apple-3 leaf,and Cassava leaf datasets.Furthermore,the effect of numbers of interactions on the recognition performance of TSPI-CNN is discussed.The experimental results show that as the number of interactions increases,the recognition accuracy of the network also increases.Finally,the network is visualized to show the working mechanism of the network and provide enlightenment for future research.展开更多
To investigate the stability and interaction mechanism of the slope-pile-footing system under surcharge effects,the finite difference method(FDM)was adopted to analyze the response laws of the stability of the reinfor...To investigate the stability and interaction mechanism of the slope-pile-footing system under surcharge effects,the finite difference method(FDM)was adopted to analyze the response laws of the stability of the reinforced slope,evolution of the critical slip surface,stress characteristic of retaining structures,deformation and failure modes of the slope foundation and building footing under surcharge parameters,including the surcharge intensity,the surcharge position,and the surcharge width.The results show that surcharge parameters significantly affect the stability and the deformation characteristics of the slope-pile-footing system.Specifically speaking,with the increasing surcharge intensity and the decreasing surcharge position and width,the deformation and failure mode of the system will gradually evolve in a direction that is harmful to its stability.The interaction mechanism of the slope-pile-footing system is further clarified as the load transfer of the building footing,the generation of the additional stress in the slope foundation,and the adjustment of pile bending moment due to the stress redistribution.Correspondingly,the safety of anti-slide piles will determine the stability of the slope foundation and building footing.These findings are expected to provide guidance for the comprehensive development and utilization of filled slopes after reinforcement.展开更多
This review focuses on the occurrence and interactions of engineered nanoparticles(ENPs)and brominated flame retardants(BFRs)such as polybrominated diphenyl ethers(PBDEs)in water systems and the generation of highly c...This review focuses on the occurrence and interactions of engineered nanoparticles(ENPs)and brominated flame retardants(BFRs)such as polybrominated diphenyl ethers(PBDEs)in water systems and the generation of highly complex compounds in the environment.The release of ENPs and BFRs(e.g.PBDEs)to aquatic environments during their usage and disposal are summarised together with their key interaction mechanisms.The major interaction mechanisms including electrostatic,van derWaals,hydrophobic,molecular bridging and steric,hydrogen andπ-bonding,cation bridging and ligand exchange were identified.The presence of ENPs could influence the fate and behaviour of PBDEs through the interactions as well as induced reactions under certain conditions which increases the formation of complex compounds.The interaction leads to alteration of behaviour for PBDEs and their toxic effects to ecological receptors.The intermingled compound(ENPs-BFRs)would show different behaviour from the parental ENPs or BFRs,which are currently lack of investigation.This review provided insights on the interactions of ENPs and BFRs in artificial,environmental water systems and wastewater treatment plants(WWTPs),which are important for a comprehensive risk assessment.展开更多
A series of novel chalcone derivatives that contain the 1,1-dichloropropene moiety was designed and synthesized. Bioactivity assays showed that most of the target compounds exhibited moderate to good antiviral activit...A series of novel chalcone derivatives that contain the 1,1-dichloropropene moiety was designed and synthesized. Bioactivity assays showed that most of the target compounds exhibited moderate to good antiviral activity against tobacco mosaic virus(TMV) at 500 mg/m L. Among the target compounds,compound 7h showed the highest in vivo inactivation activity against TMV with the EC50 and EC90value of 45.6 and 327.5 mg/m L, respectively, which was similar to that of Ningnanmycin(46.9 and 329.4 mg/m L)and superior to that of Ribavirin(145.1 and 793.1 mg/m L). Meanwhile, the microscale thermophoresis and fluorescence spectroscopy experiments showed that the compound 7h had a strong interaction with the tobacco mosaic virus coat protein.展开更多
As the poor dispersion of oily collectors and the inferior hydrophobicity of the mineral surface, the lowrank coal has an unsatisfactory flotation performance when using traditional collectors. In this paper, an ionic...As the poor dispersion of oily collectors and the inferior hydrophobicity of the mineral surface, the lowrank coal has an unsatisfactory flotation performance when using traditional collectors. In this paper, an ionic liquid microemulsion was used as a collector to enhance its floatability. Flotation test results demonstrated the microemulsion collector exhibited a superior collecting ability. A satisfactory separation performance of 78.66% combustible material recovery was obtained with the microemulsion collector consumption of 6 kg/t, which was equivalent to the flotation performance of diesel at a dosage of25 kg/t. The dispersion behavior of the microemulsion collector was investigated using the CryogenicTransmission Electron Microscopy. The interaction mechanism of the microemulsion collector on enhancing the low-rank coal flotation was elucidated through the Zeta potential and contact angle measurements, the Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analysis.The microemulsion collector exhibited superior dispersibility, which was dispersed into positively charged oil droplets with an average size of 160.21 nm in the pulp. Furthermore, the nano-oil droplets could be more efficiently adsorbed on the low-rank coal surface through electrostatic attraction, resulting in the improvement of its hydrophobicity. Thus, the microemulsion collector shows great application potential in improving the flotation performance of low-rank coal.展开更多
The interaction mechanism between the combustion products of pulverized coal injected and coke in the raceway of blast furnace was studied through thermodynamic calculation and experiments.The results indicated that a...The interaction mechanism between the combustion products of pulverized coal injected and coke in the raceway of blast furnace was studied through thermodynamic calculation and experiments.The results indicated that additives significantly affected the melting property of coal ash in high temperature zone.Although the unburnt char,raw coal ash,and catalyzed coal ash failed to wet the coke surface,the wettability of the catalyzed coal ash on the coke was greater than that of the raw coal ash.Since the unburnt char had weak reaction with the coke surface,it showed little influence on the surface morphology of the coke.The interaction between the raw coal ash and the coke gave rise to the increase in the pore size on the coke surface.However,the raw coal ash only affected the coke surface and the entrances of the pores owing to its poor fluidity.After being melted,the catalyzed coal ash was expected to immerge into the inside part of the coke and then react with the coke,resulting in an expansion and increase of coke cavities.The raw coal ash and the unburnt char reduced the coke reactivity,while the catalyzed coal ash improved the coke reactivity.Thereinto,the coal ash containing Fe2O3 exhibited a larger influence on the reactivity than that containing CaO.展开更多
This study demonstrated the interaction mechanism of collagen peptides(CPs)with 4-ethylphenol(4-EP),phenol,guaiacol,and 4-ethylguaiacol(4-EG)in the ethanol-water solution.The ultraviolet visible spectroscopy,zeta pote...This study demonstrated the interaction mechanism of collagen peptides(CPs)with 4-ethylphenol(4-EP),phenol,guaiacol,and 4-ethylguaiacol(4-EG)in the ethanol-water solution.The ultraviolet visible spectroscopy,zeta potential tests and hydrogen nuclear magnetic spectroscopy manifested that CPs interacted with the phenolic compounds.Meanwhile,Isothermal titration calorimetry determination indicated that the CPs was hydrogen bonded with 4-EP in 52%(v/v)ethanol-water solution,while the hydrophobic forces played a major role in the interaction of CPs with guaiacol and 4-EG,respectively.Moreover,hydrogen and hydrophobic bonds were involved in the interaction between CPs and phenol.Finally,Head Space-solid Phase Microextraction Gas Chromatography Mass Spectrometry analysis indicated that the content of phenolic compounds in model solution efficiently decreased with the presence of CPs.In the real liquor,it was found that the content of volatile compounds(including phenolic compounds)was obviously decreased after CPs added.展开更多
Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely...Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely clarified.In the present work,the bimolecular tautomerization mechanism induced by both concerted and radical interactions was proposed and carefully confirmed.A characteristicβ-O-4 lignin dimer,2-phenoxy-1-phenylethanol(α-OH-PPE),was used as the model compound to reveal two representative keto-phenol and enol-keto tautomerism mechanisms,based on theoretical calculations combined with pyrolysis experiments.The results indicate that the unimolecular tautomerism as the rate-determining step limits product generation,due to fairly high energy barriers.While the free hydroxy compounds and radicals derived from initial pyrolysis can further initiate bimolecular tautomerism reactions through the one-step concerted hydroxyl-assisted hydrogen transfer(hydroxylAHT)and two-step radical hydrogen abstraction interactions,respectively.By alleviating and even avoiding the large ring tension of tautomerism,the unstable tautomers(2,4-cyclohexadienone and1-hydroxy styrene)can be rapidly tautomerized into stable phenol and acetophenone with the help of intermolecular interaction.Benefitting from the significant advantage of retro-ene fragmentation in breaking theβ-O-4 bond to form tautomers,a large amount of stable phenolic and ketone products can be generated following bimolecular tautomerization in the pyrolysis ofβ-O-4 linked lignin.展开更多
Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In...Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In situ stresses can be influenced by various factors,one of the most important being the existence of faults.A fault could significantly affect the value and direction of the stress components.Reorientation and magnitude changes in stresses exist adjacent to faults and stress jumps/discontinuities across the fault.By contrast,the change in the stress state may lead to the transformation of faulting type and potential fault reactivation.Qualitative fault reactivation assessment using characteristic parameters under the current stress environment provides a method to assess the slip tendency of faults.The correlation between in situ stresses and fault properties enhances the ability to predict the fault slip tendency via stress measurements,which can be used to further refine the assessment of the fault reactivation risk.In the future,stress measurements at greater depths and long-term continuous real-time stress monitoring near/on key parts of faults will be essential.In addition,much attention needs to be paid to distinguishing the genetic mechanisms of abnormal stress states and the type and scale of stress variations and exploring the mechanisms of pre-faulting anomaly and fault reactivation.展开更多
In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the a...In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the atmosphere and the ocean. There exist two kinds of air-sea interaction waves in the coupled model, that is, the high-frequency fast waves and the low-frequency slow waves. The phase speed of the fast waves is westward and the frequencies are close to those of the equatorial Rossby waves in the atmosphere. The slow waves propagate westward in the part of short wavelengths and eastward in that of long wavelengths. There exist instabilities for both the westward and eastward propagating slow waves. If the fast waves are filtered off, there is little effect on the slow waves which have great influence on the long range process in the tropical air-sea coupled system. According to the tropical air-sea interaction waves we obtain here, a possible explanation to the propagating process of ENSO events is given.展开更多
The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can b...The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can be easily produced between these three elements in the filler metal, which greatly limited the formation of the isolated phase Pb or Bi and also eliminated the bad effect of impurity elements Pb and Bi on the spreading property of Ag-based filler metal. The metallurgical and quantum-mechanical bond formation analysis show that a strong chemical affinity was existed between the rare-earth element Ce and impurity elements Pb and Bi, which was proved by the XRD analysis results.展开更多
Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are...Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are a common constituent in shales and form the dominant pore network of many shale gas systems.展开更多
The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300...The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates(AlPO_4 and K_5P_3O_(10))compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.展开更多
This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were in...This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were investigated by enzymatic kinetics,multi-spectroscopy methods,thermodynamics analysis,molecular docking,and dynamic simulations.PC and TA could bind with CEase and inhibit the activity of enzyme in a mixed-competitive manner and non-competitive manner,which was verified by molecular docking simulations and dynamics simulations.Also,PC and TA showed the synergistic inhibition with orlistat.Fluorescence,UVvis and the thermodynamic analysis revealed that the complexes were formed from CEase and inhibitors by noncovalent interaction.As revealed by the circular dichroism results,both PC and TA decreased enzymatic activities by altering the conformations of CEase.The inhibition of PC and TA on CEase might be one mechanism for its cholesterol-lowering effect.展开更多
基金University of Science and Technology of China Quality Project History of Medicine(2023YCZX02)Digital Museum Construction Project of Chinese Centre for Disease Control and Prevention(BB2110240080)The National Key R&D project granted by the Ministry of Science and Technology(2018YFA0902400).
文摘The mass communication model and interactive ritual chain theory,which serve as communication paradigms in the new media era,facilitate and enhance the synergy between the fields of social history of medicine and health communication.This study employs a comprehensive framework based on the five elements of the mass communication model:information source,communication subject,communication object,message content,and post-communication feedback.Additionally,it incorporates the interactive ritual chain theory to examine the evolving dynamics and developmental trajectory of research in the social history of medicine during the new media era.Conclusively,this paper acknowledges the existing interaction gaps in the interaction between health communication and the social history of medicine research while outlining the challenges for fostering collaboration and proposing strategic optimizations for effective integration.
文摘Human immunodeficiency virus(HIV) and tuberculosis(TB) coinfection is a serious public health problem. HIV and TB promote each other, accelerating development of HIV to acquired immunodeficiency syndrome(AIDS) and heightening TB mortality. Determining interaction mechanism between HIV and Mycobacterium tuberculosis can lead to development of effective treatments. This study summarizes prevalence status of AIDS and TB coinfection and research advances concerning their interaction mechanism.
文摘A systematic analysis has been carried out to investigate the fields of application and interaction mechanism of polymeric carbohydrate, i.e. polysaccharides (including starch, dextrin, cellulose and cellulosic derivatives) on various oxides and salt-type minerals in the article, interaction mechanisms of electrostatic, of hydrogen bonding, and of chemical interaction between polymeric carbohydrate and these minerals are put forward.
文摘Semi-metal friction material was applied widely in brake process of traffic and dynamical system. The friction materials with rare earth additive were manufactured by heating press molding process. The effects of different reinforcing fibers and adhesives on the properties of the materials were studied by changing the formula. The results showed that the friction materials with YSM resin adhesive and hybrid fibers (Kevlar pulp and steel fiber) had higher and more stable friction coefficient and lower wear rate. Semi-metal friction materials with rare earths formed iron-rich surface layer in the worn surface, and the mechanisms of wear had obvious differences at typical temperature ranges.
文摘ESR measurements using spin trapping technique were carried out for β-carotene-halobenzene system under UV light irradiation.The ESR spectra observed in the presence and in the absence of β-carotene are markedly different.The possible scheme of β-carotene interacting with halogen atom was proposed.
文摘The electronic structure and bonding nature of adsorbing bonding complexes which consist of Amphoteric Collector-I and Mg^(2+), Ca^(2+), MgPO_4^-, CaPO_^-4, CaCO_3, as well aa MgCO_3, are studied using quantum chemistry CNDO/2, It is predicted that magnesium salts are more liable to form adsorbing chelates with Amphoteric Collector-I than calcium salts, and all results coincide with that obtained in flotation.
基金National Natural Science Foundation of China(Nos.61806051 and 61903078)Fundamental Research Funds for the Central Universities,China(Nos.2232021A-10 and 2232021D-32)Natural Science Foundation of Shanghai,China(No.20ZR1400400)。
文摘In the actual complex environment,the recognition accuracy of crop leaf disease is often not high.Inspired by the brain parallel interaction mechanism,a two-stream parallel interactive convolutional neural network(TSPI-CNN)is proposed to improve the recognition accuracy.TSPI-CNN includes a two-stream parallel network(TSP-Net)and a parallel interactive network(PI-Net).TSP-Net simulates the ventral and dorsal stream.PI-Net simulates the interaction between two pathways in the process of human brain visual information transmission.A large number of experiments shows that the proposed TSPI-CNN performs well on MK-D2,PlantVillage,Apple-3 leaf,and Cassava leaf datasets.Furthermore,the effect of numbers of interactions on the recognition performance of TSPI-CNN is discussed.The experimental results show that as the number of interactions increases,the recognition accuracy of the network also increases.Finally,the network is visualized to show the working mechanism of the network and provide enlightenment for future research.
基金funded by the National Key Research and Development Program of China(Nos.2018YFC1505302 and 2019YFC1509701)the National Natural Science Foundation of China(Nos.41977249 and 42090052)。
文摘To investigate the stability and interaction mechanism of the slope-pile-footing system under surcharge effects,the finite difference method(FDM)was adopted to analyze the response laws of the stability of the reinforced slope,evolution of the critical slip surface,stress characteristic of retaining structures,deformation and failure modes of the slope foundation and building footing under surcharge parameters,including the surcharge intensity,the surcharge position,and the surcharge width.The results show that surcharge parameters significantly affect the stability and the deformation characteristics of the slope-pile-footing system.Specifically speaking,with the increasing surcharge intensity and the decreasing surcharge position and width,the deformation and failure mode of the system will gradually evolve in a direction that is harmful to its stability.The interaction mechanism of the slope-pile-footing system is further clarified as the load transfer of the building footing,the generation of the additional stress in the slope foundation,and the adjustment of pile bending moment due to the stress redistribution.Correspondingly,the safety of anti-slide piles will determine the stability of the slope foundation and building footing.These findings are expected to provide guidance for the comprehensive development and utilization of filled slopes after reinforcement.
文摘This review focuses on the occurrence and interactions of engineered nanoparticles(ENPs)and brominated flame retardants(BFRs)such as polybrominated diphenyl ethers(PBDEs)in water systems and the generation of highly complex compounds in the environment.The release of ENPs and BFRs(e.g.PBDEs)to aquatic environments during their usage and disposal are summarised together with their key interaction mechanisms.The major interaction mechanisms including electrostatic,van derWaals,hydrophobic,molecular bridging and steric,hydrogen andπ-bonding,cation bridging and ligand exchange were identified.The presence of ENPs could influence the fate and behaviour of PBDEs through the interactions as well as induced reactions under certain conditions which increases the formation of complex compounds.The interaction leads to alteration of behaviour for PBDEs and their toxic effects to ecological receptors.The intermingled compound(ENPs-BFRs)would show different behaviour from the parental ENPs or BFRs,which are currently lack of investigation.This review provided insights on the interactions of ENPs and BFRs in artificial,environmental water systems and wastewater treatment plants(WWTPs),which are important for a comprehensive risk assessment.
基金supported by the National Natural Science Foundation of China(Nos.21362004,21562013)Subsidy Project for Outstanding Key Laboratory of Guizhou Province in China(20154004)
文摘A series of novel chalcone derivatives that contain the 1,1-dichloropropene moiety was designed and synthesized. Bioactivity assays showed that most of the target compounds exhibited moderate to good antiviral activity against tobacco mosaic virus(TMV) at 500 mg/m L. Among the target compounds,compound 7h showed the highest in vivo inactivation activity against TMV with the EC50 and EC90value of 45.6 and 327.5 mg/m L, respectively, which was similar to that of Ningnanmycin(46.9 and 329.4 mg/m L)and superior to that of Ribavirin(145.1 and 793.1 mg/m L). Meanwhile, the microscale thermophoresis and fluorescence spectroscopy experiments showed that the compound 7h had a strong interaction with the tobacco mosaic virus coat protein.
基金financially supported by the National Key Research and Development Program of China (No. 2020YFC1908801)the National Natural Science Foundation of China (No. 52204287)+1 种基金the National Natural Science Foundation of China (No. 52004250)the Key R&D and Promotion Projects in Henan Province (No. 212102310009)。
文摘As the poor dispersion of oily collectors and the inferior hydrophobicity of the mineral surface, the lowrank coal has an unsatisfactory flotation performance when using traditional collectors. In this paper, an ionic liquid microemulsion was used as a collector to enhance its floatability. Flotation test results demonstrated the microemulsion collector exhibited a superior collecting ability. A satisfactory separation performance of 78.66% combustible material recovery was obtained with the microemulsion collector consumption of 6 kg/t, which was equivalent to the flotation performance of diesel at a dosage of25 kg/t. The dispersion behavior of the microemulsion collector was investigated using the CryogenicTransmission Electron Microscopy. The interaction mechanism of the microemulsion collector on enhancing the low-rank coal flotation was elucidated through the Zeta potential and contact angle measurements, the Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analysis.The microemulsion collector exhibited superior dispersibility, which was dispersed into positively charged oil droplets with an average size of 160.21 nm in the pulp. Furthermore, the nano-oil droplets could be more efficiently adsorbed on the low-rank coal surface through electrostatic attraction, resulting in the improvement of its hydrophobicity. Thus, the microemulsion collector shows great application potential in improving the flotation performance of low-rank coal.
基金financially supported by the National Natural Science Foundation of China (No.51374166, 51574189)the Natural Science Foundation Research Project of Shaanxi,China(No.2016JQ5041)the Shaanxi Province Department of Education Fund, China(No.16JK1450)
文摘The interaction mechanism between the combustion products of pulverized coal injected and coke in the raceway of blast furnace was studied through thermodynamic calculation and experiments.The results indicated that additives significantly affected the melting property of coal ash in high temperature zone.Although the unburnt char,raw coal ash,and catalyzed coal ash failed to wet the coke surface,the wettability of the catalyzed coal ash on the coke was greater than that of the raw coal ash.Since the unburnt char had weak reaction with the coke surface,it showed little influence on the surface morphology of the coke.The interaction between the raw coal ash and the coke gave rise to the increase in the pore size on the coke surface.However,the raw coal ash only affected the coke surface and the entrances of the pores owing to its poor fluidity.After being melted,the catalyzed coal ash was expected to immerge into the inside part of the coke and then react with the coke,resulting in an expansion and increase of coke cavities.The raw coal ash and the unburnt char reduced the coke reactivity,while the catalyzed coal ash improved the coke reactivity.Thereinto,the coal ash containing Fe2O3 exhibited a larger influence on the reactivity than that containing CaO.
基金The National Key R&D Program of China(2017YFB0308500).
文摘This study demonstrated the interaction mechanism of collagen peptides(CPs)with 4-ethylphenol(4-EP),phenol,guaiacol,and 4-ethylguaiacol(4-EG)in the ethanol-water solution.The ultraviolet visible spectroscopy,zeta potential tests and hydrogen nuclear magnetic spectroscopy manifested that CPs interacted with the phenolic compounds.Meanwhile,Isothermal titration calorimetry determination indicated that the CPs was hydrogen bonded with 4-EP in 52%(v/v)ethanol-water solution,while the hydrophobic forces played a major role in the interaction of CPs with guaiacol and 4-EG,respectively.Moreover,hydrogen and hydrophobic bonds were involved in the interaction between CPs and phenol.Finally,Head Space-solid Phase Microextraction Gas Chromatography Mass Spectrometry analysis indicated that the content of phenolic compounds in model solution efficiently decreased with the presence of CPs.In the real liquor,it was found that the content of volatile compounds(including phenolic compounds)was obviously decreased after CPs added.
基金the National Natural Science Foundation of China(52276189,52106241)Natural Science Foundation of Jiangsu Province(BK20221248)for financial support。
文摘Bimolecular interactions play crucial roles in lignin pyrolysis.The tautomerization of key intermediates has a significant impact on the formation of stable products,whereas bimolecular tautomerization has been rarely clarified.In the present work,the bimolecular tautomerization mechanism induced by both concerted and radical interactions was proposed and carefully confirmed.A characteristicβ-O-4 lignin dimer,2-phenoxy-1-phenylethanol(α-OH-PPE),was used as the model compound to reveal two representative keto-phenol and enol-keto tautomerism mechanisms,based on theoretical calculations combined with pyrolysis experiments.The results indicate that the unimolecular tautomerism as the rate-determining step limits product generation,due to fairly high energy barriers.While the free hydroxy compounds and radicals derived from initial pyrolysis can further initiate bimolecular tautomerism reactions through the one-step concerted hydroxyl-assisted hydrogen transfer(hydroxylAHT)and two-step radical hydrogen abstraction interactions,respectively.By alleviating and even avoiding the large ring tension of tautomerism,the unstable tautomers(2,4-cyclohexadienone and1-hydroxy styrene)can be rapidly tautomerized into stable phenol and acetophenone with the help of intermolecular interaction.Benefitting from the significant advantage of retro-ene fragmentation in breaking theβ-O-4 bond to form tautomers,a large amount of stable phenolic and ketone products can be generated following bimolecular tautomerization in the pyrolysis ofβ-O-4 linked lignin.
基金financially supported by the National Natural Science Foundation of China (No.52204084)the Interdisciplinary Research Project for Young Teachers of USTB (the Fundamental Research Funds for the Central Universities,No.FRF-IDRY-20-013)+3 种基金the Fundamental Research Funds for the Central Universities and the Youth Teacher International Exchange and Growth Program (No.QNXM20220009)the Fundamental Research Funds for the Central Universities (No.FRF-TP-20-041A1)the China Postdoctoral Science Foundation (No.2021M700388)the National Key R&D Program of China (Nos.2022YFC2905600 and 2022YFC3004601)。
文摘Understanding the in situ stress state is crucial in many engineering problems and earth science research.The present article presents new insights into the interaction mechanism between the stress state and faults.In situ stresses can be influenced by various factors,one of the most important being the existence of faults.A fault could significantly affect the value and direction of the stress components.Reorientation and magnitude changes in stresses exist adjacent to faults and stress jumps/discontinuities across the fault.By contrast,the change in the stress state may lead to the transformation of faulting type and potential fault reactivation.Qualitative fault reactivation assessment using characteristic parameters under the current stress environment provides a method to assess the slip tendency of faults.The correlation between in situ stresses and fault properties enhances the ability to predict the fault slip tendency via stress measurements,which can be used to further refine the assessment of the fault reactivation risk.In the future,stress measurements at greater depths and long-term continuous real-time stress monitoring near/on key parts of faults will be essential.In addition,much attention needs to be paid to distinguishing the genetic mechanisms of abnormal stress states and the type and scale of stress variations and exploring the mechanisms of pre-faulting anomaly and fault reactivation.
文摘In this paper, the tropical air-sea interaction is discussed by using a simple air-sea coupled model, in which the inertia-gravity waves are filtered off and only the equatorial Rossby waves are reserved in both the atmosphere and the ocean. There exist two kinds of air-sea interaction waves in the coupled model, that is, the high-frequency fast waves and the low-frequency slow waves. The phase speed of the fast waves is westward and the frequencies are close to those of the equatorial Rossby waves in the atmosphere. The slow waves propagate westward in the part of short wavelengths and eastward in that of long wavelengths. There exist instabilities for both the westward and eastward propagating slow waves. If the fast waves are filtered off, there is little effect on the slow waves which have great influence on the long range process in the tropical air-sea coupled system. According to the tropical air-sea interaction waves we obtain here, a possible explanation to the propagating process of ENSO events is given.
文摘The mechanism of interaction relation between the rare-earth element Ce and elements Pb and Bi in Ag-based filler metal has been studied. The results show that the compounds CePb and CeBi with high melting point can be easily produced between these three elements in the filler metal, which greatly limited the formation of the isolated phase Pb or Bi and also eliminated the bad effect of impurity elements Pb and Bi on the spreading property of Ag-based filler metal. The metallurgical and quantum-mechanical bond formation analysis show that a strong chemical affinity was existed between the rare-earth element Ce and impurity elements Pb and Bi, which was proved by the XRD analysis results.
基金supported by the National Natural Science Foundation of China(grant No.41202103)China Postdoctoral Science Foundation(grant No. 2016M591350)
文摘Objective Shale gas is as an important kind of unconventional natural gas,with a great resource potential,and its exploration and development has attracted much attention around the world.Organic matter(OM)pores are a common constituent in shales and form the dominant pore network of many shale gas systems.
基金Funded by the National Natural Science Foundation of China(No.51472188)
文摘The interaction mechanism and phase evolution of ammonium polyphosphate(APP)mixed with muscovite(APP/muscovite)were studied by TG,XRD and SEM,respectively,during heating.When the temperature is not higher than 300 ℃,muscovite has no effect on the thermaldecomposition of APP,and the initialdecomposition temperature of APP/muscovite at 283 ℃ is basically the same as the APP at 295 ℃,and the main thermaldecomposition products are polyphosphoric acid and NH_4H_2PO_4 at 300 ℃.The polyphosphoric acid,the decomposition products of APP,can enable K and Siout of muscovite and interact with muscovite chemically to generate Al_2O_3·2SiO_2,α-SiO_2 and phosphates(AlPO_4 and K_5P_3O_(10))compounds during 400 ℃-800 ℃,which own obvious adhesive phenomenon and porous structure with the apparent porosity of 58.4%.Further reactions between phosphates other than reactions among Al_2O_3·2SiO_2 and α-SiO_2 can generate KAlP_2O_7 at 1 000 ℃ and the density of residualproduct is improved by low melting point phosphate filling pore to form relatively dense structure and decrease the apparent porosity to 44.4%.The flame resistant and self-supported ceramic materials are expected to enhance the fire-retarding synergistic effect between APP and muscovite.
基金supported by the National Basic Research Program of China(‘973’program,2013CB127106)。
文摘This study was aimed to analyze the effect of procyanidin B2(PC)and tannin acid(TA)on the activities of cholesterol esterase(CEase)and the inhibitory mechanisms of enzymatic activity.The interaction mechanisms were investigated by enzymatic kinetics,multi-spectroscopy methods,thermodynamics analysis,molecular docking,and dynamic simulations.PC and TA could bind with CEase and inhibit the activity of enzyme in a mixed-competitive manner and non-competitive manner,which was verified by molecular docking simulations and dynamics simulations.Also,PC and TA showed the synergistic inhibition with orlistat.Fluorescence,UVvis and the thermodynamic analysis revealed that the complexes were formed from CEase and inhibitors by noncovalent interaction.As revealed by the circular dichroism results,both PC and TA decreased enzymatic activities by altering the conformations of CEase.The inhibition of PC and TA on CEase might be one mechanism for its cholesterol-lowering effect.