Synthetic two-dimensional(2 D) polymers have totally different topology structures compared with traditional linear or branched polymers. The peculiar 2 D structures bring superior properties. Although, from linear ...Synthetic two-dimensional(2 D) polymers have totally different topology structures compared with traditional linear or branched polymers. The peculiar 2 D structures bring superior properties. Although, from linear to 2 D polymers, the study of these new materials is still in its infancy, they already show potential applications especially in optoelectronics, membranes, energy storage and catalysis, etc. In this review, we summarize the recent progress of the 2 D materials from three respects:(1) Chemistry—different types of polymerization reactions or supramolecular assembly to construct the 2 D networks were described;(2) Preparation methods—surface science, crystal engineering approaches and solution synthesis were introduced;(3) Functionalization and some early applications.展开更多
基金financially supported by the National Natural Science Foundation of China(No.21604046)the National Young Thousand Talents Program,Shandong Provincial Natural Science Foundation,China(No.ZR2016XJ004)
文摘Synthetic two-dimensional(2 D) polymers have totally different topology structures compared with traditional linear or branched polymers. The peculiar 2 D structures bring superior properties. Although, from linear to 2 D polymers, the study of these new materials is still in its infancy, they already show potential applications especially in optoelectronics, membranes, energy storage and catalysis, etc. In this review, we summarize the recent progress of the 2 D materials from three respects:(1) Chemistry—different types of polymerization reactions or supramolecular assembly to construct the 2 D networks were described;(2) Preparation methods—surface science, crystal engineering approaches and solution synthesis were introduced;(3) Functionalization and some early applications.