The western margin of Yangtze Craton is known as a significant sediment-hosted base-metal aggregate cluster,especially for Pb-Zn deposits in China,e.g.Jinding,Daliangzi,Tianbaoshan, Kuangshanchang and Qinlinchang depo...The western margin of Yangtze Craton is known as a significant sediment-hosted base-metal aggregate cluster,especially for Pb-Zn deposits in China,e.g.Jinding,Daliangzi,Tianbaoshan, Kuangshanchang and Qinlinchang deposits.In comparison with the classic MVT deposits in the world, based on the basic geology of the sediment-hosted Pb-Zn deposits,this paper focuses on temporal-spatial distribution of this deposit to further discuss its large scale mineralization and tectonic evolution history.In the SW Sanjiang Thethys,Jinding deposit is typically thrust fault-controlled and hosted mainly in the sandstones and breccia-bearing sandstones,whereas MVT-type deposits are controlled by lithology and faulting/fracturing with a strong preference for carbonate-hosted rocks.Most importantly,Jinding Pb-Zn deposit differs from the other types of sediment-hosted Pb-Zn deposits in which it was formed in a strongly deformed foreland basin within a continental collision zone.In the Kangdian area,the sediment-hosted Pb-Zn deposits were formed in the extensional basin on the side of the continental orogenic belt along the Yangtze Craton.Compared with classic MVT deposits,the Pb-Zn deposits in the Kangdian area belong to MVT deposits.This paper is significant not only for interpretation of the genesis of sediment-hosted Pb-Zn deposits but also for exploiting large base metal deposits in large sedimentary target areas.展开更多
Analyses of fluid\|inclusion leachates from ore deposits show that Na/Br ratios are within the range of 75-358 and Cl/Br 67-394, respectively, and this variation trend coincides with the seawater evaporation trajector...Analyses of fluid\|inclusion leachates from ore deposits show that Na/Br ratios are within the range of 75-358 and Cl/Br 67-394, respectively, and this variation trend coincides with the seawater evaporation trajectory on the basis of the Na/Br and Cl/Br ratios. The average Cl/Br and Na/Br ratios of mineralizing fluids are 185 and 173 respectively, which are very close to the ratios (120 and 233) of the residual evaporated seawater past the point of halite precipitation. It is suggested that the original mineralizing brine was derived from highly evaporated seawater with a high salinity. However, the inclusion fluids have absolute Na values of \{69.9\}-\{2606.2\} mmol kg\+\{-1\} and Cl values of \{106.7\}-\{1995.5\} mmol kg\+\{-1\}. Most of the values are much less than those of seawater: Na, 485 mmol kg\+\{-1\} and Cl, 566 mmol kg\+\{-1\}, respectively; the salinity measured from fluid inclusions of the deposits ranges from \{2.47 wt%\} to \{15.78 wt%\} NaCl equiv. The mineralizing brine has been diluted. The \{δ\{\}\+\{18\}O\} and δD values of ore\|forming fluids vary from \{-8.21‰\} to \{9.51‰\} and from \{-40.3‰\} to \{-94.3‰\}, respectively. The δD values of meteoric water in this region varied from \{-80‰\} to \{-100‰\} during the Jurassic. This evidenced that the ore\|forming fluids are the mixture of seawater and meteoric water. Highly evaporated seawater was responsible for leaching and extracting Pb, Zn and Fe, and mixed with and diluted by descending meteoric water, which resulted in the formation of ores.展开更多
The Kangdian axis basement can be divided into two tectonic layers. The lower tectonic layer is the crystalline basement which is made up of the Archaean Dibadu Formation and early Proterozoic Dahongshan Group. The fo...The Kangdian axis basement can be divided into two tectonic layers. The lower tectonic layer is the crystalline basement which is made up of the Archaean Dibadu Formation and early Proterozoic Dahongshan Group. The former is a kata-metamorphic basic volcano-sedimentary formation of the old geosyncline (old continental nucleus), and the latter is a medium-grade metamorphosed alkali-rich basic volcanic (emanation)-sedimentary formation of the Yuanjiang-Dahongshan marginal rift. They are in disconformable contact. The upper tectonic layer is the folded basement, and made up of the middle-late Proterozoic Kunyang Group. It is the result of Dongchuan-Yuanjiang intercontinental rifting with discordant contract with the underlying and overlying strata. Along with the evolution of Proterozoic from early to late, four types of emanation-sedimentary deposits in the Kangdian axis rift were formed in turn: emanation-sedimentary iron-copper-gold deposits related to basic volcanic rocks in the Yuanmou-Dahongshan marginal rift; emanation-sedimentary iron-copper deposits related to intermediate-basic volcanic rocks in the early stage of the Dongnchuan-Yuanjiang intercontinental rift; emanation-sedimentary copper deposits related to sedimentary rocks in the middle stage; copper deposits related to the late tectonic reworking. From early to late Proterozoic, with the evolution of the Kangdian axis rift and lowering volcanic basicity, the ore-forming elements also evolved from Fe, Cu and (Au) through Cu and Fe to Cu.展开更多
1 Introduction The Kangdian axis is an important polymetallic metallogenic belt in Southwest China,and it is also an area with a lot of hydrothermal uranium mineralization(Wang Hongjun,et al.,2009.The basic
This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yua...This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yuanjiang. Through systematically sampling of rocks, mineral and single mineral samples, this study discussed the continental geodynamics, age of magmatic rocks and metallogenic epoch, coupling relationship between polymetallic elements and ore-forming fluid, and the coupling relationship between magma evolution and polymetallic mineralization based on the latest metallogenic theory and modern analytical techniques.展开更多
Along with the evolution of the earth crust, in the south of Kangdian Axis the polycyclic rifting occurred: Ptd-Ptk, Jinshajiang continental margin sea type aulacogen, Ptk2Dongchuan-Yimen intercontinental aulacogen, Z...Along with the evolution of the earth crust, in the south of Kangdian Axis the polycyclic rifting occurred: Ptd-Ptk, Jinshajiang continental margin sea type aulacogen, Ptk2Dongchuan-Yimen intercontinental aulacogen, Z Chengjiang postorogenic rift and T3-E1 Kangdian continental rift. In these rifts respectively produced Dahongshan-Lala type volcanic-sedimentary-metamorphosed/hydrothermal sedimentary Cu-Fe deposits. Dongchuan-Yimen type, Lanniping type and Dayao-Mouding type sedimentary-reworked copper deposits, which form the storeyed texture whose geochemistry of the trace elements, isotopes of S, Pb, H, O, C. ore-forming fluid and organic matter were regularly evolved with the crust evolution.展开更多
The Neoproterozoic Kangdian Rift Basin is a continental rift basin in the western Yangtze Continent.Determining its time of opening and subsequent filling pattern is an important aspect of understanding the formation ...The Neoproterozoic Kangdian Rift Basin is a continental rift basin in the western Yangtze Continent.Determining its time of opening and subsequent filling pattern is an important aspect of understanding the formation and evolution of the Yangtze Continent,South China.The Luliang Formation is the early filling in the eastern part of this rift basin,and its deposition age and filling sequence are significant for studies of the regional stratigraphic correlation,opening time,and filling pattern of this basin.Having been correlated to the upper part of the Mesoproterozoic Kunyang Group or to the Neoproterozoic Chengjiang Formation,the age and regional stratigraphic correlation of the Luliang Formation have long been uncertain.This is due to a lack of reliable absolute age constraints.To address this issue,the first zircon SHRIMP U-Pb geochronology has been established for this formation,yielding two high-precision isotopic ages of 818.6±9.2 and 805±14 Ma for the tuff layers at the bottoms of the lower and upper members of the Luliang Formation,respectively.Given the error factor,the bottom age of the lower member of the Luliang Formation can be interpreted as ca.820 Ma,corresponding to the bottom age of the lower part of the Banxi Group,which is the early filling of the Neoproterozoic Xianggui Rift Basin,a representative basin of the Neoproterozoic rift basins in the Yangtze Continent,South China.The bottom age of the upper member of the Luliang Formation can be interpreted as ca.800±5 Ma,corresponding to the bottom age of the Chengjiang Formation in the western part of the Neoproterozoic Kangdian Rift Basin and also corresponding to the bottom age of the upper part of the Banxi Group in the Neoproterozoic Xianggui Rift Basin.These ages indicate that the Neoproterozoic Kangdian Rift Basin shares the same opening time and filling sequences as those of the other Neoproterozoic rift basins in South China.Basin analysis shows that the Neoproterozoic Kangdian Rift Basin is a typical half-graben basin,with its main boundary fault in the west and basin center in the east.This basin consisted of mini unidirectional half-graben basins in its juvenile stage and simplified to become a large united half-graben basin in its mature stage,i.e.,a supradetachment basin.展开更多
SITUATED on the eastern margin of Kangdian axis the lead-zinc mineral belt is an important mineral occur- rence of lead-zinc in southwestern China. It is 1 200 km in length from Kangding in Sichuan Province tonortheas...SITUATED on the eastern margin of Kangdian axis the lead-zinc mineral belt is an important mineral occur- rence of lead-zinc in southwestern China. It is 1 200 km in length from Kangding in Sichuan Province tonortheastern Yunnan Province, and 500 km in width from west to east. There are four large deposits,fourteen middle deposits and many small deposits or mineralized spots. Famous large deposits such as Doliangzi, Tianbaoshan, Chipu and Kuangshanchang are distributed in this belt. 1 Geological setting There are many mineral-bearing strata in carbonate-hosted lead-zinc deposits of this mineral belt,such as Dengying formation (Zbdn), Longwangmiao formation (<sub>2</sub> l) Erdaoshui formation ( <sub>3</sub> e ),Daqing formation(O<sub>2</sub> d ), Daguan formation (S<sub>2</sub>d ), the lower Devonian and Baizuo formation ( C<sub>1</sub> b).展开更多
扬子地台寒武系下统存在富含V、Ni、Mo和铂族元素(platinum group element, PGE)等的黑色页岩,局部地区有U或者Ba、Hg、As等的富集,研究这些元素富集机理有利于寻找相关矿产或者探究地质事件。6 500万年前的小行星撞击地球产生了高PGE...扬子地台寒武系下统存在富含V、Ni、Mo和铂族元素(platinum group element, PGE)等的黑色页岩,局部地区有U或者Ba、Hg、As等的富集,研究这些元素富集机理有利于寻找相关矿产或者探究地质事件。6 500万年前的小行星撞击地球产生了高PGE含量的地层或者化石,依据这一事实和陨石的特征及其他地质地球化学证据,推断下寒武统黑色页岩中Ni-Mo-PGE富集是陨石撞击结果,PGE中的Ir、Os富集最明显是因为二者最抗淋滤。U在康滇地轴东侧黑色页岩中最高可达480×10^(-6),因康滇地轴本身就存在混合型铀矿,推测黑色页岩中U来自它的风化。据V和Ba-Hg-As等的地化特性,认为V富集是受生物活动影响,但因V易于在热泉水中富集,故寒武纪早期泛非运动的构造-热事件可导致V富集成矿,Ba、Hg、As也因该事件产生构造裂隙后,它们优先随热液沿裂隙上升富集,并在海底局部成矿。此外,5.65亿年前的埃迪卡拉动物群发生地基本上就是5.8亿年前小行星撞击地点,提出此次行星撞击可能与埃迪卡拉生物群出现存在因果关系。由于在中国存在寒武纪澄江生物群大爆发事件,推测该次生物大爆发之前存在的下寒武统黑色页岩也存在陨石撞击痕迹。寒武系下统的含岩屑细砂岩夹黑色页岩甚至砾岩,反映了黑色页岩沉积时存在的突变沉积环境,加上其他地球化学特征也支持小行星撞击说。展开更多
The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization ...The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism.展开更多
基金supported by the National Basic Research Program(No.2009CB421008)the Fundamental Research Funds for the Central Universities (No.2010ZY02)+2 种基金China Postdoctoral Science Foundation (No.20090460400)Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)the 111 Project(No.B07011)
文摘The western margin of Yangtze Craton is known as a significant sediment-hosted base-metal aggregate cluster,especially for Pb-Zn deposits in China,e.g.Jinding,Daliangzi,Tianbaoshan, Kuangshanchang and Qinlinchang deposits.In comparison with the classic MVT deposits in the world, based on the basic geology of the sediment-hosted Pb-Zn deposits,this paper focuses on temporal-spatial distribution of this deposit to further discuss its large scale mineralization and tectonic evolution history.In the SW Sanjiang Thethys,Jinding deposit is typically thrust fault-controlled and hosted mainly in the sandstones and breccia-bearing sandstones,whereas MVT-type deposits are controlled by lithology and faulting/fracturing with a strong preference for carbonate-hosted rocks.Most importantly,Jinding Pb-Zn deposit differs from the other types of sediment-hosted Pb-Zn deposits in which it was formed in a strongly deformed foreland basin within a continental collision zone.In the Kangdian area,the sediment-hosted Pb-Zn deposits were formed in the extensional basin on the side of the continental orogenic belt along the Yangtze Craton.Compared with classic MVT deposits,the Pb-Zn deposits in the Kangdian area belong to MVT deposits.This paper is significant not only for interpretation of the genesis of sediment-hosted Pb-Zn deposits but also for exploiting large base metal deposits in large sedimentary target areas.
基金ThisresearchprojectwasfundedbytheNationalNaturalScienceFoundationofChina (No .4 0 1 72 0 39)
文摘Analyses of fluid\|inclusion leachates from ore deposits show that Na/Br ratios are within the range of 75-358 and Cl/Br 67-394, respectively, and this variation trend coincides with the seawater evaporation trajectory on the basis of the Na/Br and Cl/Br ratios. The average Cl/Br and Na/Br ratios of mineralizing fluids are 185 and 173 respectively, which are very close to the ratios (120 and 233) of the residual evaporated seawater past the point of halite precipitation. It is suggested that the original mineralizing brine was derived from highly evaporated seawater with a high salinity. However, the inclusion fluids have absolute Na values of \{69.9\}-\{2606.2\} mmol kg\+\{-1\} and Cl values of \{106.7\}-\{1995.5\} mmol kg\+\{-1\}. Most of the values are much less than those of seawater: Na, 485 mmol kg\+\{-1\} and Cl, 566 mmol kg\+\{-1\}, respectively; the salinity measured from fluid inclusions of the deposits ranges from \{2.47 wt%\} to \{15.78 wt%\} NaCl equiv. The mineralizing brine has been diluted. The \{δ\{\}\+\{18\}O\} and δD values of ore\|forming fluids vary from \{-8.21‰\} to \{9.51‰\} and from \{-40.3‰\} to \{-94.3‰\}, respectively. The δD values of meteoric water in this region varied from \{-80‰\} to \{-100‰\} during the Jurassic. This evidenced that the ore\|forming fluids are the mixture of seawater and meteoric water. Highly evaporated seawater was responsible for leaching and extracting Pb, Zn and Fe, and mixed with and diluted by descending meteoric water, which resulted in the formation of ores.
文摘The Kangdian axis basement can be divided into two tectonic layers. The lower tectonic layer is the crystalline basement which is made up of the Archaean Dibadu Formation and early Proterozoic Dahongshan Group. The former is a kata-metamorphic basic volcano-sedimentary formation of the old geosyncline (old continental nucleus), and the latter is a medium-grade metamorphosed alkali-rich basic volcanic (emanation)-sedimentary formation of the Yuanjiang-Dahongshan marginal rift. They are in disconformable contact. The upper tectonic layer is the folded basement, and made up of the middle-late Proterozoic Kunyang Group. It is the result of Dongchuan-Yuanjiang intercontinental rifting with discordant contract with the underlying and overlying strata. Along with the evolution of Proterozoic from early to late, four types of emanation-sedimentary deposits in the Kangdian axis rift were formed in turn: emanation-sedimentary iron-copper-gold deposits related to basic volcanic rocks in the Yuanmou-Dahongshan marginal rift; emanation-sedimentary iron-copper deposits related to intermediate-basic volcanic rocks in the early stage of the Dongnchuan-Yuanjiang intercontinental rift; emanation-sedimentary copper deposits related to sedimentary rocks in the middle stage; copper deposits related to the late tectonic reworking. From early to late Proterozoic, with the evolution of the Kangdian axis rift and lowering volcanic basicity, the ore-forming elements also evolved from Fe, Cu and (Au) through Cu and Fe to Cu.
基金supported by the China Nuclear Industry Geological Bureau Foundation (No.201637 and 201638)
文摘1 Introduction The Kangdian axis is an important polymetallic metallogenic belt in Southwest China,and it is also an area with a lot of hydrothermal uranium mineralization(Wang Hongjun,et al.,2009.The basic
基金financially supported by China Geological Survey (grant no.12120113095500)the National Basic Research Program of China (973 Program) (grant no.2015CB453000)the Foundation of China Nuclear Geology (grant no.201148)
文摘This study focused on the typical Precambrian copper- iron-gold-uranium deposits in the southwestern margin of the Yangtze block, such as the Lala in Huili, Dahongshan in Xinping, Yinachang in Wuding, and Chahe in Yuanjiang. Through systematically sampling of rocks, mineral and single mineral samples, this study discussed the continental geodynamics, age of magmatic rocks and metallogenic epoch, coupling relationship between polymetallic elements and ore-forming fluid, and the coupling relationship between magma evolution and polymetallic mineralization based on the latest metallogenic theory and modern analytical techniques.
基金Project supported by the Naional Natural Science Foundation of China.
文摘Along with the evolution of the earth crust, in the south of Kangdian Axis the polycyclic rifting occurred: Ptd-Ptk, Jinshajiang continental margin sea type aulacogen, Ptk2Dongchuan-Yimen intercontinental aulacogen, Z Chengjiang postorogenic rift and T3-E1 Kangdian continental rift. In these rifts respectively produced Dahongshan-Lala type volcanic-sedimentary-metamorphosed/hydrothermal sedimentary Cu-Fe deposits. Dongchuan-Yimen type, Lanniping type and Dayao-Mouding type sedimentary-reworked copper deposits, which form the storeyed texture whose geochemistry of the trace elements, isotopes of S, Pb, H, O, C. ore-forming fluid and organic matter were regularly evolved with the crust evolution.
基金supported by National Natural Science Foundation of China(Grant Nos.4103031541072088)China Geological Survey(Grant No.1212011121105)
文摘The Neoproterozoic Kangdian Rift Basin is a continental rift basin in the western Yangtze Continent.Determining its time of opening and subsequent filling pattern is an important aspect of understanding the formation and evolution of the Yangtze Continent,South China.The Luliang Formation is the early filling in the eastern part of this rift basin,and its deposition age and filling sequence are significant for studies of the regional stratigraphic correlation,opening time,and filling pattern of this basin.Having been correlated to the upper part of the Mesoproterozoic Kunyang Group or to the Neoproterozoic Chengjiang Formation,the age and regional stratigraphic correlation of the Luliang Formation have long been uncertain.This is due to a lack of reliable absolute age constraints.To address this issue,the first zircon SHRIMP U-Pb geochronology has been established for this formation,yielding two high-precision isotopic ages of 818.6±9.2 and 805±14 Ma for the tuff layers at the bottoms of the lower and upper members of the Luliang Formation,respectively.Given the error factor,the bottom age of the lower member of the Luliang Formation can be interpreted as ca.820 Ma,corresponding to the bottom age of the lower part of the Banxi Group,which is the early filling of the Neoproterozoic Xianggui Rift Basin,a representative basin of the Neoproterozoic rift basins in the Yangtze Continent,South China.The bottom age of the upper member of the Luliang Formation can be interpreted as ca.800±5 Ma,corresponding to the bottom age of the Chengjiang Formation in the western part of the Neoproterozoic Kangdian Rift Basin and also corresponding to the bottom age of the upper part of the Banxi Group in the Neoproterozoic Xianggui Rift Basin.These ages indicate that the Neoproterozoic Kangdian Rift Basin shares the same opening time and filling sequences as those of the other Neoproterozoic rift basins in South China.Basin analysis shows that the Neoproterozoic Kangdian Rift Basin is a typical half-graben basin,with its main boundary fault in the west and basin center in the east.This basin consisted of mini unidirectional half-graben basins in its juvenile stage and simplified to become a large united half-graben basin in its mature stage,i.e.,a supradetachment basin.
文摘SITUATED on the eastern margin of Kangdian axis the lead-zinc mineral belt is an important mineral occur- rence of lead-zinc in southwestern China. It is 1 200 km in length from Kangding in Sichuan Province tonortheastern Yunnan Province, and 500 km in width from west to east. There are four large deposits,fourteen middle deposits and many small deposits or mineralized spots. Famous large deposits such as Doliangzi, Tianbaoshan, Chipu and Kuangshanchang are distributed in this belt. 1 Geological setting There are many mineral-bearing strata in carbonate-hosted lead-zinc deposits of this mineral belt,such as Dengying formation (Zbdn), Longwangmiao formation (<sub>2</sub> l) Erdaoshui formation ( <sub>3</sub> e ),Daqing formation(O<sub>2</sub> d ), Daguan formation (S<sub>2</sub>d ), the lower Devonian and Baizuo formation ( C<sub>1</sub> b).
文摘扬子地台寒武系下统存在富含V、Ni、Mo和铂族元素(platinum group element, PGE)等的黑色页岩,局部地区有U或者Ba、Hg、As等的富集,研究这些元素富集机理有利于寻找相关矿产或者探究地质事件。6 500万年前的小行星撞击地球产生了高PGE含量的地层或者化石,依据这一事实和陨石的特征及其他地质地球化学证据,推断下寒武统黑色页岩中Ni-Mo-PGE富集是陨石撞击结果,PGE中的Ir、Os富集最明显是因为二者最抗淋滤。U在康滇地轴东侧黑色页岩中最高可达480×10^(-6),因康滇地轴本身就存在混合型铀矿,推测黑色页岩中U来自它的风化。据V和Ba-Hg-As等的地化特性,认为V富集是受生物活动影响,但因V易于在热泉水中富集,故寒武纪早期泛非运动的构造-热事件可导致V富集成矿,Ba、Hg、As也因该事件产生构造裂隙后,它们优先随热液沿裂隙上升富集,并在海底局部成矿。此外,5.65亿年前的埃迪卡拉动物群发生地基本上就是5.8亿年前小行星撞击地点,提出此次行星撞击可能与埃迪卡拉生物群出现存在因果关系。由于在中国存在寒武纪澄江生物群大爆发事件,推测该次生物大爆发之前存在的下寒武统黑色页岩也存在陨石撞击痕迹。寒武系下统的含岩屑细砂岩夹黑色页岩甚至砾岩,反映了黑色页岩沉积时存在的突变沉积环境,加上其他地球化学特征也支持小行星撞击说。
基金supported by the NSFC Project(Grant Nos.42162012 and 42072094)the Open Research Project from the Key Laboratory of Sanjiang Metallogeny and Resources Exploration and Utilization,MNR(Grant No.ZRZYBSJSYS2022001)。
文摘The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism.