期刊文献+
共找到477篇文章
< 1 2 24 >
每页显示 20 50 100
Numerical simulations of full-wave fi elds and analysis of channel wave characteristics in 3-D coal mine roadway models 被引量:12
1
作者 Yang Si-Tong Wei Jiu-Chuan +2 位作者 Cheng Jiu-Long Shi Long-Qing Wen Zhi-Jie 《Applied Geophysics》 SCIE CSCD 2016年第4期621-630,737,共11页
Currently, numerical simulations of seismic channel waves for the advance detection of geological structures in coal mine roadways focus mainly on modeling two- dimensional wave fields and therefore cannot accurately ... Currently, numerical simulations of seismic channel waves for the advance detection of geological structures in coal mine roadways focus mainly on modeling two- dimensional wave fields and therefore cannot accurately simulate three-dimensional (3-D) full-wave fields or seismic records in a full-space observation system. In this study, we use the first-order velocity-stress staggered-grid finite difference algorithm to simulate 3-D full-wave fields with P-wave sources in front of coal mine roadways. We determine the three components of velocity Vx, Vy, and Vz for the same node in 3-D staggered-grid finite difference models by calculating the average value of Vy, and Vz of the nodes around the same node. We ascertain the wave patterns and their propagation characteristics in both symmetrical and asymmetric coal mine roadway models. Our simulation results indicate that the Rayleigh channel wave is stronger than the Love channel wave in front of the roadway face. The reflected Rayleigh waves from the roadway face are concentrated in the coal seam, release less energy to the roof and floor, and propagate for a longer distance. There are surface waves and refraction head waves around the roadway. In the seismic records, the Rayleigh wave energy is stronger than that of the Love channel wave along coal walls of the roadway, and the interference of the head waves and surface waves with the Rayleigh channel wave is weaker than with the Love channel wave. It is thus difficult to identify the Love channel wave in the seismic records. Increasing the depth of the receivers in the coal walls can effectively weaken the interference of surface waves with the Rayleigh channel wave, but cannot weaken the interference of surface waves with the Love channel wave. Our research results also suggest that the Love channel wave, which is often used to detect geological structures in coal mine stopes, is not suitable for detecting geological structures in front of coal mine roadways. Instead, the Rayleigh channel wave can be used for the advance detection of geological structures in coal mine roadways. 展开更多
关键词 Channel wave 3-D wave field Numerical simulation coal mine roadway Advance detection
下载PDF
Application of 3D Visual Techniques in Daliuta Coal Mine 被引量:6
2
作者 ZHOU Ye LIN Ge +2 位作者 GONG Fa-xiong LIU Shi-lin Liu Ya-chuan 《Journal of China University of Mining and Technology》 EI 2006年第1期77-81,共5页
3D visualization is one of major problems in “Digital Mine” theory and its technological research field. Through the observation of 3D geological models, spatial structural information, connected with the informatio... 3D visualization is one of major problems in “Digital Mine” theory and its technological research field. Through the observation of 3D geological models, spatial structural information, connected with the information of production management hidden in geological data, could be detected. In order to meet the requirement of more efficient coal exploration, a case study of geological characters of the Daliuta Coal Mine is presented in which 3D visual models of the ground surface and geologic bodies are established on the basis of data models and data structures of 3D geology modeling. The main conclusions of this study are as follows: (1) Through analysis and organization of spatial discrete data, the drillhole database is designed with the data of the Daliuta mine; the connections amomg drillhole data are real- ized and displayed in a 3D environment. (2) Combining real data of the Daliuta mine, drillhole visualization is realized in a 3D environment by using the CoalMiner system. (3) The ground surface modeling of the Daliuta coal mine adopted a surface-data model and a TIN data structure. (4) 3D models of coal seams and rock formations of the Daliuta mine are established, which provide a method for the simulation of complex surfaces of geologic bodies. In the end, the models are applied to the Daliuta coal mine and the result shows that better geological effects are obtained. 展开更多
关键词 3D visualization 3D geology modelling TIN Daliuta coal mine coalminer
下载PDF
Zn^(2+)、Cr^(3+)掺杂对水热合成纳米CoAl_2O_4尖晶石色料的影响 被引量:11
3
作者 陈云霞 胡琪 +3 位作者 曹春娥 卢希龙 洪琛 沈华荣 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2012年第12期1317-1320,共4页
以CoCl2·6H2O、ZnCl2、AlCl3和CrCl3·6H2O为原料,采用水热法合成了CoAl2O4(AB2O4)尖晶石型纳米钴蓝色料.采用色度分析、X射线衍射(XRD)、透射电镜(TEM)以及高分辨透射电镜(HRTEM)等研究了A位掺杂Zn2+和B位掺杂Cr3+时不同掺杂... 以CoCl2·6H2O、ZnCl2、AlCl3和CrCl3·6H2O为原料,采用水热法合成了CoAl2O4(AB2O4)尖晶石型纳米钴蓝色料.采用色度分析、X射线衍射(XRD)、透射电镜(TEM)以及高分辨透射电镜(HRTEM)等研究了A位掺杂Zn2+和B位掺杂Cr3+时不同掺杂量以及不同水热合成温度对样品呈色、晶相组成及CoAl2O4尖晶石的晶粒大小、发育程度和晶面间距的影响.结果表明,掺杂Zn2+、Cr3+所得固溶体型钴蓝色料晶粒发育均不完整,颗粒较于相同水热条件下获得的未掺杂样品更细小.A位掺杂Zn2+可降低CoAl2O4色料的合成温度,在230℃便能制得呈色较佳的Co0.95Zn0.05Al2O4钴蓝色料.随着Zn2+掺杂量的增加,合成产物由蓝色转为绿色,且呈色逐渐变浅.B位Cr3+掺杂则随着掺杂量的增加,产物从蓝色逐步转为绿色,但呈色逐渐变深.就两者相比较,A位掺杂Zn2+更有利于色料明度值的提高而呈色鲜亮. 展开更多
关键词 coal2O4尖晶石 色料 Zn2+、Cr3+掺杂 固溶体
下载PDF
HNO_3催化氧化煤系硫铁矿生产聚铁工艺研究 被引量:2
4
作者 黄仁和 陈丽慧 《环境工程》 CAS CSCD 北大核心 2002年第2期56-57,共2页
提出一种以HNO3氧化煤系硫铁矿后产物FeSO4 、H2 SO4 以及补充的FeSO4 和H2 SO4 为原料 ,放出NO为催化剂 ,O2 为氧化剂 ,生产无机净水剂聚铁的生产方法 。
关键词 催化氧化 工艺研究 煤系硫铁矿 Hno3氧化 no2催化 聚合硫酸铁
下载PDF
CoAl_2O_4包覆LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2的电化学性能 被引量:2
5
作者 蔡济钧 崔王君 +2 位作者 李冰 余洋洋 赵金保 《电化学》 CAS CSCD 北大核心 2015年第2期145-151,共7页
通过共沉淀法制得类球形锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2,并用非水相共沉法对其进行CoAl2O4包覆得到LNCMO(x).采用x射线衍射(XRD)、扫描电子显微术(SEM)和透射电子显微术(TEM)测试材料的结构和观察材料形貌.结果表明... 通过共沉淀法制得类球形锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2,并用非水相共沉法对其进行CoAl2O4包覆得到LNCMO(x).采用x射线衍射(XRD)、扫描电子显微术(SEM)和透射电子显微术(TEM)测试材料的结构和观察材料形貌.结果表明.CoAl2O4在材料表面形成8nm均匀包覆层,未改变主体材料的结构.电化学性能测试表明,1%(bymass)CoAl204包覆量的LiNi1/3Co1/3Mn1/3O2材料(LNCMO(1))高充电电压(3.0~4.6V,150mA·g^-1)100周期循环放电容量保持率为93.7%(无包覆LNCMO(0)保持率为74.4%);55℃高温100周期循环容量保持率为77%(无包覆LNCMO(0)保持率17%).XRD和电感耦合等离子体原子发射光谱(ICP—AES)测试表明,CoAl2O4包覆的LNCMO(x)材料可有效地减缓材料中Mn离子在电解液的溶解,提高材料结构稳定性和热稳定性. 展开更多
关键词 锂离子电池 LINI1/3CO1/3MN1/3O2 电化学性能 coal2O4包覆
下载PDF
Ca(NO_(3))_(2)改性对煤基多孔炭结构及甲苯吸附性能的影响 被引量:2
6
作者 于馨凝 华哲生 +5 位作者 杨洋 刘少俊 郑成航 高翔 许德军 姜欣彤 《煤炭学报》 EI CAS CSCD 北大核心 2021年第12期4063-4070,共8页
挥发性有机物(VOCs)是光化学反应形成细颗粒物(PM_(2.5))、臭氧(O_(3))等2次污染物的重要前驱体,对大气环境和人体健康具有严重的危害。多孔炭吸附法具有效率高、成本低、可再生等优点,在VOCs处理技术中应用广泛。然而目前国内生产的煤... 挥发性有机物(VOCs)是光化学反应形成细颗粒物(PM_(2.5))、臭氧(O_(3))等2次污染物的重要前驱体,对大气环境和人体健康具有严重的危害。多孔炭吸附法具有效率高、成本低、可再生等优点,在VOCs处理技术中应用广泛。然而目前国内生产的煤基多孔炭以中低端产品为主,存在孔隙不够发达、传质过程受限等问题。围绕多孔炭制备过程的结构原位调控以及VOCs在孔道内的扩散/吸附机制开展了深入的研究。以褐煤为原料,KOH为活化剂,通过酸洗脱灰和Ca(NO_(3))_(2)浸渍预处理,在碱煤质量比为2∶1的条件下制备煤基多孔炭,并选择甲苯作为目标VOCs进行吸附机制研究。结果表明,Ca(NO_(3))_(2)改性后制备得到多孔炭的石墨芳香片层堆叠高度(L_(c))减小、层间距离(d_(002))增大,说明Ca(NO_(3))_(2)改性导致石墨微晶的破坏程度加深,有利于发达孔隙结构的形成。以甲苯分子动力学直径(0.57 nm)作为孔径范围的划分尺度,发现PC-Ca0.2在甲苯分子直径1~3倍(0.57~1.71 nm)具有最高的孔容积,同时也具有最高的甲苯吸附容量(746.2 mg/g)。采用Weber-Morris颗粒内扩散模型分析甲苯吸附的速率控制步骤,发现吸附过程由内扩散和外扩散共同控制,PC-Ca0.2具有最大的吸附速率常数和最小的扩散边界层常数。因此,当多孔炭在甲苯分子动力学直径1~3倍内具有较大的孔容积时,其孔隙结构更有利于甲苯吸附过程的扩散传质。 展开更多
关键词 煤基多孔炭 Ca(no_(3))_(2)改性 甲苯 孔道扩散 吸附平衡 吸附动力学
下载PDF
On 3D Geo-visualization of a Mine Surface Plant and Mine Roadway 被引量:11
7
作者 WANG Yunjia FU Yongming FU Erjiang 《Geo-Spatial Information Science》 2007年第4期287-292,共6页
Constructing the 3D virtual scene of a coal mine is the objective requirement for modernizing and processing information on coal mining production. It is also the key technology to establish a "digital mine". By exp... Constructing the 3D virtual scene of a coal mine is the objective requirement for modernizing and processing information on coal mining production. It is also the key technology to establish a "digital mine". By exploring current worldwide research, software and hardware tools and application demands, combined with the case study site (the Dazhuang mine of Pingdingshan coal group), an approach for 3D geo-visualization of a mine surface plant and mine roadway is deeply discussed. In this study, the rapid modeling method for a large range virtual scene based on Arc/Info and SiteBuilder3D is studied, and automatic generation of a 3D scene from a 2D scene is realized. Such an automatic method which can convert mine roadway systems from 2D to 3D is realized for the Dazhuang mine. Some relevant application questions are studied, including attribute query, coordinate query, distance measure, collision detection and the dynamic interaction between 2D and 3D virtual scenes in the virtual scene of a mine surface plant and mine roadway. A prototype system is designed and developed. 展开更多
关键词 coal mine mine surface plant 3D geo-visualization virtual reality geographical information system
下载PDF
Methods applied in Australian industry to evaluate coal mine slope stability 被引量:6
8
作者 Alison McQuillan Ismet Canbulat Joung Oh 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2020年第2期151-155,共5页
Strata failure is a principal hazard in open cut coal mining as it has the potential to cause multiple fatalities.Prior to the excavation of any slope,a geotechnical assessment should review the likely slope performan... Strata failure is a principal hazard in open cut coal mining as it has the potential to cause multiple fatalities.Prior to the excavation of any slope,a geotechnical assessment should review the likely slope performance,including the risk of slope failure.Controls to manage this risk to an acceptable level should accompany the geotechnical analysis.A survey of 43 practising geotechnical engineers indicated that kinematic and 2D limit equilibrium analyses were the methods most commonly applied to analyse excavated slope stability.While these methods are well established and widely applied in the broad rock engineering disciplines(e.g.civil,hard rock),a recent review of over 60 slope failures suggests these methods have limited suitability for modelling the complex failure mechanisms observed in excavated coal mine slopes.Kinematic techniques do not adequately capture the rock mass component of excavated slope failure and do not provide a geospatial location of potential failure,while 2D limit equilibrium techniques do not adequately capture the 3D mechanisms of excavated slope failures.Methods which do consider the 3D mechanisms of slope failure are summarized for industry consideration and application. 展开更多
关键词 SLOPE stability 2D 3D Open CUT coal mine Limit EQUILIBRIUM
下载PDF
Investigating different methods used for approximating pillar loads in longwall coal mines 被引量:4
9
作者 Deniz Tuncay a Ihsan Berk Tulu a Ted Klemetti 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第1期23-32,共10页
Accurately estimating load distributions and ground responses around underground openings play a significant role in the safety of the operations in underground mines.Adequately designing pillars and other support mea... Accurately estimating load distributions and ground responses around underground openings play a significant role in the safety of the operations in underground mines.Adequately designing pillars and other support measures relies highly on the accurate assessment of the loads that will be carried by them,as well as the load-bearing capacities of the supports.There are various methods that can be used to approximate mining-induced loads in stratified rock masses to be used in pillar design.The empirical methods are based on equations derived from large databases of various case studies.They are implemented in government approved design tools and are widely used.There are also analytical and numerical techniques used for more detailed analysis of the induced loads.In this study,two different longwall mines with different panel width-to-depth ratios are analyzed using different methods.The empirical method used in the analysis is the square-decay stress function that uses the abutment angle concept,implemented in pillar design software developed by the National Institute for Occupational Safety and Health(NIOSH).The first numerical method used in the analysis is a displacement-discontinuity(DD)variation of the boundary element method,LaModel,which utilizes the laminated overburden model.The second numerical method used in the analysis is Fast Lagrangian Analysis of Continua(FLAC)with the numerical modeling approach recently developed at West Virginia University which is based on the approach developed by NIOSH.The model includes the 2D slice of a cross-section along the width of the panel with the chain pillar system that also includes the different stratigraphic layers of the overburden.All three methods gave similar results for the shallow mine,both in terms of load percentages and distribution where the variation was more obvious for the deep cover mine.The FLAC3D model was observed to better capture the stress changes observed during the field measurements for both the shallow and deep cover cases.This study allowed us to see the shortcomings of each of these different methods.It was concluded that a numerical model which incorporates the site-specific geology would provide the most precise estimate for complex loading conditions. 展开更多
关键词 Abutment loads Numerical modeling LaModel FLAC3D Longwall coal mines
下载PDF
Investigation of stability of a tunnel in a deep coal mine in China 被引量:10
10
作者 Kulatilake P.H.S.W. Wu Qiong +1 位作者 Yu Zhengxing Jiang Fuxing 《International Journal of Mining Science and Technology》 SCIE EI 2013年第4期567-577,共11页
Stability level of tunnels that exist in an underground mine has a great influence on the safety,production and economic performance of mines.Ensuring of stability for soft-rock tunnels is an important task for deep c... Stability level of tunnels that exist in an underground mine has a great influence on the safety,production and economic performance of mines.Ensuring of stability for soft-rock tunnels is an important task for deep coal mines located in high in situ stress conditions.Using the available information on stratigraphy,geological structures,in situ stress measurements and geo-mechanical properties of intact rock and discontinuity interfaces,a three-dimensional numerical model was built by using 3DEC software to simulate the stress conditions around a tunnel located under high in situ stress conditions in a coal rock mass in China.Analyses were conducted for several tunnel shapes and rock support patterns.Results obtained for the distribution of failure zones,and stress and displacement felds around the tunnel were compared to select the best tunnel shape and support pattern to achieve the optimum stability conditions. 展开更多
关键词 coal mine Tunnel stability High in situ stress Numerical modeling 3DEC
下载PDF
LaMnO_(3)钙钛矿型复合氧化物催化氧化燃煤烟气单质汞的性能研究
11
作者 彭德骏 周子健 +4 位作者 曹田田 周玥 刘磊 刘小伟 徐明厚 《动力工程学报》 CAS CSCD 北大核心 2023年第10期1371-1376,共6页
为充分利用锰氧化物在低温下的高活性以及钙钛矿结构较强的表面活性氧流动能力,采用合成的LaMnO_(3)来处理燃煤烟气中的汞,并对合成的LaMnO_(3)进行一系列的物理化学特征表征。结果表明:催化剂比表面积较小,但其表面的氧浓度高于理论值... 为充分利用锰氧化物在低温下的高活性以及钙钛矿结构较强的表面活性氧流动能力,采用合成的LaMnO_(3)来处理燃煤烟气中的汞,并对合成的LaMnO_(3)进行一系列的物理化学特征表征。结果表明:催化剂比表面积较小,但其表面的氧浓度高于理论值,且锰离子呈+3价与+4价的混合价态;催化剂表面可参与汞氧化过程的的活性氧较少,但流动性较强,体积分数3%的O2足够使催化剂维持高氧化率;HCl可以显著增强催化剂对单质汞的催化氧化活性,说明催化剂表面的大部分氧物种均可与HCl反应生成有利于单质汞氧化的活性氯。 展开更多
关键词 单质汞 LaMno_(3) 燃煤烟气 氧流动性
下载PDF
Performance analysis of jig for coal cleaning using 3D response surface methodology 被引量:3
12
作者 Kumar Shravan Venugopal R. 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第2期333-337,共5页
Beneficiation of coal of -4.76 mm + 3 mm size fraction was investigated in a laboratory model Denver jig.Process variables were studied to analyze their effect on the performance of jig in terms of yield and ash conte... Beneficiation of coal of -4.76 mm + 3 mm size fraction was investigated in a laboratory model Denver jig.Process variables were studied to analyze their effect on the performance of jig in terms of yield and ash content of clean coal. Three-factor three-level Box-Behnken design of experiments with response surface methodology(RSM) was employed to understand the performance behavior of jig. From the study, the bed height was found to be the most significant parameter affecting the yield and ash content of clean coal. It was possible to reduce the ash content from 24.32% in feed to an ash content of 16.55% in clean coal at 2 L/min water flow rate and 10 min jigging time. Influence of operating variables of the jig on responses was presented and discussed in 3D surface plots. The developed model was found to be significant within the range of parameters under investigation with correlation of co-efficient values as 0.99(yield) and 0.98(ash). 展开更多
关键词 coal beneficiation Jigging Bed height 3D-RSM Box-Behnken
下载PDF
Even-carbon predominance of Monomethyl branched alkanes in Humic coal from Junggar Basin,NW China 被引量:1
13
作者 Qingsong Cheng Min Zhang Guanghui Huang 《Acta Geochimica》 EI CAS CSCD 2020年第3期434-444,共11页
A series of Monomethyl branched alkanes compounds were detected between nC14-nC36,in immature and low maturity Jurassic humic coal,Junggar basin.2-methyl alkanes and 3-methyl alkanes accounted for the vast majority of... A series of Monomethyl branched alkanes compounds were detected between nC14-nC36,in immature and low maturity Jurassic humic coal,Junggar basin.2-methyl alkanes and 3-methyl alkanes accounted for the vast majority of the compounds.It is worth noting that the2-methyl alkanes in the humic coal samples show an obvious distribution of even carbon predominances rarely reported in the literature.The results show that with the increase of Pr/Ph(pristane/phytane),the even carbon dominance of 2-methyl alkanes is more obvious,while the odd carbon number distribution of 3-methyl alkanes is weakened.As Pr/Ph increases in the humic coal,the relative content of the hopanes increased,while the relative content of 2-methyl alkanes and 3-methyl alkanes increases first and then decreases. 展开更多
关键词 Junggar basin Humic coal Even carbon predominance 2-methyl alkanes 3-methyl alkanes
下载PDF
Utilizing 3D DOSY NMR in the characterization of organic compounds in coal chemical wastewater 被引量:2
14
作者 Hui Ma Christian M.Pedersen +4 位作者 Qi Zhao Shiyu Jia Bin Yuan Xianglin Hou Yingxiong Wang 《Magnetic Resonance Letters》 2022年第2期69-79,I0002,共12页
Coal chemical wastewater(CCW)with the features of high toxicity and poor biodegradability is a big issue in environmental remediation,posing a great threat to aquatic ecosystems and to human beings.Such complex molecu... Coal chemical wastewater(CCW)with the features of high toxicity and poor biodegradability is a big issue in environmental remediation,posing a great threat to aquatic ecosystems and to human beings.Such complex molecular mixtures are notoriously difficult to characterize without initial physical separation.Herein,we present the 3D diffusion ordered spectroscopy(DOSY)analysis for CCW using DOSY-COSY and DOSY-HSQC methods,the advantages of this strategy have been demonstrated in the analysis of mixtures of aliphatic oxygenates and aromatic compounds,before being implemented on a genuine CCW sample in this study.The results showed that 3D DOSY is a robust and reliable tool for providing superior resolution and virtual separation of complex pollutants,and can be used as a general approach for structural elucidation. 展开更多
关键词 coal chemical wastewater 3D DOSY NMR ANALYSIS SEPARATION Structural characterization
下载PDF
A case study of multi-seam coal mine entry stability analysis with strength reduction method 被引量:6
15
作者 Tulu Ihsan Berk Esterhuizen Gabriel S. +3 位作者 Klemetti Ted Murphy Michael M. Sumner James Sloan Michael 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2016年第2期193-198,共6页
In this paper,the advantage of using numerical models with the strength reduction method(SRM) to evaluate entry stability in complex multiple-seam conditions is demonstrated.A coal mine under variable topography from ... In this paper,the advantage of using numerical models with the strength reduction method(SRM) to evaluate entry stability in complex multiple-seam conditions is demonstrated.A coal mine under variable topography from the Central Appalachian region is used as a case study.At this mine,unexpected roof conditions were encountered during development below previously mined panels.Stress mapping and observation of ground conditions were used to quantify the success of entry support systems in three room-and-pillar panels.Numerical model analyses were initially conducted to estimate the stresses induced by the multiple-seam mining at the locations of the affected entries.The SRM was used to quantify the stability factor of the supported roof of the entries at selected locations.The SRM-calculated stability factors were compared with observations made during the site visits,and the results demonstrate that the SRM adequately identifies the unexpected roof conditions in this complex case.It is concluded that the SRM can be used to effectively evaluate the likely success of roof supports and the stability condition of entries in coal mines. 展开更多
关键词 coal mine ground control Multiple seam mining Phase 2 FLAC3D Strength reduction method Roof supports
下载PDF
氧浓度对氨煤混燃高温还原区NH_(3)/煤焦/NO异相还原的影响
16
作者 陈萍 蒋博宇 +4 位作者 花昌豪 王佩佩 顾明言 樊建人 汪一 《煤炭学报》 EI CAS CSCD 北大核心 2023年第10期3912-3919,共8页
在煤粉炉中掺入无碳燃料氨可有效降低火电CO_(2)排放,近几年引起了越来越多的关注。然而,氨混烧增加了NO_(x)生成途径,研究氨煤混烧过程高温还原区NO的还原机理对实现氨煤混燃低氮排放尤为关键。高温还原区并非无氧环境,探究还原区微氧... 在煤粉炉中掺入无碳燃料氨可有效降低火电CO_(2)排放,近几年引起了越来越多的关注。然而,氨混烧增加了NO_(x)生成途径,研究氨煤混烧过程高温还原区NO的还原机理对实现氨煤混燃低氮排放尤为关键。高温还原区并非无氧环境,探究还原区微氧对未燃氨耦合煤焦还原NO的影响机理十分必要。利用高温水平管式炉研究了O_(2)体积分数(0、0.5%、1.0%、1.5%、2.0%)对NH_(3)/NO均相以及NH_(3)/煤焦/NO异相还原的影响机理,温度在1373~1773 K。研究结果表明,高温无氧环境下,随着温度升高,NH_(3)均相还原NO的效率增加;当温度高于1573 K时,NH_(3)均相还原NO随温度的升高略微降低,未燃氨对NO的最佳还原温度为1573 K。而煤焦的存在显著提高了高温下NH_(3)还原NO的效率,且将NO的最佳还原温度拓宽到1673 K,煤焦与NH_(3)对NO的还原表现为协同促进作用。相对于无氧条件,O_(2)体积分数在2.0%、温度不高于1500 K时,微氧促进了还原性自由基NH_(2)/NH的生成,对NH_(3)/NO的均相还原表现为促进作用;进一步升高温度,有利于体系内NH_(2)/NH的氧化,使得有氧条件下NH_(3)均相还原NO的效率低于无氧条件。NH_(3)/煤焦/NO的异相还原体系中,当温度不高于1473 K以及O_(2)体积分数不高于0.5%时,微氧条件下的NO异相还原效率高于无氧条件;但当O_(2)体积分数和温度的进一步提高,NHi与OH/O等氧化性自由基的氧化反应相较于NHi/煤焦还原NO过程的速率更快时,NH_(3)/煤焦/NO异相体系内NO的还原效率降低,表明存在促进高温还原区NH_(3)/煤焦异相还原NO的最佳O_(2)体积分数。 展开更多
关键词 氨煤混燃 微氧 NH_(3) 煤焦 no
下载PDF
Detection technology and application of electromagnetic method for hidden danger of water gushing at coal face 被引量:2
17
作者 SHI Xian-xin YAN Shu +1 位作者 CHEN Ming-sheng FU Jun-mei 《Journal of Coal Science & Engineering(China)》 2009年第2期197-205,共9页
The principles, methods, technologies and application effects of several electromagnetic methods for the detection of the hidden danger of water gushing at the coal face were introduced. Also, emphasis was laid on exp... The principles, methods, technologies and application effects of several electromagnetic methods for the detection of the hidden danger of water gushing at the coal face were introduced. Also, emphasis was laid on expounding the methods, principles and effects of down-hole detections by electric transmission tomography and transient electromagnetic method. The potential of point power supplied in the underground homogeneous semi-space, as well as the response to a low-resistivity abnormal body in the homogeneous semi-space, was simulated by adopting 3-D finite element method to interpret the basic theory of the electric transmission tomography. The results of actual measurement show that the mine electromagnetic method is sensitive to water-bearing low-resistivity bodies and can play a unique role in detecting the hidden danger of water gushing at the coal face. 展开更多
关键词 hidden trouble of water gushing electric transmission tomography mine transient electromagnetic method coal face high-density resistivity method 3-D finite element simulation
下载PDF
MgO-Al_(2)O_(3)复合氧化物负载MnO_(x)吸附剂的Hg脱除性能
18
作者 桂本 许杰 +4 位作者 胡玉清 陈牧 刘瑜 周子健 刘小伟 《洁净煤技术》 CAS 北大核心 2022年第8期93-101,共9页
天然矿物MgO被认为是负载MnO_(x)脱除燃煤烟气中Hg^(0)的优良载体,然而其比表面积限制了Mn物种的利用效率,对Mn物种的用量需求较高。为提高载体在脱除烟气中Hg^(0)反应过程中对Mn活性物种的利用率,采用Al_(2)O_(3)部分替换MgO,制备了MgO... 天然矿物MgO被认为是负载MnO_(x)脱除燃煤烟气中Hg^(0)的优良载体,然而其比表面积限制了Mn物种的利用效率,对Mn物种的用量需求较高。为提高载体在脱除烟气中Hg^(0)反应过程中对Mn活性物种的利用率,采用Al_(2)O_(3)部分替换MgO,制备了MgO-Al_(2)O_(3)复合氧化物负载的MnO_(x)吸附剂。利用Al_(2)O_(3)较大的比表面积以及表面较高的化学吸附氧(O_(ad))占比,提升了Mn对Hg^(0)的吸附与氧化能力,获得了Hg^(0)脱除效率更高的吸附剂。结果表明,仅负载5%的Mn物种时,在MgO载体中添加30%的Al_(2)O_(3)可使吸附剂在150℃、N_(2)+10%O_(2)气氛中提升Hg^(0)脱除效率27.7%。通过H_(2)-TPR及XPS揭示吸附剂对Hg^(0)的脱除机理,H_(2)-TPR表明添加Al_(2)O_(3)会与MgO发生交互反应形成更稳定的载体物种,XPS表明吸附剂表面Mn^(4+)物种占比对Hg^(0)脱除活性有重要影响,添加30%的Al_(2)O_(3)时吸附剂表面Mn^(4+)物种占比最高,因此Hg^(0)脱除活性最高。针对MgO载体上Mn活性组分受限的缺点,采用添加Al_(2)O_(3)的方法提升了载体对于活性物种的利用率,对天然矿物载体在Hg^(0)脱除领域的应用具有借鉴意义。 展开更多
关键词 燃煤烟气 单质汞 MgO-Al_(2)O_(3)复合载体 Mno_(x)吸附剂
下载PDF
Role of iron-based catalysts in reducing NO_(x) emissions from coal combustion
19
作者 Yuehua Liu Lili Chen +2 位作者 Shoujun Liu Song Yang Ju Shangguan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第7期1-8,共8页
Nitrogen oxide(NO_(x))pollutants emitted from coal combustion are attracting growing public concern.While the traditional technologies of reducing NO_(x) were mainly focused on terminal treatment,and the research on s... Nitrogen oxide(NO_(x))pollutants emitted from coal combustion are attracting growing public concern.While the traditional technologies of reducing NO_(x) were mainly focused on terminal treatment,and the research on source treatment is limited.This paper proposes a new coal combustion strategy that significantly reduces NO_(x) emissions during coal combustion.This strategy has two important advantages in reducing NO_(x) emissions.First,by introducing iron-based catalyst at the source,which will catalyze the conversion of coke nitrogen to volatile nitrogen during the pyrolysis process,thereby greatly reducing the coke nitrogen content.The second is de-NO_(x) process by a redox reaction between NO_(x) and reducing agents(coke,HCN,NH_(3),etc.)that occurred during coke combustion.Compared to direct combustion of coal,coke prepared by adding iron-based catalyst has 46.1% reduction in NO_(x) emissions.To determine the effect of iron-based additives on de-NO_(x) performance,demineralized coal(de-coal)was prepared to eliminate the effect of iron-based minerals in coal ash.The effects of iron compounds,additive dosages,and combustion temperatures on de-NO_(x) efficiency are systematically studied.The results revealed that the NO_(x) emission of the coke generated by pyrolysis of de-coal loaded with 3%(mass)Fe_(2)O_(3) decreases to 27.3% at combustion temperature of 900℃.Two main reasons for lower NO_(x) emissions were deduced:(1)During the catalytic coal pyrolysis stage,the nitrogen content in the coke decreases with the release of volatile nitrogen.(2)Part of the NO_(x) emitted during the coke combustion was converted into N_(2) for the catalytic effect of the Fe-based catalysts.It is of great practical value and scientific significance to the comprehensive treatment and the clean utilization process of coal. 展开更多
关键词 no_(x) coal combustion coal pyrolysis Fe2O3 catalyst
下载PDF
Application of 3-D Parallel Electrical Technology Detecting the Water-Rich Areas
20
作者 Xuan Wang Liquan Guo 《Open Journal of Geology》 2014年第10期518-523,共6页
Coal working face is damaged more and more seriously by water below the coal face floor. Therefore, floor water detection is a must in the process of extraction. This article aims to introducing application and princi... Coal working face is damaged more and more seriously by water below the coal face floor. Therefore, floor water detection is a must in the process of extraction. This article aims to introducing application and principle of the two-gateways parallel 3-D electrical technology and the arrangement of the observation system. The authors use this method to detect the water under the floor of a mine in north of Anhui. The results show that the two-gateways parallel 3-D electrical technology can accurately locate the water-rich areas, providing the basis for drilling drainage and grouting construction. 展开更多
关键词 The Two-Gateways PARALLEL 3-D Electrical Technology coal Face FLOOR Water-Rich Areas
下载PDF
上一页 1 2 24 下一页 到第
使用帮助 返回顶部