Morphological classification and three-dimensional pore structure reconstruction of shale oil reservoirs: A case from the second member of Paleogene Kongdian Formation in the Cangdong Sag, Bohai Bay Basin, East China

This study combines large volume three-dimensional reconstruction via focused ion beam scanning electron microscopy(FIB-SEM) with conventional scanning electron microscope(SEM) observation, automatic mineral identification and characterization system(AMICS) and large-area splicing of SEM images to characterize and classify the microscopic storage space distribution patterns and 3D pore structures of shales in the second member of the Paleogene Kongdian Formation(Kong 2) in the Cangdong Sag of the Bohai Bay Basin. It is shown that:(1) The Kong 2 Member can be divided into seven types according to the distribution patterns of reservoir spaces: felsic shale with intergranular micron pores, felsic shale with intergranular fissures, felsic shale with intergranular pores, hybrid shale with intergranular pores and fissures, hybrid shale with intergranular pores, clay-bearing dolomitic shale with intergranular pores, and clay-free dolomitic shale with intergranular pores.(2) The reservoir of the intergranular fracture type has better storage capacity than that of intergranular pore type. For reservoirs with storage space of intergranular pore type, the dolomitic shale reservoir has the best storage capacity, the hybrid shale comes second, followed by the felsic shale.(3) The felsic shale with intergranular fissures has the best storage capacity and percolation structure, making it the first target in shale oil exploration.(4) The large volume FIB-SEM 3D reconstruction method is able to characterize a large shale volume while maintaining relatively high spatial resolution, and has been demonstrated an effective method in characterizing the 3D storage space in strongly heterogeneous continental shales.

Magmatic hydrothermal fluid genesis of zeolite in the Paleogene Kongdian Formation of Zaoyuan oilfield,Bohai Bay Basin,China

Electronic probe,fluid inclusion homogenization temperature,Raman spectroscopy and laser ablation inductively coupled plasma mass spectrometry were utilized to identify the hydrothermal fluid-rock interactions in the second member of the Paleogene Kongdian Formation of Zaoyuan oilfield in Bohai Bay Basin(Kong 2 Member for short)of Well Z56 to find out the relationship between zeolite and hydrothermal fluid.The experimental results show that:(1)Pyrobitumen coexists with hydrothermal fluid characteristic minerals such as chlorite,barite,chalcopyrite,pyrite,natrolite and analcime in mudstone fractures.(2)The temperatures calculated from laser Raman spectrum of pyrobitumen,from the chlorite geothermometer and from measured homogenization temperature of natrolite inclusions are 324-354℃,124-166℃ and 89-196℃,respectively;although vary widely,all the temperatures are obviously higher than the normal geothermal temperature.(3)The positive Eu anomaly of chlorite and barite,and the similar distribution pattern in rare earth elements between natrolite and basalt indicate they are from magmatic hydrothermal fluid.Moreover,drilling data shows that the Kong 2 Member in Well Z56 has several sets of basalt interlayers,suggesting there was geologic base of magmatic hydrothermal fluid activity.The magmatic hydrothermal fluid-rock interaction may be one of the reasons for the abnormal enrichment of zeolite in Kong 2 Member of the Cangdong Sag.

Micropore structure characteristics and quantitative characterization methods of lacustrine shale-A case study from the member 2 of Kongdian Formation, Cangdong sag, Bohai Bay Basin

To better understand the micropore characteristics of lacustrine shale and develop quantitative methodsfor characterizing lacustrine shale, the reservoir space types, structures and spatial distribution patternsof effective pores in the shale of Member 2 of Kongdian Formation in Cangdong sag are studied usingcores, thin sections, scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM),nuclear magnetic resonance (NMR), whole-rock X-ray diffraction (XRD) data, etc. Various shale porositycalculation methods are evaluated. The study results show that the reservoir spaces of the shale mainlyinclude three types, i.e., matrix pores, organic pores and fractures. Flaky pore throats formed bydissolution-induced pores and mould pores can improve the pore connectivity. NMR effective porosity ofthe shale varies from 0.59% to 4.42% with an average of 2.38%, accounting for 49.54% of the total NMRporosity and 34.53% of the gas porosity. The shale is divided into the unimodal-type felsic shale, bimodaltype felsic shale, carbonate shale and mixed shale. The different lithologies exhibit linear correlationsamong NMR, gas and effective porosities. The shale has effective porosity of 0.56%-4.53% with an averageof 2.12%. Furthermore, the shale reservoir is divided into four classes: Class I reservoir with effectiveporosities of more than 2.5%;Class II1 reservoir with effective porosity of 2.0%-2.5%;Class II2 reservoirwith effective porosity of 1.5%-2%;and Class III reservoir with effective porosity of less than 1.5%.

Geological characteristics and key exploration technologies of continental shale oil sweet spots: A case study of Member 2 of Kongdian Formation in the Cangdong sag in the Huanghua depression, Bohai Bay Basin

Under the general trend of stepping-up oil and gas exploration and development in China,the unconventional oil and gas resources such as shale oil and gas have become an important alternative.Abundant continental shale oil resources are developed in Member 2 of Kongdian Formation(Ek2)of the Cangdong sag in the Huanghua depression of the Bohai Bay Basin which has complex structure,strong heterogeneity,and large buried depth,thus,the geological characteristic of shale oil accumulation and key exploration technologies are investigated on base of the system coring of 635.8 m,centimeter-level fine description and analysis of over ten thousand samples,therefore,the“four accurate”technologies have been developed,including the accurate selection of sweet spot areas,accurate drilling of sweet spot layers,accurate fracturing of sweet spot layers and accurate measure of fracture-rich sections.The results show that the continental shale strata in Member 2 of Kongdian Formation can be divided into three types:felsic shale,limy dolomitic shale and mixed shale.The Member 2 of Kongdian Formation is characterized by diverse mineral components,abundant laminae,good source rocks and medium thermal evolution degree,tight reservoir with rich micropore and microfractures,high oil saturation and brittle mineral content,indicating good prospect of shale oil exploration.Through sedimentological study,TOC and Ro evaluation,brittle mineral calculation,and seismic fusion inversion,a total of 126 km^(2) of Class I sweet spots in Member 2 of Kongdian Formation was delineated comprehensively,which guides horizontal well deployment(Well GD1701H and Well GD1702H).The drilling rate of sweet spot of these two horizontal wells is up to 96%by tracing thin layer through fine calibration,locating compartment through fine inversion,ensuring window entry through precise positioning,and tracking sweet spot through adjustment.The “one-excellent and five-highs”criterion is used to select perforation points to realize differential designs of fracturing intervals and clusters.Micro-seismic and potentiometry monitoring show that the artificial fractures formed by volumetric fracturing are 300e400 m long and 120 m high,and control a volume of about 0.07 km^(3).The maximum daily oil production of two horizontal wells is 48 t and 66 t respectively to realize the economic exploitation of shale oil reserves controlled by fractures.The shale oil exploration in Member 2 of Kongdian Formation shows that the continental shale oil has great potential of exploration and development,and the above technologies are critical and effective for shale oil efficient recovery.

Reclassification and distribution patterns of discovered oils in theDongying Depression, Bohai Bay Basin, China

The Dongying Depression is an important petrolifeous province,with diverse source rocks and complex petroleum distribution patterns.A total of 32 crude oils were analyzed by the gas chromatographyemass spectrometry and isotopic compositions to better understanding the petroleum systems in the study area.Three oil types were classified by hierarchical cluster analyses.Type I and II oils have closely correlation with the discovered source rocks,which have been confirmed to be mainly derived from the lower third and upper forth member of the Eocene Shahejie Formation source rocks(Es3^(L) and Es4^(U)),respectively.Obviously,type III oils contain abundant gammacerane,tricyclic terpanes and C_(29) steranes and have lower values of δ13C than type I and II oils,indicating a completely different source rock and biological origins.Until recently,type III oils fail to match any of the discovered source rock,which contains main contribution of aquatic organism or/and bacteria inputs.In addition,the spacial distribution of these three oil types were discussed.Type I oils mainly distributed in the Es3 and Es4 reservoirs that closed to the generative kitchens.Type II oils occurred in the Es4 reservoirs in the sourthern slope of the depression,which probably caused by lateral migration along the horizontal fractures and sandstone layers within the Es4 interval.Differently,type III oils in the sourthern slope of the depression were mainly discovered in the Eocene Kongdian or Ordocician reservoirs,which suggests great exploration potential of deep underlying strata.