Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output t...Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output to 1925×108m3in 2020,making it the fourth largest gas-producing country in the world.Based on 1696 molecular components and carbon isotopic composition data of alkane gas in 70 large gas fields in China,the characteristics of carbon isotopic composition of alkane gas in large gas fields in China were obtained.The lightest and average values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become heavier with increasing carbon number,while the heaviest values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become lighter with increasing carbon number.Theδ^(13)C_(1)values of large gas fields in China range from-71.2‰to-11.4‰(specifically,from-71.2‰to-56.4‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-18.9‰for coal-derived gas,and from-35.6‰to-11.4‰for abiogenic gas).Based on these data,theδ^(13)C_(1)chart of large gas fields in China was plotted.Moreover,theδ^(13)C_(1)values of natural gas in China range from-107.1‰to-8.9‰,specifically,from-1071%o to-55.1‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-13.3‰for coal-derived gas,and from-36.2‰to-8.9‰for abiogenic gas.Based on these data,theδ^(13)C_(1)chart of natural gas in China was plotted.展开更多
The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple pro...The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake.展开更多
The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China...The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China. Sulfides minerals including sphalerite, galena and pyrite postdate or coprecipitate with gangue mainly consisting of fluorite, quartz, and barite, making this deposit distinct from most lead-zinc deposits in the SYG. This deposit is controlled by tectonic structures, and most mineralization is located along or near faults zones. Emeishan basalts near the ore district might have contributed to the formation of orebodies. The j34S values of sphalerite, galena, pyrite and barite were estimated to be 3.6‰-13.4‰, 3.7‰-9.0‰, -6.4‰ to 29.2‰ and 32.1‰34.7‰, respectively. In view of the similar δ34S values of barite and sulfates being from the Cambrian strata, the sulfur of barite was likely derived from the Cambrian strata. The homogenization temperatures (T ≈ 134--383℃) of fluid inclusions were not suitable for reducing bacteria, therefore, the bacterial sulfate reduction could not have been an efficient path to generate reduced sulfur in this district. Although thermochemical sulfate reduction process had contributed to the production of reduced sulfur, it was not the main mechanism. Considering other aspects, it can be suggested that sulfur of sulfides should have been derived from magmatic activities. The δ34S values of sphalerite were found to be higher than those of coexisting galena. The equilibrium temperatures calculated by using the sulfur isotopic composition of mineral pairs matched well with the homogenization temperature of fluid inclusions, suggesting that the sulfur isotopic composition in ore-forming fluids had reached a partial equilibrium.展开更多
The Huogeqi orefield located on the northern side of Mt. Langshan, Inner Mongolia occurs in the Middle Proterozoic Langshan Group metamorphic rocks, and the orebodies arc stratiform. In the past twenty years, many Chi...The Huogeqi orefield located on the northern side of Mt. Langshan, Inner Mongolia occurs in the Middle Proterozoic Langshan Group metamorphic rocks, and the orebodies arc stratiform. In the past twenty years, many Chinese geologists have conducted researches on the Huogeqi Cu-Pb-Zn deposit, but there has been still a controversy on its origin. Some advocate that the deposit is of sedimentary-metamorphic rcworking origin, some hold that it is of sea-floor SEDEX origin, and others have a preference for magmatic superimposition origin. The crux of the controversy is that there is no common understanding about the source of ore-forming materials. In this paper, the Pb isotopic compositions of regional Achaean-Early Proterozoic basement rocks, various types of sedimentary- metamorphic rocks and volcanic rocks in the mining district, Late Proterozoic and Hercynian magmatic rocks arc introduced and compared with the orc-lead composition, so as to constrain the source of the ore lead. The result indicates that (1) sulfides in the ores have homogeneous Pb isotopic compositions, showing a narrow variation range. Their ^206pb/^204pb ratios arc within a range of 17.027- 17.317; ^207Pb/^204pb ratios, 15.451-15.786 and ^208Pb/^204pb ratios, 36.747-37.669; (2) the Pb isotopic compositions of the regional Achaean-Early Proterozoic basement rocks arc characteristic of the old Pb isotopic composition at the early-stage evolution of the Earth, which varies over a wider range, reflecting significant differences in Pb isotopic compositions of the ores. All this indicates that the source of ore lead has no bearing on the basement rocks; (3) the sedimentary-metamorphic rocks in the mining district arc characterized by highly variable and more radiogenic Pb isotopic compositions and their Pb isotopic ratios arc obviously higher than those of ores, demonstrating that ore lead did not result from metamorphic rcworking of these rocks; (4) Pb isotopic compositions of Late Proterozoic diorite-gabbro and Hercynian granite are higher than those of ores. Meanwhile, the Pb isotopic compositions of sulfides in the small-sized strata-penetrating mineralized veinlets formed at later stages arc completely consistent with that of sulfides in stratiform-banded ores, suggesting that these veiniets arc the product of autochthonous rcworking of the stratiform-banded ores during the period of metamorphism and the late magmatic superimposition-mineralization can be excluded; (5) amphibolite, whose protolith is basic volcanic rocks, has the same Pb isotopic compositions as ores, implying that ore lead was derived probably from basic volcanism. So, the source of ore-forming materials for the Huogeqi deposit is like that of the volcanic massive sulfide (VMS) deposits. However, the orebodies do not occur directly within the volcanic rocks, and instead they overlie the volcanic rocks, showing some differences from those typical VMS-type deposits.展开更多
Carbonate precipitation and hydrothermal reaction are the two major processes that remove Mg from seawater.Mg isotopes are significantly(up to 5%)fractionated during carbonate precipitation by preferential incorporati...Carbonate precipitation and hydrothermal reaction are the two major processes that remove Mg from seawater.Mg isotopes are significantly(up to 5%)fractionated during carbonate precipitation by preferential incorporation of ^(24)Mg,while hydrothermal reactions are associated with negligible Mg isotope fractionation by preferential sequestration of^( 26)Mg.Thus,the marine Mg cycle could be reflected by seawater Mg isotopic composition(δ^(26)Mg_(sw)),which might be recorded in marine carbonate.However,carbonates are both texturally and compositionally heterogeneous,and it is unclear which carbonate component is the most reliable for reconstructing δ^(26)Mg_(sw).In this study,we measured Mg isotopic compositions of limestone samples collected from the early Carboniferous Huangjin Formation in South China.Based on petrographic studies,four carbonate components were recognized:micrite,marine cement,brachiopod shell,and mixture.The four components had distinct δ^(26)Mg:(1)micrite samples ranged from -2.86% to -2.97%;(2)pure marine cements varied from -3.40% to -3.54%,while impure cement samples containing small amount of Rugosa coral skeletons showed a wider range(-3.27% to-3.75%);(3)values for the mixture component were-3.17% and -3.49%;and (4)brachiopod shells ranged from -2.20% to -3.07%,with the thickened hinge area enriched in ^( 24)Mg.Due to having multiple carbonate sources,neither the micrite nor the mixture component could be used to reconstruct δ^(26)Mg_(sw).In addition,the marine cement was homogenous in Mg isotopes,but lacking the fractionation by inorganic carbonate precipitation that is prerequisite for the accurate determination of δ^(26)Mg_(sw).Furthermore,brachiopod shells had heterogeneous C and Mg isotopes,suggesting a significant vital effect during growth.Overall,the heterogeneous δ^(26)Mg of the Huangjin limestone makes it difficult to reconstruct δ^(26)Mg_(sw)using bulk carbonate/calcareous sediments.Finally,δ^(26)Mg_(sw)was only slightly affected by the faunal composition of carbonate-secreting organisms,even though biogenic carbonate accounts for more than 90% of marine carbonate production in Phanerozoic oceans and there is a wide range(0.2%–4.8%)of fractionation during biogenic carbonate formation.展开更多
Noble gas isotopic compositions of various layers in three-layered (outer, porous and compact layers) cobalt-rich ferromanganese crusts and their basaltic and phosphorite substrates from the western Pacific Ocean we...Noble gas isotopic compositions of various layers in three-layered (outer, porous and compact layers) cobalt-rich ferromanganese crusts and their basaltic and phosphorite substrates from the western Pacific Ocean were analyzed by using a high vacuum gas mass spectrum. The analytical results show that the noble gases in the Co-rich crusts have derived mainly from the ambient seawater, extraterrestrial grains such as interplanetary dust particles (IDPs) and wind-borne continental dust grains, and locally formation water in the submarine sediments, but different noble gases have different sources. He in the crusts derives predominantly from the extraterrestrial grains, with a negligible amount of radiogenic He from the eolian dust grains. Ar is sourced mainly from the dissolved air in the seawater and insignificantly from radiogenic Ar in the eolian continental dust grains or the formation water. Xe and Ne derive mainly from the seawater, with minor amounts of extraterrestrial Xe and Ne in the IDPs. Compared with the porous and outer layers, the compact layer has a relatively high 4He content and lower 3He/4He ratios, suggesting that marine phosphatization might have greatly modified the noble gas isotopic compositions of the crusts. Besides, the 3He/4He values of the basaltic substrates of the cobalt-rich crusts are very low and their R/R. ratios are mostly 〈0.1 R., which are similar to that of phosphorite substrates (0.087 R.), but much lower than that of fresh submarine MORB (8.75±14 Ra) or seamount basalts (3-43 Ra), implying that the basaltic substrates have suffered strong water/rock interaction and reacted with radiogenic ^4He and P-rich upwelling marine currents during phosphatization. The trace elements released in the basalt/seawater interaction might favor the growth of cobalt-rich crusts. The relatively low ^3He/^4He values in the seamount basalts may be used as an important exploration criterion for the cobalt-rich ferromanganese crusts.展开更多
Eighteen samples of hydrothermal sediments from the Jade hydrothermal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2× 10^(-3)to 7.2× 10^(-...Eighteen samples of hydrothermal sediments from the Jade hydrothermal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2× 10^(-3)to 7.2× 10^(-3), δ^(34)S values for 7 sulfate samples vary from 16.3 × 10^(-3) to 22.3 × 10^(-3), and 1 native sulphur sample has a δ^(34)S value of 8.2 × 10^(-3). The major sources of sulfur for hydrothermal sediment are intermediate to acid volcanic rocks and sea water sulfate, and it is possible that the partial sulfur of hydrothermal sediment is from the pelagic sediment by the interaction between hydrothermal fluid and sediment. The reasons of causing the distinct differences in sulfur isotopic values for sulfide samples from hydrothermal sediment ( compared with other hydrothermal fields), are the differences in the sources of sulfur, the magmatic activity and the tectonic evolution in different hydrothermal fields. The sulfur evolution is a long and complex process in the seafloor hydrothermal system, involving the ascending of heating sea water, the interaction between fluid and volcanic rocks, the mixing of sea water sulfate and sulfur from intermediate to acid volcanic rocks, and the fluid/pelagic-sediment interaction. And the interaction between sea water and intermediate to acid volcanic rocks is an important mechanism for the sulfur evolution in the Jade hydrothermal field.展开更多
Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of th...Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl-MTTC and dimethyl- MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl-MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water-columned depositional environment and subsequent non-intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl-MTTCs and dimethyl-MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11‰ and 5.75‰, respectively). This obviously demonstrates that the methyl-MTTC and dimethyl-MTTCs cannot be of bacteria origin, which is different from the previous point of view about non-photosynthetic bacteria products or possible bacteria-reworked products. On the contrary, the stable carbon isotopic compositions of methyl-MTTC and dimethyl-MTTCs in the two samples were similar to that of the same carbon-numbered n-alkanes (nC27-nC28-nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon-numbered steranes with ααα- 20R isomer (mostly less than 0.4‰). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl-MTTC and dimethyl-MTTCs in the saline lake sediments should be of algal biogenesis origin.展开更多
We report geochemical data, SHRIMP zircon ages and Hf-in-zircon isotopic compositions for Cenozoic granitoids from major fault systems in the Tethyan belt in western Yunnan Province, southwestern China.Four magmatic p...We report geochemical data, SHRIMP zircon ages and Hf-in-zircon isotopic compositions for Cenozoic granitoids from major fault systems in the Tethyan belt in western Yunnan Province, southwestern China.Four magmatic pulses occurred in the Paleogene, namely at ca.57 Ma, ca.50 Ma, 45–40 Ma, and 38–34 Ma.Early magmatism of this episode(57–50 Ma) produced S-type granites whose zircons yielded εHf(t) values of-5.0 to-0.3.In contrast, late magmatism of this episode reflects heterogeneous sources.Zircons from a granite porphyry along the Ailaoshan-Red River fault system have slightly positive εHf(t) values suggesting derivation from relatively young crust and/or a juvenile source.However, zircons from a granite along the Gaoligong fault system have strongly negative εHf(t) values and suggest derivation from a Paleoproterozoic crustal source.The composition of the granitoids varies with age(from ca.57 Ma to ca.34 Ma) from peraluminous to metaluminous and also suggests a change from syn-collisional to late-orogenic tectonic setting.A new tectonic model, impacting lithospheric wedge(ILW) is shown for the origin of Paleogene granitoids in this paper.展开更多
Objective The Yingyangguan Group is widely exposed in the southwestern segment of boundary belt between Yangtze and Cathaysian blocks and is mainly composed of a suit of lower-grade metamorphic marine volcanoclastic-...Objective The Yingyangguan Group is widely exposed in the southwestern segment of boundary belt between Yangtze and Cathaysian blocks and is mainly composed of a suit of lower-grade metamorphic marine volcanoclastic- sedimentary rocks (Zhou Hanwen et al., 2002). Its forming age and petrogenesis are critical for better understanding the orogenic process and relationship of the Yangtze and Cathaysian blocks since the Neoproterozoic. However, few zircon U-Pb ages of samples from the Yingyangguan Group have been reported, which are much debated, such as the metamorphic spilite (819±11 Ma), keratophyre (415.1±2.1 Ma) and ignimbrite (821.3±3.9 Ma) (Tian Yang et al., 2015 and references in). In this study, we focus on the new discovered Early Yanshannian monzogranite and its mafic enclaves from the Yingyangguan Group, and conducted zircon U-Pb dating and in-situ Hf isotopic analyses to constrain their petrogenesis.展开更多
1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14’4...1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14’42"E112°14’40",展开更多
The paper systematically deals with the background of regional isotopic compo-sitions in the lower and middle reaches of the Yangtze River and neighbouring areas. It isshown that the lead isotopic compositions of diff...The paper systematically deals with the background of regional isotopic compo-sitions in the lower and middle reaches of the Yangtze River and neighbouring areas. It isshown that the lead isotopic compositions of different geological formations and units are con-trolled by the primary mantle heterogeneity, dynamic process of crust-mantle interchange,abundances of uraninm, thorium and lead of various layers of the earth and timing. Studies onthe background of regional isotopic compositions may offer significant information forgeochemical regionalization, tracing of sources of ore-forming materials, and regionalprognosis of ore deposits.展开更多
Uliramafie xenoliths provide an important constraint on the composition,strueture and evolution of the lithosphere mantle beneath eastern China. Most of the xenoliths entrained by the Cenzoic basalts have de pleted Sr...Uliramafie xenoliths provide an important constraint on the composition,strueture and evolution of the lithosphere mantle beneath eastern China. Most of the xenoliths entrained by the Cenzoic basalts have de pleted Sr and Nd isotopie composition. Interestingly evidences have been found for old ehriehed lithosphere mantle beneath thick Arehaean and post-Arehaean erust (>35 km ) and for relatively homogeneous and depleted lithosphere mantle bencath thin erust (< 35 km ). Furthermore the chemieal composition of the lithosphere mantle is overall fertile regardless of the age of the overlying erust. The spatial variability in ehemieal and Sr and Nd isotopie eompositions of the ultramafie xenoliths in relation to the lithospherie ages and geometry implies a mixture strueture of the lithosphere mantle beheath easiern China. which consists of recently aecreted asthenospherie diapirs and old modified remnants. Isotopie eomposition of the Cenozoie basalts show obvious similarities with ocein island basalt (OIH ). We argue that enriehed lithosphere mantle delamineted during Mesozoic-Cenozoie tectonie-thermal events was generally involved in the Cenozoie basaltic voleanism.展开更多
This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South ...This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South Qinling are characterized by a strong block-effect anddepletion in U-Pb and Th-Pb, showing that these rocks came from the same lead isotopetectono-geochemical province, while those of North Qinling are characterized by higher U-Pband Th-Pb for Late Proterozoic to Early Paleozoic ones and lower U-Pb and Th-Pb forLate-Palaeozoic and younger ones in their feldspar lead isotopic composition. In the NorthQinling block, lead isotopic signatures reflect that the source of granitic magma had changedsince the Late Palaeozoic. Comparison of feldspar lead isotopic composition between SouthQinling and North Qinling shows that there is marked difference in lead isotopic compositionfor pre-Palaeozoic granitoids, indicating that the South Qinling and the North Qinling blocksbelong to different tectonic units, but the similarities in lead isotopic composition are quiteclear, which indicates that the South Qinling block had been welded with the North Qinlingblock and that the magma sources of both blocks were identical. The analysis provides directevidence for underplating of the continental crust of South Qinling beneath the North Qinlingblock in the continent-continent interaction stage of the Eastern Qinling oregenic belt.展开更多
Lanping Basin is one part of the three-rivers Tethyan tectonic domain and located in western Yunnan or southeastern Qinghai-Tibet Plateau.Yunlong salt-bearing Formation had formed under the condition of strong arid
A total of 1 264 sulfur isotopic values for modern seafloor hydrothermel sediments from different hydrothermal fields have been collected.On this basis,combining our sulfur isotpic data for surface hydrothermal sedime...A total of 1 264 sulfur isotopic values for modern seafloor hydrothermel sediments from different hydrothermal fields have been collected.On this basis,combining our sulfur isotpic data for surface hydrothermal sediments from the Jade hydrohtermal field in the Okinawa Trough and the TAG hydrothermal field in the Mid-Atlantic Ridge,respectively,and comparing the sulfur isotopic compositions and analyzing their sources of sulfur in seafloor hydrothermal sediments from different geologic-tectonic setting,the results show that:(1) sulfur isotopic values of sulfides and sulfates in modern seafloor hydrothermal sediments are concentrated in a narrow range,δ 34S values of sulfides vary from 1×10 -3 to 9×10 -3,with a mean of 4.5×10 -3 (n=1042),δ 34S values of sulfates vary from 19×10 -3 to 24×10 -3,with a mean of 21.3×10 -3(n=217);(2) comparing the sulfur isotopic compositions of hydrothermal sediments from the sediment-hosted hydrothermal fields,the range of sulfur isotopic values for hydrothermal sediments from the sediment-free hydrothermal fields is narrow relatively;(3) the differences of sulfur isotopic compositions in sulfides from different hydrothermal fields show the differences in the sources of sulfur.The sulfur of hydrothermal sulfides in the sediment-free mid-ocean ridges is mainly from mid- ocean ridge basalt,and partially from the reduced seawater sulfate,and it is the result of partially reduced seawater sulfate mixed with basaltic sulfur.In the sediment-hosted mid-ocean ridges and the back-arc basins,the volcanics,the sediments and the organic matters also can offer their sulfur for forming hydrothermal sulfides;(4)the variations of sulfur isotopic compositions and the different sources of sulfur for hydrothermal sediments may be attributed to the various physical-chemical characteristics of hydrothermal fluids,the magmatic evolution and the different geologic-tectonic settings of seafloor hydrothermal systems.展开更多
Previous studies have investigated the boron isotopic composition of salt lake brines in the Qaidam Basin,western China.However,the research on boron isotopic composition of halite is very limited due to halite’s low
Uranium ore is an essential material in the preparation of nuclear fuel for civilian and military uses.Uranium deposits are also important sources of energy for countries which depend heavily on nuclear power(e.g.Fran...Uranium ore is an essential material in the preparation of nuclear fuel for civilian and military uses.Uranium deposits are also important sources of energy for countries which depend heavily on nuclear power(e.g.France).展开更多
Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inle...Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ^13C) values of the carbonate sediment (-1‰ to -2‰) have no relation to the oxygen isotope composition of the carbonate (δ^18O) values (-7‰ to -8‰), with both isotopes showing a low variability. The carbonate content is low (〈20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ^13C values between approximately +0.5‰ and +3‰, and δ^18O values between -1‰ and -5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg-calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg-calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.展开更多
基金Supported by the National Natural Science Foundation of China(41472120)General Project of National Natural Science Foundation of China(42272188)+1 种基金Special Fund of PetroChina and New Energy Branch(2023YQX10101)Petrochemical Joint Fund of Fund Committee(U20B6001)。
文摘Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output to 1925×108m3in 2020,making it the fourth largest gas-producing country in the world.Based on 1696 molecular components and carbon isotopic composition data of alkane gas in 70 large gas fields in China,the characteristics of carbon isotopic composition of alkane gas in large gas fields in China were obtained.The lightest and average values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become heavier with increasing carbon number,while the heaviest values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become lighter with increasing carbon number.Theδ^(13)C_(1)values of large gas fields in China range from-71.2‰to-11.4‰(specifically,from-71.2‰to-56.4‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-18.9‰for coal-derived gas,and from-35.6‰to-11.4‰for abiogenic gas).Based on these data,theδ^(13)C_(1)chart of large gas fields in China was plotted.Moreover,theδ^(13)C_(1)values of natural gas in China range from-107.1‰to-8.9‰,specifically,from-1071%o to-55.1‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-13.3‰for coal-derived gas,and from-36.2‰to-8.9‰for abiogenic gas.Based on these data,theδ^(13)C_(1)chart of natural gas in China was plotted.
基金co-supported by the National Natural Science Foundation of China (grant Nos.40773064,40331012 and 40041004)"973" Program of China (No.G1999043501)
文摘The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake.
基金granted by the Key Research Program of the Chinese Academy of Sciences (KZCX2-YW-Q04-05)a Special Research Fund of the SKLOG, IGCAS (KCZX20090103)
文摘The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China. Sulfides minerals including sphalerite, galena and pyrite postdate or coprecipitate with gangue mainly consisting of fluorite, quartz, and barite, making this deposit distinct from most lead-zinc deposits in the SYG. This deposit is controlled by tectonic structures, and most mineralization is located along or near faults zones. Emeishan basalts near the ore district might have contributed to the formation of orebodies. The j34S values of sphalerite, galena, pyrite and barite were estimated to be 3.6‰-13.4‰, 3.7‰-9.0‰, -6.4‰ to 29.2‰ and 32.1‰34.7‰, respectively. In view of the similar δ34S values of barite and sulfates being from the Cambrian strata, the sulfur of barite was likely derived from the Cambrian strata. The homogenization temperatures (T ≈ 134--383℃) of fluid inclusions were not suitable for reducing bacteria, therefore, the bacterial sulfate reduction could not have been an efficient path to generate reduced sulfur in this district. Although thermochemical sulfate reduction process had contributed to the production of reduced sulfur, it was not the main mechanism. Considering other aspects, it can be suggested that sulfur of sulfides should have been derived from magmatic activities. The δ34S values of sphalerite were found to be higher than those of coexisting galena. The equilibrium temperatures calculated by using the sulfur isotopic composition of mineral pairs matched well with the homogenization temperature of fluid inclusions, suggesting that the sulfur isotopic composition in ore-forming fluids had reached a partial equilibrium.
基金supported jointly by the Bureau of Resources and Environment,Chinese Academy of Sciences(KZCX3-SW-125)the National Natural Science Foundation of China(Grant No,40172037).
文摘The Huogeqi orefield located on the northern side of Mt. Langshan, Inner Mongolia occurs in the Middle Proterozoic Langshan Group metamorphic rocks, and the orebodies arc stratiform. In the past twenty years, many Chinese geologists have conducted researches on the Huogeqi Cu-Pb-Zn deposit, but there has been still a controversy on its origin. Some advocate that the deposit is of sedimentary-metamorphic rcworking origin, some hold that it is of sea-floor SEDEX origin, and others have a preference for magmatic superimposition origin. The crux of the controversy is that there is no common understanding about the source of ore-forming materials. In this paper, the Pb isotopic compositions of regional Achaean-Early Proterozoic basement rocks, various types of sedimentary- metamorphic rocks and volcanic rocks in the mining district, Late Proterozoic and Hercynian magmatic rocks arc introduced and compared with the orc-lead composition, so as to constrain the source of the ore lead. The result indicates that (1) sulfides in the ores have homogeneous Pb isotopic compositions, showing a narrow variation range. Their ^206pb/^204pb ratios arc within a range of 17.027- 17.317; ^207Pb/^204pb ratios, 15.451-15.786 and ^208Pb/^204pb ratios, 36.747-37.669; (2) the Pb isotopic compositions of the regional Achaean-Early Proterozoic basement rocks arc characteristic of the old Pb isotopic composition at the early-stage evolution of the Earth, which varies over a wider range, reflecting significant differences in Pb isotopic compositions of the ores. All this indicates that the source of ore lead has no bearing on the basement rocks; (3) the sedimentary-metamorphic rocks in the mining district arc characterized by highly variable and more radiogenic Pb isotopic compositions and their Pb isotopic ratios arc obviously higher than those of ores, demonstrating that ore lead did not result from metamorphic rcworking of these rocks; (4) Pb isotopic compositions of Late Proterozoic diorite-gabbro and Hercynian granite are higher than those of ores. Meanwhile, the Pb isotopic compositions of sulfides in the small-sized strata-penetrating mineralized veinlets formed at later stages arc completely consistent with that of sulfides in stratiform-banded ores, suggesting that these veiniets arc the product of autochthonous rcworking of the stratiform-banded ores during the period of metamorphism and the late magmatic superimposition-mineralization can be excluded; (5) amphibolite, whose protolith is basic volcanic rocks, has the same Pb isotopic compositions as ores, implying that ore lead was derived probably from basic volcanism. So, the source of ore-forming materials for the Huogeqi deposit is like that of the volcanic massive sulfide (VMS) deposits. However, the orebodies do not occur directly within the volcanic rocks, and instead they overlie the volcanic rocks, showing some differences from those typical VMS-type deposits.
基金supported by the Natural Science Foundation of China (41272017, 41322021, and 41172001)the China Postdoctoral Science Foundation (2014M55006)
文摘Carbonate precipitation and hydrothermal reaction are the two major processes that remove Mg from seawater.Mg isotopes are significantly(up to 5%)fractionated during carbonate precipitation by preferential incorporation of ^(24)Mg,while hydrothermal reactions are associated with negligible Mg isotope fractionation by preferential sequestration of^( 26)Mg.Thus,the marine Mg cycle could be reflected by seawater Mg isotopic composition(δ^(26)Mg_(sw)),which might be recorded in marine carbonate.However,carbonates are both texturally and compositionally heterogeneous,and it is unclear which carbonate component is the most reliable for reconstructing δ^(26)Mg_(sw).In this study,we measured Mg isotopic compositions of limestone samples collected from the early Carboniferous Huangjin Formation in South China.Based on petrographic studies,four carbonate components were recognized:micrite,marine cement,brachiopod shell,and mixture.The four components had distinct δ^(26)Mg:(1)micrite samples ranged from -2.86% to -2.97%;(2)pure marine cements varied from -3.40% to -3.54%,while impure cement samples containing small amount of Rugosa coral skeletons showed a wider range(-3.27% to-3.75%);(3)values for the mixture component were-3.17% and -3.49%;and (4)brachiopod shells ranged from -2.20% to -3.07%,with the thickened hinge area enriched in ^( 24)Mg.Due to having multiple carbonate sources,neither the micrite nor the mixture component could be used to reconstruct δ^(26)Mg_(sw).In addition,the marine cement was homogenous in Mg isotopes,but lacking the fractionation by inorganic carbonate precipitation that is prerequisite for the accurate determination of δ^(26)Mg_(sw).Furthermore,brachiopod shells had heterogeneous C and Mg isotopes,suggesting a significant vital effect during growth.Overall,the heterogeneous δ^(26)Mg of the Huangjin limestone makes it difficult to reconstruct δ^(26)Mg_(sw)using bulk carbonate/calcareous sediments.Finally,δ^(26)Mg_(sw)was only slightly affected by the faunal composition of carbonate-secreting organisms,even though biogenic carbonate accounts for more than 90% of marine carbonate production in Phanerozoic oceans and there is a wide range(0.2%–4.8%)of fractionation during biogenic carbonate formation.
文摘Noble gas isotopic compositions of various layers in three-layered (outer, porous and compact layers) cobalt-rich ferromanganese crusts and their basaltic and phosphorite substrates from the western Pacific Ocean were analyzed by using a high vacuum gas mass spectrum. The analytical results show that the noble gases in the Co-rich crusts have derived mainly from the ambient seawater, extraterrestrial grains such as interplanetary dust particles (IDPs) and wind-borne continental dust grains, and locally formation water in the submarine sediments, but different noble gases have different sources. He in the crusts derives predominantly from the extraterrestrial grains, with a negligible amount of radiogenic He from the eolian dust grains. Ar is sourced mainly from the dissolved air in the seawater and insignificantly from radiogenic Ar in the eolian continental dust grains or the formation water. Xe and Ne derive mainly from the seawater, with minor amounts of extraterrestrial Xe and Ne in the IDPs. Compared with the porous and outer layers, the compact layer has a relatively high 4He content and lower 3He/4He ratios, suggesting that marine phosphatization might have greatly modified the noble gas isotopic compositions of the crusts. Besides, the 3He/4He values of the basaltic substrates of the cobalt-rich crusts are very low and their R/R. ratios are mostly 〈0.1 R., which are similar to that of phosphorite substrates (0.087 R.), but much lower than that of fresh submarine MORB (8.75±14 Ra) or seamount basalts (3-43 Ra), implying that the basaltic substrates have suffered strong water/rock interaction and reacted with radiogenic ^4He and P-rich upwelling marine currents during phosphatization. The trace elements released in the basalt/seawater interaction might favor the growth of cobalt-rich crusts. The relatively low ^3He/^4He values in the seamount basalts may be used as an important exploration criterion for the cobalt-rich ferromanganese crusts.
基金This work was financially supported in part by the National Natural Science Foundation of China under contract No. 40176020 the National Major Fundamental Research Development Project of China under contract No. G2000046703.
文摘Eighteen samples of hydrothermal sediments from the Jade hydrothermal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2× 10^(-3)to 7.2× 10^(-3), δ^(34)S values for 7 sulfate samples vary from 16.3 × 10^(-3) to 22.3 × 10^(-3), and 1 native sulphur sample has a δ^(34)S value of 8.2 × 10^(-3). The major sources of sulfur for hydrothermal sediment are intermediate to acid volcanic rocks and sea water sulfate, and it is possible that the partial sulfur of hydrothermal sediment is from the pelagic sediment by the interaction between hydrothermal fluid and sediment. The reasons of causing the distinct differences in sulfur isotopic values for sulfide samples from hydrothermal sediment ( compared with other hydrothermal fields), are the differences in the sources of sulfur, the magmatic activity and the tectonic evolution in different hydrothermal fields. The sulfur evolution is a long and complex process in the seafloor hydrothermal system, involving the ascending of heating sea water, the interaction between fluid and volcanic rocks, the mixing of sea water sulfate and sulfur from intermediate to acid volcanic rocks, and the fluid/pelagic-sediment interaction. And the interaction between sea water and intermediate to acid volcanic rocks is an important mechanism for the sulfur evolution in the Jade hydrothermal field.
文摘Significantly high abundant methyl-Methyl Trimethyl Tridecyl Chromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl-MTTC and dimethyl- MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl-MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water-columned depositional environment and subsequent non-intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl-MTTCs and dimethyl-MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11‰ and 5.75‰, respectively). This obviously demonstrates that the methyl-MTTC and dimethyl-MTTCs cannot be of bacteria origin, which is different from the previous point of view about non-photosynthetic bacteria products or possible bacteria-reworked products. On the contrary, the stable carbon isotopic compositions of methyl-MTTC and dimethyl-MTTCs in the two samples were similar to that of the same carbon-numbered n-alkanes (nC27-nC28-nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon-numbered steranes with ααα- 20R isomer (mostly less than 0.4‰). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl-MTTC and dimethyl-MTTCs in the saline lake sediments should be of algal biogenesis origin.
基金financially supported by Geological Survey of China Projects(Nos.1212010814054,1212010911049)Ministry of land and resources of public welfare scientific research(No.201311116)
文摘We report geochemical data, SHRIMP zircon ages and Hf-in-zircon isotopic compositions for Cenozoic granitoids from major fault systems in the Tethyan belt in western Yunnan Province, southwestern China.Four magmatic pulses occurred in the Paleogene, namely at ca.57 Ma, ca.50 Ma, 45–40 Ma, and 38–34 Ma.Early magmatism of this episode(57–50 Ma) produced S-type granites whose zircons yielded εHf(t) values of-5.0 to-0.3.In contrast, late magmatism of this episode reflects heterogeneous sources.Zircons from a granite porphyry along the Ailaoshan-Red River fault system have slightly positive εHf(t) values suggesting derivation from relatively young crust and/or a juvenile source.However, zircons from a granite along the Gaoligong fault system have strongly negative εHf(t) values and suggest derivation from a Paleoproterozoic crustal source.The composition of the granitoids varies with age(from ca.57 Ma to ca.34 Ma) from peraluminous to metaluminous and also suggests a change from syn-collisional to late-orogenic tectonic setting.A new tectonic model, impacting lithospheric wedge(ILW) is shown for the origin of Paleogene granitoids in this paper.
基金financially supported by the China Geological Survey(grants No.12120113063200 and DD20160035-1)
文摘Objective The Yingyangguan Group is widely exposed in the southwestern segment of boundary belt between Yangtze and Cathaysian blocks and is mainly composed of a suit of lower-grade metamorphic marine volcanoclastic- sedimentary rocks (Zhou Hanwen et al., 2002). Its forming age and petrogenesis are critical for better understanding the orogenic process and relationship of the Yangtze and Cathaysian blocks since the Neoproterozoic. However, few zircon U-Pb ages of samples from the Yingyangguan Group have been reported, which are much debated, such as the metamorphic spilite (819±11 Ma), keratophyre (415.1±2.1 Ma) and ignimbrite (821.3±3.9 Ma) (Tian Yang et al., 2015 and references in). In this study, we focus on the new discovered Early Yanshannian monzogranite and its mafic enclaves from the Yingyangguan Group, and conducted zircon U-Pb dating and in-situ Hf isotopic analyses to constrain their petrogenesis.
基金supported by projects of the Siberian Branch, Russian Academy of Sciences "The role of ice cover in the seasonal geochemical and hydrobiological cycles of small salt and freshwater lakes of Transbaikalia" and no. 56 "Forecasted modeling and multidisciplinary research of several years dynamic of meromictic lakes ecosystems state in Siberia"
文摘1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14’42"E112°14’40",
基金This study was co-supported by the State Eighth Five-Year Plan Scientific Project(No.85-901-03-08D)and National Natural Science Foundation of China(No.49473187).
文摘The paper systematically deals with the background of regional isotopic compo-sitions in the lower and middle reaches of the Yangtze River and neighbouring areas. It isshown that the lead isotopic compositions of different geological formations and units are con-trolled by the primary mantle heterogeneity, dynamic process of crust-mantle interchange,abundances of uraninm, thorium and lead of various layers of the earth and timing. Studies onthe background of regional isotopic compositions may offer significant information forgeochemical regionalization, tracing of sources of ore-forming materials, and regionalprognosis of ore deposits.
文摘Uliramafie xenoliths provide an important constraint on the composition,strueture and evolution of the lithosphere mantle beneath eastern China. Most of the xenoliths entrained by the Cenzoic basalts have de pleted Sr and Nd isotopie composition. Interestingly evidences have been found for old ehriehed lithosphere mantle beneath thick Arehaean and post-Arehaean erust (>35 km ) and for relatively homogeneous and depleted lithosphere mantle bencath thin erust (< 35 km ). Furthermore the chemieal composition of the lithosphere mantle is overall fertile regardless of the age of the overlying erust. The spatial variability in ehemieal and Sr and Nd isotopie eompositions of the ultramafie xenoliths in relation to the lithospherie ages and geometry implies a mixture strueture of the lithosphere mantle beheath easiern China. which consists of recently aecreted asthenospherie diapirs and old modified remnants. Isotopie eomposition of the Cenozoie basalts show obvious similarities with ocein island basalt (OIH ). We argue that enriehed lithosphere mantle delamineted during Mesozoic-Cenozoie tectonie-thermal events was generally involved in the Cenozoie basaltic voleanism.
基金This study was supported by the National Natural Science Foundation of China Grant No.49290102.
文摘This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South Qinling are characterized by a strong block-effect anddepletion in U-Pb and Th-Pb, showing that these rocks came from the same lead isotopetectono-geochemical province, while those of North Qinling are characterized by higher U-Pband Th-Pb for Late Proterozoic to Early Paleozoic ones and lower U-Pb and Th-Pb forLate-Palaeozoic and younger ones in their feldspar lead isotopic composition. In the NorthQinling block, lead isotopic signatures reflect that the source of granitic magma had changedsince the Late Palaeozoic. Comparison of feldspar lead isotopic composition between SouthQinling and North Qinling shows that there is marked difference in lead isotopic compositionfor pre-Palaeozoic granitoids, indicating that the South Qinling and the North Qinling blocksbelong to different tectonic units, but the similarities in lead isotopic composition are quiteclear, which indicates that the South Qinling block had been welded with the North Qinlingblock and that the magma sources of both blocks were identical. The analysis provides directevidence for underplating of the continental crust of South Qinling beneath the North Qinlingblock in the continent-continent interaction stage of the Eastern Qinling oregenic belt.
文摘Lanping Basin is one part of the three-rivers Tethyan tectonic domain and located in western Yunnan or southeastern Qinghai-Tibet Plateau.Yunlong salt-bearing Formation had formed under the condition of strong arid
文摘A total of 1 264 sulfur isotopic values for modern seafloor hydrothermel sediments from different hydrothermal fields have been collected.On this basis,combining our sulfur isotpic data for surface hydrothermal sediments from the Jade hydrohtermal field in the Okinawa Trough and the TAG hydrothermal field in the Mid-Atlantic Ridge,respectively,and comparing the sulfur isotopic compositions and analyzing their sources of sulfur in seafloor hydrothermal sediments from different geologic-tectonic setting,the results show that:(1) sulfur isotopic values of sulfides and sulfates in modern seafloor hydrothermal sediments are concentrated in a narrow range,δ 34S values of sulfides vary from 1×10 -3 to 9×10 -3,with a mean of 4.5×10 -3 (n=1042),δ 34S values of sulfates vary from 19×10 -3 to 24×10 -3,with a mean of 21.3×10 -3(n=217);(2) comparing the sulfur isotopic compositions of hydrothermal sediments from the sediment-hosted hydrothermal fields,the range of sulfur isotopic values for hydrothermal sediments from the sediment-free hydrothermal fields is narrow relatively;(3) the differences of sulfur isotopic compositions in sulfides from different hydrothermal fields show the differences in the sources of sulfur.The sulfur of hydrothermal sulfides in the sediment-free mid-ocean ridges is mainly from mid- ocean ridge basalt,and partially from the reduced seawater sulfate,and it is the result of partially reduced seawater sulfate mixed with basaltic sulfur.In the sediment-hosted mid-ocean ridges and the back-arc basins,the volcanics,the sediments and the organic matters also can offer their sulfur for forming hydrothermal sulfides;(4)the variations of sulfur isotopic compositions and the different sources of sulfur for hydrothermal sediments may be attributed to the various physical-chemical characteristics of hydrothermal fluids,the magmatic evolution and the different geologic-tectonic settings of seafloor hydrothermal systems.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41002060, 41272274)the Foundation of Youth Innovation Promotion Association of Chinese Academy of Sciences (Grant to QS Fan)
文摘Previous studies have investigated the boron isotopic composition of salt lake brines in the Qaidam Basin,western China.However,the research on boron isotopic composition of halite is very limited due to halite’s low
文摘Uranium ore is an essential material in the preparation of nuclear fuel for civilian and military uses.Uranium deposits are also important sources of energy for countries which depend heavily on nuclear power(e.g.France).
基金funded by NSFC grants(no.:40773064,40331012,and 40041004).
文摘Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ^13C) values of the carbonate sediment (-1‰ to -2‰) have no relation to the oxygen isotope composition of the carbonate (δ^18O) values (-7‰ to -8‰), with both isotopes showing a low variability. The carbonate content is low (〈20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ^13C values between approximately +0.5‰ and +3‰, and δ^18O values between -1‰ and -5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg-calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg-calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.