As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring sys...As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring system.In order to solve the problem of wavelength redundancy in full spectrum partial least squares(PLS)modeling for VOCs concentration analysis,a new method based on improved interval PLS(iPLS)integrated with Monte-Carlo sampling,called iPLS-MC method,was proposed to select optimal characteristic wavelengths of VOCs spectra.This method uses iPLS modeling to preselect the characteristic wavebands of the spectra and generates random wavelength combinations from the selected wavebands by Monte-Carlo sampling.The wavelength combination with the best prediction result in regression model is selected as the characteristic wavelengths of the spectrum.Different wavelength selection methods were built,respectively,on Fourier transform infrared(FTIR)spectra of ethylene and ethanol gas at different concentrations obtained in the laboratory.When the interval number of iPLS model is set to 30 and the Monte-Carlo sampling runs 1000 times,the characteristic wavelengths selected by iPLS-MC method can reduce from 8916 to 10,which occupies only 0.22%of the full spectrum wavelengths.While the RMSECV and correlation coefficient(Rc)for ethylene are 0.2977 and 0.9999 ppm,and those for ethanol gas are 0.2977 ppm and 0.9999.The experimental results show that the iPLS-MC method can select the optimal characteristic wavelengths of VOCs FTIR spectra stably and effectively,and the prediction performance of the regression model can be significantly improved and simplified by using characteristic wavelengths.展开更多
To implement the prediction of the logistics demand capacity of a certain region,a comprehensive index system is constructed,which is composed of freight volume and other eight relevant economic indices,such as gross ...To implement the prediction of the logistics demand capacity of a certain region,a comprehensive index system is constructed,which is composed of freight volume and other eight relevant economic indices,such as gross domestic product(GDP),consumer price index(CPI),total import and export volume,port's cargo throughput,total retail sales of consumer goods,total fixed asset investment,highway mileage,and resident population,to form the foundation for the model calculation.Based on the least square method(LSM)to fit the parameters,the study obtains an accurate mathematical model and predicts the changes of each index in the next five years.Using artificial intelligence software,the research establishes the logistics demand model of multi-layer perceptron(MLP)neural network,makes an empirical analysis on the logistics demand of Quanzhou City,and predicts its logistics demand in the next five years,which provides some references for formulating logistics planning and development strategy.展开更多
基金supported by National Key Scientific Instrument and Equipment Development Project of China,Grant Nos.2013YQ220643the National 863 Program of China,Grant Nos.2014AA06A503.
文摘As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring system.In order to solve the problem of wavelength redundancy in full spectrum partial least squares(PLS)modeling for VOCs concentration analysis,a new method based on improved interval PLS(iPLS)integrated with Monte-Carlo sampling,called iPLS-MC method,was proposed to select optimal characteristic wavelengths of VOCs spectra.This method uses iPLS modeling to preselect the characteristic wavebands of the spectra and generates random wavelength combinations from the selected wavebands by Monte-Carlo sampling.The wavelength combination with the best prediction result in regression model is selected as the characteristic wavelengths of the spectrum.Different wavelength selection methods were built,respectively,on Fourier transform infrared(FTIR)spectra of ethylene and ethanol gas at different concentrations obtained in the laboratory.When the interval number of iPLS model is set to 30 and the Monte-Carlo sampling runs 1000 times,the characteristic wavelengths selected by iPLS-MC method can reduce from 8916 to 10,which occupies only 0.22%of the full spectrum wavelengths.While the RMSECV and correlation coefficient(Rc)for ethylene are 0.2977 and 0.9999 ppm,and those for ethanol gas are 0.2977 ppm and 0.9999.The experimental results show that the iPLS-MC method can select the optimal characteristic wavelengths of VOCs FTIR spectra stably and effectively,and the prediction performance of the regression model can be significantly improved and simplified by using characteristic wavelengths.
基金Educational Research Project of Social Science for Young and Middle Aged Teachers in Fujian Province,China(No.JAS19371)Social Science Research Project of Education Department of Fujian Province,China(No.JAS160571)Key Project of Education and Teaching Reform of Undergraduate Universities in Fujian Province,China(No.FBJG20190130)。
文摘To implement the prediction of the logistics demand capacity of a certain region,a comprehensive index system is constructed,which is composed of freight volume and other eight relevant economic indices,such as gross domestic product(GDP),consumer price index(CPI),total import and export volume,port's cargo throughput,total retail sales of consumer goods,total fixed asset investment,highway mileage,and resident population,to form the foundation for the model calculation.Based on the least square method(LSM)to fit the parameters,the study obtains an accurate mathematical model and predicts the changes of each index in the next five years.Using artificial intelligence software,the research establishes the logistics demand model of multi-layer perceptron(MLP)neural network,makes an empirical analysis on the logistics demand of Quanzhou City,and predicts its logistics demand in the next five years,which provides some references for formulating logistics planning and development strategy.
