A series of seven novel lanthanide（Ⅲ ） nitrato complexes with 4-[ N-（2-methoxybenzylimine）formyl] 1-2, 3- dimethyl-1-phenyl-3-pyazolin-5-one （2mbfa）, were synthesized. These complexes were characterized by elem...A series of seven novel lanthanide（Ⅲ ） nitrato complexes with 4-[ N-（2-methoxybenzylimine）formyl] 1-2, 3- dimethyl-1-phenyl-3-pyazolin-5-one （2mbfa）, were synthesized. These complexes were characterized by elemental analysis, molecular mass determination, conductance and magnetic moment measurements, IR, UV-visible, and ^13CNMR spectral studies, In these complexes, the Schiff base, 2mbfa, acts as neutral bidentate ligand by utilizing the carbonyl oxygen and azomethine nitrogen as donor sites. All the three nitrate ions are also coordinated unidentately with 7 coordination for the lanthanide（Ⅲ） ions with a tentative monocapped octahedral geometry for the complexes. All the seven lanthanide（Ⅲ） complexes have a general formula, [ Ln（2mbfa）：（NO3）3 ].展开更多
A bishydrazone formed by the condensation of isatinmonohydrazone and salicylaldehyde reacted with lanthanide（Ⅲ） chloride to form complexes of the type [Ln（HISA）2Cl3], where, Ln=La（Ⅲ）, Ce（Ⅲ）, Pr（Ⅲ）, Nd（...A bishydrazone formed by the condensation of isatinmonohydrazone and salicylaldehyde reacted with lanthanide（Ⅲ） chloride to form complexes of the type [Ln（HISA）2Cl3], where, Ln=La（Ⅲ）, Ce（Ⅲ）, Pr（Ⅲ）, Nd（Ⅲ）, Sm（Ⅲ）, Eu（Ⅲ）, or Gd（Ⅲ） and HISA= [（2-hydroxybenzaldehyde）-3-isatin]bishydrazone. Both reactions were carried out under microwave conditions. The ligand and the metal complexes were characterized on the basis of elemental analysis, molar conductance, magnetic susceptibility measurements, UV visible, infrared, far infrared, and proton NMR spectral data. The ligand acted as neutral tridentate, coordinating through the carbonyl oxygen, azomethine nitrogen, and phenolic oxygen without deprotonation. The ligand and lanthanum（Ⅲ） complex were subjected to X-ray diffraction studies. The X-ray diffraction pattern of ligand exhibited its crystalline nature and that of the lanthanum（Ⅲ） complex indicated its amorphous character. The thermal decomposition behaviour of the complex, [La（HISA）2Cl3], was examined in the temperature range of 40-800 ℃ using TG, DTG, and DTA. The ligand and the metal complexes were screened for their antifungal activities.展开更多
A new unsymmetrical solid Schiff base (LLi) was synthesized using L-lysine, o-vanillin and 2-hydroxy-l-naphthaldehyde. Solid La(Ⅲ) complex of this ligand [LaL(NO3)](NO3)·2H2O was prepared and characterized by el...A new unsymmetrical solid Schiff base (LLi) was synthesized using L-lysine, o-vanillin and 2-hydroxy-l-naphthaldehyde. Solid La(Ⅲ) complex of this ligand [LaL(NO3)](NO3)·2H2O was prepared and characterized by elemental analyses, IR, UV and molar conductance. The thermal decomposition kinetics of the complex for the second stage were studied under non-isothermal condition by TG and DTG methods. The kinetic equation may be expressed as: dα/dt=A·e-E/RT·(1-α)2. The kinetic parameters(E, A), activation entropy S≠ and activation free-energy G≠ were also gained.展开更多
A new La（Ⅲ） complex, {[La（L）（NO3）（H2O）3]·H2O}n （L = 1,10-phenanthroline- 2,9-dicarboxylate）, has been synthesized and structurally determined by X-ray diffraction analysis. The complex crystallizes in ...A new La（Ⅲ） complex, {[La（L）（NO3）（H2O）3]·H2O}n （L = 1,10-phenanthroline- 2,9-dicarboxylate）, has been synthesized and structurally determined by X-ray diffraction analysis. The complex crystallizes in the monoclinic system, space group P21/c with a = 7.7358（17）, b = 8.1664（18）, c = 28.271（6） A, β= 95.184（4）°, V= 1778.6（7） A3, Z = 4, C14H14LaN3O11, Mr = 539.19, Dc = 2.014 g/cm^3, μ= 2.471 mm^-1, F（000） = 1056, the final R = 0.0350 and wR = 0.0659. In this complex, each metal center adopts a ten-coordination geometry formed by two N atoms from a ligand L and eight O atoms from three H2O molecules, a nitrate ion and carboxylates of two ligands. Each ligand adopts a N2,O3-pentdentate coordination mode using two N and two O atoms chelating a La（Ⅲ）, and using another O atom of carboxylate to bridge another La（Ⅲ） center resulting in a 1D helical chain molecule. Intermolecular strong O-H…O and weak C-H…O hydrogen bonds extend the 1D chain structure into a 3D supramolecular architecture.展开更多
A new unsymmetrical Schiff base ligand (H2LLi) was synthesized using L-lysine, salicylaldehyde and 2-hydroxy-1-naphthaldehyde. Three solid metal complexes of this ligand \[Ln(H2L)(NO3)\] NO3·2H2O (Ln=La, ...A new unsymmetrical Schiff base ligand (H2LLi) was synthesized using L-lysine, salicylaldehyde and 2-hydroxy-1-naphthaldehyde. Three solid metal complexes of this ligand \[Ln(H2L)(NO3)\] NO3·2H2O (Ln=La, Sm, Ho) have been prepared and characterized by elemental analyses, IR spectra, UV spectra, TG-DTG and molar conductance. The antibacterial activities of the ligand and its complexes are also studied. The antibacterial experiments indicate that the ligand and its complexes possess antibacterial activity against Escherichia coli, Staphylococcus aureus and Bacillus subtilis and that the complexes have higher activity than those of the ligand.展开更多
Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and...Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and characterized by infrared spectrometry, 1H nuclear magnetic resonance, elemental analysis and gas chromatograph-mass spectrometry. The ligand synthetic route was optimized. The fluorescence properties of the complex in solid state, in different kind of solvents and in solutions with different pH values were investigated in detail. The results show that the yields of DSPDA and 4-SPDA reach over 78% by Wittig-Horner reaction and other eight pyridine-2, 6-dicarboxylic acid derivatives with different substituents on pyridine ring, and their complexes with Tb(Ⅲ) are also obtained. The fluorescence intensities of the complexes with electron-donating groups are more intense than those of the complexes with electron-withdrawing groups on pyridine ring; fluorescence intensities of the complexes are the strongest in neutral solution (pH=7), and the less the dipole moment of solvent molecule is, the stronger the fluorescence intensity is. It is found that the two ligands (4-APDA and DSPDA) are the good sensitizers for Tb(Ⅲ) ion.展开更多
Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydr...Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydrothermally synthesized by altering the metal/carboxylate ratios or in the presence of an additional chelate 2,2′ bpy ligand, and characterized by single crystal X ray diffraction. The results show that different metal/carboxylate ratios can influence the polymeric structures and the presence of 2,2′ bpy ligand alters the topology of the framework from two dimensional to three dimensional.展开更多
A rapid synthesis of size-controlled gold nanoparticles was proposed.The method is based on the sensitive intramolecular photoreduction reaction of Fe（Ⅲ）-EDTA complex in chloroacetic acid-sodium acetate buffer solu...A rapid synthesis of size-controlled gold nanoparticles was proposed.The method is based on the sensitive intramolecular photoreduction reaction of Fe（Ⅲ）-EDTA complex in chloroacetic acid-sodium acetate buffer solution,where Fe（Ⅱ）-EDTA complex generated by photo-promotion acts as a reductant of AuCl-4 ions.Gold nanoparticles formed were stabilized by EDTA ligand or other protective agents added.As a result,well-dispersed gold nanoparticles with an average diameter range of 6.7 to 50.9 nm were obtained.According to the characterizations by the UV spectrum and TEM,the intramolecular charge transfer of the excited states of complex Fe（Ⅲ）-EDTA and the mechanism of forming gold nanoparticles were discussed in detail.展开更多
A novel lanthanide-organic framework compound [La（seb）（Hseb）（H2O）]n （H2seb = sebacic acid） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, TG and single-cr...A novel lanthanide-organic framework compound [La（seb）（Hseb）（H2O）]n （H2seb = sebacic acid） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, TG and single-crystal X-ray diffraction. Complex 1 crystallizes in the triclinic system, space group P with a = 8.5849（7）, b = 9.0641（8）, c = 15.4049（13）, α = 98.1830（10）, β = 100.6870（10）, γ= 97.5650（10）°, Z = 2, V = 1150.44（17） 3, Dc = 1.612 g/cm3, Mr = 558.39, λ（MoKα） = 0.71073 , μ = 1.903 mm-1, F（000） = 568, R = 0.0219 and wR = 0.0507 for 3797 observed reflections with I 2σ（I）. The structure contains edge-shared chains of [LaO8（H2O）] tricapped trigonal prisms that propagate along the b axis. In aliphatic ligand participation, complex 1 exhibits a three-dimensional supramolecular framework. Moreover, the thermal stability of complex 1 has been investigated.展开更多
The structure of complexes Dy[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 and La[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 was studied by single crystal X ray diffraction. The two compounds are isostructural and all form...The structure of complexes Dy[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 and La[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 was studied by single crystal X ray diffraction. The two compounds are isostructural and all form monoclinic crystal with space group P 2 1/ c . The crystal data Dy: a =1 8564(3)[1 8857(2)] nm, b =0 9769(2) [0 9834(1)] nm, c =2 1863(6)[2 2008(7)] nm, β =96 08(2)[95 72(2)]°, V =3 942(1)[4 061(1)] nm 3, Z =4. Dy 3+ [La 3+ ] is coordinated through three carbonyls of the three organic ligands and the three nitrates are all bidentate. So each Dy 3+ [La 3+ ] is coordinated by nine oxygen atoms which form a distorted tricapped trigonal prism.展开更多
A new three-dimensional coordination polymer [Ce_2(C_4H_4O_4)_3(H_2O)_2]_n·3.2 nH_2 O, constructed by Ce(Ⅲ) ion and succinate ion and lattice water molecules has been synthesized under hydrothermal conditions. I...A new three-dimensional coordination polymer [Ce_2(C_4H_4O_4)_3(H_2O)_2]_n·3.2 nH_2 O, constructed by Ce(Ⅲ) ion and succinate ion and lattice water molecules has been synthesized under hydrothermal conditions. It crystallizes in triclinic system, space group P1 with a = 7.8865(6), b = 12.0260(8), c = 12.2598(9) ?, α = 112.456(2)o, β = 90.046(2)o, γ = 100.423(2)o, Mr = 722.14, V = 1053.73(13) ?~3, Z = 2, Dc = 2.276 g/cm^3, μ = 4.35/mm, F(000) = 696, GOF = 1.029, R = 0.0203 and w R = 0.0570. The asymmetric unit contains two Ce^(3+) cations and both of them are nine-coordinated and their coordination geometries can be described as two distorted monocapped square antiprisms. In the title compound, a three-dimensional coordination network with one-dimensional hexagon honeycomb-like channels along the a axis is generated. TG measurement has been carried out, and its result analysis along with the powder XRD determination indicates the residue to be CeO_2.展开更多
Seven new lanthanide（Ⅲ） complexes with 4-hydroxyantipyrine were synthesized. These complexes were characterized by elemental analysis, molar conductance, magnetic moment measurements, FT-IR, electronic and 1HNMR sp...Seven new lanthanide（Ⅲ） complexes with 4-hydroxyantipyrine were synthesized. These complexes were characterized by elemental analysis, molar conductance, magnetic moment measurements, FT-IR, electronic and 1HNMR spectra, X-ray powder diffraction, and thermogravimetric studies. The ligand, 4-hydroxyantipyrine （hap）, contained carbonyl oxygen and hydroxyl oxygen as potential donor sites. On coordination, deprotonation occurred and as a result, hap acted as a monobasic bidentate ligand. A coordination number 6 was assigned to the lanthanide（Ⅲ） ions in these complexes with orthorhombic structure. All the complexes were thermally stable-150℃ and underwent decomposition in three stages with the formation of Ln2O3 as the final residues.展开更多
A new Bismuth(Ⅲ)-Lanthanum(Ⅲ) heterobimetallic polymer complex,{[(H2O)5La(μ4-edta)Bi(NO3)2]·3H2O}n(edta=diaminetetraacecarboxylate),has been hydrothermally synthesized and characterized by elemental analysis,F...A new Bismuth(Ⅲ)-Lanthanum(Ⅲ) heterobimetallic polymer complex,{[(H2O)5La(μ4-edta)Bi(NO3)2]·3H2O}n(edta=diaminetetraacecarboxylate),has been hydrothermally synthesized and characterized by elemental analysis,FT-IR,and X-ray diffraction single crystal structure analysis.It crystallizes in the monoclinic system,with space group P2(1)/n,a=1.27395(5)nm,b=0.82608(4) nm,c=2.38819(11) nm,β=104.9000(10)°,V=2.42879(19) nm3,Z=4,Dc=2.438 g·cm-3,μ=9.077mm-1,F(000)=1678,R1=0.0343,wR2=0.0906.In this complex,Bi atom is coordinated by four carboxyl O atoms from a single edta4-anion.La atom is bonded to four O atoms from four bridging carboxyl O atoms belonging to four different edta4-anions and five O atoms from five H2O molecules.Bi atoms and La atoms are linked by bridged edta4-anions,resulting into a novel infinite 3D network structure.TG-DSC and IR indicate that thermal decomposition proceeds in several stages,dehydration,pyrolysis of ligand,and finally decomposition of salt,and the residue is composite oxide based on δ-Bi2O3 at the temperature of 600℃.展开更多
基金Ph.D. Programme at the Department of Chemistry, University of Kerala, India
文摘A series of seven novel lanthanide（Ⅲ ） nitrato complexes with 4-[ N-（2-methoxybenzylimine）formyl] 1-2, 3- dimethyl-1-phenyl-3-pyazolin-5-one （2mbfa）, were synthesized. These complexes were characterized by elemental analysis, molecular mass determination, conductance and magnetic moment measurements, IR, UV-visible, and ^13CNMR spectral studies, In these complexes, the Schiff base, 2mbfa, acts as neutral bidentate ligand by utilizing the carbonyl oxygen and azomethine nitrogen as donor sites. All the three nitrate ions are also coordinated unidentately with 7 coordination for the lanthanide（Ⅲ） ions with a tentative monocapped octahedral geometry for the complexes. All the seven lanthanide（Ⅲ） complexes have a general formula, [ Ln（2mbfa）：（NO3）3 ].
文摘A bishydrazone formed by the condensation of isatinmonohydrazone and salicylaldehyde reacted with lanthanide（Ⅲ） chloride to form complexes of the type [Ln（HISA）2Cl3], where, Ln=La（Ⅲ）, Ce（Ⅲ）, Pr（Ⅲ）, Nd（Ⅲ）, Sm（Ⅲ）, Eu（Ⅲ）, or Gd（Ⅲ） and HISA= [（2-hydroxybenzaldehyde）-3-isatin]bishydrazone. Both reactions were carried out under microwave conditions. The ligand and the metal complexes were characterized on the basis of elemental analysis, molar conductance, magnetic susceptibility measurements, UV visible, infrared, far infrared, and proton NMR spectral data. The ligand acted as neutral tridentate, coordinating through the carbonyl oxygen, azomethine nitrogen, and phenolic oxygen without deprotonation. The ligand and lanthanum（Ⅲ） complex were subjected to X-ray diffraction studies. The X-ray diffraction pattern of ligand exhibited its crystalline nature and that of the lanthanum（Ⅲ） complex indicated its amorphous character. The thermal decomposition behaviour of the complex, [La（HISA）2Cl3], was examined in the temperature range of 40-800 ℃ using TG, DTG, and DTA. The ligand and the metal complexes were screened for their antifungal activities.
文摘A new unsymmetrical solid Schiff base (LLi) was synthesized using L-lysine, o-vanillin and 2-hydroxy-l-naphthaldehyde. Solid La(Ⅲ) complex of this ligand [LaL(NO3)](NO3)·2H2O was prepared and characterized by elemental analyses, IR, UV and molar conductance. The thermal decomposition kinetics of the complex for the second stage were studied under non-isothermal condition by TG and DTG methods. The kinetic equation may be expressed as: dα/dt=A·e-E/RT·(1-α)2. The kinetic parameters(E, A), activation entropy S≠ and activation free-energy G≠ were also gained.
基金Supported by the Funding Project for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality
文摘A new La（Ⅲ） complex, {[La（L）（NO3）（H2O）3]·H2O}n （L = 1,10-phenanthroline- 2,9-dicarboxylate）, has been synthesized and structurally determined by X-ray diffraction analysis. The complex crystallizes in the monoclinic system, space group P21/c with a = 7.7358（17）, b = 8.1664（18）, c = 28.271（6） A, β= 95.184（4）°, V= 1778.6（7） A3, Z = 4, C14H14LaN3O11, Mr = 539.19, Dc = 2.014 g/cm^3, μ= 2.471 mm^-1, F（000） = 1056, the final R = 0.0350 and wR = 0.0659. In this complex, each metal center adopts a ten-coordination geometry formed by two N atoms from a ligand L and eight O atoms from three H2O molecules, a nitrate ion and carboxylates of two ligands. Each ligand adopts a N2,O3-pentdentate coordination mode using two N and two O atoms chelating a La（Ⅲ）, and using another O atom of carboxylate to bridge another La（Ⅲ） center resulting in a 1D helical chain molecule. Intermolecular strong O-H…O and weak C-H…O hydrogen bonds extend the 1D chain structure into a 3D supramolecular architecture.
文摘A new unsymmetrical Schiff base ligand (H2LLi) was synthesized using L-lysine, salicylaldehyde and 2-hydroxy-1-naphthaldehyde. Three solid metal complexes of this ligand \[Ln(H2L)(NO3)\] NO3·2H2O (Ln=La, Sm, Ho) have been prepared and characterized by elemental analyses, IR spectra, UV spectra, TG-DTG and molar conductance. The antibacterial activities of the ligand and its complexes are also studied. The antibacterial experiments indicate that the ligand and its complexes possess antibacterial activity against Escherichia coli, Staphylococcus aureus and Bacillus subtilis and that the complexes have higher activity than those of the ligand.
基金Project(20761002) supported by the National Natural Science Foundation of China
文摘Two novel ligands named 4-styrylpyridine-2,6-dicarboxylic acid (4-SPDA) and 4-(4-(2-(2, 6-dicarboxypyridin-4-yl)- vinyl)styryl)pyridine-2,6-dicarboxylic acid(DSPDA) and their complexes with Tb(Ⅲ) were synthesized and characterized by infrared spectrometry, 1H nuclear magnetic resonance, elemental analysis and gas chromatograph-mass spectrometry. The ligand synthetic route was optimized. The fluorescence properties of the complex in solid state, in different kind of solvents and in solutions with different pH values were investigated in detail. The results show that the yields of DSPDA and 4-SPDA reach over 78% by Wittig-Horner reaction and other eight pyridine-2, 6-dicarboxylic acid derivatives with different substituents on pyridine ring, and their complexes with Tb(Ⅲ) are also obtained. The fluorescence intensities of the complexes with electron-donating groups are more intense than those of the complexes with electron-withdrawing groups on pyridine ring; fluorescence intensities of the complexes are the strongest in neutral solution (pH=7), and the less the dipole moment of solvent molecule is, the stronger the fluorescence intensity is. It is found that the two ligands (4-APDA and DSPDA) are the good sensitizers for Tb(Ⅲ) ion.
文摘Three polymeric erbium(Ⅲ) complexes [Er(oba)(Hoba)(H 2O) 2]H 2O (A),[Er 2(oba) 3(H 2O) 4] (B), [Er 2(oba) 3(2,2′ bpy) 2] (C) (H 2oba=4,4′ oxybis(benzoic acid), 2,2′ bpy = 2,2′ bipyridine) were hydrothermally synthesized by altering the metal/carboxylate ratios or in the presence of an additional chelate 2,2′ bpy ligand, and characterized by single crystal X ray diffraction. The results show that different metal/carboxylate ratios can influence the polymeric structures and the presence of 2,2′ bpy ligand alters the topology of the framework from two dimensional to three dimensional.
基金Supported by the Natural Science Foundation of Yunnan Province,China(No.2000E0008Z).
文摘A rapid synthesis of size-controlled gold nanoparticles was proposed.The method is based on the sensitive intramolecular photoreduction reaction of Fe（Ⅲ）-EDTA complex in chloroacetic acid-sodium acetate buffer solution,where Fe（Ⅱ）-EDTA complex generated by photo-promotion acts as a reductant of AuCl-4 ions.Gold nanoparticles formed were stabilized by EDTA ligand or other protective agents added.As a result,well-dispersed gold nanoparticles with an average diameter range of 6.7 to 50.9 nm were obtained.According to the characterizations by the UV spectrum and TEM,the intramolecular charge transfer of the excited states of complex Fe（Ⅲ）-EDTA and the mechanism of forming gold nanoparticles were discussed in detail.
基金supported by Science and Technology Planning Project of Henan Province(No.2009A150011)
文摘A novel lanthanide-organic framework compound [La（seb）（Hseb）（H2O）]n （H2seb = sebacic acid） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, TG and single-crystal X-ray diffraction. Complex 1 crystallizes in the triclinic system, space group P with a = 8.5849（7）, b = 9.0641（8）, c = 15.4049（13）, α = 98.1830（10）, β = 100.6870（10）, γ= 97.5650（10）°, Z = 2, V = 1150.44（17） 3, Dc = 1.612 g/cm3, Mr = 558.39, λ（MoKα） = 0.71073 , μ = 1.903 mm-1, F（000） = 568, R = 0.0219 and wR = 0.0507 for 3797 observed reflections with I 2σ（I）. The structure contains edge-shared chains of [LaO8（H2O）] tricapped trigonal prisms that propagate along the b axis. In aliphatic ligand participation, complex 1 exhibits a three-dimensional supramolecular framework. Moreover, the thermal stability of complex 1 has been investigated.
文摘The structure of complexes Dy[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 and La[CH 2(CH 2) 4CONC 4H 9] 3(NO 3) 3 was studied by single crystal X ray diffraction. The two compounds are isostructural and all form monoclinic crystal with space group P 2 1/ c . The crystal data Dy: a =1 8564(3)[1 8857(2)] nm, b =0 9769(2) [0 9834(1)] nm, c =2 1863(6)[2 2008(7)] nm, β =96 08(2)[95 72(2)]°, V =3 942(1)[4 061(1)] nm 3, Z =4. Dy 3+ [La 3+ ] is coordinated through three carbonyls of the three organic ligands and the three nitrates are all bidentate. So each Dy 3+ [La 3+ ] is coordinated by nine oxygen atoms which form a distorted tricapped trigonal prism.
基金financially supported by the National Natural Science Foundation of China(51872109)the Natural Science Foundation of Jiangsu Provincial Department of Education(Nos.15KJA150003,17KJA150002,14KJA150003)
文摘A new three-dimensional coordination polymer [Ce_2(C_4H_4O_4)_3(H_2O)_2]_n·3.2 nH_2 O, constructed by Ce(Ⅲ) ion and succinate ion and lattice water molecules has been synthesized under hydrothermal conditions. It crystallizes in triclinic system, space group P1 with a = 7.8865(6), b = 12.0260(8), c = 12.2598(9) ?, α = 112.456(2)o, β = 90.046(2)o, γ = 100.423(2)o, Mr = 722.14, V = 1053.73(13) ?~3, Z = 2, Dc = 2.276 g/cm^3, μ = 4.35/mm, F(000) = 696, GOF = 1.029, R = 0.0203 and w R = 0.0570. The asymmetric unit contains two Ce^(3+) cations and both of them are nine-coordinated and their coordination geometries can be described as two distorted monocapped square antiprisms. In the title compound, a three-dimensional coordination network with one-dimensional hexagon honeycomb-like channels along the a axis is generated. TG measurement has been carried out, and its result analysis along with the powder XRD determination indicates the residue to be CeO_2.
基金Project supported by Ph.D. programme at the Department of Chemistry, University of Kerala, Kariavattom Campus, Trivandrum-695 581 Kerala, India
文摘Seven new lanthanide（Ⅲ） complexes with 4-hydroxyantipyrine were synthesized. These complexes were characterized by elemental analysis, molar conductance, magnetic moment measurements, FT-IR, electronic and 1HNMR spectra, X-ray powder diffraction, and thermogravimetric studies. The ligand, 4-hydroxyantipyrine （hap）, contained carbonyl oxygen and hydroxyl oxygen as potential donor sites. On coordination, deprotonation occurred and as a result, hap acted as a monobasic bidentate ligand. A coordination number 6 was assigned to the lanthanide（Ⅲ） ions in these complexes with orthorhombic structure. All the complexes were thermally stable-150℃ and underwent decomposition in three stages with the formation of Ln2O3 as the final residues.
文摘A new Bismuth(Ⅲ)-Lanthanum(Ⅲ) heterobimetallic polymer complex,{[(H2O)5La(μ4-edta)Bi(NO3)2]·3H2O}n(edta=diaminetetraacecarboxylate),has been hydrothermally synthesized and characterized by elemental analysis,FT-IR,and X-ray diffraction single crystal structure analysis.It crystallizes in the monoclinic system,with space group P2(1)/n,a=1.27395(5)nm,b=0.82608(4) nm,c=2.38819(11) nm,β=104.9000(10)°,V=2.42879(19) nm3,Z=4,Dc=2.438 g·cm-3,μ=9.077mm-1,F(000)=1678,R1=0.0343,wR2=0.0906.In this complex,Bi atom is coordinated by four carboxyl O atoms from a single edta4-anion.La atom is bonded to four O atoms from four bridging carboxyl O atoms belonging to four different edta4-anions and five O atoms from five H2O molecules.Bi atoms and La atoms are linked by bridged edta4-anions,resulting into a novel infinite 3D network structure.TG-DSC and IR indicate that thermal decomposition proceeds in several stages,dehydration,pyrolysis of ligand,and finally decomposition of salt,and the residue is composite oxide based on δ-Bi2O3 at the temperature of 600℃.
