To investigate the dynamic behavior and energy dissipation of the rock−concrete interface,dynamic splitting tests on bi-material discs were conducted by using the split Hopkinson pressure bar.The test results reveal t...To investigate the dynamic behavior and energy dissipation of the rock−concrete interface,dynamic splitting tests on bi-material discs were conducted by using the split Hopkinson pressure bar.The test results reveal that with the change of the interface inclination angles(θ),the influence of interface groove width on the bearing capacity of specimens also varies.Whenθincreases from 0°to 30°,the bearing capacity of the specimen increases first and then decreases with the rise of the interface groove width;the optimal groove width on the rock surface in this range of interface inclination angles is 5 mm.Whenθincreases from 45°to 90°,the bearing capacity of the specimen has no obvious change.Moreover,whenθincreases from 0°to 45°,the dissipated energy of the specimens rises obviously at first and then tends to be stable as the width of the interface groove increases.展开更多
Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation ...Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation agrees well with that determined from deposition rate. The interfacial roughness parameter ξof several samples calculated by X-ray diffraction is between 3.5(?) and 5.6(?).展开更多
This paper developed a hot Pressing aided exothermic synthesis (HPES) technique. to fabricate NiAl matrix composites containing 0 and 20 v.% TiB_2 particles. The conversion to the product was complete. and TiB_2 parti...This paper developed a hot Pressing aided exothermic synthesis (HPES) technique. to fabricate NiAl matrix composites containing 0 and 20 v.% TiB_2 particles. The conversion to the product was complete. and TiB_2 particles in the matrix were uniformly dispersed. The inter faces between nail and TiB_2 were atomically flat. sharp and free from any inter facial phases in most cases. In some cases. however. thin inter facial amorphous layers existed at NiAl/ TiB_2 interfaces. In addition, the microstructure and inter faces were highly thermal stable. In all processing states. the yield strengths at room temperature or at 1000℃ of the composite were approximately three times as strong as that of the unrein forced NiAl. The ambient fracture toughness of the composite was also superior to monolithic NiAl.展开更多
Currently for the steel tube reinforced concrete composite pile research, although predecessors make a comprehensive research on the composite pile beating performance, design technology, but there are still many prob...Currently for the steel tube reinforced concrete composite pile research, although predecessors make a comprehensive research on the composite pile beating performance, design technology, but there are still many problems have not been solved, such as the steel tube reinforced concrete pile composite interracial force learn performance research is still in the initial stage. In this paper, we mainly discuss the research methods of several interface mechanical properties and propose the possibility of studying the mechanical properties of the steel tube reinforced concrete composite pile by using the principle of ultrasonic speckle.展开更多
Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as a...Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as anisotropic hard/soft-magnetic multilayer films,ferromagnetic/antiferromagnetic/ferromagnetic trilayers,[Pt/Co]/NiFe/NiO heterostructures,Co/NiO and Co/NiO/Fe trilayers on an anodic aluminum oxide(AAO) template.The exchange-coupling interaction between soft-and hard-magnetic phases,interlayer and interfacial exchange couplings and magnetic and magnetotransport properties in these magnetic films have been investigated in detail by adjusting the magnetic anisotropy of ferromagnetic layers and by changing the thickness of the spacer layer,ferromagnetic layer,and antiferromagnetic layer.Some particular physical phenomena have been observed and explained.展开更多
The Ge metal-oxide-semiconductor (MOS) capacitors were fabricated with HfO2 as gate dielectric.AlON,NdON,and NdAlON were deposited between the gate dielectric and the Ge substrate as the interfacial passivation layer ...The Ge metal-oxide-semiconductor (MOS) capacitors were fabricated with HfO2 as gate dielectric.AlON,NdON,and NdAlON were deposited between the gate dielectric and the Ge substrate as the interfacial passivation layer (IPL).The electrical properties (such as capacitance-voltage (C-V) and gate leakage current density versus gate voltage (J_(g)-V_(g))) were measured by HP4284A precision LCR meter and HP4156A semiconductor parameter analyzer.The chemical states and interfacial quality of the high-k/Ge interface were investigated by X-ray photoelectron spectroscopy (XPS).The experimental results show that the sample with the NdAlON as IPL exhibits the excellent interfacial and electrical properties.These should be attributed to an effective suppression of the Ge suboxide and HfGeOx interlayer,and an enhanced blocking role against inter-diffusion of the elements during annealing by the NdAlON IPL.展开更多
In this work, low-carbon steel specimens were subjected to the quenching and partitioning process after being partially or fully austenitized to investigate their microstructural evolution and mechanical properties. A...In this work, low-carbon steel specimens were subjected to the quenching and partitioning process after being partially or fully austenitized to investigate their microstructural evolution and mechanical properties. According to the results of scanning electron microscopy and transmission electron microscopy observations, X-ray diffraction analysis, and tensile tests, upper bainite or tempered martensite appears successively in the microstructure with increasing austenitization temperature or increasing partitioning time. In the partially austenitized specimens, the retained austenite grains are carbon-enriched twice during the heat treatment, which can significantly stabilize the phases at room temperature. Furthermore, after partial austenitization, the specimen exhibits excellent elongation, with a maximum elongation of 37.1%. By contrast, after full austenitization, the specimens exhibit good ultimate tensile strength and high yield strength. In the case of a specimen with a yield strength of 969 MPa, the maximum value of the ultimate tensile strength reaches 1222 MPa. During the partitioning process, carbon partitioning and carbon homogenization within austenite affect interface migration. In addition, the volume fraction and grain size of retained austenite observed in the final microstructure will also be affected.展开更多
Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurate...Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.展开更多
In addition to electrical insulation properties,the thermal properties of nanodielectrics,such as glass transition temperature,thermal expansion coefficients,thermal conductivity,and mechanical properties,including Yo...In addition to electrical insulation properties,the thermal properties of nanodielectrics,such as glass transition temperature,thermal expansion coefficients,thermal conductivity,and mechanical properties,including Young's modulus,bulk modulus,and shear modulus,are also very important.This paper describes the molecular dynamics simulations of epoxy resin doped with SiO_(2)nanoparticles and with SiO_(2)nanoparticles that have been surface grafted with hexamethyldisilazane(HMDS)at 10%and 20%grafting rates.The results show that surface grafting can improve certain thermal and mechanical properties of the system.Our analysis indicates that the improved thermal performance occurs because the formation of thermal chains becomes easier after the surface grafting treatment.The improved mechanical properties originate from two causes.First,doping with SiO_(2)nanoparticles inhibits the degree of movement of molecular chains in the system.Second,the surface grafting treatment weakens the molecular repulsion between SiO_(2)and epoxy resin,and the van der Waals excluded region becomes thinner.Thus,the compatibility between SiO_(2)nanoparticles and polymers is improved by the grafting treatment.The analysis method and conclusions in this paper provide guidance and reference for the future studies of the thermal and mechanical properties of nanodielectrics.展开更多
One of the challenges for catalytic CO_(2)reduction is to control product selectivity,and new findings that can modify selectivity would be transformative.Herein,two kinds of TiO_(2)(homemade and commercial)with the s...One of the challenges for catalytic CO_(2)reduction is to control product selectivity,and new findings that can modify selectivity would be transformative.Herein,two kinds of TiO_(2)(homemade and commercial)with the same crystal phase but different surface properties are chosen as supports to prepare Ni-based catalysts for CO_(2)reduction,which show distinctly different product selectivity for CO_(2)reduction to CH_(4) or CO,as well as the CO_(2)conversion.The catalysts based on the homemade TiO_(2)support are highly selective for CH_(4) formation,while the latter ones are about 100%selective for CO formation under the same reaction conditions.In addition,the former ones are much active(more than 3 times)than the latter ones.We found that the collaborative contribution of Ti^(3+)and Ni^(2+)species and the electronic metal-support interactions effect maybe the main driving force behind for determining the product selectivity.Methane is almost exclusively produced over the catalysts with abundant Ti^(3+)and Ni^(2+)species and greater electronic metal-support interaction,otherwise,it will give priority to CO generation.The addition of CeO_(2)can reduce the Ni particle size and improve the dispersion of Ni nanoparticles,as well as create more Ti^(3+)species,contributing to the enhancement of CO_(2)conversion,but shows a negligible effect on product selectivity.Furthermore,the in situ DRIFT experiments and kinetic experiments indicate that the CO route is probably involved in the CO_(2)reduction process over the homemade Ni-CeO_(2)/TiO_(2)-CO catalyst with abundant Ti^(3+)and Ni^(2+)species and a strong electronic transform effect.展开更多
An interlayer perpendicular standing spin wave mode is observed in the skyrmion-hosting[Pt/Co/Ta]_(10) multilayer by measuring the time-resolved magneto-optical Kerr effect.The observed interlayer mode depends on the ...An interlayer perpendicular standing spin wave mode is observed in the skyrmion-hosting[Pt/Co/Ta]_(10) multilayer by measuring the time-resolved magneto-optical Kerr effect.The observed interlayer mode depends on the interlayer spin-pumping and spin transfer torque among the neighboring Co layers.This mode shows monotonically increasing frequency-field dependence which is similar to the ferromagnetic resonance mode,but within higher frequency range.Besides,the damping of the interlayer mode is found to be a relatively low constant value of 0.027 which is independent of the external field.This work expounds the potential application of the[heavy-metal/ferromagnetic-metal]_(n) multilayers to skyrmion-based magnonic devices which can provide multiple magnon modes,relatively low damping,and skyrmion states,simultaneously.展开更多
Our recent research achievements in the perpendicular magnetic anisotropy (PMA) properties of the CoFeB sand- wiched by MgO and tantalum layers are summarized. We found that the PMA behaviors of Ta/CoFeB/MgO and MgO...Our recent research achievements in the perpendicular magnetic anisotropy (PMA) properties of the CoFeB sand- wiched by MgO and tantalum layers are summarized. We found that the PMA behaviors of Ta/CoFeB/MgO and MgO/CoFeB/Ta thin films are different. The larger PMA in the latter film is related to the lower magnetization of CoFeB deposited on MgO. Furthermore, we have demonstrated a large anomalous Hall effect in perpendicular CoFeB thin fihn. Our results show large anomalous Hall resistivity, large longitudinal resistivity, and low switching field can be achieved, all at the same time, in the perpendicular CoFeB thin film. Anomalous Hall effect with high and linear sensitivity is also found in an MgO/CoFeBFFa thin film with a thick MgO layer, which opens a door tbr future device applications of perpendicular ferromagnetic thin films.展开更多
A self-made 2-acrylamide-2-methyl propylene sulfonic (AMPS)-modified polyacrylic acid superplasticizer and two other commercially available superplasticizers with different molecular structures are used in this stud...A self-made 2-acrylamide-2-methyl propylene sulfonic (AMPS)-modified polyacrylic acid superplasticizer and two other commercially available superplasticizers with different molecular structures are used in this study to investigate the effect of an AMPS-modified polyacrylic acid superplasticizer on the properties of concrete materials. In the experiments, initial and 1.5 h slumps over time after admixtion are determined by adding different dosages of three superplasticizers into the premixed concrete to characterize the slump loss resistance of the premixed concrete. The water-reducing rates of three different types of concrete are determined to characterize the water-reducing capacity of the concrete with each superplasticizer. The 3, 7 and 28 d compressive strength is determined to characterize the mechanical properties of the concrete with each superplasticizer. In the meanwhile, 1, 1.5 and 2.0 h slump loss rates over time after admixtion are determined by adding different dosages of the three superplasticizers into the high-performance concrete (HPC) to characterize the slump loss resistance of HPC. The 7, 28, 60 and 90 d compressive strength is determined to characterize the compressive properties of HPC with each superplasticizer. The dry shrinkage rates of three different types of HPC are determined with each superplasticizer. Electric flux after standard curing for 56 d and chloride ion diffusion coefficient after curing for 28 d of I-IPC are determined to characterize the impermeability of HPC with each superplasticizer. The cross-section was examined using a scanning electron microscopy (SEM) system. Results demonstrate that the AMPS-modified polyacrylic acid superplasticizer has better water-reducing effect and slump than the two commercially available polyacrylie acid superplasticizers. The AMPS-modified polyacrylic acid superplasticizer also shows significant improvement of the compressive strength, especially in comprehensive performance of HPC. In conclusion, the AMPS-modified polyacrylic acid superplastieizer is particularly suitable for the preparation of HPC.展开更多
RE‐Ba‐Cu‐O(REBCO,where RE=Y,Gd,Sm,and other rare earth elements)coated conductor(CC)tapes are promising for applications in high‐energy physics and high‐field science owing to their significant advantages such as...RE‐Ba‐Cu‐O(REBCO,where RE=Y,Gd,Sm,and other rare earth elements)coated conductor(CC)tapes are promising for applications in high‐energy physics and high‐field science owing to their significant advantages such as high critical magnetic field,high current density,and the ability to achieve superconductivity at liquid nitrogen temperatures.Nevertheless,the mechanical and superconducting performances of these CC tapes are significantly affected by interface failures,such as interfacial delamination and coating fractures,which arise from the complex interplay of mechanical stress induced by magnet processing,thermal mismatch stress during cooling,electromagnetic stress under high magnetic fields,and thermal stress during quenching.This study comprehensively reviews the interface properties and failure behavior of REBCO CC tapes.First,the research progress in characterizing the intricate interface properties of REBCO CC is systematically reviewed.Furthermore,the interface failure behavior in extreme multifield environments was analyzed and summarized.Subsequently,this study outlines optimization strategies to mitigate interface failure risks in REBCO superconducting magnet structures.Finally,we address the current challenges and future perspectives on interface issues in REBCO CC tapes.By addressing these challenges,this study offers valuable insights for advancing the development and practical implementation of superconducting technologies in diverse applications.展开更多
Amorphous/crystalline silicon heterojunctions(a-Si:H/c-Si SHJ) were prepared by plasma-enhanced chemical vapor deposition(PECVD).The influence of the initial transient state of the plasma and the hydrogen pre-tre...Amorphous/crystalline silicon heterojunctions(a-Si:H/c-Si SHJ) were prepared by plasma-enhanced chemical vapor deposition(PECVD).The influence of the initial transient state of the plasma and the hydrogen pre-treatment on the interfacial properties of the heteroj unctions was studied.Experimental results indicate that: (1) The instability of plasma in the initial stage will damage the surface of c-Si.Using a shutter to shield the substrate for 100 s from the starting discharge can prevent the influence of the instable plasma process on the Si surface and also the interface between a-Si and c-Si.(2) The effect of hydrogen pre-treatment on interfacial passivation is constrained by the extent of hydrogen plasma bombardment and the optimal time for hydrogen pre-treatment is about 60 s.展开更多
The interface electrochemical properties of clay were theoretically analyzed to obtain some relationships among point of zero net charge (PZNC), point of zero net proton charge (PZNPC), intrinsic surface reaction ...The interface electrochemical properties of clay were theoretically analyzed to obtain some relationships among point of zero net charge (PZNC), point of zero net proton charge (PZNPC), intrinsic surface reaction equilibrium constants (K in 1-pK model, Ka1^int and Ka2^int in 2-pK model, *KNa^int and *KNO3^int in inert electrolyte chemical binding model) and structural negative charge density (σst) of clay, and some interface electrochemical parameters of kaolinite were measured. The following main conclusions were obtained. For clay possessing structural negative charges, the PZNC independent of electrolyte concentration (c) should exist just as amphoteric solid without structural charges such as oxides or hydroxides. A common intersection point (CIP) should appear among the potentiometric (or acid-base) titration curves at different c and the pH at the CIP should be PHPZNC. A CIP among potentiometric titration curves at different c for kaolinite was observed, and the value of PHPZNC of kaolinite was 2.16. The values of pHPZNPC were decreased with increasing c, which arises from the presence of structural negative charges of kaolinite. In addition, it was observed that a good linear relationship existed between pHPZNPC and 1g c. According to the values of PHPZNC and σst measured, the intrinsic surface reaction equilibrium constants, pK and pKa1^int and pKa2^int of 1-pK and 2-pK models could be directly calculated for clay, and the values of pK, pKa1^int and pKa2^int for kaolinite were 2.93, 1.90 and 3.97, respectively. These experimental values of pKa1^int and pKa2^int for kaolinite are obviously lower than those optimized with fitting programs in literatures, which maybe arises from the introduction of a type of permanent negatively charged sites in the models of literatures. An interesting result obtained in this study is that the inert electrolyte chemical binding does not exist for kaolinite, which also arises from the presence of structural negative charges.展开更多
Laser cladding deposited Ti-6Al-4V titanium alloy universally shows more complex microstructures,each of which has significant effect on mechanical properties. Of particular α/β interface phase has been observed in ...Laser cladding deposited Ti-6Al-4V titanium alloy universally shows more complex microstructures,each of which has significant effect on mechanical properties. Of particular α/β interface phase has been observed in this paper under certain conditions. It demonstrates that the influence of the α/β interface phase on the tensile properties is closely associated with dislocations and twin substructure through comparison experiments. The results show that the α/β interface phase hinders dislocation motion and decreases effective slip length. In addition, the twin substructure has been activated in the α/β interface phase during tensile process and has acted somehow like grain boundaries. Therefore, the strength and the work-hardening rate of the laser cladding deposited Ti-6Al-4V titanium alloy have been significantly improved due to the dynamic Hall-Petch effect. Besides, the α/β interface phase leads to more uniform dislocations distribution, which implies that relative lower local concentrated stress will be produced along the α/β interface phase or colony boundary after the same amount of plastic deformation. Moreover,the twinning-induced plasticity effects in the α/β interface phase further increase the plastic deformation capacity. These results in higher elongation for the laser cladding deposited Ti-6Al-4V titanium alloy.It can be concluded that the current work suggests an effective method to simultaneously improve the strength and plasticity of laser cladding deposited Ti-6Al-4V titanium alloy based on the α/β interface phase.展开更多
The first- and second-order statistical properties of ultrasound -speckles reflected from an interface are studied theoretically and experimentally. A theoretical model for predicting statistical properties of ultraso...The first- and second-order statistical properties of ultrasound -speckles reflected from an interface are studied theoretically and experimentally. A theoretical model for predicting statistical properties of ultrasound speckles is constructed based on the Fresnel-Huygens principle and three basic assumptions. Distributions of amplitude and phase of ultrasound speckles in a scattering space are studied. And the study shows that they are in the form of Rayleigh and uniform distribution respectively. Using the proposed model, the average transverse size of the speckles within a scattering domain which are received by a focus probe is investigated. The average transverse size is found to be dependent on the characteristics of the measuring system only, and does not vary with the position in the domain. To verify the applicability of the theoretical model, a special experimental set-up was designed and the corresponding experiments were conducted for measuring the sound pressure of the ultrasound speckles reflected from an interface between water and Aluminium alloy. The numerical results are compared with the experimental ones. The comparison demonstrates that the theoretical model and the three related assumptions are suitable for analysing statistical properties of ultrasound speckles reflected from an interface.展开更多
Semiconducting monolayer (ML) blue phosphorene (BlueP) shares similar stability with ML black phosphorene (BP), and it has recently been grown on an Au surface. Potential ML BlueP devices often require direct co...Semiconducting monolayer (ML) blue phosphorene (BlueP) shares similar stability with ML black phosphorene (BP), and it has recently been grown on an Au surface. Potential ML BlueP devices often require direct contact with metal to enable the injection of carriers. Using ab initio electronic structure calculations and quantum transport simulations, for the first time, we perform a systematic study of the interfacial properties of ML BlueP in contact with metals spanning a wide work function range in a field effect transistor (FET) configuration. ML BlueP has undergone metallization owing to strong interaction with five metals. There is a strong Fermi level pinning (FLP) in the ML BlueP FETs due to the metal-induced gap states (MIGS) with a pinning factor of 0.42. ML BlueP forms n-type Schottky contact with Sc, Ag, and Pt electrodes with electron Schottky barrier heights (SBHs) of 0.22, 0.22, and 0.80 eV, respectively, and p-type Schottky contact with Au and Pd electrodes with hole SBHs of 0.61 and 0.79 eV, respectively. The MIGS are eliminated by inserting graphene between ML BlueP and the metal electrode, accompanied by a transition from a strong FLP to a weak FLP. Our study not only provides insight into the ML BlueP-metal interfaces, but also helps in the design of ML BlueP devices.展开更多
Enhanced oil recovery(EOR)has been widely used to recover residual oil after the primary or secondary oil recovery processes.Compared to conventional methods,chemical EOR has demonstrated high oil recovery and low ope...Enhanced oil recovery(EOR)has been widely used to recover residual oil after the primary or secondary oil recovery processes.Compared to conventional methods,chemical EOR has demonstrated high oil recovery and low operational costs.Nanofluids have received extensive attention owing to their advantages of low cost,high oil recovery,and wide applicability.In recent years,nanofluids have been widely used in EOR processes.Moreover,several studies have focused on the role of nanofluids in the nanofluid EOR(N-EOR)process.However,the mechanisms related to N-EOR are unclear,and several of the mechanisms established are chaotic and contradictory.This review was conducted by considering heavy oil molecules/particle/surface micromechanics;nanofluidassisted EOR methods;multiscale,multiphase pore/core displacement experiments;and multiphase flow fluid-solid coupling simulations.Nanofluids can alter the wettability of minerals(particle/surface micromechanics),oil/water interfacial tension(heavy oil molecules/water micromechanics),and structural disjoining pressure(heavy oil molecules/particle/surface micromechanics).They can also cause viscosity reduction(micromechanics of heavy oil molecules).Nanofoam technology,nanoemulsion technology,and injected fluids were used during the EOR process.The mechanism of N-EOR is based on the nanoparticle adsorption effect.Nanoparticles can be adsorbed on mineral surfaces and alter the wettability of minerals from oil-wet to water-wet conditions.Nanoparticles can also be adsorbed on the oil/water surface,which alters the oil/water interfacial tension,resulting in the formation of emulsions.Asphaltenes are also adsorbed on the surface of nanoparticles,which reduces the asphaltene content in heavy oil,resulting in a decrease in the viscosity of oil,which helps in oil recovery.In previous studies,most researchers only focused on the results,and the nanoparticle adsorption properties have been ignored.This review presents the relationship between the adsorption properties of nanoparticles and the N-EOR mechanisms.The nanofluid behaviour during a multiphase core displacement process is also discussed,and the corresponding simulation is analysed.Finally,potential mechanisms and future directions of N-EOR are proposed.The findings of this study can further the understanding of N-EOR mechanisms from the perspective of heavy oil molecules/particle/surface micromechanics,as well as clarify the role of nanofluids in multiphase core displacement experiments and simulations.This review also presents limitations and bottlenecks,guiding researchers to develop methods to synthesise novel nanoparticles and conduct further research.展开更多
基金supported by the National Natural Science Foundation of China (No.41772313)the National Natural Science Foundation for Young Scientists of China (No.52104111)+3 种基金the Hunan Science and Technology Planning Project,China (No.2019RS3001)the Natural Science Foundation of Hunan Province,China (No.2021JJ30819)Key Science and Technology Project of Guangxi Transportation Industry (Research on fine blasting and disaster control technology of mountain expressway tunnel),Chinathe financial contribution and convey their appreciation for supporting this basic research。
文摘To investigate the dynamic behavior and energy dissipation of the rock−concrete interface,dynamic splitting tests on bi-material discs were conducted by using the split Hopkinson pressure bar.The test results reveal that with the change of the interface inclination angles(θ),the influence of interface groove width on the bearing capacity of specimens also varies.Whenθincreases from 0°to 30°,the bearing capacity of the specimen increases first and then decreases with the rise of the interface groove width;the optimal groove width on the rock surface in this range of interface inclination angles is 5 mm.Whenθincreases from 45°to 90°,the bearing capacity of the specimen has no obvious change.Moreover,whenθincreases from 0°to 45°,the dissipated energy of the specimens rises obviously at first and then tends to be stable as the width of the interface groove increases.
文摘Fe/C multilayer thin films were deposited by magnetron sputtering. Small angle X-ray diffraction measurements show very well periodicity of the samples. The modulation period determined from a modified Bragg equation agrees well with that determined from deposition rate. The interfacial roughness parameter ξof several samples calculated by X-ray diffraction is between 3.5(?) and 5.6(?).
文摘This paper developed a hot Pressing aided exothermic synthesis (HPES) technique. to fabricate NiAl matrix composites containing 0 and 20 v.% TiB_2 particles. The conversion to the product was complete. and TiB_2 particles in the matrix were uniformly dispersed. The inter faces between nail and TiB_2 were atomically flat. sharp and free from any inter facial phases in most cases. In some cases. however. thin inter facial amorphous layers existed at NiAl/ TiB_2 interfaces. In addition, the microstructure and inter faces were highly thermal stable. In all processing states. the yield strengths at room temperature or at 1000℃ of the composite were approximately three times as strong as that of the unrein forced NiAl. The ambient fracture toughness of the composite was also superior to monolithic NiAl.
文摘Currently for the steel tube reinforced concrete composite pile research, although predecessors make a comprehensive research on the composite pile beating performance, design technology, but there are still many problems have not been solved, such as the steel tube reinforced concrete pile composite interracial force learn performance research is still in the initial stage. In this paper, we mainly discuss the research methods of several interface mechanical properties and propose the possibility of studying the mechanical properties of the steel tube reinforced concrete composite pile by using the principle of ultrasonic speckle.
基金Project supported by the National Basic Research Program of China (Grant No. 2010CB934603)Ministry of Science and Technology of China and the National Natural Science Foundation of China (Grant Nos. 50931006,50971123,and 51271177)
文摘Recent advances in the study of exchange couplings in magnetic films are introduced.To provide a comprehensive understanding of exchange coupling,we have designed different bilayers,trilayers and multilayers,such as anisotropic hard/soft-magnetic multilayer films,ferromagnetic/antiferromagnetic/ferromagnetic trilayers,[Pt/Co]/NiFe/NiO heterostructures,Co/NiO and Co/NiO/Fe trilayers on an anodic aluminum oxide(AAO) template.The exchange-coupling interaction between soft-and hard-magnetic phases,interlayer and interfacial exchange couplings and magnetic and magnetotransport properties in these magnetic films have been investigated in detail by adjusting the magnetic anisotropy of ferromagnetic layers and by changing the thickness of the spacer layer,ferromagnetic layer,and antiferromagnetic layer.Some particular physical phenomena have been observed and explained.
基金Funded by the National Natural Science Foundation of China (No. 61704113)the Higher Vocational Brand Mayer in Guangdong Province (No.610103)the Educational Science Planning Project of Guangdong Province (Higher Education Special)。
文摘The Ge metal-oxide-semiconductor (MOS) capacitors were fabricated with HfO2 as gate dielectric.AlON,NdON,and NdAlON were deposited between the gate dielectric and the Ge substrate as the interfacial passivation layer (IPL).The electrical properties (such as capacitance-voltage (C-V) and gate leakage current density versus gate voltage (J_(g)-V_(g))) were measured by HP4284A precision LCR meter and HP4156A semiconductor parameter analyzer.The chemical states and interfacial quality of the high-k/Ge interface were investigated by X-ray photoelectron spectroscopy (XPS).The experimental results show that the sample with the NdAlON as IPL exhibits the excellent interfacial and electrical properties.These should be attributed to an effective suppression of the Ge suboxide and HfGeOx interlayer,and an enhanced blocking role against inter-diffusion of the elements during annealing by the NdAlON IPL.
基金funded by China Scholarship Council (No. 201406460053)
文摘In this work, low-carbon steel specimens were subjected to the quenching and partitioning process after being partially or fully austenitized to investigate their microstructural evolution and mechanical properties. According to the results of scanning electron microscopy and transmission electron microscopy observations, X-ray diffraction analysis, and tensile tests, upper bainite or tempered martensite appears successively in the microstructure with increasing austenitization temperature or increasing partitioning time. In the partially austenitized specimens, the retained austenite grains are carbon-enriched twice during the heat treatment, which can significantly stabilize the phases at room temperature. Furthermore, after partial austenitization, the specimen exhibits excellent elongation, with a maximum elongation of 37.1%. By contrast, after full austenitization, the specimens exhibit good ultimate tensile strength and high yield strength. In the case of a specimen with a yield strength of 969 MPa, the maximum value of the ultimate tensile strength reaches 1222 MPa. During the partitioning process, carbon partitioning and carbon homogenization within austenite affect interface migration. In addition, the volume fraction and grain size of retained austenite observed in the final microstructure will also be affected.
基金financial support from the National Natural Science Foundation of China(11472242,11672264,and 11621062)the Zhejiang Provincial Natural Science Foundation(LZ17A020001)the Fundamental Research Funds for the Central Universities
文摘Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.
基金Project supported by the National Key Research and Development Program of China(Grant.Nos.2017YFB0902503 and 2016YFB0900802)。
文摘In addition to electrical insulation properties,the thermal properties of nanodielectrics,such as glass transition temperature,thermal expansion coefficients,thermal conductivity,and mechanical properties,including Young's modulus,bulk modulus,and shear modulus,are also very important.This paper describes the molecular dynamics simulations of epoxy resin doped with SiO_(2)nanoparticles and with SiO_(2)nanoparticles that have been surface grafted with hexamethyldisilazane(HMDS)at 10%and 20%grafting rates.The results show that surface grafting can improve certain thermal and mechanical properties of the system.Our analysis indicates that the improved thermal performance occurs because the formation of thermal chains becomes easier after the surface grafting treatment.The improved mechanical properties originate from two causes.First,doping with SiO_(2)nanoparticles inhibits the degree of movement of molecular chains in the system.Second,the surface grafting treatment weakens the molecular repulsion between SiO_(2)and epoxy resin,and the van der Waals excluded region becomes thinner.Thus,the compatibility between SiO_(2)nanoparticles and polymers is improved by the grafting treatment.The analysis method and conclusions in this paper provide guidance and reference for the future studies of the thermal and mechanical properties of nanodielectrics.
基金supported by the National Natural Science Foundation of China(No.51774159)the Open Project Program of the State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering(No.2020-KF-25)the Qinglan Project of Kunming University of Science and Technology。
文摘One of the challenges for catalytic CO_(2)reduction is to control product selectivity,and new findings that can modify selectivity would be transformative.Herein,two kinds of TiO_(2)(homemade and commercial)with the same crystal phase but different surface properties are chosen as supports to prepare Ni-based catalysts for CO_(2)reduction,which show distinctly different product selectivity for CO_(2)reduction to CH_(4) or CO,as well as the CO_(2)conversion.The catalysts based on the homemade TiO_(2)support are highly selective for CH_(4) formation,while the latter ones are about 100%selective for CO formation under the same reaction conditions.In addition,the former ones are much active(more than 3 times)than the latter ones.We found that the collaborative contribution of Ti^(3+)and Ni^(2+)species and the electronic metal-support interactions effect maybe the main driving force behind for determining the product selectivity.Methane is almost exclusively produced over the catalysts with abundant Ti^(3+)and Ni^(2+)species and greater electronic metal-support interaction,otherwise,it will give priority to CO generation.The addition of CeO_(2)can reduce the Ni particle size and improve the dispersion of Ni nanoparticles,as well as create more Ti^(3+)species,contributing to the enhancement of CO_(2)conversion,but shows a negligible effect on product selectivity.Furthermore,the in situ DRIFT experiments and kinetic experiments indicate that the CO route is probably involved in the CO_(2)reduction process over the homemade Ni-CeO_(2)/TiO_(2)-CO catalyst with abundant Ti^(3+)and Ni^(2+)species and a strong electronic transform effect.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12074189,11704191,11774160,and 61427812)the Natural Science Foundation of Jiangsu Province,China(Grant Nos.BK20192006 and BK20211144)the Postdoctoral Research Funding Program of Jiangsu Province,China(Grant No.2021K503C)。
文摘An interlayer perpendicular standing spin wave mode is observed in the skyrmion-hosting[Pt/Co/Ta]_(10) multilayer by measuring the time-resolved magneto-optical Kerr effect.The observed interlayer mode depends on the interlayer spin-pumping and spin transfer torque among the neighboring Co layers.This mode shows monotonically increasing frequency-field dependence which is similar to the ferromagnetic resonance mode,but within higher frequency range.Besides,the damping of the interlayer mode is found to be a relatively low constant value of 0.027 which is independent of the external field.This work expounds the potential application of the[heavy-metal/ferromagnetic-metal]_(n) multilayers to skyrmion-based magnonic devices which can provide multiple magnon modes,relatively low damping,and skyrmion states,simultaneously.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB933102)the National Natural Science Foundation of China(Grant Nos.50871120,11079052,and 11174354)
文摘Our recent research achievements in the perpendicular magnetic anisotropy (PMA) properties of the CoFeB sand- wiched by MgO and tantalum layers are summarized. We found that the PMA behaviors of Ta/CoFeB/MgO and MgO/CoFeB/Ta thin films are different. The larger PMA in the latter film is related to the lower magnetization of CoFeB deposited on MgO. Furthermore, we have demonstrated a large anomalous Hall effect in perpendicular CoFeB thin fihn. Our results show large anomalous Hall resistivity, large longitudinal resistivity, and low switching field can be achieved, all at the same time, in the perpendicular CoFeB thin film. Anomalous Hall effect with high and linear sensitivity is also found in an MgO/CoFeBFFa thin film with a thick MgO layer, which opens a door tbr future device applications of perpendicular ferromagnetic thin films.
基金Funded by the Fujian Education Department(Nos.JA11329,JA12412)Quanzhou(Fujian)Technology Research and Development Program(Nos.2013Z47,2013Z158,2010G7)
文摘A self-made 2-acrylamide-2-methyl propylene sulfonic (AMPS)-modified polyacrylic acid superplasticizer and two other commercially available superplasticizers with different molecular structures are used in this study to investigate the effect of an AMPS-modified polyacrylic acid superplasticizer on the properties of concrete materials. In the experiments, initial and 1.5 h slumps over time after admixtion are determined by adding different dosages of three superplasticizers into the premixed concrete to characterize the slump loss resistance of the premixed concrete. The water-reducing rates of three different types of concrete are determined to characterize the water-reducing capacity of the concrete with each superplasticizer. The 3, 7 and 28 d compressive strength is determined to characterize the mechanical properties of the concrete with each superplasticizer. In the meanwhile, 1, 1.5 and 2.0 h slump loss rates over time after admixtion are determined by adding different dosages of the three superplasticizers into the high-performance concrete (HPC) to characterize the slump loss resistance of HPC. The 7, 28, 60 and 90 d compressive strength is determined to characterize the compressive properties of HPC with each superplasticizer. The dry shrinkage rates of three different types of HPC are determined with each superplasticizer. Electric flux after standard curing for 56 d and chloride ion diffusion coefficient after curing for 28 d of I-IPC are determined to characterize the impermeability of HPC with each superplasticizer. The cross-section was examined using a scanning electron microscopy (SEM) system. Results demonstrate that the AMPS-modified polyacrylic acid superplasticizer has better water-reducing effect and slump than the two commercially available polyacrylie acid superplasticizers. The AMPS-modified polyacrylic acid superplasticizer also shows significant improvement of the compressive strength, especially in comprehensive performance of HPC. In conclusion, the AMPS-modified polyacrylic acid superplastieizer is particularly suitable for the preparation of HPC.
基金supported by the National Natural Science Foundation of China(12272156 and 11932008)Shanghai Superconductor Technology Co.,Ltd–Lanzhou University Superconducting Materials and Mechanics Open Foundation for Industry-University-Research.
文摘RE‐Ba‐Cu‐O(REBCO,where RE=Y,Gd,Sm,and other rare earth elements)coated conductor(CC)tapes are promising for applications in high‐energy physics and high‐field science owing to their significant advantages such as high critical magnetic field,high current density,and the ability to achieve superconductivity at liquid nitrogen temperatures.Nevertheless,the mechanical and superconducting performances of these CC tapes are significantly affected by interface failures,such as interfacial delamination and coating fractures,which arise from the complex interplay of mechanical stress induced by magnet processing,thermal mismatch stress during cooling,electromagnetic stress under high magnetic fields,and thermal stress during quenching.This study comprehensively reviews the interface properties and failure behavior of REBCO CC tapes.First,the research progress in characterizing the intricate interface properties of REBCO CC is systematically reviewed.Furthermore,the interface failure behavior in extreme multifield environments was analyzed and summarized.Subsequently,this study outlines optimization strategies to mitigate interface failure risks in REBCO superconducting magnet structures.Finally,we address the current challenges and future perspectives on interface issues in REBCO CC tapes.By addressing these challenges,this study offers valuable insights for advancing the development and practical implementation of superconducting technologies in diverse applications.
基金Project supported by the National Key Basic Research Program of China(No.2011CBA00705)the Knowledge Innovation Project of the Chinese Academy of Sciences(No.KGCX2-YW-351).
文摘Amorphous/crystalline silicon heterojunctions(a-Si:H/c-Si SHJ) were prepared by plasma-enhanced chemical vapor deposition(PECVD).The influence of the initial transient state of the plasma and the hydrogen pre-treatment on the interfacial properties of the heteroj unctions was studied.Experimental results indicate that: (1) The instability of plasma in the initial stage will damage the surface of c-Si.Using a shutter to shield the substrate for 100 s from the starting discharge can prevent the influence of the instable plasma process on the Si surface and also the interface between a-Si and c-Si.(2) The effect of hydrogen pre-treatment on interfacial passivation is constrained by the extent of hydrogen plasma bombardment and the optimal time for hydrogen pre-treatment is about 60 s.
基金Project supported by National Key Basic Research Program of China (No. 2004CB418504), the National Natural Science Foundation of China (No. 20573065) and the Natural Science Foundation of Shandong Province of China (No. Z2005B02).
文摘The interface electrochemical properties of clay were theoretically analyzed to obtain some relationships among point of zero net charge (PZNC), point of zero net proton charge (PZNPC), intrinsic surface reaction equilibrium constants (K in 1-pK model, Ka1^int and Ka2^int in 2-pK model, *KNa^int and *KNO3^int in inert electrolyte chemical binding model) and structural negative charge density (σst) of clay, and some interface electrochemical parameters of kaolinite were measured. The following main conclusions were obtained. For clay possessing structural negative charges, the PZNC independent of electrolyte concentration (c) should exist just as amphoteric solid without structural charges such as oxides or hydroxides. A common intersection point (CIP) should appear among the potentiometric (or acid-base) titration curves at different c and the pH at the CIP should be PHPZNC. A CIP among potentiometric titration curves at different c for kaolinite was observed, and the value of PHPZNC of kaolinite was 2.16. The values of pHPZNPC were decreased with increasing c, which arises from the presence of structural negative charges of kaolinite. In addition, it was observed that a good linear relationship existed between pHPZNPC and 1g c. According to the values of PHPZNC and σst measured, the intrinsic surface reaction equilibrium constants, pK and pKa1^int and pKa2^int of 1-pK and 2-pK models could be directly calculated for clay, and the values of pK, pKa1^int and pKa2^int for kaolinite were 2.93, 1.90 and 3.97, respectively. These experimental values of pKa1^int and pKa2^int for kaolinite are obviously lower than those optimized with fitting programs in literatures, which maybe arises from the introduction of a type of permanent negatively charged sites in the models of literatures. An interesting result obtained in this study is that the inert electrolyte chemical binding does not exist for kaolinite, which also arises from the presence of structural negative charges.
基金supported by the National Key Research And Development Plan, China (No. 2016YFB1100100)the Research Fund of the State Key Laboratory of Solidification Processing (NWPU), China (No. KP201611)the National Natural Science Foundation of China (No. 51475380)
文摘Laser cladding deposited Ti-6Al-4V titanium alloy universally shows more complex microstructures,each of which has significant effect on mechanical properties. Of particular α/β interface phase has been observed in this paper under certain conditions. It demonstrates that the influence of the α/β interface phase on the tensile properties is closely associated with dislocations and twin substructure through comparison experiments. The results show that the α/β interface phase hinders dislocation motion and decreases effective slip length. In addition, the twin substructure has been activated in the α/β interface phase during tensile process and has acted somehow like grain boundaries. Therefore, the strength and the work-hardening rate of the laser cladding deposited Ti-6Al-4V titanium alloy have been significantly improved due to the dynamic Hall-Petch effect. Besides, the α/β interface phase leads to more uniform dislocations distribution, which implies that relative lower local concentrated stress will be produced along the α/β interface phase or colony boundary after the same amount of plastic deformation. Moreover,the twinning-induced plasticity effects in the α/β interface phase further increase the plastic deformation capacity. These results in higher elongation for the laser cladding deposited Ti-6Al-4V titanium alloy.It can be concluded that the current work suggests an effective method to simultaneously improve the strength and plasticity of laser cladding deposited Ti-6Al-4V titanium alloy based on the α/β interface phase.
基金This work was supported by the National Natural Science Foundation of China (10074017).
文摘The first- and second-order statistical properties of ultrasound -speckles reflected from an interface are studied theoretically and experimentally. A theoretical model for predicting statistical properties of ultrasound speckles is constructed based on the Fresnel-Huygens principle and three basic assumptions. Distributions of amplitude and phase of ultrasound speckles in a scattering space are studied. And the study shows that they are in the form of Rayleigh and uniform distribution respectively. Using the proposed model, the average transverse size of the speckles within a scattering domain which are received by a focus probe is investigated. The average transverse size is found to be dependent on the characteristics of the measuring system only, and does not vary with the position in the domain. To verify the applicability of the theoretical model, a special experimental set-up was designed and the corresponding experiments were conducted for measuring the sound pressure of the ultrasound speckles reflected from an interface between water and Aluminium alloy. The numerical results are compared with the experimental ones. The comparison demonstrates that the theoretical model and the three related assumptions are suitable for analysing statistical properties of ultrasound speckles reflected from an interface.
基金This work was supported by the National Natural Science Foundation of China (Nos. 11274016, 11474012, 11674005, 11274233, and 11664026), the National Basic Research Program of China (Nos. 2013CB932604 and 2012CB619304), Ministry of Science and Technology (National Materials Genome Project) of China (Nos. 2016YFA0301300 and 2016YFB0700600), and Foundation of Henan Educational Committee (No. 17A430026).
文摘Semiconducting monolayer (ML) blue phosphorene (BlueP) shares similar stability with ML black phosphorene (BP), and it has recently been grown on an Au surface. Potential ML BlueP devices often require direct contact with metal to enable the injection of carriers. Using ab initio electronic structure calculations and quantum transport simulations, for the first time, we perform a systematic study of the interfacial properties of ML BlueP in contact with metals spanning a wide work function range in a field effect transistor (FET) configuration. ML BlueP has undergone metallization owing to strong interaction with five metals. There is a strong Fermi level pinning (FLP) in the ML BlueP FETs due to the metal-induced gap states (MIGS) with a pinning factor of 0.42. ML BlueP forms n-type Schottky contact with Sc, Ag, and Pt electrodes with electron Schottky barrier heights (SBHs) of 0.22, 0.22, and 0.80 eV, respectively, and p-type Schottky contact with Au and Pd electrodes with hole SBHs of 0.61 and 0.79 eV, respectively. The MIGS are eliminated by inserting graphene between ML BlueP and the metal electrode, accompanied by a transition from a strong FLP to a weak FLP. Our study not only provides insight into the ML BlueP-metal interfaces, but also helps in the design of ML BlueP devices.
基金funded by the 973 National Basic Research Program of China(Grant No.2015CB251403).
文摘Enhanced oil recovery(EOR)has been widely used to recover residual oil after the primary or secondary oil recovery processes.Compared to conventional methods,chemical EOR has demonstrated high oil recovery and low operational costs.Nanofluids have received extensive attention owing to their advantages of low cost,high oil recovery,and wide applicability.In recent years,nanofluids have been widely used in EOR processes.Moreover,several studies have focused on the role of nanofluids in the nanofluid EOR(N-EOR)process.However,the mechanisms related to N-EOR are unclear,and several of the mechanisms established are chaotic and contradictory.This review was conducted by considering heavy oil molecules/particle/surface micromechanics;nanofluidassisted EOR methods;multiscale,multiphase pore/core displacement experiments;and multiphase flow fluid-solid coupling simulations.Nanofluids can alter the wettability of minerals(particle/surface micromechanics),oil/water interfacial tension(heavy oil molecules/water micromechanics),and structural disjoining pressure(heavy oil molecules/particle/surface micromechanics).They can also cause viscosity reduction(micromechanics of heavy oil molecules).Nanofoam technology,nanoemulsion technology,and injected fluids were used during the EOR process.The mechanism of N-EOR is based on the nanoparticle adsorption effect.Nanoparticles can be adsorbed on mineral surfaces and alter the wettability of minerals from oil-wet to water-wet conditions.Nanoparticles can also be adsorbed on the oil/water surface,which alters the oil/water interfacial tension,resulting in the formation of emulsions.Asphaltenes are also adsorbed on the surface of nanoparticles,which reduces the asphaltene content in heavy oil,resulting in a decrease in the viscosity of oil,which helps in oil recovery.In previous studies,most researchers only focused on the results,and the nanoparticle adsorption properties have been ignored.This review presents the relationship between the adsorption properties of nanoparticles and the N-EOR mechanisms.The nanofluid behaviour during a multiphase core displacement process is also discussed,and the corresponding simulation is analysed.Finally,potential mechanisms and future directions of N-EOR are proposed.The findings of this study can further the understanding of N-EOR mechanisms from the perspective of heavy oil molecules/particle/surface micromechanics,as well as clarify the role of nanofluids in multiphase core displacement experiments and simulations.This review also presents limitations and bottlenecks,guiding researchers to develop methods to synthesise novel nanoparticles and conduct further research.