Influencing factors on as-cast and heat treated 400-18 ductile iron grade characteristics

As-cast and heat-treated 400-18 ductile iron （DI） grade was obtained in different foundry conditions, as metallic charge, Mg-treatment alloy and inoculation. It was found that the Pearlitic Influence Factor （P） and Anti- nodulizing Complex Factor （K1） have an important influence on property of DI, depending on the Mn and P level, the metallurgical quality of iron melt, rare earth （RE） and inoculation. It was also found that the influence of Mn is depended on the phosphorus and residual elements level in ductile iron. Less than 0.03%P and 0.2%Mn and P〈2.0 are the basic conditions to obtain as-cast ferritic structure. At the same lower level of Mn and P, the increasing of residual elements （P〉2.0） determines presence of pearlite in as-cast structure, while ferrite structure is obtained after a short annealing heat treatment. Lower level of phosphorus （P〈0.025%） and residual elements （Px〈2.0） allow to use relative high Mn content （0.32%-0.38%）, in condition of ferritic structure, including in as-cast state. High P （0.04%- 0.045%） and Mn （0.25%-0.35%） content stabilized peadite, especially at lower level of residual elements （P 〈2.0）. Antinodulizing action of elements was counteracted up to K1=2.0 level, by RE included in Mg-treatment alloy, which are beneficial for K1〈1.2 and compulsory for K1〉1.2. Si has a significant influence on the mechanical properties of heat treated ductile irons： an important decreasing of elongation level and a moderate increasing of yield and tensile strength and their ratio in 150-170 HB typical hardness field. A typical final chemical composition for as-cast 400-18 ductile iron could include 3.5%-3.7%C, 2.4%-2.5%Si, max.0.18%Mn, max.0.025%P, max.0.01%S, 0.04%-0.05%Mg for Px〈1.5 and K1〈1.1. High purity pig iron, RE-bearing FeSiMg and powerful inoculant are also recommended.

Effect of Bauxite Aggregate on Properties of Al_2O_3-SiC-C Iron Trough Castables

A1203-SiC-C iron trough castables were prepared using high alumina bauxite clinker GL-90 （ 〉 1 mm ） or homogenized bauxite GL-88 to replace the traditional brown corundum aggregates （ 〉 1 mm ） to reduce the cost of iron trough castables. Effects of the two bauxite aggregates on properties of iron trough eastables were investigated. The results show that the two kinds of bauxite affect flowability, bulk density, strength and slag corrosion resistance of trough castables differently. Compared with homogenized bauxite, high alumina bauxite clinker is more suitable to substitute brown corundum. The castables prepared from the bauxite clinker have similar performances with those prepared from brown corundum, especially used in medium or small blast furnaces with weak thermal impact and lower temperature hot metal. However, in large blast furnaces with severe thermal impact and high temperature hot metal, the performances of the two castables are significantly different. So it is suggested to use the brown corundum based castables in the front gyral zone of the slag skimmer.

Evaluation of the Dietary Reference Intakes for Japanese (2010 Edition): Recommended Protein, Pantothenic acid, Vitamin D, and Iron Intakes for Breast-Fed Infants Aged 6 - 11 Months

Objective: With regard to the 2010 edition of Dietary Reference Intakes for Japanese (DRIs-2010), we investigated whether the DRIs for two age groups, breast-fed infants aged 6-8 and 9-11 months, can be fulfilled for every nutrient in actual dietary practice. Design: We evaluated (1) whether the DRIs for all nutrients can be fulfilled in a formula with energy and protein exceeding their DRIs, (2) whether the DRIs for all nutrients can be fulfilled in a formula prepared in accordance with Japanese government-recommended weaning guidelines, and (3) what kinds of formulas can be prepared if the DRIs for all nutrients are fulfilled without referring to the weaning guidelines. Setting: Simulation of diet menu on the basis of published data in our university and survey of diet menu in a university hospital attached to a national medical school. Subjects: The three types of formulas were planned for ten days. Results: It was impossible to simultaneously fulfil the DRIs for 6 - 8-month-old infants concerning pantothenic acid, vitamin D, and iron and those for 9 - 11-month-old infants concerning these nutrients plus protein. Conclusion: According to the DRIs-2010, the DRI for all nutrients could not be fulfilled in an ingestible formula.

Synthesis and Crystal Structure of Tris(N-p-methylphenyl-3-hydroxy-2-ethyl-4-pyridinonato)iron(III)

The complex [Fe(C14H14NO2)3]2H2O has been prepared by reaction of N-p-methylphenyl-3-hydroxy-2-ethyl-4-pyridinone with FeCl36H2O. A single-crystal X-ray study shows that the iron atoms lie in a trigonally distorted octahedral environment coordinated to the hydroxy and ketone oxygen atoms of three ligands in the mer configuration Mr=773.57(C42H46N3O8Fe). The crystal is hexagonal with space group P31c; a=15.943(2), c=17.612(4)? V=3877.0(12)?, Z=4, Dc=1.325g/cm3, m=0.445mm-1, F(000)=1634, R=0.0446, wR= 0.1154 for 3085 reflections with I >2s(I). The bond lengths from iron to oxygens are 1.980(1)?for the ketone oxygens and 2.071(1)?for the hydroxy oxygens. The molecule exhibits the expected propeller shape, and the angle of the trigonal twist is 48.37. The dihedral angles are 0.5(2)?between chelate ring plane and pyridine ring plane and 71.31(7)?between pyridine ring plane and benzene ring plane. The solvent H2O(O(3) and O(4)) molecules are linked with O(2) and O(1) by hydrogen bonds with bond lengths 2.900(1) and 2.999(1)? respectively.

Corrosion of Magnesia-chrome Brick by Smelting Reduction Slag with Iron Bath

Effects of FeO content （0, 5%, 10%, and 15% in mass, respectively ） in lab-synthesized smelting redttc- tion slag with iron bath and test temperature （1 450, 1 500, 1550, anti 1 600 ℃ ） on corrosion am,amount and microstructure of fused rebonded magnesia - chrome brick with 26.02 massqc of Cr2O3 were researched by rotary cylinder method. The results show that ： （ 1 ） the corro- sion amolult of magnesia -chrome brick by slag without FeO is higher than that by the slag with 5% FeO, and the vorrosion amount increases when FeO content increa- ses from 5% to 15% ; （2） the test temperature is one of the important factors affecting the slag corrosion resist- ance of magnesia - chrome brick, and the corrosion of smelting reduction slag to brick increases with the temperature rising.

Two New Iron Coordination Polymers Based on Fe-pyta Chains Incorporating Pyridine-2,4,6-tricarboxylate

Reaction of FeCIz＇6H20, pyridine-2,4,6-tricarboxylic acid（H3pyta） and NaOH in the hydrothermal system at 185 ℃ resulted in the formation of 1D coordination polymer[Fe（Hpyta）（H2O）2]（1） based on Fe-Hpyta chains. When the abpt[abpt=-4-amino-3,5-bis（4-pyridyl）-l,2,4-triazole] ligand was employed in the reaction system, a 3D supramolecular porous network （H2bpt）[Fe（pyta）（H2O）2]·4H2O（2） was obtained. The framework was constructed with negative （Fe-pyta） chains and the positive H3bpt^＋ in situ, formed from the abpt reagent, to form 1D channels filled with guest water molecules via hydrogen-bonds. X-Ray diffraction crystal structure analysis shows that complex 1 crystallized in the monoclinic system, space group C2/c, a=1.1490（5） nm, b=0.9008（4） nm, c=1.0058（5） nm, B=107.254（9）°, V=0.9942（8） nm3, Z=4; and complex 2 crystallizes in the triclinic system, space group P1 with a=0.90392（11） nm, b=0.96027（11 ） nm, c=1.55540（18） nm, a=73.558（2）°,B= 86.126（2）°,r= 68.745（2）°, V=1.2059（2） nm^3 and Z=2.

Design,Synthesis and Crystal Structure of Two One-dimensional Zigzag Chain-like Compounds

Two one-dimensional chain-like cyanide-bridged compounds, [Fe（Phen）2（CN）2Ni（Cyclam）]（ClO4）2·DMF-2H2O 1 （Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylformamide） and [Fe（Phen）2（CN）2Zn（Cyclam）]（PF6）2·CH3CN 2, were prepared by the reaction of [Fe（Phen）2（CN）2]·2H2O with M（Cyclam）^2＋ （M = Ni, Zn）. In complexes 1 and 2, the metal atoms are connected alternatively with CN groups. X-ray structure and IR analyses for 1 and 2 were performed. Structure analysis revealed that both complexes are centrosymmetric and the geometry around each metal atom is an octahedron. The two complexes crystallize in triclinic with space group of P^1-. For 1, a = 10.439（4）, b = 14.976（7）, c = 15.914（8）A,α = 83.168（15）, β = 74.338（15）, γ = 78.023（15）°, V = 2338.3（18）A^3, Z = 2, Mr = 1035.37, Dc = 1.471 g/cm^3, F（000） = 1076,μ = 0.895 mm^-1, the final R = 0.0616 and wR = 0.1414 for 5849 observed reflections （1 〉 2σ（I））. For 2, a = 9.656（6）, b = 15.404（9）, c = 15.822（10）A, α = 78.68（2）, β= 78.917（19）, γ = 77.15（2）°, V = 2223（2）A^3, Z = 2, Mr = 1064.87, Dc = 1.587 g/cm^3, F（000） = 1078,μ = 1.032 mm^-1, the final R = 0.0672 and wR = 0.1595 for 6819 observed reflections （I 〉 2σ（I））.

Elevated free cholesterol in a p62 overexpression model of non-alcoholic steatohepatitis

AIM: To characterize how insulin-like growth factor 2 (IGF2) mRNA binding protein p62/IMP2-2 promotes steatohepatitis in the absence of dietary cholesterol.

Green fuel from coal via Fischer-Tropsch process： scenario of optimal condition of process and modelling

Extracting, transportation and the using from fossil fuels can damage to the hydrosphere, the biosphere and the Earth＇s atmosphere. But humans always need to this valuable substance. The production of oil derivatives by means of forest waste and coal through the Fischer-Tropsch process is an appropriate solution for the cleanliness of all parts of the environment. For the production of favorite products by the synthesis of Fischer-Tropsch, the performance of the catalyst under different operating conditions should be predictable. For this reason, in this paper, eight mathematical models were determined for the selectivity of five products of methane, light hydrocarbons, gasoline, diesel and wax based on three factors of reduction temperature, time on stream, and He/CO ratio inlet gas on iron-based catalyst. The results showed that the reduction temperature factor had the most effective on the selectivity of hydrocarbon products, exception diesel, so that the increase of the reduction temperature led to increase of the selectivity of methane, light hydrocarbons, gasoline and reduce of the degree of selectivity of the wax and vice versa. For the diesel selectivity, factor of the He/CO ratio inlet gas was the most effective than other factors.

不同碳源对Al2O3-SiC-C铁钩料性能的影响

研究不同碳源下Al2O3-SiC-C铁钩料的性能。分别以球沥青、焦炭和炭黑为碳源,比较了常温下三者的显气孔率、抗折和抗压强度。结果表明,不同种类碳源将对试样的气孔率和抗折强度产生不同程度的影响。

Application Research of Dense Sintered Alumina in Iron Runner Castables

Three different kinds of corundum aggregates-tabular sintered alumina, dense sintered alumina, and fused dense corundum-were introduced into the silica fume .free or silica fume containing Al2O3 -SiC - C iron runner castables to investigate their influences on the flow ability, linear change on heating, bulk density, apparent porosity, cold strength, hot modulus of rupture, therm, al shock resistance, slag resistance, oxidation resistance as well as wear resistance of Al2O3 - SiC - C iron runner castables. The results show that （ 1 ） compared with the specimens with fused dense corundum, the specimens with dense sintered alumina have equivalent installation property, slag resistance and oxidation resistance, equivalent or even higher cold modulus of rupture, cold crushing strength and hot modulus of rupture, exhibiting better thermal shock resistance and cold wear resistance ; （2） adopting bimodal alumina micropowder LISAL22RABL as well as water reducers ZX2 and ZD2 can well reduce the water requirement of silica fume free castables, solving the problem of deteriorated flow ability resulted from the lack of silica fume; since the lack of silica fume avoids the formation of low melting point liquid, the hot modulus of rupture and the thermal shock resistance of the silica fume free castables are both better than those of the silica fume containing castables ; （3） the density of the castable specimens with dense sintered alumina is 4% -6% lower than that of the castable specimens with Jhsed dense corundum so the refractories consumption of one iron runner reduces by 5% by using the tastable with dense sintered alumina, which obviously reduces the cost of refractories.

Ferroptosis mechanism and Alzheimer's disease

Regulated cell death is a genetically determined form of programmed cell death that commonly occurs during the development of living organisms.This process plays a crucial role in modulating homeostasis and is evolutionarily conserved across a diverse range of living organisms.Ferroptosis is a classic regulatory mode of cell death.Extensive studies of regulatory cell death in Alzheimer’s disease have yielded increasing evidence that fe rroptosis is closely related to the occurrence,development,and prognosis of Alzheimer’s disease.This review summarizes the molecular mechanisms of ferroptosis and recent research advances in the role of ferro ptosis in Alzheimer’s disease.Our findings are expected to serve as a theoretical and experimental foundation for clinical research and targeted therapy for Alzheimer’s disease.

马口铁加固古建筑榫卯节点抗震试验

为保护古建筑,采用试验方法,研究了马口铁加固古建筑榫卯节点后对节点抗震性能的影响。基于故宫太和殿三次间结构原型,制作了1:8缩尺比例的木结构空间框架模型,并考虑梁柱连接为燕尾榫形式,进行了低周反复加载试验,其中未加固构架和马口铁加固构架试验各做了3组。基于试验相关数据,获得了节点的弯矩-转角滞回曲线和骨架曲线,并对比分析了节点加固前后的耗能能力,刚度退化和延性等抗震指标。结果表明:马口铁加固榫卯节点后,虽然节点耗能能力略有下降,但节点拔榫量减小,抗弯承载力提高,刚度退化不明显,且节点仍具有较好的变形能力。因此,马口铁具有较好的加固效果。

马口铁加固古建筑抗震试验

采用试验方法,研究了马口铁加固古建筑榫卯节点后木构架的抗震性能.基于故宫太和殿三次间的相关尺寸,制作了1∶8的4梁4柱榫卯连接木结构空间框架模型,采用人工加载方式,进行了低周反复加载试验,获得了加固前后构架的力-侧移滞回曲线和骨架曲线,分析了加固前后的构架耗能能力、刚度退化规律及变形能力.结果表明,马口铁加固榫卯节点后,马口铁对榫卯节点的约束作用在一定程度上减小了节点拔榫量,提高了构架的侧移刚度及承载力;加固后的构架刚度退化不明显,变形能力较强,但是耗能能力减弱.

古建筑榫卯节点抗震加固试验

为探究中国古代大木作结构抗震加固的有效方法,分别采用马口铁和CFRP加固榫卯节点,研究了节点加固前后构架的抗震性能。制作了1∶8缩尺比例的木结构空间模型,通过进行低周反复加载试验,获得了构架加固前后的力-侧移曲线,并对比分析了相应的骨架曲线、耗能能力、刚度退化、变形能力等抗震指标。结果表明:马口铁和CFRP均可提高构架的刚度和承载力,且加固后的构架仍有很好的变形性能,但是耗能能力则不如加固前;另一方面,CFRP加固榫卯节点的效果优于马口铁。

基于自适应同步的混沌系统参数辨识方法的研究

利用混沌系统的动力学特性对参数极其敏感的特点,以驱动响应同步结构为框架,设计了与同步误差有关的二次型指标函数,采用优化方法对参数进行自适应调节,直到同步误差最小,即实现混沌同步.该方法实现了参数未知混沌系统的参数辨识和自适应同步。为了研究参数收敛速度,对准高斯牛顿法、Hook-Jeeves方法(又名模式搜索法)和共轭梯度法等三种优化方法进行了对比研究.对具有两个未知参数的离散Hénon系统和连续Lorenz系统的仿真研究表明,基于共轭梯度的参数调节方法参数收敛速度最快,可以应用于混沌保密通信的解密.

媒体漫画的主要类型与特征

本文从美术学角度出发,根据现代媒体漫画表现形式,论述了媒体漫画的主要类型以及基本特征。

铁水罐顷翻吊钩工作载荷研究

以某钢铁企业140 t铁水罐的顷翻吊钩的工作过程为研究对象,采用几何结构和积分计算方法对顷翻过程中铁水罐的工作载荷进行研究,得到了顷翻吊钩随着罐体顷翻角度变化的倾动力矩曲线和吊钩工况载荷曲线。

提速道岔尖轨与基本轨不密贴解决对策

依据分动钩式外锁闭装置技术标准规定,在分析了分动钩式外锁闭提速道岔的结构的基础上,对道岔尖轨与基本轨之间存在2mm不密贴间隙问题进行了探讨,提出了解决方案,并介绍了现场实际运用情况。

陕北黄土高原极端降水对温度变化的响应研究

随着全球变暖,极端降水事件频发,容易造成滑坡和洪水等自然灾害。研究极端降水与露点和地表温度变化的响应关系,可以为未来极端降水趋势的预测及其灾害风险研究提供可靠依据。以陕北黄土高原为研究区域,基于1970—2017年6个气象站的资料,选取6个极端降水指数,采用线性趋势法、滑动平均法和空间插值法等分析其极端降水指数的时空演变规律以及极端降水对露点和地表温度变化的响应特征,并评估其稳健性。结果表明:1970—2017年陕北黄土高原露点和地表温度呈波动上升趋势,极端降水指数中除持续湿润指数略呈下降趋势外,年总降水量、日降水强度、强降水量、强降水天数和5 d最大降水量均呈上升趋势,且呈现“南高北低”特征。日极端降水与露点温度的响应关系呈单调递增趋势,其响应强度均呈C-C标度,而日极端降水与地表温度的响应关系呈Hook结构,其在吴旗和横山站响应强度呈超C-C标度,在其余4个站均呈C-C标度,且日极端降水与露点温度的响应强度小于地表温度的。相比地表温度,极端降水与露点温度的响应关系更为稳健。