液芯光纤光度法在乙醇水溶液中测定铂(Ⅱ)、钛(Ⅳ)

采用氟塑料长光纤管，以４２％乙醇水溶液作液芯，组成液芯光纤，基于铂与氯化亚锡、钛与过氧化氢形成黄色络合物在乙醇水溶液中很稳定，拟定了测定铂、钛的液芯光纤光度法。该法灵敏度高，用 １ｍ长光纤作吸收池，铂的灵敏度为 ４． ８４５ Ａ／ｍｇ· Ｌ－１，钛的灵敏度为１．４１Ａ／ｍｇ· Ｌ－１（Ａ为吸光度），与常规法（１ｃｍ）比色皿相比灵敏度提高了 １００倍。该法测定了催化剂中铂，煤灰粉中钛，结果与推荐值相符。

Influence of amplified spontaneous emission and fluorescence of β-carotene on stimulated Raman scattering of carbon disulfide

β-carotene with double fluorescence characteristics and large third-order optical nonlinearities,which is dissolved in the carbon disulfide(CS2) as the core medium of a liquid core optical fiber(LCOF),is applied in the study of the CS2 stimulated Raman scattering(SRS). The results of this study show that when the concentrations of solution are more than 3.72×10-7 mol/L,the amplified spontaneous emis-sion(ASE) of β-carotene is the main factor influencing the threshold and intensity of Stokes lines; when the concentrations of solution are lower than 3.72×10-7 mol/L,the ASE disappears and the fluorescence plays the key role:The high-order Stokes lines may be observed at very low input-laser power,and the Stokes thresholds decrease as the solution concentration increases. The result may be widely used in the study of broadband stimulated radiation laser and seeding laser.

外部荧光种子植入法增强液芯光纤中CS_2的受激拉曼散射研究

本文报道了运用外部荧光种子(罗丹明6G乙醇溶液)植入法对液芯光纤中CS2受激拉曼散射的增强研究。实验结果表明,CS2的二阶、三阶Stokes波分别获得了1.92和11.71倍的增益。并对外部荧光种子植入法增强液芯光纤中受激拉曼散射的机制进行了分析。